Pool Water Testing Devices and Methods
Pool Water Testing Devices and Methods
Proper water chemistry management is important to maintain a safe healthy pool environment for patrons. Several testing kits
are available that work based on different chemistry aspects. Despite the reported accuracy and precision of certain tests, a group
of people can perform the same test at the same time and find variable results. This creates a great deal of anxiety for pool
owners.
For guidelines on proper chemistry management, local regulations often have sections dedicated to water testing. For example,
the Pennsylvania state code mandates that “testing kits shall be provided for making the necessary tests for residual disinfection
and pH.” The state code also references the required accuracy of the measurements for chlorine within 0.1 mg/L and for pH
within 0.2 pH. Commercial pools also require more frequent testing compared to residential pools due to the larger variance in
pool conditions due to bather load. For Pennsylvania, a minimum of two tests must be completed each day the pool is in use.
This paper will include a description of pool water testing basics, a comparison of chemical test equipment, and a review of
appropriate sampling techniques.
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Pool Water Testing: Devices and Methods
Colorimetric Tests
A test method where a reagent reacts with a specific analyte
in the sample to produce a color in proportion to the
concentration of the analyte (e.g. strips, OTO, DPD)
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The Langelier Saturation Index (LSI) is one way to determine water balance. It is an equilibrium model of the saturation of
water with respect to calcium carbonate. The equation factors in calcium hardness, total alkalinity, pH, and temperature to
determine this water balance. The pool manager can use the parameters measured from test results to determine the tendency of
scaling in the pool. The test results can also be compared to the pre-determined ideal levels available through the NSPF
(National Swimming Pool Foundation). The below chart from the Certified Pool Operator (CPO) handbook contains this pool
chemistry information. (Table 1.)
The test results of the chemical test kit are compared against these ideal levels and corrective actions are taken depending on the
differences between the measured and ideal values. The amount of a specific chemical to add depends on this difference. A
summary of corrective actions is found in Table 2. One note to consider is the water quality of the fill water. Most fill water
contains minerals and even a moderate amount of chloramines for disinfection of drinking water.Multiple tools to calculate the
quantity of chemicals to add are available with little operator time. An example of one of these is the online pool chemistry
calculator at www.poolcalculator.com. When the size of the pool and the test data is added, it calculates the quantity of each
chemical to add to balance the pool chemistry. Free iphone apps are also available that do the same and may also have a feature
to log pool data.
Table 1. Commonly accepted chemical parameters for pool maintenance. (CPO Handbook 2005)
Parameter Minimum Ideal Maximum Who
1.0 2.0 - 4.0 5.0 Pools, Waterparks
Free Chlorine, ppm
2.0 3.0 - 5.0 10.0 Spas
0 0 0.2 Pools, Waterparks
Combined Chlorine, ppm
0 0 0.5 Spas
Total Bromine, ppm 2.0 4.0 - 6.0 10.0 All types
PHMB, ppm 30 30 - 50 50 All types
pH 7.2 7.4 - 7.6 7.8 All types
Total Alkalinity, ppm 60 80 - 100* / 100 - 120** 180 All types
Total Dissolved Solids, ppm NA NA 1,500 over start-up All types
Calcium Hardness, ppm 150 200 - 400 1,000 Pools, Waterparks
as CaCO3 100 150 - 250 800 Spas
Heavy Metals None None None All types
Visible Algae None None None All types
Bacteria None None Local Code All types
Cyanuric Acid, ppm 0 30 - 50 *** All types
78˚F 80.5˚F 82˚F Competition Pools
Temperature ˚F - Personal Preference 104˚F Other Pools
- - 104˚F Spas
0.1 over 8-hour time wtd.
Ozone, ppm - - All types
avg.
ORP Calibrate to Disinfectant Level**** All types
† These commonly accepted chemical parameters do not supercede product label directions or local or state codes and regulations.
* For calcium hypochlorite, lithium hypochlorite or sodium hypochlorite.
** For sodium dichlor, trichlor, chlorine gas, BCDMH.
*** Dictated by state or local codes. Typically 100 ppm. (Some codes are higher, some are lower).
**** Some state or local codes may dictate a minimum and maximum.
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As a general rule of operation, the certified pool operator handbook recommends shocking the pool when the combined chlorine
level exceeds 0.5ppm. The commonly used rule for super-chlorination is to add free chlorine in the amount of 10 times the
combined chlorine level. For example, if the combined chlorine level is 0.5ppm, the equivalent amount of free chlorine to result
in 5ppm of free chlorine is added.
Test Strips
Test strips are the cheapest option for qualitative pool water
chemistry testing. Each strip contains one or more indicator-
impregnated test pads for each test. A quick dip and color
comparison is all that is required for a quick result.
Basic Test Kits - Drops Drawbacks of the basic test kit using color comparison
include:
Basic test kits use DPD-drop reagents for pool water testing. • Poor accuracy +/- 0.5 ppm
The test kit typically includes sample vials, a color chart, • Decreasing reliability above 5ppm
color wheel, or color comparator, and manufacturer directions. • Do not work above chlorine levels of 10ppm (at this
The DPD reagent is often packaged with phenol red reagent level, the test may bleach out and may give the false
for pH as well as other reagents for hardness and alkalinity. reading that no chlorine is present)
An example of this kit is Taylor’s K-2005 High DPD test kit.
The estimated cost of this kit is $40-50. One improvement to the basic kit is to include DPD-FAS
titration. These kits more accurately determine chlorine levels
by including the FAS reagent bottle. As with the basic kit, a
pink color change indicates the total chlorine in the sample.
Then, FAS is added to the sample drop-wise until the sample
changes from pink to clear. FAS binds the free chlorine and
leaves combined chlorine.
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Spectrophotometry
Amperometry is the detection of ions in a solution based on on the meter is the difference in potential between positive
changes in electric current. In the pool testing world, and reference electrodes.
amperometers can be seen as single hand-held devices or as
part of a continuous monitoring system. Typically, each probe Generally, ORP meters can relate the effectiveness of the
can only measure one parameter at a time. oxidizer, free chlorine. However, other factors have an effect
on the degree of ORP that makes this answer less precise. As
ORP meters measure the difference in electrical potential the pH increases in a chlorine pool, the oxidation reduction
between a reference and the pool water. The reading displayed potential decreases since there is less hypochlorous acid in the
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pool. For this reason, ORP meters are often coupled with a pH calibration of the pH probe however the ORP probe is
probe. Other chemicals in the pool can also skew an ORP generally factory calibrated.
reading including chloramines.
The cost for the meter is comparable to other photometers.
Amperometers are simpler to use and operate than other test The approximate cost of one of these meters that include both
methods. There are no reagents to add and no counting of ORP and pH is about $200-300. An example is the Hanna
drops. The probe is inserted into the sample and allowed to Instruments HI 98121 Combination pH and ORP tester. This
stabilize to provide a reading. This stabilization time can be as unit has a removable pH electrode for easy replacement and
long as 10-12 minutes. Some probes may require priming also comes with a 6 month warranty. The unit has an accuracy
with solution to reduce the time it takes to get a stable of +/- 0.05 pH and +/- 2 mV. Calibration of the pH is required
reading. Cleaning of the probe after each use and proper every month of use. After the warranty period, it may be
storage is important to maintain a reliable testing device. easier and more cost-effective to simply buy new rather than
Manufacturers’ often provide solutions with known pH for repair.
SAMPLING TECHNIQUE
Sampling technique and especially operator error is often the Storage
greatest obstacle to achieving accurate repeatable results.
Reading the manufacturers instructions for the specific Reagents will naturally degrade over time as they are exposed
equipment used is of the utmost importance. While it can be to the environment. Since they cannot feasibly be stored in a
expected that different testing methods have different vacuum, certain considerations need to be realized to get the
instructions for proper testing, it cannot be assumed that most out of the chemical’s limited shelf-life.
similar test kits from different manufacturers will have the
same instructions. • Store reagents at a consistent temperature in the range
from 36-85°F. Avoid extremes such as storing them in a
car or refridgerator.
Here are general tips to follow when water testing as • Keep reagent bottles tightly capped to protect against
follows: moisture and other contaminants. Replace defective or
broken caps immediately.
Sample
• Keep reagents separate from pool chemicals as much as
possible.
For consistency, it is recommended that a representative
• Keep reagents out of direct sunlight as the sunrays may
sample be collected first prior to testing. Representative
degrade certain light-sensitive reagents.
means that the sample is taken from an area of the pool that is
well-mixed. To collect the sample, use the following
Dilution
guidelines:
Where applicable, it may be possible to read levels above the
• Use a clean sample bottle that is large enough to produce
limit of the test employed. Dilution is one method to continue
2-3 times the water necessary to perform the test. A bottle
in this case without having to change testing methods. There
that is closeable is preferred. Glass is recommended over
are some specific tips regarding dilution however:
plastic since the plastic has chlorine demand.
• Rinse the bottle three times with the pool water.
• Always dilute the sample before adding the reagent.
• Choose a location that is away from chemical injection
• Use only distilled water to dilute the sample not tap
inlets or the shallow end. A location that is midway
water.
between shallow and deep ends of the pool is preferable.
• Always fill to the fill line on the test vial. If doing a 2x
• Insert the bottle upside down into the water atleast two
dilution, fill half with pool water sample then fill to line
feet down below the water surface.
with deionized water.
• Invert the bottle to fill it with the sample.
• Understand that with dilution will sacrifice some
• Remove the bottle from the water and quickly cap it
accuracy. As a rule of thumb, multiply the resolution by
unless the water is tested immediately.
the dilution factor as well to get the new precision of the
test.
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• These instruments require more care and maintenance to 6. Sweazy, Joe and Chuppe, Drew. “Pool and Spa 101.”
extend life and should be calibrated regularly against Wcponline.com. Water Conditioning & Purification.
reliable standards. November 2005. 22 May 2014. http://www.wcponline.
• Do not allow probes to dry in storage. Probe should be com/pdf/1105%20sweazy.pdf.
stored wet with the solution provided by the manufacturer
and not with deionized nor distilled water. 7. “Learn More: Chemistry Topics.” TaylorTechnologies.
• Limit the performance of the calibration task to only one com. 2011. 22 May 2014. http://www.taylortechnologies.
operator. com/learnmore_chemistry.asp.
• After each use, cleaning of the instrument is required to
keep it in working order for the next test. 8. Steininger, Jacques and Pareja, Catherine. “ORP Sensor
• Follow additional guidelines by the manufacturer for Response in Chlorinated Water.” NSPI Water Chemistry
handling and use to optimize the life of the unit. Syposium. 2 July 2001. 22 May 2014. http://www.
sbcontrol.com/orppaper.pdf.
CONCLUSION
9. Williams, Kent. “ORP and Oxidation.” Professional Pool
Several factors need to be considered when purchasing a pool Operators of America. Ppoa.org. 19 May 2011. 22 May
water quality testing device. These should include primarily 2014. http://ppoa.org/?p=572.
the cost per test and types of tests required and also the
reliability, accuracy, and durability of the selected test. Local 10. McPherson, Lori. "Amperometric vs. Colorimetric
codes often set limits for minimum accuracy of pool tests. Methods for Online Measurement of Chlorine."
This paper provides a survey of the testing available. By WaterWorld.com. 22 May 2014.
attaining a grasp of pool water chemistry and understanding
the various testing methods, a cost-effective testing regimen
can be better developed to meet local regulations.
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PoolPak Technical Library Series PoolPak Technical Library Series PoolPak Technical Library Series
www.poolpak.com Bromine Pools www.poolpak.com Dehumidification Considerations & options www.poolpak.com New Free Chlorine Standards for
Indoor Pools and water Parks
AN INTRO TO TREATING SWIMMING POOLS WITH BROMINE
Chlorine remains the #1 used and approved chemical treatment for indoor pools. However, we continue to find out more about the NEw FREE ChloRINE STaNdaRdS aRE ouT.
corrosive and deleterious health impacts of airborne chloramines and the more than 600 other Disinfection ByProducts (DBP) of a aRE You FamIlIaR wITh ThE ChaNgES IN FREE ChloRINE lEVElS?
chlorine pool. As a result, the search for alternatives to chlorine or supplementary treatments to minimize chlorine use is ongoing.
The only other EPA approved chemical for indoor pools is bromine. A halogen in the same group as chlorine,
Many public and private indoor pool owners are just becoming aware that the free chlorine levels are on the rise. This is due primarily to outbreaks of serious health
bromine occurs naturally in ocean water as a salt. For swimming pools, bromine performs similarly on issues such as E. coli where swimmers have become gravely ill because of improperly sanitized pool water.
bacteria and viruses at a slightly higher residual (3-4ppm) than chlorine. Because of its increased resistance
to degradation from higher temperatures, it is the preferred chemical treatment for spas and hot-tubs. Contaminants introduced by swimmers can dramatically influence the operation of indoor and outdoor swimming pools. Sources include micro-organisms from infected
swimmers and body oils including sweat, cosmetics, suntan lotion, urine, saliva and fecal matter. In addition, the interaction between disinfectants and pool water
The main benefit to bromine is that the chloramine-equivalent, bromamine, is a non-issue for bromine pools. In fact, bromamine contaminants can produce a mixture of chloramines and other disinfection by-products.
is as effective for disinfection as both free chlorine and bromine. Bromamine is also a lot less likely to gas off from the water. See
the below comparative list with respect to chlorine. Pathogenic contaminants are of greatest concern in swimming pools as they have been associated with numerous recreational water illnesses (RWIs). Public health
pathogens can be present in swimming pools as viruses, bacteria, protozoa and fungi. Diarrhea is the most commonly reported illness associated with pathogenic
contaminants, while other diseases associated with untreated pools are Cryptosporidiosis and Giardiasis. Other illnesses commonly occurring in poorly maintained
The Good The Bad swimming pools include otitis externa, commonly called swimmers ear, skin rashes and respiratory infections.
• Bromamine is as effective at disinfecting as free bromine • More expensive in annual chemical costs
• No similar airborne chloramine issues (odor, respiratory • A weak oxidizer, bromine may require occasional oxidizer
irritation, and metal surface corrosion) shock to rid the water of organic wastes
• Bromine can be regenerated from bromide ions by adding • Does not wash off in the shower as well as chlorine
oxidizer (chlorine, or non-chlorine shock) • Not suitable for outdoor pools, bromine degrades rapidly
• Bromine can be automatically generated or fed similar to with sunlight and cannot be stabilized with cyanuric acid
chlorine: electrolytic generation, erosion feed, or other • Allergic skin reactions more likely (ie. “hot tub rash”)
• Carcinogenic DBP’s still form (ie. bromoform)
Sorting through Pool room DehumiDifiCation oPtionS
Whether you are building a new indoor pool facility, refurbishing an older one or wishing to optimize an existing operation, there are a number of
considerations that should be examined before committing to an expensive decision on choosing a dehumidification system. Balancing comfort, cost
and appearance all have trade-offs, and it’s important to establishing your priorities in advance.
Indoor pool rooms are complex environments that need constant care and maintenance. There is an ongoing relationship between internal and
external temperatures, humidity level, structure type, ventilation, pool water chemistry and equipment. When all are working in harmony, the facility
will provide a comfortable, healthy environment that is cost effective. When the variables begin to change, comfort, operating cost and/or maintenance
can suffer greatly.
Indoor pool designers and owners need to control and balance five crucial variables: 1) pool water chemistry, 2) indoor air quality (IAQ), 3) occupant
comfort, 4) energy cost and 5) asset protection. The interrelationship between the variables is complex, and changing one or more may affect the
others.
Small variations in the pool environment may result in discomfort; large imbalances in the pool environment can result in very high operating cost,
destruction of equipment and structure and even occupant injury.
It is important to clearly understand and identify your goals for the facility. Typical conditions for general purpose pools are normally considered to be
82° for water temperature, 84° for air temperature and 50% to 60% relative humidity. Athletic pools hosting swim meets generally operate with cooler
water/air temperatures and health/therapy facilities tend to have higher water/air temperatures.
Today’s even larger indoor waterparks are a breed unto their own. These facilities with their great expanses of space, sprays, slides and water cannons
generate huge volumes of evaporated water, and ideal conditions can be difficult as well as expensive to maintain.
Managing the quantity of free chlorine residual in the pool is also difficult as chlorine is quickly depleted by reactions with contaminants in the pool. When chlorine
reacts with organic compounds, it may only partially oxidize the compounds resulting in intermediate products known as disinfection by-products (DBPs). A very strong
“chlorine” smell is caused by DBPs and may be indicative of poor pool water chemistry. Chloramines, the most common DBPs, are directly attributable to swimmers
complaints of skin irritation and eye burn. The long term effect of chloramines can also have devastating effects to dehumidifying equipment and metallic supports as
condensate laden with chloramines are extremely corrosive.
Due to the above issues, there is a large demand for alternative disinfection methods to replace chlorine or atleast minimize its deleterious effects. This research paper
attempts to define UV treatment as a possible solution to this issue.
Provided by:
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