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Reaction of Aldehyde Complete

1) Aldehydes can undergo oxidation reactions using reagents like potassium permanganate, potassium dichromate, or Fehling's solution to form carboxylic acids. 2) They can also undergo addition reactions, such as with hydrocyanic acid to form cyanohydrins, or with 2,4-dinitrophenylhydrazine to form orange precipitates. 3) Aldehydes can be reduced to primary alcohols using sodium borohydride or lithium aluminum hydride.

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48 views1 page

Reaction of Aldehyde Complete

1) Aldehydes can undergo oxidation reactions using reagents like potassium permanganate, potassium dichromate, or Fehling's solution to form carboxylic acids. 2) They can also undergo addition reactions, such as with hydrocyanic acid to form cyanohydrins, or with 2,4-dinitrophenylhydrazine to form orange precipitates. 3) Aldehydes can be reduced to primary alcohols using sodium borohydride or lithium aluminum hydride.

Uploaded by

Joko Susilo
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Reaction of Aldehydes - Must know reaction

oxidation
O

O H 3C C O OH
triiodomethane or
–
H C O Na + idoform reaction
KMnO4 or K2Cr2O7 O
I2
oxidation
dilute HCl
CHI3 (s) NaOH (aq) heat or reflux H3C C O – result:
warm tollen’s = silver mirror
fehling = reddish-brown ppt
Fehling’s solution or
Tollen’s reagent warm
K2Cr2O7, dilute H2SO4 O
OH
reflux with immediate distillation
H 3C C H H 3C C H
H oxidation
NaBH4 (aq), r.t.
or 1. LiAlH4, dry ether
HCN 2. H2O, r.t.
trace NaCN or or H2 (g), Pt, heat
2,4-DNPH trace NaOH
r.t
10-20oC

O2N
H3 OH
C
H 3C C H OH
H C N N NO2
H H3C C H
CN H
condensation (orange ppt) nucleophilic additon reduction

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