Scribd
Upload
69 views3 pages

Race-30 - Atomic Structure

The document contains a chemistry exam with multiple choice questions about atomic orbitals and the Schrodinger wave equation. It tests understanding of quantum numbers, radial and angular nodes, probability distributions, and the radial and angular parts of the wave function for the hydrogen atom. The answers provided are: 1) 7f 2) 4d 3) 4s 4) 2, 0 5) 2 6) 2 7) 0 8) A, B, C 9) A, B, C 10) 4s 11) ZX 12) D 13) 0.75 Å 14) D.

Uploaded by

Itish mann
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
69 views3 pages

Race-30 - Atomic Structure

The document contains a chemistry exam with multiple choice questions about atomic orbitals and the Schrodinger wave equation. It tests understanding of quantum numbers, radial and angular nodes, probability distributions, and the radial and angular parts of the wave function for the hydrogen atom. The answers provided are: 1) 7f 2) 4d 3) 4s 4) 2, 0 5) 2 6) 2 7) 0 8) A, B, C 9) A, B, C 10) 4s 11) ZX 12) D 13) 0.75 Å 14) D.

Uploaded by

Itish mann
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 3

RACE # 30 ATOMIC STRUCTURE CHEMISTRY

SCHRODINGER WAVE EQUATION


1. The radial probability distribution curve of an orbital of H has '4' local maxima. If orbital has 3 angular
node then orbital will be :
(A) 7f (B) 8f (C) 7d (D) 8d
2. Which orbital is represented by the complete wave function, y 420 ?
(A) 4s (B) 4p (c) 4d (D) 4f
3. The orbitals amongest the following having three nodal sufaces:
(A) 1s (B) 2s (C) 3s (D) 4s
4. The number of radial nodes of 3s and 2p orbitals are respectively:
(A) 2, 0 (B) 0,2 (C) 1, 2 (D) 2 , 1
5. For an electron, with n = 3 has only one radial node. The orbital angular momentum of the electron Will
be:

h h æ h ö
(A) 0 (B) 6 (C) 2 (D) 3 çè ÷ø
2p 2p 2p
6. How many angular nodes does a d-orbital possess?
(A) 1 (B) 2 (C) 3 (D) 4
7. How many radial nodes does a 3d-orbital possess?
(A) 0 (B) 1 (C) 2 (D) 3
8. The radial part of schrodinger wave equation for hydrogen atom is
1 s
y(r) = 3/ 2
(s – 1) (s2 – 8s + 12) e– /2
16 4 a 0
Where a0 = constant & s = 2r/na0 ; n = principle quantum number
Select the correct statements :
(A) Distance of nearest radial node from the nucleus is 2a0.
(B) Distance of farthest radial node from the nucleus is 12a0.
(C) Number of maxima in the curve 4pr2y2(r) vs r are 4.
(D) y(r) is for 4p orbital.
9. Observe the following plots carefully :

Orbital-I Orbital-II

Y1 Y2

r
r
Identify the correct option (s) -
(A) Y2 may represent a 2p-orbital
(B) Y1 should represent 2s-orbital
(C) Variation of probability with r in each direction is same for orbital-I
(D) Variation of probability with r in each direction is same for orbital-II
10. The schrodinger wave equation for hydrogen atom is
3/ 2
1 æZö 2Zr
y(r)= ç ÷
16 4 è a 0 ø
{éë(s - 1)(s 2
}
- 8s + 12) ùû e -s / 2 where a & Z are constant, s =
0 a 0 then select correct statement.

a0
(A) Minimum distance of radial node from nucleus is
Z

a0
(B) Maximum distance of radial node from nucleus is
Z
(C) y(r) is for 4s-orbital
(D) y(r) is for 5p-orbital
11. Which of the following is the nodal plane of dxy orbital ?
(A) XY (B) YZ (C) ZX (D) All
Paragraph for Question 12 to 14
For an orbital of H-like species radial function is :

3/2
1 æ Zö
R(r) = ç ÷ (4 – s) s e-s / 2
9 6 è a0 ø

2Zr
where s = ; a0 = 0.5 Å , Z = atomic number of species , r = radial distance from nucleus.
na 0

12. Which of the following statements about the orbital whose radial function is given above is CORRECT?
(A) This is an s-orbital
(B) This cannot be p-orbital
(C) Principal quantum number (n) of this orbital is 4
(D) This orbital has one radial node.
13. At what distance from the nucleus will this orbital have a radial node in Be+3 ion ?
(A) 0.5 Å (B) 2 Å (C) 1 Å (D) 0.75 Å
14. Choose the correct statement among the following

(A) Radial distribution function ( Y 2 ·4pr 2dr ) give probability at a particular distance along one chosen direction

(B) Y 2 ( r ) give probability density at a particular distance over a spherical surface

(C) For 's' orbitals Y (r, q, f) is dependent on q and f

(D) '2p' orbital with quantum numbers. n = 2, l = 1, m = 0, also shows angular dependence
Answers

RACE # 30
1. (A) 2. (C) 3. (D) 4. (A) 5. (C) 6. (B) 7. (A) 8. (ABC)
9. (ABC) 10. (C) 11. (C) 12. (D) 13. (D) 14. (D)

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy