ONLY ONE OPTION IS CORRECT

Q.1 The metal X is prepared by the electrolysis of fused chloride. It reacts with hydrogen to form a colourless
solid from which hydrogen is released on treatment with water. The metal is :
(A) Al (B) Ca (C) Cu (D) Zn
Q.2 Magnesium has polarising power close to that of
(A) Li (B) Na (C) K (D) Cs
Q.3 Mortar is a mixture of
(A) Ca(OH)2 silica and water (B) CaCO3 and SiO2
(C) CaO and silica (D) CaCO3, SiO2 and water
Q.4 Na2CO3 + Fe2O3  A + CO2 what is A in the reaction?
(A) NaFeO2 (B) Na3FeO3 (C) Fe3O4 (D) Na2FeO2
Q.5 Ferrous sulphate on heating gives
(A) SO2 and SO3 (B) SO2 only (C) SO3 only (D) S only
Q.6 In comparison of ferrous salts, ferric salts are
(A) more stable (B) less stable (C) equally stable (D) none of these
Q.7 Sodium burns in air to give
(A) Na2O (B) Na2O2 (C) NaO2 (D) Na3N
Q.8 Oxone is
(A) CaO (B) N2O (C) Na2O2 (D) NaBO3
Q.9 Which of the following is not an ore of magnesium?
(A) carnallite (B) magnesite (C) dolomite (D) gypsum
Q.10 At high temperature, nitrogen combines with CaC2 to give
(A) calcium cyanide (B) calcium cyanamide (C) calcium carbonate (D) calcium nitride
Q.11 When magnesium burns in air, compounds of magnesium formed are magnesium oxide and
(A) Mg3N2 (B) MgCO3 (C) Mg(NO3)2 (D) Mg(NO2)2
Q.12 Which of the following is different from other three oxides?
(A) MgO (B) SnO (C) ZnO (D) PbO
Q.13 When alumina is electrolysed in presence of cryolite, the gas liberated at graphite anode is
(A) F2 (B) O2 (C) CF4 (D) F2O
Q.14 In Nessler's reagent, the ion present is
(A) HgI2— (B) HgI42— (C) Hg+ (D) Hg2+
Q.15 Chrome yellow is chemically called
(A) lead chromate (B) lead sulphate (C) lead iodide (D) basic lead acetate
Q.16 Aluminium metal is purified by
(A) Hoope's process (B) Hall's process (C) Serpeck's process (D) Baeyer's process
Q.17 Which of the following is true for magnesium?
(A) It is more electropositive that sodium
(B) It is manufactured by electrolysis of aqueous magnesium chloride
(C) It is a strong reducing agent.
(D) It resembles, in chemical properties, with its diagonally placed element Boron in 13 group of the
Periodic Table.
Q.18 A piece of magnesium ribbon was heated to redness in a atmosphere of nitrogen and then cooled with
water. The gas evolved in
(A) Ammonia (B) Hydrogen (C) Nitrogen (D) Oxygen
Q.32 High purity copper metal is obtained by
(A) carbon reduction (B) hydrogen reduction (C) electrolytic reduction (D) thermite reduction
Q.33 Silica is added to roasted copper ores during smelting in order to remove
(A) cuprous sulphide (B) ferrous oxide (C) ferrous sulphide (D) cuprous oxide
Q.34 Roasting of copper pyrites is done
(A) to remove moisture and volatile impurities (B) to oxidise free sulphur
(C) to decompose pyrites into Cu2S and FeS (D) for all the above
Q.35 In the electrolytic refining of copper, Ag and Au are found
(A) on cathode (B) on anode (C) in the anodic mud (D) in the cathodic mud
Q.36 In a transition series, as the atomic number increases, paramagnetism
(A) Increases gradually (B) Decreases gradually
(C) First increases to a maximum and then decreases
(D) First decreases to a minimum and then increases
Q.37 Sodium thiosulphate, Na2S2O3.5H2O is used in photography to :
(A) Reduce the silver bromide grains to metallic silver
(B) Convert the metallic silver to silver salt
(C) remove undecomposed AgBr as soluble silver thiosulphate complex
(D) remove reduced silver
Q.38 When AgNO3 comes in contact with skin, it leaves a black stain. This is because of
(A) HNO3 produced by hydrolysis of AgNO3 (B) AgOH produced by hydrolysis of AgNO3
(C) Its reduction to silver (D) Its oxidation to silver oxide
Q.39 The element which is present in every amalgam is
(A) copper (B) Silver (C) Iron (D) Mercury
Q.40 Which of the following statements is incorrect?
(A) Mercurous ion exists as Hg+
(B) Mercurous ion is diamagnetic and exists as dimer Hg22+
(C) Mercurous ion is colourless
(D) There is a covalent bond between two Hg+ ions.
Q.41 CuSO4 solution + lime is called
(A) Luca's reagent (B) Bafoed's reagent (C) Fehling solution A (D) Bordeaux mixture
Q.42 Silver can be separated from lead by
(A) fractional crystallisation (B) amalgamation
(C) filteration (D) addition of zinc
Q.43 Red precipitate is obtained when silver nitrate is added to
(A) K2CrO4 (B) KI (C) KBr (D) Na2S2O3
Q.44 Photographic films or plates have ......... as an essential ingredient
(A) silver oxide (B) silver bromide (C) silver thiosulphate (D) silver nitrate
Q.45 Silver nitrate is usually supplied in coloured bottles because it is
(A) oxidised in air (B) decomposes in sunlight
(C) explodes in sunlight (D) reacts with air in sunlight
Q.46 Disodium hydrogen phospahte in presence of NH4Cl and NH4OH gives a white ppt. with a solution of
Mg2+ ion. The precipitate is :
(A)Mg(H2PO4)2 (B) Mg3(PO4)2 (C) MgNH4PO4 (D) MgHPO4
Q.47 Verdigris is
(A) Basic copper acetate (B) Basic lead acetate (C) Basic lead (D) None
 CHOOSE THE CORRECT OPTION. MORE THAN ONE ARE CORRECT
Q.1 When H2S is passed through an ammonical salt solution of X, a black precipitate is formed. The X can be:
(A) cobalt salt (B) nickel salt (C) manganese salt (D) zinc salt
Q.2 Which of the following are soluble in excess of NaOH?
(A) Al(OH)3 (B) Cr(OH)3 (C) Fe(OH)3 (D) Zn(OH)2
Q.3 Which are interfering radicals?
(A) SO 24 (B) PO 34 (C) BO33 (D) C 2 O 24
Q.4 A solution of a salt in HCl when diluted with water turns milky. It indicates the presence of :
(A) Zn (B) Bi (C) Fe (D) Sb
Q.5 Which statements about mercury are correct?
(A) Hg is a liquid metal (B) Hg forms two series of salts
(C) Hg forms no amalgam with iron and platinum (D) Hg does not show variable valency
Q.6 When excess of Sn(II) chloride solution is added to Hg (II) chloride solution, the substances formed are:
(A) Sn-amalgam (B) Hg2Cl2 (C) SnCl4 (D) Hg
Q.7 Identify the correct statements:
(A) Fluorine is a super halogen (B) Iodine shows basic nature
(C) AgF is insoluble in water (D) SCN– is the pseudohalide
Q.8 Which reactions are used for the preparation of the halogen acid?
(A) 2KBr + H2SO4  K2SO4 + 2HBr (B) CaF2 + H2SO4  CaSO4 + 2HF
(conc.) (conc.)
(C) NaCl + H2SO4  NaHSO4 + HCl (D) NaHSO4 + NaCl  Na2SO4 + HCl
(conc.)
Q.9 Available chlorine is liberated from bleaching powder when it:
(A) is heated (B) reacts with acid (C) reacts with water (D) reacts with CO2
Q.10 Which of the following gases on dissolution in water make the solution acidic?
(A) CO (B) CO2 (C) SO3 (D) PH3
Q.11 Reducing property of sulphur dioxide is shown in the reactions:
(A) 2H2S + SO2  3S + 2H2O
(B) 5SO2 + 2KMnO4+ 2H2O  K2SO4 + 2MnSO4 + 2H2SO4
(C) SO2 + 2HNO3  H2SO4 + 2NO2 (D) 4Na + 3SO2  Na2SO3 + Na2S2O3
Q.12 Which statements are correct for ozone?
(A) It is obtained by silent electric discharge on oxygen
(B) It can be obtained by the action of ultraviolet rays on oxygen
(C) It is regarded as an allotrope of oxygen (D) Ozone molecule is paramagnetic like oxygen molecule
Q.13 Phosphine is obtained by the reaction when:
(A) white phosphorus is heated with NaOH (B) Ca3P2 reacts with water
(C) red phosphorus is heated with NaOH (D) phosphorus is heated in a current of hydrogen.
Q.14 At high temperatures, nitrogen directly combines with:
(A) Zn (B) Mg (C) Al (D) Fe
Q.15 The compounds obtained by heating of orthophosphoric acid are:
(A) metaphosphoric acid (B) pyrophosphoric acid (C) P4O6 (D) P4O10
Q.16 Which are used as refrigerant?
(A) NH3 (B) CO2 (C) CCl2F2 (D) CO
Q.17 Identify the correct statements regarding structure of diborane:
(A) there are two bridging hydrogen atoms (B) each boron atom forms four bonds
(C) the hydrogen atoms are not in the same plane (D) each boron atom is in sp3 hybridized state
 MATCH THE COLUMN
Q.1 Column I Column II
(A) Dithionous acid (P) S–O–S bond is not present
(B) Thiosulphuric acid (Q) All S atom in the molecule has oxidation state +3
(C) Caro's acid (R) Acidic strength of all H atoms present in the
molecule is different
(D) Pyrosulphurous acid (S) at least one S atom has oxidation state +5 in molecule
Q.2 Column I Column II
(A) XeF5+ (P) Two lone pairs
(B) ICl4– (Q) Planar
(C) TeCl4 (R) Non-planar
(D) I3+ (S) sp3d2 (Hybridization of central atom)
Q.3 Select the option which correctly represents the order of Boiling points of given compounds.
Column I Column II
(A) H2O NH3 HF (P) a>b>c
[a] [b] [c]
(B) SbH3 PH3 AsH3 (Q) c>b>a
[a] [b] [c]
(C) C2H6 C3H8 C4H10 (R) b>a>c
[a] [b] [c]

(D) CH3OH CH 2  CH 2 CH3Cl (S) a>c>b

| |
OH OH
[a] [b] [c]
ANSWER KEY
ONLY ONE OPTION IS CORRECT
Q.1 B Q.2 A Q.3 A Q.4 A Q.5 A Q.6 A Q.7 B
Q.8 C Q.9 D Q.10 B Q.11 A Q.12 A Q.13 B Q.14 B
Q.15 A Q.16 A Q.17 C Q.18 A Q.19 C Q.20 D Q.21 A
Q.22 A Q.23 D Q.24 B Q.25 A Q.26 B Q.27 A Q.28 C
Q.29 D Q.30 C Q.31 C Q.32 C Q.33 B Q.34 D Q.35 C
Q.36 C Q.37 C Q.38 C Q.39 D Q.40 A Q.41 D Q.42 D
Q.43 A Q.44 B Q.45 B Q.46 C Q.47 A Q.48 D Q.49 C
Q.50 D Q.51 A Q.52 B Q.53 A Q.54 D Q.55 A Q.56 C
Q.57 C Q.58 B Q.59 C Q.60 D Q.61 D Q.62 A Q.63 C
Q.64 B Q.65 B
CHOOSE THE CORRECT OPTION. MORE THAN ONE ARE CORRECT
Q.1 A,B Q.2 A,B,D Q.3 B,C,D Q.4 A,B,D
Q.5 A,B,C,D Q.6 B,C,D Q.7 A,B,D Q.8 B,C,D
Q.9 B,C,D Q.10 B,C Q.11 B,C Q.12 A,B,C
Q.13 A,B Q.14 B,C Q.15 A,B,D Q.16 A,B,C
Q.17 A,B,C,D Q.18 B,C,D Q.19 C,D Q.20 B,D
Q.21 B,C,D Q.22 B,D Q.23 A,C,D Q.24 A,B,C,D
Q.25 B,D Q.26 A,B,D Q.27 A,B Q.28 A,B,C
Q.29 A,B,C,D Q.30 C,D Q.31 A,C Q.32 C,D

MATCH THE COLUMN

Q.1 (A) P,Q; (B)P; (C) P,R; (D) P,R,S Q.2 (A) R, S; (B) P, Q, S; (C) R; (D) P, Q
Q.3 (A) S, (B) S, (C) Q, (D) R