Easy Guide For Valve Material Selection
Easy Guide For Valve Material Selection
MATERIAL SELECTION
EHSAN HATAMI
QC MANAGER
FICO VALVES
MAY-2023
ASTM A216 Non-corrosive applications including water, oil and gases at temperature between -20ºF (-30ºC) and +800ºF
Carbon Steel
Grade WCB (+425ºC).
ASTM A217 1 1/4% Chrome Non-corrosive applications including water, oil and gases at temperatures between -20ºF (-30ºC) and +1100ºF
Grade WC6 1/2% Moly Steel (+593ºC).
ASTM A217 Non-corrosive applications including water, oil and gases at temperatures between -20ºF (-30ºC) and +1100ºF
2 1/4% Chrome
Grade C9 (+593ºC).
ASTM A217 5% Chrome Mild corrosive or erosive applications as well as non-corrosive applications at temperatures between -20ºF
Grade C5 1/2% Moly (-30ºC) and +1200ºF (+649ºC).
ASTM A217 9% Chrome Mild corrosive or erosive applications as well as non-corrosive applications at temperatures between -20ºF
Grade C12 1% Moly (-30ºC) and +1200ºF (+649ºC).
ASTM A217
13% Chrome Corrosive application at temperature up to +1300ºF (+704ºC).
Grade CA15
ASTM A351 Corrosive or either extremely low or high temperature non-corrosive services between -450ºF (-268ºC) and
316 SS
Grade CF8M +1200ºF (+649ºC). Above +800ºF (+425ºC) specify carbon content of 0.04% or greater.
ASTM 351 Primarily for high temperature, corrosive applications between -450ºF (-268ºC) and +1200ºF (+649ºC). Above
347 SS
Grade CF8C +1000ºF (+540ºC) specify carbon content of 0.04% or greater.
ASTM A351 Corrosive or extremely high temperature non-corrosive services between -450ºF (-268ºC) and +1200ºF
304 SS
Grade CF8 (+649ºC). Above +800ºF (+425ºC) specify carbon content of 0.04% or greater.
ASTM A351
304L SS Corrosive or non-corrosive services to +800ºF (+425ºC).
Grade CF3
ASTM A351
316L SS Corrosive or non-corrosive services to +800ºF (+425ºC).
Grade CF3M
ASTM A351
Alloy 20 Good resistance to hot sulfuric acid -51ºF (-46ºC) to +300ºF (+150ºC).
Grade CN7M
ASTM A990
Alloy 20 (New*) Good resistance to hot sulfuric acid to -51ºF (-46ºC) to 300ºF~ 800ºF (150ºC~ 425ºC).
Grade CN3MCu*
ASTM 743 Weldable grade. Good resistance to corrosion by all common organic acids and salt water. Also highly resistant to
Monel
Grade M3-35-1 most alkaline solutions to +750ºF (+400ºC).
ASTM A743 Is well suited for handling hydrofluoric acid at all concentrations and temperatures. Good resistance to sulphuric and
Hastealloy B
Grade N-12M phosphoric acids to +1200ºF (+649ºC).
ASTM A743 Good resistance to strong oxidation conditions. Good properties at high temperatures. Good resistance to sulphuric
Hastealloy C
Grade CW-12M and phosphoric acids to +1200ºF (+649ºC).
ASTM A743 Very good for high temperature service. Good resistance to strongly corrosive media and atmosphere to +800ºF
Inconel
Grade CY-40 (+425ºC).
ASTM B62 Bronze Water, oil or gas: up to 400ºF (205ºC). Excellent for brine and seawater service.
* The specially controlled process of this alloy, provides castings with heat resistance near or equal to wrought grades of alloy 20, that is say 800ºF (425ºC) but at time of this publication this
had not yet been established by ANSI B16.34.
Common Forged Valve Materials
ASTM Casting
Description Common Service Recommendations Body/Bonnet Material
Designation Comparison
General service such as oil, oil vapor, gas, steam and water at temperatures
A105(1) Carbon Steel A216-WCB
-20ºF to 1000ºF (-28ºC to 537ºC).
Suitable for temperatures -50ºF and not above 650ºF (-46ºC and not above
A350-LF2 CL1 Low Temperature Carbon Steel A352-LCB
343ºC).
For high temperatures from -20ºF to 1100ºF to minimise graphitisation
A182-F11 CL2 1 1/4% Cr, 1/2% Mo Alloy Steel A217-WC6
(-28ºC to 593ºC).
For services requiring greater strength than F11 at temperatures from
A182-F22 CL3 (2) 2 1/4% Cr, 1% Mo Alloy Steel A217-WC9
-20ºF to 1100ºF (-28ºC to 593ºC).
For corrosive/erosive refinery use requiring resistance at temperatures from
A182-F5 5% Cr, 1/2% Mo Alloy Steel A217-C5
-20ºF to 1100ºF (-28ºC to 590ºC).
For services involving media with higher sulphur content to combat oxidation
A182-F9 9% Cr, 1% Mo Alloy Steel A217-C12
to 1100ºF (593ºC).
For corrosive services and atmospheres from -450ºF to 1000ºF (-268ºC to
A182-F304 18% Cr, 8% Ni Stainless Steel A351-CF8
537ºC).
A182-F316 18% Cr, 8% Ni, 2% Mo Stainless Steel For superior resistance to corrosion from -450ºF to 1000ºF (-268ºC to 537ºC). A351-CF8M
(1) Permissible but not recommended for prolonged use above 800ºF (425ºC)
(2) Consideration should be given to the possibility of excessive oxidation (scaling) when used above 1050ºF (563ºC)
HASTELLOY Nickel Alloy Good high temperature properties. Excellent corrosion resistance in hydrochloric acid.
INCONEL
Nickel Alloy For high temperature service. Used for nuclear applications.
INCOLOY
MONEL Nickel-Copper Alloy For corrosive service up to 842ºF (450ºC). Resistant to sea water, acids, alkalies.
TITANIUM Transition Metal Good resistance to corrosion together with low specific weight.
ASTM A182 F20 Alloy 20 - Specialty Alloy For corrosive service such as hot sulphuric acid. Resists -49ºF to 600ºF (-45ºC to 316ºC).
ASTM A182 F51 Ferritic-Austenitic Stainless Steel Very high strength, resistance to corrosion, pitting and stress corrosion in chloride media.
ASTM A182 F44 Austenitic Stainless Steel Very high strength, high resistance to corrosion.
13% Cr, Type 410 Stainless Steel For oil and oil vapors and general services with heat treated seats and wedges.
13% Cr, Type 410 plus Hardfacing Universal trim for general service requiring long service life up to 1100ºF (593ºC).*
Type 316 Stainless For liquids and gases which are corrosive to 410 Stainless Steel, up to 1000ºF (537ºC).*
Monel For corrosive service to 842ºF (450ºC) such as acids, alkalies, salt solutions, etc.
Alloy 20 For corrosive service such as hot acids -49ºF to 608ºF (-45ºC to 320ºC).
NACE Specially treated 316 or 410 trim combined optionally with B7M Bolts and 2HM nuts to meet NACE MR-01-75 requirements.
Full Stellite Full hard faced trim, suitable for abrasive & severe services up to 1200ºF (650ºC).*
If we don’t have the valve in stock we can source it from our overseas network of stockists and very short lead-time specialty manufacturers. We can
even supply exotic grades like Nickel, Super Duplex F55 and Monel (ASTM A494-M35-1) Cd4M-Cu, Hastelloy C (ASTM A-494 CW12MW), 317
. (C8G8M) in short lead-time
, For other ANSI, ASME, ISO, API, valve related technical cross references relating to pressure, temperature, application, suitability
.equivalents, valve body & trim materials, valve manufacturing & test standards, go to the technical section of our website
TRIM SERVICE APPLICATIONS & OLD BS DESIGNATION
API Trim Old BS
Service
Number Designation
For oil and oil vapors and general services with heat treated seats and wedges. General very low erosive or non-corrosive service between -100ºC and 320ºC. This stainless steel material lends itself
11 readily to hardening by heat treatment and is excellent for contacting parts such as stems, gates, and discs. Steam, gas & general service to 370ºC. Oil & Oil vapor 480ºC.
Cr13
21 For moderate pressure in corrosive, low erosive service between -265ºC and 450ºC. 18-8Ti
3 For moderate pressure in corrosive or non corrosive service between -265ºC and 450ºC. 25-20
4 Seats 275 BHN min. As trim 1 but for medium pressure and more corrosive service. HF
5 High pressure slightly erosive and corrosive service between -265ºC and 650ºC and higher pressure. Premium trim service to 650ºC. Excellent for high pressure water and steam service. HF
5a As trim 5 where Co is not allowed. HF
6 As trim 1 and more corrosive service. Cr and Cu-Ni
7 Seats 750 BHN min. As trim 1 but for higher pressure and more corrosive/erosive service. Cr and Cu-Ni
8 Universal trim for general service requiring long service life up to 593ºC. As trim 5 for moderate pressure and more corrosive service. Steam, gas & general service to 540ºC. Standard trim for gate valves. Cr + HF
8a As trim 5a for moderate pressure and more corrosive service. Cr + HF
For corrosive service to 450ºC such as acids, alkalies, salt solutions, etc. Very corrosive fluids.
9 Erosive-corrosive service between -240ºC and 480ºC. Resistant to sea water, acids, alkalies. Has excellent corrosion resistance in chlorine and alkylation service.
Ni-Cu
For superior resistance to corrosion for liquids and gases which are corrosive to 410 stainless steel up to 455ºC. As trim 2 but a higher level of corrosive service. Provides excellent resistance to corrosive
10 media at high temperatures and toughness for service at low temperatures. Low temperature service standard for 316SS valves.
18/10/2002
11 As trim 9 but for medium pressure and more corrosive service. HF-Ni
12 As trim 10 but for medium pressure and more corrosive or abrasive service. -
13 Very corrosive service. For moderate pressure between -45ºC and 320ºC. -
14 As trim 13 but for medium pressure and more corrosive service. -
15 As trim 2 but more erosive service & higher pressure. -
16 As trim 10 but more erosive service & higher pressure. -
17 As trim 13 but more corrosive service & higher pressure. Combines good corrosion resistance with high temperature resistance up to 800ºC. 18-8 Nb
18 As trim 13 but more corrosive service & higher pressure. Water, gas or low pressure steam to 230ºC. -
Bronze Water, oil, gas, or low pressure steam to 232ºC. -
1
API lists as obsolete but still used in the valve industry. (Trim# 1 is still used for API603 gates as well as globe & check valves). Also, even though API no longer references trim# 2, for API603 gate,
globe & check, (and in some commodity API600 gate valves in lower classes and under 300NB) it is still manufactured as it is specified by clients.
Important Note: Data provided in this chart is for informational purposes only. Always consult current API publications to verify information and trim date. Australian Pipeline Valve recommend that
customer’s engineers analyse service requirements and specify the materials they consider optimum for their service conditions. Temperatures shown will vary depending on service applications,
pressure and media type.
F6 UNS S41000 13Cr ASTM A182 F6a A4276-410 DIN X12Cr13 1.4006
304 UNS S30400 18-8 Cr-Ni ASTM A182 F304 A276-304 DIN X5CrNi 18 10 1.4301
316 UNS S31600 18-8 Cr-Ni (18-10-2) ASTM A182 F316 A276-316 DIN X5CrNiMo 18 10 1.4401
321 UNS S32100 18 Cr-10 Ni-Ti ASTM A182 F321 A276-321 DIN X6CrNiTi 18 10 1.4541
347 UNS S34700 18 Cr-10 Ni-Cb ASTM A182 F347 A276-347 DIN X6CrNiNb 18 10 1.455
MONEL® UNS N04400 67Ni-30Cu ASTM B564-N04400 B164-N04400 DIN 17743 2.436
ALLOY 20 UNS N08020 28Ni-19Cr-Cu-Mo ASTM A182-F20* ASTM B473 DIN 14500 2.466
ALLOY 625 UNS N06625 60Ni-22Cr-9Mo-3.5Cb ASTM B564-N06625 ASTM B564-N06625 DIN 17361 2.4865
C276 UNS N10276 54Ni-15Cr-16Mo ASTM B564-N10276 ASTM B574-N10276 DIN NiMo 16 Cr 15 W 2.4819
17/4PH UNS S17400 0C417Ni4Cu4Nb ASTM A4750 UNS S17400 ASTM A4705 UNS S17400 X5CrNiCuNb17-4-4 1.4548
St. Gr6 UNS R30006 Co Cr-A AMS 5894 Stellite® Gr6
We stock valves in A105, LF2, 304, 304L, 316, 316L, F51, CF8, CF3, CF8M, WC5, WC6, WC9, F11, F22, F5, Bronze, Iron, etc. in
Ball, Butterfly, Check, Control, Gate, Globe,
Needle, Parallel slide, Plug, etc. Valves are manufactured to API600, API602, API603, API6A, API6D, BS1868 and numerous other
standards.
GENERAL NOTES:
(a) The user is responsible for assuring that bolting material is not used beyond the limits specified in the governing code or regulations.
(b) ASME Boiler and Pressure Vessel Code Section II material that also meet the requirements of the listed ASTM specification may also be
used.
(c) Material limitations, restrictions, and special requirements are shown on pressure-temperature tables.
(d) Check latest version of ASME B16.34 as this standard is continually updated. Do not use these tables for design or ordering purposes. The
above data is extracted from ASME B16.34 2009.
(e) Note (1) below applies to all grades.
NOTES:
(1) Repair welding of bolting material is not permitted.
(2) Where austenitic bolting materials have been carbide solution treated but not strain hardened, they are designated Class 1 or Class 1A in
ASTM A193. ASTM A194 nuts of corresponding material are recommended.
(3) Where austenitic bolting materials have been carbide solution treated and strain hardened, they are designated Class 2 in ASTM A193.
ASTM A194 nuts of corresponding material are recommended.
(4) For limitations of usage and strength levels, see ASME B16.34 para. 5.1.2.
(5) Bolts with drilled or undersize heads shall not be used.
(6) For ferritic bolting materials intended for service at low temperatures, ASTM A194 Gr. 7 nuts are recommended.
(7) Acceptable nuts for use with quenched and tempered steel bolts are ASTM A194 Grade 2 and 2H.
(8) Mechanical property requirements for studs shall be the same as for bolts.
(9) Bolting materials suitable for high-temperature service with austenitic stainless steel valve materials.
(10) Nuts may be of the same material or may be of compatible grade of ASTM A194.
(11) Forging quality not permitted unless the producer last heating or working these parts tests them as required for other permitted conditions
in the same specification and certifies their final tensile, yield, and elongation properties to equal or exceed the requirements for one of the
other permitted conditions.
(12) Maximum operating temperature is arbitrarily set at 260ºC (500ºF), unless material has been annealed solution annealed, or hot finished,
because hard temper adversely affects design stress in the creep-rupture temper range.
† ASTM A194 Grade 7 replaces Grade 4 (ASTM has withdrawn Grade 4 whilst still acceptable was removed from ASTM Standard due to lack of use and material availability).
* Alloy steel bolting, A193 Gr B7 bolts and A194 Gr 2H nuts can only be used at moderate temperatures depending on the permissible differential expansion of valve design which may
vary between manufacturers.
** ASTM A193 Gr B8/B8M bolting can rate from -198ºC to 800ºC, however many manufacturers of bolts and/or valves specify the narrower rating range shown.
*** For temperatures lower than -200ºC (-325ºF) ASTM A320 Gr B8/B8M bolting must be impact tested. Class 2 strain hardened required for high pressure/larger sizes (refer to
manufacturer) and low temperature service.
† All L7 bolts and Grade 7 nuts must be charpies impact tested (standard for A320 L7/L7M) for service temperature lower than -29ºC. Whilst still acceptable, A194 Grade 4 have been
withdrawn from ASTM standard due to lack of use and availability (Grade 7 is used in lieu). An ‘L’ is added as a suffix to indicate charpies testing on nuts only i.e. Gr 7L. Charpies
testing is required for 5/8” size and over as per ASTM A194 supplementary section S3 if the valve is used in service lower than -29ºC.
The above chart shows the combined temperature range, taking into account the valve and bolting material ratings. Refer to
ASTM pressure/temperature charts. For limitations of usage and strength levels refer ANSI B16.34.
Where austenitic bolting materials have be carbide solution treated but not strain hardened, they are designated Class 1 or
Class 1A. Where austenitic bolting materials have been carbide solution treated and strain hardened, they are designated Class
2. In B8 and B8M, ‘Class 2’ is recommended for higher classes 900lb and above in larger sizes depending on temperature due
to it’s higher tensile strength (carbide solution treated, strain hardened).
A193 Gr B7 and Gr L7 are acceptable for NACE (as class III NACE Bolting) service as bolting is “Non wetted parts”, however if
bolts themselves must conform to NACE, then B7M, L7M bolts are required. B8M bolting being equivalent to 316, automatically
conforms to NACE.
Temperature range of studs can vary widely depending on size, stud, manufacturer, bonnet enclosure and valve manufacturers
calculation. Also refer to ASTM standard for ‘design temperature rating’ of bolting.
For technical references and ASTM/ASME cross reference information on stainless, duplex, chrome-moly and alloy steel
.used in valves & piping systems in the petrochemical and refining
We can supply exotic grades like Nickel, Super Duplex F55 and Monel (ASTM A494-M35-1), Cd4M-Cu, Hastelloy C (ASTM
Alloy 400 Resistance to sea water and brine but can suffer crevice corrosion.
Alloy 625 Excellent sea water crevice corrosion resistance.
Alloy 825 Resistant to organic alkalis and salts, H2S and some acids.
Alloy B-2 Principally used for HCI under reducing conditions (all strengths).
Alloy C-276 Good resistance to a wide range of waters and chemicals.
Titanium and Alloys Suitable for a wide range of acids, alkalis and sea water.
PVDF, FEB, PTFE Acids, alkalis, solvents and other organic substances.
Ceramics Used for valve balls & seats wear ring. Resistant to a wide range of fluids. Care should be taken to
ensure that materials containing binders are acceptable for given duty.
Sintered Solids
Coatings
Linings and Coatings
Glass/Enamel All conditions except pure water, hydrofuoric acid and hot alkalis.
Note Holes in linings and coatings can result in severe corrosion. It is vital that the surface be correctly
prepared before coating and tested after coating.
Hastealloy ‘B’
Hastealloy ‘B’
St. St. 13%Cr.
Carbon Steel
St. St. F304
Inconel
Inconel
MEDIA MEDIA
Monel
Monel
Acetic Acid - pure C A B A A A A Creosote - crude B B A A A A A
Acetic Acid - 10% C B B A A A A Dowtherms B A A A A A A
Acetic Anhydride C B B A A A A Ethers A B A A D C B
Acetone B A A A A A A Ethyl Alcohol B B A A B B B
Alcohol Methyl (Methanol) B A A A A A A Ethyl Glycol A A A A A A A
Alcohol Methyl 65º B C C B B A A Ferric Chloride D D D D D D D
Ammonia - Conc. & Aq. Sol. B A A A B A A Ferric Sulphate D C B A C B C
Ammonia - Gas A A A A B A B Ferrous Chloride D D D C C C D
Ammonium Chloride - Still C C B B B A B Ferrous Sulphate D B B A B B D
Ammonium Nitrate B B A A C A D Fluorine D D C B B B B
Ammonium Phosphate - Sat. D B A A B A B Formaldehyde - cold B B B A A A A
Ammonium Suplhate Formic Acid D C C B B A C
1% & 5% - Agit. & Aer. C C B B D B B
Furtural B B B B B B B
Ammonium - Saturated C C C A B B B Gasoline Sour B B A A C C C
Amyl Acetate C C B B B A A Gasoline Refined A A A A A A A
Aniline C C B B B B B Gelatine D C B A A A A
Arsenic Acid - 65ºC D C B B D D D Glucose B B A A A A A
Asphalt B A A A A A A Glue - Dry A A A A A A A
Barium Chloride - Sat. C C B B B B B Glycerine A A A A A A A
Barium - Acqueous Sol. C C B A A A A Hydrolchloric Acid (Muriatic) D D D C C C B
Benzoic Acid D C A A A A A Hydrocyanic Acid C C A A C B B
Benzol B B A A A A A Hydrofluoric Acid D D D D B D B
Boric Acid D C B B A A A Hydrogen Gas B A A A A A A
Butane Gas B B B B B B B Hydrogen Peroxide D D C B B B B
Butyric Acid D A B A B B B Hydrogen Sulphide - Dry B B A A A A A
Calcium Bisulphite D C C B D D C Hydrogen Sulphide - Wet C C B A B A A
Calcium Carbonate D C B A B B B Iodine - Dry - Wet D D D D A A C
Calcium Chloride C C C B A B B Kerosene B A A A A A A
Calcium Hypochlorite D D C C C B B Laquer Solvents B B A A B A A
Carbon Tetrachloride C C B A A A B Lactic Acid - 1% D B A A C A B
Carbonic Acid D C B A B A A Lactic Acid - 5% D B A A C A A
Chlorine - Dry Gas B B B B B A B Lactic Acid - 5% - Boiling D D C B D B B
Chlorine - Moist. D D D D D D D Lactic Acid - 10% - 65ºC D D C B C B B
Chromic Acid C C B A B B D Lactic Acid - Conc. - 21ºC D D D D D B B
Citric Acid - 5% - Still D A A A A A A Lime Sulphur A A A A B B B
Citric Acid - Sat. D D C B B B A Linseed Oil B B B B B B B
Copper Nitrate D D A A D C D Lubricating Oil - Sour C B A A C B B
Copper Sulphate D C B A C D C Lubricating Oil - Refined A A A A B A A
Hastealloy ‘B’
Hastealloy ‘B’
St. St. 13%Cr.
Carbon Steel
St. St. F304
Inconel
Inconel
MEDIA MEDIA
Monel
Monel
Magnesium Chloride D C B B A A A Sodium Bicarbonate C C A A B B B
Magnesium Hydroxide B B A A A A A Sodium Carbonate - 5 - 50% B B A A B A A
Magnesium Sulphate B C B B A B A Sodium Chloride C C B A A A B
Mecuric Chloride D D D C D D C Sodium Cyanide B C B B B B B
Mercury B B A A B A A Sodium Hydroxide C C B A A A A
Methane Gas B B B B B B B Sodium Hypochlorite D D C B C C B
Methylethylketone A A A A A A A Sodium Nitrate B B B A B A D
Milk (Fresh or Sour) D B A A A A A Sodium Phosphate (di - Basic) C C B B B B B
Naphtha (Crude or Pure) B B A A B A B Sodium Phosphate (tri - Basic) B B B B B A B
Natural Gas B A A A A A A Sodium Sulphate B B B A A B D
Nickel Chloride D C B B B B A Sodium Sulphide B B B A A A D
Nickel Sulphate D D B B B B D Steam A A A A A A A
Nitric Acid - Crude D D C B D B D Stearic Acid - Conc. C C A A B A A
Nitric cid - 5 - 50% D D B B D B D Sulphur - 260ºC - Molten C B A A A A B
Nitric Acid - Conc. 21ºC D D A A D B D Sulphur Dioxide B B A A B B B
Nitric Acid - Conc. Boiling D D D D D D D Sulphuric Acid - <10% D D D C B B A
Nitric Acid - Fuming Conc. 43ºC D D C C D D D Sulphuric Acid - 50% - 21ºC D D D D B B A
Nitric Acid - Fuming Conc. Boiling D D D D D D D Sulphuric Acid - 50% - Boil. D D D D C D A
Nitrobenzene D D B A B B A Sulphuric Acid - Con. - 21ºC B B B A D D A
Oil - Miner. & Veget B B A A B C B Sulphuric Acid - 149ºC D D D D D D D
Oxalic Acid 10% - 21ºC C C A A B B B Sulphuric Acid - Fuming D D C B D D A
Oxlic Acid - 10% - Boiling D D D C B A B Sulphurous Acid - Sat. D D C B D D D
Oxygen B A A A A A A Sulphurous Acid - Spray D D C C D D D
Petroleum Oils - Crude B A A A A A A Tannic Acid - 10% D D B A B B B
Phosphoric Acid - Crude D D D D D B A Tannic Acid - 10% - Boil. D D C B C C B
Phosphoric Acid - 5% & Boiling D D C A B A A Tar B A A A A A A
Phosphoric Acid - 10% Still D C B A C A A Tartatic Acid - 21ºC D C B A A A B
Phosphoric Acid - 10% Agitated D D C B D A A Tartatic Acid - 65ºC D D B A B A B
Phosphoric Acid - 10% Aer. - Boil. D D D C D B A Trichlorethylene C C B B D D B
Picric Acid C C A A D D B Turpentine B B A A A A A
Potassium Chloride D D C B A A B Tomato Juice C B A A A A A
Potassium Cyanide B B B B B B B Vinegar D A A A A A A
Potassium Hydroxide - 5% - Still B B A A A A A Water (Fresh) C A A A A A A
Potassium Hydroxide - 50% - Boil. D D B A A A A Water Distilled (Labor. Grade) D D A A B A A
Potassium Nitrate B A A A B B C Water Distilled (Return. Cond.) B A A A B B C
Propane Gas B A A A A A A Zinc Chloride D D D B B B B
Sea Water D D B A A A A Zinc Sulphate D C B A A B B
Soap Solution A A A A A A A
A = Good resistance B = Satisfactory C = Poor D = Not recommended
This table is intended as a general guide only and does not imply guarantee of service performance. Final selection of material should
be dictated by the specific environmental requirements. Factors such as:- temperature, valve type, pressure, flow conditions, other
trim components, valve brand, etc., can ll have significant effect on material selection hence this is only a rough guide. Furthermore,
recommendations vary between manufacturers.
If we don’t have the valve in stock we can source it from overseas network of stockists and very short lead-time specialty manufacturers. We
can supply exotic grades like Nickel, Super Duplex F55 and Monel (ASTM A494-M35-1) Cd4M-Cu, Hastelloy C (ASTM A-494 CW12MW), 317
(C8G8M) in short lead-time.
We stock valves in A105, LF2, 304, 304L, 316, 316L, F51, CF8, CF3, CF8M, WC5, WC6, F11, F5, F22 Bronze, Iron, etc., in Ball, Butterfly,
Check, Control, Gate, Globe, Needle, Parallel slide, Plug, etc. Valves are manufactured to API600, API602, API603, API6A, API6D, BS1868 and
numerous other standards.
Ranking numbers can be used to make a preliminary selection of the materials for certain applications. However,
practical trials may be necessary in many cases, with due consideration of the operational conditions and the
function to be fulfilled by the component. For a sufficiently reliable assessment of the durability of a material,
parameters such as pressure, temperature, composition of the medium, concentration and pH value should all be
taken into account.
Austenitic steel
Austenitic steel
ºC Temperature
ºC Temperature
Grey/malleable
Grey/malleable
NBR/Perbunan
NBR/Perbunan
(1.4571) 316Ti
(1.4571) 316Ti
Carbon steel
Carbon steel
PTFE/Teflon
PTFE/Teflon
MEDIA MEDIA
FKM/Viton
FKM/Viton
cast iron
cast iron
Mass per Mass per
Bronze
Bronze
EPDM
EPDM
unit volume unit volume
in % in %
Acetaldehyde Liquid 20 3 3 1 2 2 3 3 1 Carbonic acid Aqueous solution 20 3 3 1 1 1 1 1 1
Acetic anhydride Liquid 20 3 3 1 3 3 3 3 1 Aqueous solution
Castor oil 20 2 2 1 1 3 1 1 1
Liquid
Acetone Liquid 20 1 1 1 1 1 3 3 1
Chlorine, dry Gas 20 1 1 1 2 1 3 1 1
Acetylene Gas 20 1 1 1 3 1 1 1 1 Chlorine water,
Aqueous solution 20 3 3 3 3 1 3 1 1
Acrylonitrile Liquid 20 1 1 1 1 1 3 2 1 saturated
Chlorine, wet Gas 20 3 3 3 3 3 3 1 1
Aluminium chloride 26% solution 20 3 3 3 3 1 2 1 1
Chloroform, dry Liquid 60 2 2 1 2 3 3 2 1
Aluminium sulphate 10% solution 20 3 2 1 3 1 1 1 1
Chlorosulphuric acid,
Ammonia, anhydrous Gas 20 2 1 1 3 1 2 3 1 10% solution 20 2 2 2(L) 2 3 3 3 1
dry
Ammonia, aqueous 30% solution 20 1 1 1 3 1 2 3 1 Chlorosulphuric acid,
10% solution 20 3 3 3 3 3 3 3 1
wet
Ammonium carbonate 20% solution 20 3 3 1 3 1 1 3 1 Chromic acid 10% solution 30 3 3 1 3 (1) 3 1 1
Ammonium cholride 10% solution 20 3 3 1(L) 3 1 1 1 1 Copper acetate Aqueous solution 20 3 3 1 3 1 1 1 1
Ammonium Copper sulphate Aqueous solution 20 3 3 1 2 1 1 1 1
10% solution 20 2 2 1 1 1 1 1 1
monophosphate
Cresols Aqueous solution 20 2 2 1 3 3 3 1 1
Ammonium nitrate Aqueous solution 100 3 3 1 3 1 2 1 1
Cutting oil Liquid 20 2 2 1 2 3 1 1 1
Ammonium sulphate 50% solution 20 3 3 1 2 1 1 1 1
Diesel fuel Liquid 20 1 1 1 1 3 1 1 1
Amyl acetate 50% solution 20-130 2 2 1 2 1 3 3 1
Diethylamine Liquid 25 1 1 1 3 1 2 3 1
Anline Liquid 20-60 1 1 1 1 3 3 1 1
Ethane Gas 20 2 2 2 1 3 1 1 1
Apple juice Liquid 20 3 3 1 3 1 1 1 1
Ethanoic acid 25% solution 20 3 3 1 3 1 3 3 1
Asphalt Liquid 20-80 2 2 1 1 1 3 1 1
Ethanoic acid,
Barium carbonate 20% solution 20 2 2 1 1 1 1 1 1 Liquid 20 3 3 1 2 1 1 1 1
anhydrous
Barium chloride 10% solution 20 3 2 1(L) 2 1 1 1 1 Ether Liquid 20 2 1 1 1 2 3 3 1
Barium sulphate Aqueous solution 20 3 3 1 1 1 1 1 1 Ethyl acetate Liquid 20 3 2 1 3 3 3 3 1
Beer Aqueous solution 20 3 3 1 1 1 1 1 1 Ethyl alcohol Liquid 20 2 2 1 1 1 1 3 1
Beet sugar liquor Aqueous solution 20 2 2 1 1 1 1 1 1 Ethyl chloride, dry Gas 20 2 2 1(L) 2 3 2 2 1
Benzaldehyde Liquid 20 3 3 1 2 1 2 1 1 Ethyl chloride, wet Gas 20 3 3 1 3 3 2 2 1
Benzene Liquid 20 1 1 1 1 3 2 1 1 Ethylene glycol Liquid 20 2 2 1 2 1 1 1 1
Benzoic acid Liquid 20 2 2 1 1 1 1 1 1 Fatty acids Liquid 150 3 3 1 2 3 3 1 1
Benzol Liquid 20 1 1 1 1 3 3 1 1 Fluorine, anhydrous Gas 20 1 1 1 1 1 3 1 1
Boric acid 50% solution 20 3 3 1 2 1 1 1 1 Formaldeyd 40% solution 60 3 3 1 1 1 3 2 1
Brines 10-15% solution 20 3 3 2 2 1 1 1 1 Formic acid 50-100% solution 20-70 3 3 1 2 2 3 3 1
Bromine, wet Liquid 20 3 3 3 2 1 3 1 1
Freons, anhydrous Liquid 20 2 2 1 1 1 3 3 1
Butane Gas 20 2 2 1 1 2 1 1 1
Fruit juices Aqueous solution 20 3 3 1 2 1 1 1 1
Buttermilk Aqueous solution 90 3 3 1 3 1 1 1 1
Furfural Gas 20 2 2 1 1 3 3 3 1
Butyl acetate Liquid 20 1 1 1 1 2 3 3 1 Aqueous solution,
Glucose 20 2 2 1 1 1 1 1 1
Butyric acid Solution 100 3 3 1 3 1 2 1 1 conc.
Aqueous solution, Glycerol Liquid 20 2 2 1 1 1 1 1 1
Calcium carbonate 20 2 2 1(L) 2 1 1 1 1
saturated Glycols Liquid 20 2 2 1 1 1 1 1 1
Calcium chloride 25% solution 20 3 3 1 2 1 1 1 1
Heating oil, heavy Liquid 20 2 2 1 2 3 2 1 1
Calcium
4% solution 20 3 3 2 2 1 1 1 1 Heating oil, light Liquid 20 2 2 1 2 3 1 1 1
hydrogensulphite
Calcium hydroxide Aqueous solution 20 1 1 1 1 1 1 1 1 Heptane Liquid 20 2 2 1 1 3 1 1 1
Calcium sulphate 10% solution 20 3 3 1 2 1 1 1 1 Hydralic fluid Liquid 20 2 2 1 2 3 1 1 1
Carbolic (phenic) acid 90% solution 20-100 3 3 1 2 3 3 1 1 Hydrobromic acid Aqueous solution 20 3 3 3 3 1 3 1 1
Hydrochloric acid 10% solution 20 3 3 3 3 1 2 1 1
Carbon dioxide, dry Gas 20 1 1 1 1 1 1 1 1
Hydrochloric acid 32% solution 20 3 3 3 3 1 2 1 1
Carbon disulphide Gas 50 2 2 1 3 3 3 1 1
Hydrofluoric acid 60% solution 20 3 3 3 3 1 1 3 1
Carbon tetracholride,
Liquid 20 2 2 1(L) 2 3 3 1 1
wet Hydrogen Gas 20 2 2 1 1 1 1 1 1
1 = very suitable 2 = suitable 3 = not advisable L = risk of pitting corrosion S = risk of crevice corrosion
Austenitic steel
Austenitic steel
ºC Temperature
ºC Temperature
Grey/malleable
Grey/malleable
NBR/Perbunan
NBR/Perbunan
(1.4571) 316Ti
(1.4571) 316Ti
Carbon steel
Carbon steel
PTFE/Teflon
PTFE/Teflon
MEDIA MEDIA
FKM/Viton
FKM/Viton
cast iron
cast iron
Mass per Mass per
Bronze
Bronze
EPDM
EPDM
unit volume unit volume
in % in %
Hydrogen peroxide 30% solution 20 3 3 1 3 1 3 1 1 Potassium dichromate 30% solution 20 3 3 1 3 1 2 1 1
Iron(III) chloride 10% solution 50 3 3 3 3 1 1 1 1 Potassium
20% solution 20 1 1 1 2 1 1 1 1
Iron nitride Aqueous solution 20 3 3 1 3 1 1 1 1 disphosphate
Potassium hydroxide Molten 360 2 2 1 3 3 3 3 3
Iron(III) sulphate 10% solution 20 3 3 1 3 1 1 1 1
Potassium hydroxide 70% solution 100 2 2 1(S) 3 2 3 2 1
Isopropyl alcohol Liquid 20 2 2 1 1 1 2 1 1
Potassium sulphate 50% solution 50 3 3 1 2 1 1 1 1
Isopropyl ether Liquid 20 2 1 1 1 1 2 2 1
Producer gas Gas 20 2 2 1 2 1 1 1 1
Kerosine (paraffin) Liquid 20 1 1 1 1 3 1 1 1
Propane Gas 20-80 2 2 1 1 1 1 1 1
Lemon juice 15% solution 20 3 3 1 1 1 1 3 1
Propanol (propyl
Lactic acid 10-50% solution 20 3 3 1 2 3 1 1 1 Solution 20 2 2 1 1 1 1 1 1
alcohol)
Lead acetate 25% solution 20 3 3 1 3 1 1 1 1 Propylene glycol Liquid 20 2 2 1 1 1 2 1 1
Lighting gas Gas 20 1 1 1 1 3 1 1 1 Salicylic acid 20% solution 20 3 3 1 2 1 1 1 1
Linseed oil Liquid 20 1 1 1 1 3 1 1 1 Seawater Aqueous solution 20 3 3 1 1 1 1 1 1
Magnesium sulphate 10% solution 20 3 3 1 1 1 1 1 1 Soap solution 10% solution 20 2 1 1 1 1 1 1 1
Maleic acid 50% solution 100 3 2 1 3 1 1 1 1 Sodium acetate Aqueous solution 20 3 3 2 2 1 2 1 1
Methane Gas 100 2 2 1 1 2 1 1 1 Sodium aluminate Aqueous solution 20 2 2 1 2 1 1 1 1
Methyl acetate Solution 20 2 2 1 1 3 3 3 1 Sodium bisulphite 50% solution 20 3 3 1 2 1 1 1 1
Methyl alcohol Liquid 20 2 2 1 2 1 2 2 1 Sodium bromide 10% solution 20 3 3 2(L) 2 1 1 1 1
Methyl chloride Gas 100 2 2 1 1 1 3 1 1 Sodium chloride 20% solution 20 3 3 1 2 1 1 1 1
Methyl cellulose Aqueous solution 20 2 2 1 1 3 3 2 1 Sodium chromate 20% solution 20 2 2 1 2 1 1 1 1
Methylene chloride Liquid 20 3 3 1(L) 3 3 3 1 1 Sodium hydroxide 70% solution 20 2 2 1 3 2 1 1 1
Milk Liquid 20 3 3 1 1 1 1 1 1 Sodium meta-
10% solution 20 2 2 1 2 1 1 1 1
phosphate
Mineral oil Liquid 20 2 2 1 2 3 1 1 1
Sodium metasilicate 10% solution 20 3 3 1 2 1 1 1 1
Molasses Liquid 20 3 3 1 1 1 1 1 1
Sodium peroxide 10% solution 20 3 3 1 3 1 3 1 1
Naphtha Liquid 20 2 2 1 2 3 1 1 1
Sodium sulphate 20% solution 20 3 3 1 3 1 1 1 1
Nickel sulphate Aqueous solution 20 3 3 1 2 1 1 1 1
Sodium sulphide 25% solution 20 3 3 1 3 1 1 1 1
Nitric acid 30% solution 20 3 3 1 3 2 3 1 1
Sodium thiosulphate 25% solution 20 3 3 1 3 1 3 1 1
Nitric acid 100% solution 20 3 3 1 3 3 3 3 1
Steam (water vapour) Saturated steam 100 1 1 1 1 1 3 2 1
Nitrobenzene Liquid 20 2 2 1 2 3 3 3 1
Sulphur Molten 130 2 2 1 3 3 3 1 1
Nitrous fumes Gas 100 3 3 1 3 3 3 3 1
Sulphuric acid 7% solution 20 3 3 1 3 1 1 1 1
Oil (crude oil, sour) Liquid 20 3 3 1 3 3 1 1 1
Sulphuric acid 50% solution 20 3 3 3 3 1 1 1 1
Oil (fish oil) Liquid 150 2 2 1 1 3 1 1 1
Sulphuric acid 98% solution 20 2 2 1 3 3 3 2 1
Oil (lubricating oil) Liquid 20 1 1 1 1 3 1 1 1
Stearic acid Liquid 100 3 3 1 2 1 1 1 1
Oil (mineral oil,
Liquid 20 2 1 1 1 3 1 1 1 Sugar solution 10% solution 20 2 2 1 1 1 1 1 1
refined)
Oleic acid: see fatty Tartaric acid 50% solution 20 3 3 1 3 1 1 1 1
Liquid 150 3 3 1 3 3 3 1 1
acid
Tetraethyl lead Liquid 20 3 3 1 2 3 3 3 1
Oleum Liquid 20 3 2 2 2 2 3 1 1
Tin(II) chloride 20% solution 20 3 3 3 3 1 1 1 1
Olive oil Liquid 100 2 2 1 1 3 2 1 1
Toluol Liquid 20 1 1 1 1 3 3 2 1
Oxalic acid 25-50% solution 20 3 3 1 3 1 1 1 1
Tomato juice Aqueous solution 20 3 3 1 3 1 1 1 1
Oxygen Gas 20 2 2 1 1 1 2 1 1
Transformer oil Aqueous solution 20 2 1 1 2 3 1 2 1
Ozone, dry Gas 20 1 1 1 1 3 3 1 1
Trichloroethylene Aqueous solution 20 2 2 1(L) 2 3 3 1 1
Ozone, wet Gas 20 3 3 1 2 3 3 1 1
Turpentine Liquid 100 2 2 1 1 3 1 1 1
Palm oil Liquid 100 3 3 1 2 3 2 1 1
Aqueous solution,
Pentane Gas 100 2 2 1 1 3 1 1 1 Urea 20 2 2 1 2 1 1 1 1
conc.
Perchloroethylene Liquid 20 2 2 1(L) 3 3 3 1 1 Vegetable oil (edible) Liquid 20 2 2 1 1 3 1 1 1
Petroleum jelly Liquid 20 2 2 1 2 3 1 1 1 Water, distilled
Liquid 20 3 3 1 1 1 1 1 1
(carbonic)
Phenol 80% solution 100 3 3 1 2 3 3 1 1 Water (make-up
Liquid 20 2 2 1 1 1 1 1 1
Phosphoric acid 10% solution 20 3 3 1 2 1 1 1 1 water)
Wax emulsion Aqueous solution 50 2 1 1 1 3 1 1 1
Phosphoric acid 50% solution 20 3 3 1 2 1 1 1 1
Xylol Liquid 20 2 2 1 1 3 3 1 1
Potassium carbonate 50% solution 20 2 2 1 2 1 1 1 1
Aqueous solution, Zinc sulphate 20% solution 20-100 3 3 1 2 1 1 1 1
Potassium chlorate 100 3 3 1 2 1 3 1 1
saturated
1 = very suitable 2 = suitable 3 = not advisable L = risk of pitting corrosion S = risk of crevice corrosion
DISCLAIMER:- This is a general overview. Information provided should not be used to make you operational or design decision. We accept no responsibility for the information and do not guarantee correctness. Factors such as trim materials, bolting, gaskets, seals, carbon content, heat treatment, etc., can vary temperature rating. Refer to actual
ASTM P/T charts as only short term use at high temperatures is allowed in some cases. Ratings shown may vary dependant upon different combinations of materials, sizes and service applications where different safety factors may apply. These tables shown are standard class - A, special class - B (high ratings) refer to ANSI B16.34 - 2009.
A105/WCB/LF2/LF3 1.1 19.60 29.40 21.56 51.10 76.65 56.21 102.10 153.15 112.31 136.10 204.15 149.71 153.00 229.4 168.3 255.30 382.95 280.83 425.50 638.25 468.05
WCC/LCC 1.2 19.80 29.70 21.78 51.70 77.55 56.87 103.40 155.10 113.74 137.83 206.75 151.62 155.00 232.50 175.00 258.60 387.90 284.46 430.9 646.35 473.99
LCB 1.3 18.40 27.60 20.24 48.00 72.00 52.80 96.00 144.00 105.60 127.97 191.95 140.76 144.00 216.00 158.40 240.10 360.15 264.11 400.10 600.15 440.11
F11/WC6 1.9 19.80 29.70 21.78 51.70 77.55 56.87 103.40 155.10 113.74 137.83 206.75 151.62 155.00 232.50 170.50 258.60 387.90 284.46 430.9 646.35 473.99
F22/WC9 1.10 19.80 29.70 21.78 51.70 77.55 56.87 103.40 155.10 113.74 137.83 206.75 151.62 155.00 232.50 170.50 258.60 387.90 284.46 430.9 646.35 473.99
F5a/C5 1.13 20.00 30.00 22.00 51.70 77.55 56.87 103.40 155.10 113.74 137.83 206.75 151.62 155.00 232.50 170.50 258.60 387.90 284.46 430.9 646.35 473.99
F5/F12 1.17 19.80 29.70 21.78 51.70 77.55 56.87 103.40 155.10 113.74 137.83 206.75 151.62 155.00 232.50 170.50 258.60 387.90 284.46 430.9 646.35 473.99
F304/F304H/304/CF10/CF8 2.1 19.00 28.50 20.90 49.60 74.40 54.56 99.30 148.95 109.23 132.37 198.55 145.60 148.80 232.20 163.70 248.20 372.30 273.02 413.70 620.55 455.07
F316/F316H/F317/316/CF3A/
2.2 19.00 28.50 20.90 49.60 74.40 54.56 99.30 148.95 109.23 132.37 198.55 145.60 148.80 232.20 163.70 248.20 372.30 273.02 413.70 620.55 455.07
CF10M/CG3M/CF8A/CF8M/CG8M
F316L/F317L/304L/316L/TP304L/
2.3 15.90 23.85 17.49 41.40 62.10 45.54 82.70 124.05 90.97 110.24 165.36 121.26 124.00 186.00 136.40 206.80 310.20 227.48 344.70 517.05 379.17
CF3/CF3M
F347/347/CF8C 2.5 19.00 28.50 20.90 49.60 74.40 54.56 99.20 144.88 109.10 132.30 198.40 145.50 148.80 232.20 163.70 248.80 372.10 272.8 413.40 620.10 454.7
F51/F55/F53/S31254/S31803/
S32760/CK3MCuN/CE8MN/CD3MN/ 2.8 20.00 30.00 22.00 51.00 76.50 56.10 103.40 155.10 113.74 137.83 206.75 151.62 258.40 387.60 284.80 258.60 387.90 284.46 430.6 645.90 473.70
CD3MWCuN/A995 Gr. 4A/5A/6A
N04400/M35-1/M35-2 MONEL 400 3.4 15.90 23.85 17.49 41.40 62.10 45.54 82.70 124.00 90.90 110.20 165.40 121.30 124.00 186.00 136.40
CN7M 3.17 15.90 23.85 17.49 41.40 62.10 45.54 82.70 124.00 90.90 110.20 165.40 121.30 124.00 186.00 136.40