Nanotechnologyin Food Processingand Packaging
Nanotechnologyin Food Processingand Packaging
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Krishnakumar T.
ICAR-Central Tuber Crops Research Institute, Trivandrum, Kerala
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SYNOPSIS
1. Introduction
2. Potential food applications
3. Nanotechnology food processing
Nanoemulsions
Nanostructured multilayer emulsions
Biopolymeric nanoparticles
Nanolaminates
Nanocochleates
4. Nanotechnology in food packing
Nanoplastic packing
Nanocomposites
Active packaging
Intelligent packaging
The electronic nose (e-nose) technology
The electronic tongue technology
Nanofibers and nanotubes
5. Nanofoods pose new health risks
6. Regulation nanotech in food industry
7. Conclusion
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
INTRODUCTION
The current global population is nearly with 4 billion people in Asia, which is than 60% of the
world's current human population. A large proportion of those living in developing countries face
daily food shortages as a result of environmental impacts or political instability, while in the
developed world there is a food surplus. For developing countries the drive is to develop drought
and pest resistant crops which also maximize yield. In developed countries, the food industry is
driven by consumer demand which is currently for fresher and healthier foodstuffs. This is big
business, for example the food industry in the UK is booming with an annual growth rate of
5.2% and the demand for fresh food has increased by 10% in the last few years.
The potential of nanotechnology to revolutionize the health care, textile, materials,
information and communication technology and energy sectors has been well-publicized. In fact
several products enabled by nanotechnology are already in the market, such as antibacterial
dressings, transparent sunscreen lotions, stain-resistant fabrics, scratch free paints for cars and
self cleaning windows. The application of nanotechnology to the agricultural and food industries
was first addressed by a United States Department of Agriculture roadmap published in
September 2003. The prediction is that nanotechnology will transform the entire food industry,
changing the way food is produced, processed, packaged, transported and consumed.
NANOTECHNOLOGY
The word “nano” meaning “dwarf” in Greek language refers to dimensions on the order
of magnitude of 10-9. Nanotechnology, focusing on special properties of materials emerging
from nanometer size, for e.g. in biological systems, the first level of organization occurs at the
nanoscale structure where all the fundamental properties and functions are systematically
defined.
Nanotechnology has the potential to revolutionize the scientific world by slowing
scientists to manipulate matter at the atomic or molecular scale using physics, engineering,
chemistry and biology. Nanotechnology is a broad and interdisciplinary area of research and
development activity that has been growing at a rapid pace worldwide in the past few years. It
enables researchers to understand the relationship between macroscopic properties and molecular
structure in biological materials of plants and animal origin. Using nanotechnology, scientitsts
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
are able to self assemble atoms into sturcutres with highly controlled properties e.g. nanowires,
self assembled molecules and particles.
Second, it may have to protect the functional ingredient from chemical or biological
degradation (for example, oxidation) during processing, storage and utilization; this
maintains the functional ingredient in its active state.
Third, it may have to be capable of controlling the release of the functional ingredient,
such as the release rate or the specific environmental conditions that trigger release (for
example, pH, ionic strength, or temperature).
Fourth, the delivery system has to be compatible with the other components in the
system, as well as being compatible with the physicochemical and qualitative attributes
(that is, appearance, texture, taste, and shelf-life) of the final product.
A wide variety of delivery systems have been used to encapsulate functional ingredients
including simple solutions, association colloids, emulsions, biopolymer matrices and so on. Each
type of delivery system has its own specific advantages and disadvantages for encapsulation,
protection and delivery of functional ingredients, as well as cost, regulatory status, ease of use,
biodegradability and biocompatibility. A number of potential delivery systems based on
nanotechnology are given in the Figure 2:
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
ASSOCIATION COLLOIDS
Surfactant micelles, vesicles, bilayers, reverse micelles and liquid crystals are all
examples of association colloids. A colloid is a stable system of a substance containing small
particles dispersed throughout. An association colloid is a colloid whose particles are made up of
even smaller molecule which is used for many years to deliver polar, nonpolar and amphiphilic
functional ingredients, association colloids range in size from 5 nm to 100 nm. The major
advantages of association colloid systems are thermodynamically favorable and typically
transparent solutions. On the other hand, the major disadvantage is that a large quantity of
surfactant (and in many cases, cosurfactant) is required to form them which may lead to
problems with flavor, cost or legality.
NANOEMULSIONS
An emulsion is a mixture of two or more liquids (such as oil and water) that do not easily
combine. The use of high-pressure valve homogenizers or microfluidizers often causes
emulsions with droplet diameters of less than 100 to 500 nm. Therefore, a nanoemulsion is an
emulsion in which the diameters of the dispersed droplets measure 500 nm or less.
Nanoemulsions can encapsulate functional ingredients within their droplets, which can facilitate
a reduction in chemical degradation. In fact, different types of nanoemulsions with more-
complex properties such as nanostructured multiple emulsions or nanostructured multilayer
emulsions—offer multiple encapsulating abilities from a single delivery system that can carry
several functional components.
BIOPOLYMERIC NANOPARTICLES
Food-grade biopolymers such as proteins or polysaccharides can be used to produce
nanometer-sized particles. Using aggregative (net attraction) or segregative (net repulsion)
interactions, a single biopolymer separates into smaller nanoparticles. The nanoparticles can then
be used to encapsulate functional ingredients and release them in response to distinct
environmental triggers. One of the most common components of many biodegradable
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
biopolymeric nanoparticles is polylactic acid (PLA). PLA is often used to encapsulate for deliver
drugs, vaccines and proteins, but it has limitations: it is quickly removed from the bloodstream,
remaining isolated in the liver and kidneys. Because its purpose as a nanoparticle is to deliver
active components to other areas of the body, PLA needs an associative compound such as
polyethylene glycol to be successful in this regard.
NANOLAMINATES
Besides nanodispersions and nanocapsules, another nanoscale
technique is commercially viable for the food industry i.e.
nanolaminates. This Consist of two or more layers of material with
nanometer dimensions, a nanolaminate is an extremely thin food-
grade film (1–100 nm/ layer) that has physically bonded or
chemically bonded dimensions.
Because of its advantages in the preparation of edible films, a
nanolaminate has a number of important food-industry
applications. Edible films are present on a wide variety of
foods: fruits, vegetables, meats, chocolate, candies, baked
goods and French fries. Such films protect foods from
moisture, lipids and gases and they can improve the textural
properties of foods and serve as carriers of colors, flavors,
antioxidants, nutrients and antimicrobials. Currently, edible
nanolaminates are constructed from polysaccharides, proteins, and lipids. Although
polysaccharide- and protein-based films are good barriers against oxygen and carbon dioxide,
but they are poor at protecting against moisture. On the other hand, lipid-based nanolaminates
are good at protecting food from moisture, but they offer limited resistance to gases and have
poor mechanical strength.
For now, coating foods with nanolaminates involves either dipping them into a series of
solutions containing substances that would adsorb to a food’s surface or spraying substances
onto the food surface (figure 4). While there are various methods that can cause adsorption, it is
commonly a result of an electrostatic attraction between substances that have opposite charges.
The degree of a substance’s adsorption depends on the nature of the food’s surface as well as the
nature of the adsorbing substance. Different adsorbing substances can constitute different layers
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
Figure 5: Possible components that could be used to assemble multilayered edible films or
coatings
These functional agents would increase the shelf life and quality of coated foods. These
nanolaminated coatings could be created entirely from food-grade ingredients (proteins,
polysaccharides, lipids) by using simple processing operations such as dipping and washing.
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
NANOCOCHLEATES
In food and beverage industry, attempts have been made to add micronutrients and
antioxidants to food substances. But these antioxidants degrade during manufacturing and food
storage. Nano cocohleates delivery system
protects these substances from degradation.
Example, Polyphenols and Resveratrol are the
substances present in most foods and wine
respectively. They gets degraded and oxidized
when exposed to air. Nanocochleates solve
early oxidation by individually capturing and
wrapping them in a phospholipid wrap and
maintaining the internal nutrients secure from
water and oxygen.
BioDelivery Sciences International have developed nanocochleates which are 50nm
coiled nanoparticles that can be used to deliver nutrients such as vitamins, lycopene and omega 3
fatty acids more efficiently to cells, without affecting the colour or taste of food. The delivery
vehicle is made of soyphophatidylserine which is 100% safe. It provides a protective coat for
range of nutrient additives (Table 2).
Table 2: Nanomaterials in food additives
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
ability due to lower viscosity and recycling properties. This has led to the development of a
variety of nanoparticle reinforced polymers, also termed as ‘‘nanocomposites’’.
Two types ofhybrids—intercalationandexfoliation—are ideal nanoscale composites
(Figure 6).
Intercalation is the state in which extended polymer chains are present between the clay
layers, resulting in a multilayered structure with alternating polymer/inorganic layers at a
repeated distance of a few nanometers. Exfoliation is a state in which the silicate layers are
completely separated and dispersed in a continuous polymer matrix. The structure and properties
of the resulting nanocomposites can be altered by controlling subtle polymer-clay interactions.
The polymer composites incorporating clay nanoparticles are among the first
nanocomposites to emerge on the market as improved materials for food packaging. The
nanoclay mineral used in these nanocomposites is montmorillonite
(also known as bentonite), which is a relatively cheap and widely
available natural clay derived from volcanic ash/ rocks. Nanoclay–
polymer composites for potential use in a variety of food-
packaging applications such as processed meats, cheese,
confectionery, cereals, boil-in-the-bag foods, as well as in
extrusion-coating applications for fruit juices and dairy products, or
co-extrusion processes for the manufacture of bottles for beer and
carbonated drinks. The polymers used for clay–polymer nanocomposites are PA (polyamides),
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
ACTIVE PACKAGING
Actively changes the conditions of the packaged food to extend shelf-life or to improve
food safety and quality.
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
These products commonly use nanoparticles of silver although some use nano zinc oxide
or nano chlorine dioxide (Table 4). Nano magnesium oxide, nano copper oxide, nano titanium
dioxide and carbon nanotubes are also predicted for future use in antimicrobial food packaging.
Table 4: Nano-based antibacterial food packaging and food contact materials
NANOTECNOLOGY NANOTECHNOLOGY IN FOOD PROCESSING AND PACAKGING
INTELLIGENT PACKAGING
Monitors the conditions of packaged food products and gives information about their
safety and quality during transport and storage
in parts per trillion (PPT) and could be used in packaging to trigger a color change that would
alert the consumer if a food has become contaminated or if it had begun to spoil.
Food researches believe the electronic tongue is going to be vital to food studies. As an
example, a meat package with a built in tongue can taste the first signs of spoilage and active a
color change as a warning to the consumer.
The electronic tongue is made from a silicon chip that has micro beads arrayed on it.
Each of the beads responds to different analytes. The different analytes of the e-tongue are
similar to the taste buds on the human tongue. The tongue responds to sweet sour, salty & bitter
tastes in a similar fashion as the taste buds on your tongue do.
The food and beverage industries may see the potential to use the e-tongue to develop a
digital library of tastes. The collection data would include tastes that have been proven to the
popular with consumers. The e-tongue could also monitor the flavors of existing products.
Summarizing, nanosensors such as electronic tongues and electronic noses, the use of
nano barcodes have the potential to provide safe food products and packaging. The embedded
sensors in food packaging will respond to the release of particular chemicals when a certain food
begins to spoil. So, as soon as the food starts to go bas the packaging will change color to warn
the shopper. This system could also provide a more accurate and safer method.
Attaching an RFID tag to a package makes it "intelligent" because this silicon chip
functions as a mobile database, holding valuable information, such as the product's history,
location and destination. The data that these tags contain can be updated and read in bulk by
radio waves.
These displays involve utilization of smart labels that will assist quick and accurate
distribution of a wide variety of goods with limited shelf-life. The RFID polymeric transistors
use nanoscale organic thin-film technology. The RFID systems will be designed to operate
automatically and will provide exception reports for temperature, short-life span products.
NANOTECHNOLOGY
NANOTECNOLOGY IN FOOD PROCESSING AND PACAKGING
While there are lots of opportunities for using nanotechnology to improve food production,
packaging and quality, there is also some concern about how this will play out. The nanotech
materials have “the potential for use in vast variety of products and may pose new and unique
safety issues”.
According to the research, nanotech in food packaging will bring benefits in the form of:
There are however, risks associated with this. The first type of the risk deals with inconclusive
research on impacts and lack of effect data:
In August 2006, the U.S Food and Drug Administration (FDA) formed a Nanotechnology Task
Force with goals that included:
In its February, 2007 meeting, the European Food Safety Authority Regulatory agency
announced that it was forming scientific panel to conduct a risk assessment of nanoparticles in
food and food packaging. This panel should be able to draw input and expertise from across
Europe. For example, Denmark’s National Food Institutes is working on a project together
toxicology information on nanoparticles and the UK Food Safety Authority has put together a
report that provided “an outline of potential areas for future regulation relating to the use of
nanotechnology and nanomaterials in food”.
While the regulatory agencies may be making these efforts a little late, because
some products are already available and development has been started on many more,
one can hope that discussions would help consumers to benefit from improved and safe
food products with a minimum of controversy.
CONCLUSION
The impact of nanotechnology in food industry which provides new methods to improve
foof safety and nutritional value of foods. Now –a – days the scientist had focused on the
nanoencapsulation in food processing and nanoclay polymer etc, in food packaging. But in
future the combination of DNA and nanotechnology research generates the new nutrition
delivery system, which brings the active agents more precisely to the wanted parts of the human
bodies and cells. There is lots of challenge in forthcoming food nanotechnology, which could
eradicate hunger. Nanotechnology in the food industry was currently valued at $410 million and
would grow to $58 billion by 2010.