S.R./Chem-11/S.S.-IU/04.02.

2023

Subject: Chemistry (043) 2nd Semester nination 2022-23 Time:-3 hrs.

Standard: - 11th Science (A,B,C) M. M.:- 70

General Instructions:
) There are 35 questions in this
question paper with internal choice. All questions are
Section A consists of 18 multiple choice questions carrying 1 mark eac.
compuiso
(i)
(ii) Section B consists of 7 very short answer questions carrying 2 marks eac.
(iv) Section C Consists of 5 short answver questions
carrying 3 mnarks each.
(v) Section-D Consists of 2 case-based questions
(vi)
carrying 4
marks each.
Section - E consists of 3 long answer questions carrying 5 marks each.

(vii) Use of log tables and calculators is not allowed.

SECTION - A [1 Marks Each]

1. If the concentration of ghucose (C,H,0,)in blood is 0.9 gt'what will be the molarity of glucose
in blood?

(a) 5 M (b) 50 M (c) 0.005 M (d) 0.5 M

2 The total number of atomic orbitals in fourth energy level of an atom is:
(a) 4 (b) 8 () 16 (d) 32
3. Which of the following is the correct order of size of the given species?
(a) I>I>1' (b) I > >F
l (d)T>l>r
4. The correct order of electronegativities of N,0,F and P is
(a) F>N> P>0 (b) F>0> P>N () F>0>N>P (d) N>0>F>P

5. Which of the following species has tetrahedral geometry?

(a) BH (b) NH (c) co (d) H,0
6. Predict the sign of AS° for the following reaction:

2H,Sg)+30,(8)--2H,o(s)+250,(8)
(a) +ve
(b) - ve
(c) zero (d) Cannot be predicted
7. The enthalpies of elements in their standard states are taken as zero. The enthalpy of formation

of a compound:
(a) is always negative (b) is always positive
(c) may be positive or negative (d) is never negative.
Acidity of BF can be explained on the basis of which of the following concepts?
8.
Arrhenius concept (b) Bronsted Lowry concept
(a)
Lewis concept (d) Bronsted Lowry as well as Lewis concept
(c)
9 For the reversible reaction
N,(s)+3H,(e)2NH,(g) AH = -ve
forward direction.
The equilibrium shifts in the
concentration of NH, (g).
(a) By increasing the
(b) By decreasing the pressure.
concentration of N,(g) and H, (g).
(c) By decreasing the
(d) By increasing pressure
and decreasing temperature.
 10. In the reaction C7, +Oll

(a) Chlorine is oxidized

(b) Chlorine is reduced
(c) Chlorine is oxidized as well as reduced
(d) Chlorine is neither oxidized nor reduced
11, lonic species are stabilized by the dispersal ot
charge. Which of the following carboxylate ion is
the most stable?

(a) CH,-C-®
(b) CICH,-C-

(c)F-CH,-C-0 d) CH-C-

12. Heterolysis of a carbon- chlorine bond produces.

(a) Two free radicals
(b) Two carbocations
(c) One cation and one anion
(d) Two carbanions.
13. Which is the most stable carbocation?

(a) (CH,)C CH,

(b) CH () (d) (CH,), H
14. Which of the following is not in accordance to lUPAC name?
(a) Br-CH,-CH =CH, (1 - bromoprop-2-ene)

CH,

(b) CH,-CH C -CH, - CH -CH, (4-bromo-2,4- dinmethyl hexane)

Br CH

(c) CH- CH -CH-CH, - CH, (2-methyl-3-phenyl pentane)

cH,

(d) CH,-C-CH, -CH, -CH, -COOH (5- oxo hexanoic acid)

estion no. 15 to 18 consist of two (A) and Reason (R). Answer
these questions selecting the statements
ents
labelled as Assertion
(a) Both A and R are true and
appropriate option given belotw:
R is the correct
(b) Both A and R are
true but R is not the
explanation of A.
correct
(c) A is true but R is explanation of A.
false.
(d) A is false and R is
true.

15. ASsertion: An orbital connot have more than two electrons and their spin must be sit
Keason: No two electrons in an atom can have same set of all the four quantum numbe
16. Assertion: F- atom has less
negative electron gain enthalpy than Cl atom.
Reason: Additional electrons are repelled more effectively by 3p electrons in a y
electrons in F atom.
17. Assertion: Pent -1-ene and pent -2-ene are
position isomers.
Reason: Position isomers differ in the position of functional group or a substituent.
18. Asscrtion: The ionic size of O* is bigger than that of F"ion.
Reason: O' and F°are isoelectronic ions.

SECTION-B 2 Marks Each]

19. (a) Arrange the following orbitals in the increasing order of energy.
5p, 4d, 5d, 4f, 6s
Indicate the number of unpaired electrons in P (Z-15).
(b)
Why is the first ionization enthalpy of nitrogen greater than that of oxygen?
20. (a)
Noble gases have high positive valucs of electron gain enthalpics.
(b)
21. Calculatc the pH of the resultant mixtures.
10 ml of 0.2 M Ca (0H), +25 ml of 0.1 M HCI[log 10 =1, log 4.3-0.631]
OR

At 450 K, K, =2.0x10"bar for the given

reaction 2S0,(g)+O,(3)-2S0,(g)at equilibrium
What is Kçat this temperature?
Addition of H,, (ii) addition of CH,OH (ii) remova! of CO, (iv)
22 Describe the effect of (i)
of the reaction: 2H,(s)+COlg) = = CH,OH(g).
removal of CH,OH, on the equilibrium
23. Balance the following equation:
BrO +H,O(in acidicmedium)
Br +H,O,
OR

N,H,()+CI0, (aq) NO(g)+Cl (ag). (in basic medium)

reaction
24. Complete the
(a) CH,-C =CH-CH;

CH
CH,C= CH+ H,OHeL
(b) will have higher b.pt and why?
hex -2 ene. Which isomer
trans isomers ot
25. Draw the cis and
 13 Marks Iaci
SECTION - C
n.
26, (a) The electronic configuuration of valence shell of Cu is 3"4s'and not 3d 4s A
Write the four quantum numbers lor 21" electron of ,Se.
(b)
(c) How many electrons in sulphur (Z =16)can have n +l =3?

27. Commercially available concentrated hydrochloric acid contains 38'% HCI by mass.

(a) What is the molarity of the solution? The density is 1.19g cm".

(b) What volume of concentrated hydrochloric acid is required to make 1.00 L of 0.10M Hl

[At mass: Cl =35u,H = lu]

28. (a) Arrange the following in order of decreasing bond angles NH, NH2, Hi.

(b) On the basis of VSEPR explain the non -linear

shape of H,S.
(c) Arrange the following in increasing order of bond - length stating reason,.
C-C, C=C, C=C.
29. Calculate the standard enthalpy of formation of CH,OH ()from the following data:

(a) CH,OH(?)+20, («)co,(«)+2H,0)} a,1°=-726 k/ mol

(b) C+0 («)>co,(g) A,1°= -393kJmof"
(c) H,s)+;0,«)>H,00) A,1° -286k/mol" -

OR
What is the value of equilibrium constant for the following reaction at 400 K?
2NOCI (g)-2N0(s)+ CI, (8)
AH = 17.5kJ mol", R=8.314J mol K, As° =135 JK mol

Anti log of .06 1148, Anti log of .94 - 8710]

30. (a) The value of Kc in the reaction:

24 B+C is 2x10. At a given time the composition of reaction mixture is

4-B=C]=3x10*M. In which direction the reaction will proceed?
()Calculate the pH of 10 M HCI solution. [log 1.1=0.0414, log 10 1]

SECTION - D 4 Marks ach]

31. Dipole moment depends upon polarity and shapes of molecuies. Shapes of molecules can be

determined by VSEPR theory as well as hybridization. Hydrogen bond is formed between

hydrogen and F, O, N. Intramolecular H -bonding is within the molecules which is weaker than

intermolecular H- bonding between the molecules.

(a) Why does CO, have zero dipole moment?

(b) Why do all bonds in CO have equal bond length?
(c) Draw the shape of the following moiecules on the basis of VSEPR theory: SP,and H,0.
 OR
()i) Which hybrid orbitals are used bycarbon in the following molecule

CH=CH-C= N.
i) Why is H,0 aliquid whereas H,Sis a
gas?
Fiydrocarbons are compounds of carbon and hvdrogen. Can be classiied as hain,
Saturated (alkanes) unsaturated (alkenes and alkynes), cyclic (alicyclic) and aromatic based on

structure.
DelZene and benzenoid show aromatic character. Thev follow Huckel's rule (4n +2)Telectrons
W e n must be delocalized. The presence of activating and deactivating groups decide the

position of the electrophile after electrophilic substitution.

NO2 CH

(a) Out of . NO2 which will undergo nitration most easily and why?

Huckel's rule?
( Which of the following compounds are aromatic according to

(B) =CH,

the mechanism of the reaction.

(c) Addition of HBr to propene yiclds 2-bromopropane. Give
OR
substitution reactions easily and
) ) Why does benzene undergo electrophilic
nucleophilic substitutions with difficulty?
of alkene. What is the
Gi) Propanal and pentan -3 -one are the ozonolysis products an

slructural formula of the alkene?

SECTION E 5 Marks Each]

For the reaction: 2No(g)+0, (s) 2NO,(g)the enthalpy and entropy changes are
33. (a)
Find the temperature at which this reaction is
-113.0. kJ mol and 145 JK" respectively.
spontaneous.
Comment on the thermodynamic stability of NO(g) and NO, (g)given:
(b)
N,(s)0.(e)> No(s) a,H°=90 kJ mol"

Nolg)+50,e) NO,(«) a,1° = -74k mol"

work done system, it lost 120 J of energy as heat. Calculate the
When 430 J of was on a

value of internal energy for this process.

34. (a) Equal volumes of 0.002 M solutons of sodium iodate (alO,) and copper chiorate

Cu(CIo,).Jare mixed together. Wil it lead to the precipitation of copper iodate.

Cu(1O,),1? [For copper iodate A= 7,4x 10"]

(b) Why do we pass H,S in presence Or HCl in

group lI in salt analysis?
() Write the conjugate acid and conjugate base for the
species (i) HCO;, (i) NH,
OR
(a) The ionization constant of acetic acid is 1.74x
10 Calculate the degree of dissociation of
.

acetic acid in 0.05M solution. Calculate the concentration of

acetate ions in solution and
the pH of the solution. [log 9.3 0.97]

b) A solution of NH,Cl in water shows pH less than 7. Explain.

(c) Which of the following are Lewis acids: H,0, BF, H',
NH.
35. (a) Which is expected to be more stable:
0,NCH CH,0 or CH,CH,0 and why?
(6) Arrange benzene, n-hexane and ethyne in decreasing order of acidic behavior, giving
reason for this behavior.
(c) Draw the resonating structures of C,H,CHO (Benzaldehyde) and indicate whether it
exhibits + R or- R effect.

(d) Amongst the following isomeric alkanes arrange them in

decreasing order of their boiling
points stating reason.
CH CH
CH,-CH - CH - CH,, CH, - C - CH,, CH, - CiH, -CH, -CH, -CH;.

CH
Complete the reaction:
(CHC= CiH.Ku
OR
(a) Convert benzene into
acetophenone.
(b) Complete the reaction: CH,COONa + NaOH .
But-1 yne isweakly acidic but -2-yne is
-

not.
(d) Draw the
resonating slructure of C,ll,0H (phenol). Will it show ortho, para or meta
directing iníluence for electrophilic substitution rexn.
(e) Write the product formed by addition reaction of hex -1-ene with HBr in the
presence of
peroxide.
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