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352 views46 pagesGaseous State
Uploaded by
Varshini PraveenCopyright
© © All Rights Reserved
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/ 46
CHAPTER
Gaseous
State
EXERCISE | (JEE MAIN)
Gaseous Parameters and Gas Laws
1. The pressure outside a jet plane flying
at high altitude falls considerably below
atmospheric pressure at sea level, The air
inside the cabin must therefore be pres
surized to protect the passengers. What
is the pressure (in atmosphere) in the
cabin if the barometer reading is 688 mm
of Hg?
(a) 0.905 atm
(b) 6.88 atm
(©) 9.05 atm
(d) data, insufficient
2. Dibutylphthalate is often used as a mono-
meter fluid. It has a density of 1.047 g/ml
How many torts are represented by 1 mm
of this fluid?
(a) 0.077 torr (b) 1 torr
(©) 12.98 torr (d) 760 torr
3. A liquid of density 1.70 g/ml is filled in
the barometer, in place of mercury. What
should be the length of liquid column, if
another barometer filled with mercury, is
measuring 75 cm pressure?
(a) 750m
(©) 9.375 em
(b) 600 em
(4) 6000 em
4.
A barometer is placed in open space of
laboratory of weather bureau. If the level
of mercury in the barometer falls consid-
cerably, it will represent
(a) normal weather
(b) very slow speed of wind after some
time
(©) very high speed of wind after some
time
(d) very high atmospheric pressure
At a constant temperature a gas occu-
pies a volume of 200 ml at a pressure of
0.720 bar. It is subjected to an external
pressure of 0.900 bar. What is the result-
ing volume of the gas?
(a) 160 mI
(©) 80ml
(b) 320 ml
(d) 400 ml
A volume of 2.51 of a sample of a gas at
27°C and 1 bar pressure is compressed to
a volume of 500 ml keeping the tempera-
ture constant, the percentage increase in
pressure is
(a) 100%
(©) 500%
(b) 400%
(d) 80% 32
8
10.
ul.
2.
= Chapter 3
‘When we inflate cycle tubes, the volume
of tube as well as the pressure of air
inside tube increases
(a) Itisan exceptional case of Boyle’s Law.
(b) It happens because air is not ideal
gas.
(©) It happens because mass of air is not
constant,
(4) It happens because external force is
applied in inflating the tubes.
The value of Boyle's Law constant (in S.1.
unit) for 200 ml of gas at 1.2 atm is about
(a) 240 atm-ml (b) 0.24 atm-1
(© 24.33 (@) 0.245
In the outer space, the pressure recorded
is 5 x 10° torr, How much outer space
could be compressed into 1 dm’ box at a
pressure of 1 atm?
(a) 1.52 10" dm’
(b) 4.56 x 10! dm’
(©) 2.28 x 10° dm?
(d) 1.14 x 10" dm?
What is the increase in volume, when the
temperature of 600 ml of air increases
from 27°C to 47°C under constant
pressure?
(a) 50mb (b) 60 ml
(©) 80m (d) 40 ml
The temperature of a certain mass of a
gas increased from 37°C to 38°C. The
volume of the gas
(a) will decrease by of its volume at
Ene D
(b) will increase by + of its volume at
23K ”
(©) will increase by 1 of its volume at
310K ae
(@) will remain the same,
At 4°C, a gas occupies 200 ml and the
same amount of gas at the same pressure
occupies 300 ml at 144°C. The absolute
zero from this data is
13.
14.
15.
16.
7.
18,
(a) -273°C
(©) 276K
(b) -276°C
(d) -3°C
When a definite mole of different gases
are heated from 20°C to 40°C at constant
pressure, their volume
(a) becomes double
(b) increases in the ratio of their molecu-
Jar masses
(©) increases by the same extent
(d) decreases by the same extent
A sample of gas at 35°C and 1 atmos-
pherie pressure occupies a volume of
3.75 1. At what temperature should the
gas be kept, if it is required to reduce the
volume to 3.0 I at the same pressure?
(a) -26.6°C (b) 0°c
(©) 3.98°C (d) 28°C
A toy balloon can occupy 500 ml at 27°C.
The maximum stretching capacity of
the balloon is three times of the volume
at 27°C. The temperature above which
the balloon will burst, if pressure of the
balloon does not change
(a) 300K. (b) 900 K
(©) 625°C (d) 225°C
One day, when the temperature and pres-
sure were 300 K and 760 mm, a mass of
gas had a volume of 1200 ml. On the next
day, the volume had changed to 1218 ml
while the pressure was the same. What
was the temperature on the next day?
(a) 546K (b) 304.5 K
(© 315K (@) 300K
If the pressure of a certain amount of a
gas increases by 1% on heating by 1°C at
constant volume, its initial temperature
must be
(a) 100K,
(©) 250K
(b) 100°C
(d) 250°C
A gas has a volume of V cm’ at 10°C. If
the pressure is doubled, at what tempera-
ture will the volume still be V cm"? (a) 273°C
(c) 283°C
(b) 300°C
(d) 293°C
Gaseous State" 33
ozone at the same room temperature and
pressure. The ratio of total number of
atoms of these gases present in the differ-
19. A quantity of 10 g of a gas at | atm pres-
sure is cooled from 273°C to 273 K keep- cpl oaey oes
ing its volume constant, the final pressure @ Lent (b) 1:2:2:3
of the gas will be (©) 21:23 @ 12:21
(a) 273 atm (b) 0.5 atm 23. Reducing the pressure from 1.0 atm to
(©) 0.2atm (@) 0.1 atm 0.5 atm would change the number of
20. A pre-weighed vessel was filled with oxy- ca
gen at NTP and weighed. It was then (a) 75% of initial value
evacuated, filled with SO, at the same cb) 202 fofnitial value
temperature and pressure, and again (P22 of initial value
weighed. The mass of oxygen will be Oe ot se
(a) the same as that of SO, 24, A closed container contains N molecules
(b) half that of SO, at P atm and TK. If the absolute tem-
(©) twice that of SO, perature is doubled,
(d) one-fourth of SO, (a) number of molecules present in the
21. According to Avogadro's hypothesis, container will become 2N
equal volumes of all gases under the same Cb) Jammer {off molecules] present in) the
conditions of temperature and pressure Container will become W/2
will contain (©) gas pressure become 2P
(@) the same number of molecules (@) gas pressure become P/2
(b) different number of molecules 25. Reducing the pressure from 1.0 t0 0.5 atm
(©) the same number of molecules only if ‘would change the number of molecules in
their molecular masses are equal one mole of ammonia to
(@) the same number of molecules if their (a) 75% of initial value
densities are equal (b) 50% of initial value
22, Four 1-1 flasks are separately filled with (©) 25% of initial value
the gas hydrogen, helium, oxygen and (d) None of these
Ideal Gas Equation
26. Under what conditions will a pure sample (a) decreasing the volume but keeping
of an ideal gas not only exhibit a pressure the quantity and pressure fixed
of 1 atm, also a concentration of 1 mole (b) decreasing the quantity but keeping
litre"? the pressure and volume fixed
(a) AtSTP (c) decreasing the pressure but keeping
(b) when V=22.41 the quantity and volume fixed
(©) when T= 12K (@) decreasing the pressure and volume
(d) Impossible under any condition but keeping the quantity fixed
27. The temperature of an ideal gas can be 28 The approximate length of the side of
raised by
a cube containing 850 million gas mol-
ecules at 0°C and 1 atm would be 34
29,
30.
31.
32.
33.
34.
= Chapter 3
(a) 3.15 x 10%em.
(©) Imm
(b) 3x 10° cm
(@) 5.25 x 10% em
The pressure of interstellar space is about
4.0 x 10 atm, If the temperature is 3 K,
how many molecules are present per litre?
(R= 0.08 l-atm/K-mol)
(a) 2430 (b) 1420
(c) 845 (d) 1002
‘The molar volume of CO, is maximum at
(a) 273 Kand 1 atm
(b) 546 K and 1 atm
(©) 273K and 2 atm
(d) $46 K and 2 atm
The volume occupied by 1.8 g H,O at 4°C
and 760 mm pressure is
(@) 181
(©) 2.271
(b) 1.8 mi
(d) 2.98 ml
If air is pumped slowly but continuously
into a metallic cylinder of strong wall, what
‘would happen to the air inside the cylinder?
(a) temperature of air would increase
(b) pressure of air would increase
(©) pressure of air would decrease
(@) temperature and pressure of air
would increase
V vs T curves at different pressures P,
and P, for an ideal gas are shown below.
Which one of the following is correct?
(a) P,>P,
(b) P,
At which of the following four condi-
tions, the density of an ideal gas will be
maximum?
37.
(a) 273 K and 1 atm
(b) 273 K and 2 atm
(©) 546 K and 1 atm
(d) 546 K and 2 atm
A vessel contains | mole of O, gas at a tem-
perature T. The pressure of the gasis P. An
identical vessel containing 1 mole of He
gas at a temperature 27 has a pressure of
(a) PIS (b) P
(©) 2P @ 8P
A 101 bulb contains an ideal gas of molar
mass 81 at 27°C. Some gas is removed
from the bulb until the pressure of gas
decreased by 0.82 atm. The mass of gas
removed is
(a) 27g
(c) 40.5g
(b) 81g
(d) 548
A bulb with chlorine gas at ambient pres-
sure contains 3.55 gat (°C. When the bulb
is placed in a second thermostat at a tem-
perature 30°C higher and the stopcock of
the bulb temporarily opened (and closed
again) to restore the initial pressure, the
bulb is now found to contain 32 g of
chlorine. What is the value of °C?
(a) 281°C (b) 8.21°C
(©) 8:12°C (d) 1.28°C
If the absolute temperature of an ideal
gas having volume V cm’is doubled and
the pressure is reduced to half, the final
volume of gas will be
(a) 0.254
(c) 2V?
(b) 0.507
@ av
A 0.5 dm’ flask contains gas A and | dm’
flask contains gas B at the same tempera-
ture. If density of A is twice that of Band
the molar mass of A is half of B, then the
ratio of pressure exerted by gases is
(a) PyPy=2 (b) PyPy=1
(©) PylPy=4 @) PAP,
Density of a gas is found to be 5.46 g/dm’
at 27°C at 2 bar pressure. Its density at
STP will be 4.
42.
43.
45,
(a) 1 g/m’ (b) 2 gidm*
(c) 3 gdm? (d) 4.g/dm*
A student forgot to add the reaction mix-
ture to the round-bottomed flask at 27°C
but put it on the flame. After a lapse of
time, he realized his mistake. Using a
pyrometer, he found the temperature of
the flask as 477°C. What fraction of air
‘would have been expelled out?
(@) 53 (b) 3/5
(© 25 (@ 32
Pressure of 1 g of an ideal gas A at 27°C
is found to be 2 bar. When 2 g of another
ideal gas B is introduced in the same
flask at same temperature the pressure
becomes 3 bar. What is the relationship
between their molecular masses?
(b) My=M,
(d) M,=2M,
A compound exists in the gaseous phase
both as monomer (A) and dimer (B). The
molecular mass of A is 48. In an experi-
‘ment, 96 g of the compound was confined
in a vessel of volume 33.6 1 and heated to
546 K. What is the pressure developed if
the compound exists as dimer to the extent
of 50% by weight under these conditions?
(a) 2atm (b) 4atm
(© 3am (@) 0.5 atm
A 2.24 1 cylinder of oxygen at 0°C and
1 atm is found to develop a leakage. When
the leakage was plugged, the pressure
dropped to $70 mm of Hg. The number
of moles of gas that escaped will be
(a) 0.025 (b) 0.050
(©) 0.075 (@) 0.09
A container contains certain gas of
mass m at high pressure. Some of the
gas has been allowed to escape from the
container. After some time, the pressure
of the gas becomes half and its absolute
temperature two-third. The amount of
the gas escaped is
41.
49.
Gaseous State" 3.5
(a) 2m/3 (b) mi2
(c) mi4 (d) mi6
A. perfectly expandable balloon filled
with helium gas at 27°C and a pressure
of 720 mm of Hg has a volume of 100 1
‘The balloon rises to an altitude where the
pressure is 420 mm of Hg and the tem-
perature ~53°C. What is the change in the
volume of the balloon?
(a) 161 (b) 25.71
(©) 481 (@) 15.71
There is 101 of a gas at STP. Which of
the following changes keep the volume
constant?
(a) 273 K and 2.0 bar pressure
(b) 546 K and 2.0 bar pressure
(c) 546 K and 0.5 bar pressure
(@) 273 K and 0.5 bar pressure
A certain mass of an ideal gas at 9 atm
and 30°C is first heated to 131°C at con-
stant volume and then the amount of the
gas is increased by 50% at constant vol-
ume and temperature. The final pressure
of the gas becomes
(a) 9atm
(©) 18 atm
(b) 4.5 atm
(d) 13.5 atm
A quantity of 10 g of an ideal gas is
expanded at constant temperature until
its pressure becomes half of the initial
pressure. The quantity of 1.25 g of the
rarefied gas occupies 50 ml at the same
final pressure and temperature. The ini-
tial volume of the gas was
(a) 200 ml (b) 400 ml
(©) 800 ml (d) 25 mi
One mole of N,O,(g) at 300 K is kept in
a closed container under 1 atmospheric
pressure. It is heated to 600 K when
20% by mass of N,O,(g) decomposes to
NO,(g). The resultant pressure is
(a) 12 atm (b) 2.4atm
(©) 2.0.atm @ 10am 36
= Chapter 3
Dalton’s Law
51.
52.
53.
55.
56.
Which of the following mixture of gases
at room temperature follows Dalton’s law
of partial pressure?
(a) NH,, HCI
(b) H,, 0,
(c) NO, 0,
(d) All the above
The partial pressures of N,, O, and CO,
in a vessel are 38 em of Hg, 190 torr and
0.5 atm, respectively. The total pressure
of the mixture at the same temperature is
(a) 0.96 atm
(b) 1.02 atm
(©) 1.64 atm
(@) 1.25 atm
Assume that air is 21% O, and 79% N,
by volume. If the barometric pressure is
740 mm, the partial pressure of O, is clos-
est to which one of the following
(a) 155mm. (b) 310 mm
(©) 580mm. (d) 740 mm.
Equal masses of ethane and hydrogen are
mixed in an empty container at 25°C. The
fraction of the total pressure exerted by
hydrogen is
(a) 1:2
(© 1:16
(b) 1:
(d) 15:16
‘A mixture of hydrogen and oxygen at one
bar pressure contains 20%, by weight, of
hydrogen. The partial pressure of hydro-
gen will be
(a) 8 bar (b) 0.8 bar
(©) 4 bar (@) 6 bar
Quantities of 16 g of oxygen and 14 g
of nitrogen are contained in a closed
bottle. The pressure inside the bottle is
4 atm. Now, 8 g O, gas is removed from
the bottle, What will be the new pressure
inside the bottle?
(a) 2atm
(© 6am
(b) 4atm
(a) 3.atm
61.
62.
The mass of pure CH, gas to be mixed
with 70 g of pure CO so that the partial
pressure of CO is equal to the partial
pressure of CH,, is
(a) 40g (b) 70g
© 16g @ 8g
A box of 1 1 capacity is divided into two
equal compartments by a thin partition,
which is filled with 2 g hydrogen and 16 g
methane, respectively. The pressure in
each compartment is recorded as P atm.
The total pressure when the partition is
removed will be
(a) P
(c) PI2
(b) 27
(d@) PIs
A closed vessel contains equal number
of nitrogen and oxygen molecules at a
pressure of P mm. If nitrogen is removed
from the system, then the pressure will be
(a) P (b) 2P
(©) PI2 @) P
A vessel is filled with a mixture of oxygen
and nitrogen. At what ratio of par-
tial pressures will the mass of gases be
identical?
(a) P(O,) = 0.785 P(N,)
(b) PO.) =8.75 P(N,)
(©) PO,)=114 PN)
(d) P(O,)= 0.875 PIN,)
The volumes of the two vessels are in
the ratio of 2:1. One contains nitrogen
and the other oxygen at 800 mm and
680 mm pressure, respectively, Determine
the resulting pressure when they are con-
nected together.
(a) 760 mm
(c) 140mm
(b) 670 mm
(d) 1480 mm
What will be the pressure of the gas mix-
ture when 0,5 1 of H, at 0.8 bar and 2.01
of oxygen at 0.7 bar are introduced in a
IL vessel at 27°C? 63.
65,
66.
67.
(a) 3 bar (b) 1.8 bar
(c) I bar (a) 18 bar
A quantity of 4 gH, reacts with 9x 10° Cl,
molecules and forms HCI gas. If the total
pressure of the system after reaction is
700 mm, what is the partial pressure of
HCI? Assume complete reaction.
(a) 200 mm, (b) 350. mm
(©) 300mm (d) 600 mm
A vessel has N, gas saturated with water
vapours at a total pressure of 1 atm. The
vapour pressure of water is 0.3 atm. The
contents of this vessel are completely
transferred to another vessel having one-
third of the capacity of original volume,
at the same temperature. The total
pressure of this system in the new vessel is
(a) 3.0.atm (b) T atm
(©) 3.33 atm (@) 2.4atm
There is some liquid in a closed bottle.
The amount of liquid is continuously
decreasing. The vapour in the remaining
part
(a) must be saturated
(b) must be unsaturated
(©) must be super saturated
(d) there will be no vapour
‘A sample of air contains only N,, O, and
H,0. It is saturated with water vapour
and pressure is 640 torr. The vapour pres-
sure of water is 40 torr and the molar
ratio of N,:O, is 3:1. The partial pressure
of N, in the sample is
(a) 540 torr
(b) 900 torr
(©) 1080 torr
(@) 450 torr
Oxygen gas is collected by downward
displacement of water in a jar. The level
of water inside the jar is adjusted to the
height of water outside the jar. When the
adjustment is made, the pressure exerted
by the oxygen is
68.
70.
Gaseous State" 3.7
(a) equal to the atmospheric pressure
(b) equal to the vapour pressure of
oxygen at that temperature
(c) equal to atmospheric pressure plus
aqueous tension at that temperature
(4) equal to atmospheric pressure minus
aqueous tension at that temperature
At 20°C, the vapour pressure of water
is recorded as 22.57 mbar. What will be
vapour pressure of water in the apparatus
shown after the piston is lowered, thereby
decreasing the volume of the gas above
liquid to half of the original volume
(a) 45.14 mbar
(b) 22.57 mbar
(c) 11.28 mbar
(@) between 11.28 and 22.57 mbar
=== — Liquid vapour
Water vapour
If the concentration of water vapour in
the air is 1% and the total atmospheric
pressure equals 1 atm, then the partial
pressure of water vapour is
(a) 0.1 atm (b) | mm Hg
(©) 7.6mm Hg (@) 100 atm
A volume of 190.0 ml of N, was collected
in a jar over water at some temperature,
water level inside and outside the jar
standing at the same height. If barom-
eter reads 740 mm Hyg and aqueous ten-
sion at the temperature of the experiment
is 20 mm Hg, the volume of the gas at
1 atm pressure and at the same tempera-
ture would be
(a) 185.0 ml
(©) 195.0 mt
(b) 180.0 ml
(@) 200 mi 38
= Chapter 3
Graham's Law
n.
nR.
2B.
14,
15.
16.
If helium and methane are allowed to
diffuse out of the container under the
similar conditions of temperature and
pressure, then the ratio of rate of diffu-
sion of helium to methane is
(@ 2.0 (b) 10
(©) 05 (@) 40
An unknown gas ‘X’ has rate of diffusion
measured to be 0.88 times that of PH, at
the same conditions of temperature and
pressure. The gas may be
(@) CH, (b) Co
(©) NO, (@) NO
A quantity of 2 g of hydrogen diffuses
from a container is 10 min. How many
grams of oxygen would diffuse through
the same container in the same time
under similar conditions?
(a) 5g (b) 4g
(©) 6g (d) 8g
A gas with formula C,H,,. diffuses
through the porous plug at @ rate one-
sixth of the rate of diffusion of hydrogen
gas under similar conditions. The for-
mula of gas is
(a) C,H,
(©) CHy
(b) CoH,
(d@) CH,
A class consists of 7 rows. The teacher
releases laughing gas, N,O from the front
row and a mischievous student releases
a tear gas of molecular weight 176 from
rear most. The student of which row
from the first will weep and smile simul-
taneously
(a) fifth (b) first
(©) second (d) third
A balloon is filled with N,O is pricked
with a sharp point and quickly plunged
into a tank of CO, under the same pres-
sure and temperature. The balloon will
B.
2.
80.
(a) be enlarged
(b) shrink
(c) remain unchanged in size
(@) collapse completely
A certain gas diffuses from two different
vessels A and B. The vessel A has a circu-
lar orifice while vessel B has square orifice
of length equal to the radius of the orifice
of vessel A. The ratio of the rates of dif
fusion of the gas from vessel A to vessel
B, assuming same temperature and pres-
sure is,
(@)m () Un
©1 @2
A volume of 180 ml of hydrocarbon takes
15 min to diffuse. Under the same con-
ditions 120 ml of sulphur dioxide takes
20 min, The molecular weight of hydro-
carbon is
(@) 16
(c) 48
(b) 32
(d) 64
Ina glass tube of I m length and uniform
cross section, NH,(g) from one end and
BF,(g) from the other end are sent at a
time. The distance from the ammonia end
where the addition compound, BF,-NH,
will first form is (B= 11; F = 19)
(a) 66.67 em (b) 33.33 em
(©) 50.00em (d) 60.00 em
For 10 min each, at 27°C, from two iden-
tical holes nitrogen and an unknown
gas are leaked into a common vessel of
3 1 capacity. The resulting pressure is
4.18 bar and the mixture contains 0.4
mole of nitrogen. The molar mass of the
unknown gas is
(a) 112g mot"
(b) 242 g mot"
(©) 224g mol"
(d) 422 g mol Kinetic Theory of Gases
81.
82.
83,
85,
86.
87.
The ratio of root mean square speed of
H, at 50 K and that of O, at 800 K is
(a) 4 (b) 2
ol @ 4
If only one gas molecule is taken in a con-
tainer, the correct relation between average
speed, c, root mean square (RMS) speed,
xu, and most probable speed, ot, becomes
(@) aN,>0,> HBr
(b) HBr >O,>N,>H,
(©) HBr>H,>0,>N,
(d) N,>0,>H,> HBr
‘Two gases X and Y have their molecular
speed in ratio of 3:1 at certain tempera-
ture, The ratio of their molecular masses
MM, is
(@) 13 (b) 3:1
(© 1:9 (d) 9:1
At what temperature will the total trans-
lational kinetic energy of 0.30 mole of
He gas be the same as the total transla-
tional kinetic energy of 0.40 mol of Ar at
400 K?
1.
92.
Gaseous State = 3.9
(a) 933K
(©) 300K
(b) 400 K
(d) 266K
The translational kinetic energy of N’
molecules of O, is x J at -123°C. Another
sample of O, at 27°C has translational
kinetic energy of 2x J. The latter sample
contains
(a) N molecules of O,
(b) 2N molecules of O,
(c) N/2 molecules of O,
(d) N/4 molecules of O,
Helium atom is two times heavier than a
hydrogen molecule. At 298 K, the average
kinetic energy of a helium atom is
(a) two times that of hydrogen molecule
(b) same as that of a hydrogen molecules
(c) fourtimes thatof a hydrogen molecules
(d) half that of a hydrogen molecule
The translational kinetic energy of 10”
molecules of nitrogen at a certain tem-
perature is 0.63 J. The temperature is
(a) 23°C (b) 31.3°C
(©) 30.1°C (d) 43.3°C
Consider three identical flasks with differ-
ent gases:
Flask A: CO at 760 torr and 273 K
Flask B: N, at 250 torr and 273 K
Flask C: H, at 100 torr and 273 K
In which flask will the molecules have the
greatest average kinetic energy per mole?
@A (b) B
Cc (@) same in all
Maxwell and Boltzmann have shown
that the actual distribution of molecular
velocities in all molecules in a given gas
depends on
(a) temperature and pressure
(b) temperature and molecular mass
(©) volume and temperature
(d) pressure and molecular mass 3.10 * Chapter 3
93. A gas container observes Maxwellian molecules per unit time under particular
distribution law of speed. If the num- conditions, then the collision frequency
ber of molecules between the speed 5.0 of the gas containing N molecules per
and 5.1 km per sec at 298 K is N, what unit volume is
would be number of molecules between (a) XIN () wx
this range of speed if the total number of (©) 2NX (@) wxR,
molecules in the vessel are doubled?
(a) 2N () N 95. Which of the following gas molecule has
a 2 the longest mean free path at the same
(©) 2N" @ NR
pressure and temperature?
94. If X is the total number of collisions () H, (b) N,
which a gas molecule registers with other © 0, (@ Ch
Real Gases
96. Consider an ideal gas contained in a (a) (e+ S)e-o- RT
vessel. If the intermolecular interactions a
suddenly begin to act, which of the fol-
lowing happen? (
(a) the pressure decreases
(b) the pressure increases (
(©) the pressure remains unchanged
(@) the gas collapses
97. A real gas obeying van der Waal'’s
equation will resemble ideal gas if the .
Pnaranta 100. The numerical value of a, the van der
a) aa : Waal's constant is maximum for
(a) aand bare small
(b) ais large and b is small (a) He (b) H
(©) ais small and bis large © 0, (d) NH,
(d) aand b are large 101. The molecular radius for a certain gas
98. The behaviour of a real gas is usually = 1.25 A. What is the reasonable estimate
depicted by plotting compressibility of the magnitude of the van der Waal’s
factor Z versus P at a constant tempera- constant, 6, for the gas?
ture. At high temperature and high pres- (a) 0.98 x 10° litre/mole
sure, Z is usually more than 1, This fact (b) 1.43 x 107 litre/mole
can be explained by van der Waal’s equa- (©) 1.97. 107 litre/mole
tion when (@) 3.33 x 10 litre/mole
(a) the constant ais negligible and not b 102, What is the pressure exerted by 32 g of
(b) the constant b is negligible and not a methane in a 250 ml vessel at 300 K
(c) both constants a and b are negligible using van der Waal’s equation, Given
(d) both constants aand bare not negligible a=2.253 atm | mol? and b= 0.0428 | mot
99, The van der Waal’s equation for (/) mole (a) 227.54 atm (b) 299.64 atm
of a gas
(©) 72.096 atm (d) None of these 103. van der Waal’s constant b for a gas is
0.0391 I mole", What is the radius of the
gas molecule?
Gaseous State = 3.11
(©) at high temperature and high pressure
(@) at low temperature and low pressure
105. The PV-P isotherms of 1 mole of differ-
(a) 3.8765 A (b) 1.5708 A ent gases at 273 K, if the limit of pressure
(© 8.36754 (@) 5.8075 A tending to zero, converge to a value of
104. When there is more deviation in the PV=
behaviour of a gas from the ideal gas (a) 11.2 atm
equation PV =nRT (b) 22.4 1-atm
(a) at high temperature and low pressure (c) zero
(b) at low temperature and high pressure (d) 22.41
Liquefaction of Gases
106. Only the vapours of a liquid exist 109. The van der Waal's parameters for gases
(a) below boiling point
(b) below critical temperature
(0) below inversion temperature
(d) above critical temperature
107. van der Waal’s constants and the cor-
responding values of critical tempera-
ture for three gases P, Q and R, are given
below
Gas Critical van der Waal’s
temperature constant 5
P =200°6 0.03 mol
Q = 100°C 0.02 mol
R +50°C 0.01 Vmol
Which of the gases are liquefiable at a
temperature -110°C by application of
increasing pressure?
@ PQR
(b) P.Q
OQR
(@) None of them
108. For a certain gas obeying van der Waal’s
equation, the critical temperature is
305.5 K and the critical pressure is
48.2 atm, The critical volume is
(a) 0.0981 (b) 0.1951
© 0.2311 (@) 0.3211
110.
1.
W,X, Y and Z are
a(atmPimoF) 6 (V/mol)
w 40 0.027
x 8.0 0.030
Y 60 0.032
Zz 120 0.027
Which one of these gases has the highest
critical temperature?
@ Ww
() ¥
(b) X
@)Z
The critical constants P, and 7, for four
gases are
Critical
Gas Critical
temperature pressure
0, 153K 50 bar
a, 417K 76 bar
H, 339K 13.5 bar
He 512K 22 bar
The gas with smallest value of van der
Waal’s constant b is
(a) 0,
© H,
) Cl,
(@) He
Under critical conditions, the compress-
ibility factor for a gas is 3.12 * Chapter 3
(a) 38 (b) 8/3
ol @ 14
112. The behaviour of temporary gases like
carbon dioxide approaches that of per-
manent gases such as nitrogen, oxygen,
ete., as We go
(a) below critical temperature
(b) above critical temperature
(©) above absolute zero
(@) below absolute zero
113. The van der Waal’s constants for three
gases R, Sand T are given below
Gas (atm L’/fmol’)
52
114.
115.
The correct sequence of placing the easily
liquefiable gas last and the one difficult to
liquefy first is
(a) R,S,T (b) STR
© TSR @ S,R,T
The correct order of the values of critical
temp, Tc; Boyle temp, 7, and inversion
temp, 7, of a real gas is
(@) T.