CHEMISTRY PRA PSPM 2 SET 3

SK025 KOLEJ MATRIKULASI KEDAH

2022/2023

KOLEJ MATRIKULASI KEDAH

BAHAGIAN MATRIKULASI
KEMENTERIAN PENDIDIKAN MALAYSIA

PRA PSPM 2
SEMESTER II, SESI 2022/2023

KIMIA
2 jam

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

ARAHAN KEPADA CALON:

Kertas ini mengandungi 6 soalan. Jawab semua soalan.

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CHEMISTRY PRA PSPM 2 SET 3
SK025 KOLEJ MATRIKULASI KEDAH
2022/2023

TABLE OF RELATIVE ATOMIC MASSES

Element Symbol Proton number Relative atomic mass
Aluminum Al 13 27.0
Silver Ag 47 107.9
Argon Ar 18 40.0
Arsenic As 33 74.9
Gold Au 79 197.0
Barium Ba 56 137.3
Beryllium Be 4 9.0
Bismuth Bi 83 208.0
Boron B 5 10.8
Bromine Br 35 79.9
Iron Fe 26 55.9
Fluorine F 9 19.0
Phosphorus P 15 31.0
Helium He 2 4.0
Mercury Hg 80 200.6
Hydrogen H 1 1.0
Iodine I 53 126.9
Cadmium Cd 48 112.4
Potassium K 19 39.1
Calcium Ca 20 40.1
Carbon C 6 12.0
Chlorine Cl 17 35.5
Cobalt Co 27 58.9
Cerium Ce 58 140.1
Krypton Kr 36 83.8
Chromium Cr 24 52.0
Copper Cu 29 63.6
Lithium Li 3 6.9
Magnesium Mg 12 24.3
Manganese Mn 25 54.9
Sodium Na 11 23.0
Neon Ne 10 20.2
Nickel Ni 28 58.7
Nitrogen N 7 14.0
Oxygen O 8 16.0
Platinum Pt 78 195.1
Lead Pb 82 207.2
Protactinium Pa 91 231.0
Radium Ra 88 226.0
Radon Rn 86 222.0
Rubidium Rb 37 85.5
Selenium Se 34 79.0
Cerium Ce 58 140.1
Cesium Cs 55 132.9
Silicon Si 14 28.1
Scandium Sc 21 45.0
Tin Sn 50 118.7
Antimony Sb 51 121.8
Strontium Sr 38 87.6
Sulphur S 16 32.1
Uranium U 92 238.0
Tungsten W 74 183.9
Zinc Zn 30 65.4

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CHEMISTRY PRA PSPM 2 SET 3
SK025 KOLEJ MATRIKULASI KEDAH
2022/2023

LIST OF SELECTED CONSTANT VALUES

Ionization constant for water at 25C Kw = 1.0  10−14 mol2 dm−6

Molar volume of gases Vm = 22.4 dm3 mol−1 at STP

= 24 dm3 mol−1 at room condition

Speed of light in a vacuum c = 3.0  108 m s−1

Specific heat of water = 4.18 kJ kg−1 K−1

= 4.18 J g−1 K−1
= 4.18 J g−1 C−1

Avogadro’s number NA = 6.021023 mol−1

Faraday constant F = 96500 C mol−1

Planck constant h = 6.6310−34 J s

Rydberg constant RH = 1.097  107 m−1

= 2.18  10−18 J

Molar of gases constant R = 8.314 J mol-1 K−1

= 0.08206 L atm mol−1 K−1

Density of water  = 1 g cm−3

Freezing point of water = 0.00 C

= 273.15 K

Vapour pressure of water at 25C P H2O = 23.76 torr

UNIT AND CONVERSION FACTOR

VOLUME 1L = 1 dm3
1 mL = 1 cm3

ENERGY 1 J = 1 kg m2 s−2 = 1 N m = 1  107 erg

1 calorie = 4.184 J
1eV molecule−1 = 96.7 kJ mol−1

PRESSURE 1 atm = 760 mmHg = 760 torr = 101 325 Pa = 101 325 N m-2

TEMPERATURE 0C = 273.15 K

OTHERS 1 Faraday (F) = 96 500 Coulomb

1 Newton (N) = 1 kg m s−2

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CHEMISTRY PRA PSPM 2 SET 3
SK025 KOLEJ MATRIKULASI KEDAH
2022/2023

Answer all questions.

1. (a) The rate constant for decomposition reaction of C2H6 is X s-1.

C2H6(g) C2H4 (g) + H2(g)

(i) Write the differential rate equation for the above reaction.

(ii) Calculate the rate constant X, when 5% C2H6 is decomposing for 6.75 minutes
at temperature 500K.

(iii) Calculate the half-life for decomposition of reaction above.

[5 marks]

(b) TABLE 1, show the experiment data at temperature 25ºC for a reaction

(CH3 )3CBr + OH- (CH3 )3COH + Br-

Experiment Initial concentration (M) Reaction rate

(CH3 )3CBr OH- (M min-2)
1 0.15 0.25 3.0 x 10-3
2 0.15 0.50 6.0 x 10-3
3 0.45 0.25 9.0 x 10-3
TABLE 1

Determine the order of reaction with respect to the concentration of t-butyl bromide
and hydroxide ion. Hence, write the rate equation for this reaction.
[5 marks]

2. (a) When 40cm3 of 1.00 M HCl is added to 60cm3 1.00M NaOH in a calorimeter, the
change in temperature is 4˚C.Calculate the enthalpy of neutralization for the reaction.
(Ccal is 158 J˚C-1,cwater =4.18 Jg-1 ˚C-1,density of solution = density of water =1gcm-3)
[5 marks]

(b) By using the following standard enthalpy of combustion, calculate the enthalpy of
formation of ethyne, C2H2.

∆Hoc, C2H2 (g) = -1300 kJ/mol

∆Hoc C(s) = -394 kJ/mol

∆Hoc H2(g) = -286 kJ/mol [5 marks]

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CHEMISTRY PRA PSPM 2 SET 3
SK025 KOLEJ MATRIKULASI KEDAH
2022/2023

3. The diagram shows an electrochemical cell consist of concentrated aqueous ZnCl2 as an

electrolyte.

(a) Write half-cell equation at cathode and anode.

(b) Determine the product at cathode and anode.

(c) If 0.50A current is supply for 5 hours, calculate quantity of charge in Faraday.

[Eº Zn2+|Zn = -0.76V, Eº H2O|H2 = -0.83V, Eº Cl2|Cl-=+1.36V, Eº H2O|O2 = +1.23V]

[7 marks]

4. The reaction scheme of 1-methylcyclobutene with several reagents are given below:
CH3
Br2,CH2Cl 2 i)O 3
P Q
ii)Zn, H 2O

Br2,H2O

(a) Draw the structure of P, Q and R.

(b) Give a suitable alkyl halide and reaction condition to produce 1-methylcyclobutene.

(c) The reaction of 1-methylcyclobutene with cold dilute alkaline KMnO4 solution is
known as confirmatory test of alkene. State the observation and write the chemical
equation. [6 Marks]

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CHEMISTRY PRA PSPM 2 SET 3
SK025 KOLEJ MATRIKULASI KEDAH
2022/2023

5. Benzene can be converted to benzoic acid as shown in the reaction scheme below.
O OH

CH3CH(Br)CH3 reagent B
A
AlBr3

(a) Draw the structure of A and give the reagent B.

(b) Write the mechanism for the formation of A.

[7 Marks]

6. Compounds A and B are among isomers of C4H9Br. A reacts faster towards SN1whereas B
reacts faster towards SN2. Compound A produces C upon treatment with water while B
yields D when react with sodium cyanide.

(a) Draw the structures of A, B, C and D.

(b) Show the mechanism for the formation of C.

[7 Marks]

7.
Y

PCl5

+ conc HCl, ZnCl2

KMnO4, H Cloudy solution formed immediately
No observeable change X , C5H12O
heat

+
heat CH3COOH, H

(a) Based on the reaction scheme above, draw the structural formulae of X, Y and Z.

(b) W is isomer of X which gives positive result with alkaline iodine. Draw the structure
of W.
(c) Predict the product formed when W is heated with acidic K2Cr2O7.
[5 Marks]

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CHEMISTRY PRA PSPM 2 SET 3
SK025 KOLEJ MATRIKULASI KEDAH
2022/2023

8. (a) Refer to the reaction scheme below:

O

H3C CH2 C Cl +
KCN/H
P Q
AlCl 3

i) S
+
ii) H 3O

OH
C CH2 CH3
CH3

Draw the structures of P, Q and S and give IUPAC name for P.

(b) Given that G with molecular formula, C8H8O contain benzene ring. Upon
reaction with 2,4-DNPH a yellow precipitate formed. G also gives yellow
precipitate with alkaline iodine. Alcohol I is obtained when G react with
LiAlH4 followed by acidic hydrolysis.

(i) Deduce the structures of G and I.

(ii) Write the chemical equation for reaction of G with alkaline iodine.
[7 Marks]

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CHEMISTRY PRA PSPM 2 SET 3
SK025 KOLEJ MATRIKULASI KEDAH
2022/2023

9.
K

+
CH3CH2OH, H heat

+
i) LiAlH4 KMnO4, H
L p-isopropylbenzoic acid J
+ heat
ii) H 3O

SOCl2 NH3

pyridine heat

M N

FIGURE 1

(a) Based on FIGURE 1, draw the structures of J, K, L, M and N.

(b) Arrange the following compounds in decreasing order of acidity. Explain your
answer.

2,4-dichloropentanoic acid, 1-pentanol, pentanoic acid, 5-chloropentanoic acid,

2-chloropentanoic acid

[10 Marks]

10. (a) X and Y are isomers of amine with molecular formula C7H9N. Both X and Y have
benzene ring. When X react with nitrous acid, gas bubble is released. Y produced
an intermediate that can undergo coupling reaction to yield dye when react with
the same reagent.
(i) Deduce the structures of X and Y.

(ii) Write the chemical equation when X is treated with Hinsberg’s reagent.

(b) Arrange the following amines in order of decreasing solubility in water. Explain.
propanamine, N,N-dimethylmethanamine, N-methylethanamine

[7 Marks]

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CHEMISTRY PRA PSPM 2 SET 3
SK025 KOLEJ MATRIKULASI KEDAH
2022/2023

11. The main functional groups exist in amino acid are amino and carboxyl group.

(a) The amino acid below has pI value 6.02. Give its IUPAC name.
CH3

H3C CH CH COOH
NH2

(b) Draw the structures of the above amino acid at isoelectric point, pH = 2
and pH = 12.
[ 4 Marks]