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Atomic WS 2

The document contains 19 multiple choice questions about atomic structure and quantum numbers. It covers topics like identifying the quantum numbers of an electron in an orbital diagram, electron configuration, Hund's rule, subshell filling order, Pauli exclusion principle, and degenerate orbitals. The questions test understanding of key concepts in atomic structure including the four quantum numbers and their significance.

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Mayank Bansal
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67 views3 pages

Atomic WS 2

The document contains 19 multiple choice questions about atomic structure and quantum numbers. It covers topics like identifying the quantum numbers of an electron in an orbital diagram, electron configuration, Hund's rule, subshell filling order, Pauli exclusion principle, and degenerate orbitals. The questions test understanding of key concepts in atomic structure including the four quantum numbers and their significance.

Uploaded by

Mayank Bansal
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Atomic Structure

Q.1 What is a possible set of quantum numbers for the unpaired electron in the orbital box diagram below ?

(A) n = 1,  = 1, m = –1, ms = +1/2 (B) n = 4,  = 1, m = –1, ms = +1/2


(C) n = 4,  = 2, m = –2, ms = +1/2 (D) n = 4,  = 0, m = 0, ms = +1/2

Q.2 Which element has the following ground state electron configuration ?

(A) Se (B) As (C) S (D) Ge

Q.3 Hund’s rule states that the most stable arrangement of electrons (for a ground state electron configuration)
(A) has three electrons per orbital, each with identical spins
(B) has m values greater than or equal to +1
(C) has the maximum number of unpaired electrons, all with the same spin
(D) has two electrons per orbital, each with opposing spins

Q.4 Which of the following statements regarding subshell filling order for a neutral atom is/are correct ?
(I) Electrons are assigned to the 4s subshell before they are assigned to the 3d subshell
(II) Electrons are assigned to the 4f subshell before they are assigned to the 6s subshell
(III) Electrons are assigned to the 4d subshell before they are assigned to the 5p subshell
(A) I only (B) II only (C) I and III (D) I, II and III

Q.5 How many electrons can be described by the quantum numbers n = 5,  = 2 in a particular atom?
(A) 2 (B) 6 (C) 10 (D) 14

Q.6 The total number of electrons in Cr atom for which m = 0


(A) 1 (B) 8 (C) 12 (D) 16

Q.7 The Pauli exclusion principle states that


(A) no two electrons in an atom can have the same four quantum numbers
(B) electrons can have either ±1/2 spins
(C) electrons with opposing spins are attracted to each other
(D) no two electrons in an atom can have the same spin

Q.8 What type of orbital is designated n = 2,  = 3, m = –2 ?


(A) 4p (B) 4d (C) 4f (D) None
Match the column :
Q.9 Column-I Column-II

(A) No. of electrons in Na(11) having m = 0 (P) 7

(B) No. of electrons in S(16) having (n + ) = 3 (Q) 15

(C) No. of maximum possible electrons having S = +1/2 spin in Cr(24) (R) 8

(S) 12
1
Q.10 If an electron has spin quantum number of + and magnetic quantum number of –1 it cannot be present in
2

(A) f-orbital (B) d-orbital (C) p-orbital (D) s-orbital

Q.11 Principal, azimuthal and magnetic quantum numbers are respectively related to
(A) size, shape and orientation (B) shape, size and orientation
(C) size, orientation and shape (D) none of these

Q.12 Consider the ground state of Cr (Z = 24). The numbers of electrons with the azimuthal quantum numbers
l = 1 and 2 respectively are
(A) 16 and 4 (B) 12 and 5 (C) 12 and 4 (D) 16 and 5

Q.13 Degenerate atomic orbitals have


(A) equal energy (B) nearly equal energy
(C) different energy (D) none of the above

Q.14 When the quantum number n,l,m,s are represented by 3,3,2,+1/2, the symbolism for the electron is
(A) 3s (B) 3d
(C) 3f (D) impossible set of quantum number

Q.15 For a 6s electron the values of n,l,m,s respectively could be:


(A) 6,4,4,+1/2 (B) 1,0,0,+1/2 (C) 6,1,0,+1/2 (D) 6,0,0, +1/2

Q.16 Any p-orbital can accomodate up to


(A) four electrons (B) Two electrons in parallel spin
(C) Six electrons (D) Two electrons with opposite spin
Q.17 Which one of the following sets of quantum numbers (n,l,m,s) represents an impossible arrangement?

(A) 3,2,–2,+1/2 (B) 4,0,0,+1/2 (C) 3,2,–3,+1/2 (D) 5,3,0,–1/2

Q.18 Match the column:


(‘l’ and ‘m’ are respectively the azimuthal and magnetic quantum numbers)

Column I Column II

(A) Total number of values of (l) for a shell (P) 0, 1, 2, .................(n–1)

(B) Values of (l) for a shell (Q) +l, .....+2, +1, 0, –1, –2, .......–l

(C) Total number of values of (m) for a subshell (R) (2l + 1)

(D) Values of (m) for a subshell (S) n

Q.19 Imagine a universe in which the four quantum no. can have the same possible values as in our universe
except that angular quantum no. (l) can have integral values from 0, 1, 2 .... n + 1.
(a) Find the no. of electron n = 1 & 2 shell.
(b) Predict the electronic configuration for elements with atomic no. 15 & 25 using aufbau (n + l)
rule.

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