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2 - Basic Bricks - Dec 2017 Incl RED2

This document discusses basic bricks for cement rotary kilns. It describes that these bricks consist of two main components: magnesia for its thermal resistance and chemical resistance properties, and spinel as a flexibilizing additive. The document covers different types of raw materials used, including natural and synthetic magnesia as well as different spinel compositions. It also discusses the production process for synthetic magnesia and quality criteria for magnesia selection. Brick types are classified based on the raw material combinations of magnesia and spinel used.

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100% found this document useful (1 vote)
326 views62 pages

2 - Basic Bricks - Dec 2017 Incl RED2

This document discusses basic bricks for cement rotary kilns. It describes that these bricks consist of two main components: magnesia for its thermal resistance and chemical resistance properties, and spinel as a flexibilizing additive. The document covers different types of raw materials used, including natural and synthetic magnesia as well as different spinel compositions. It also discusses the production process for synthetic magnesia and quality criteria for magnesia selection. Brick types are classified based on the raw material combinations of magnesia and spinel used.

Uploaded by

quỳnh lê
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Basic Bricks for Cement Rotary Kilns

Subtitle
Vienna, Nov. 1st 2017
1 Introduction

2 Raw materials Sintered Magnesia

3 Raw materials Spinel

4 Brick types and Lining Recommendation

2
Production of basic cement rotary kiln bricks

Hagen/D
DGG

Mainzlar/D
MGG

Veitsch/AT
MGG

York/US Dalian/CN
DGG MGG

Ramos Arizpe/MX
MGG

Contagem/BR
MGG

3
Approach E – ME – A – CIS – IN
Shipping

Hagen/D
DGG

Mainzlar/D
MGG

Veitsch/AT
MGG

York/US Dalian/CN
DGG MGG

Ramos Arizpe/MX
MGG

Contagem/BR
MGG

4
Products for the Cement Industry

BRICKS CASTABLES

ANKRAL
BASIC
MAGKOR

MAXIAL COMPRIT
NON-BASIC RESISTAL DIDURIT
LEGRAL LEGRIT

shaped unshaped
13
Conditions in a Cement Rotary Kiln

High temperature
Dynamic mechanical load

Chemical attack /
alkali salts,
clinker melt
15
Basic Bricks for Cement Rotary Kilns

In general bricks for cement rotary kilns consist of two components:

 Magnesia
High thermal resistance
High chemical resistance

High thermal expansion


High thermal conductivity
 Low thermal shock resistance

 Spinel
as flexibilising additive

16
1 Introductions

2 Raw materials Sintered Magnesia

3 Raw materials Spinel

4 Brick types and Lining Recommendation

17
Types of Sintered Magnesia

• Synthetic sintered magnesia, MgO content > 98%


out of sea water or salt lakes, salt brines and salt deposits

• Natural sintered magnesia, MgO content < 98%


In nature magnesium carbonate is always associated with other minerals.

Typical impurities are: calcium carbonate


quartz und silicates,
iron compounds (pyrite), siderite

Two types of natural magnesia can be distinguished:

o coarse crystalline alpine magnesia, iron rich


o fine crystalline magnesia, low in iron
DBM97, DMB96, DBM95,…

18
From Raw Material to Sintered Magnesia (DBM)

Magnesite deposits occurence in form of


magnesium carbonate (MgCO3)

coarse crystalline:
alpine type: Breitenau
Hochfilzen
Radenthein

microcrystalline (cryptocrystalline): Tutluca

Magnesium-chloride
sea water or salt lakes, salt brines and salt
deposits

Magnesium-hydroxide (brucite)
deposits (CIS; China …)
without importance for refractories
Breitenau Mine/Styria, Austria
19
From Raw Material to DBM
Example of Breitenau

20
Production of Magnesia from Sea Water
Synthetic Magnesia

MgCl2 + Ca(OH)2 Mg(OH)2 + CaCl2

1000°C
Mg(OH)2 MgO + H2O (CCM) D~2 g/cm3

Briquetting

Sintering (1700 – 2000°C) D ~3,4 g/cm3


or fusing (>2800°C) D ~3,5 g/cm3

21
Types of Magnesia
Natural Magnesia Synthetic Magnesia
Source: salt brine MgCl
Source: Magnesite MgCO3
sea water MgCl

Iron rich: Low iron: typical composition:


typical composition: typical composition:
MgO 88 – 93 % MgO 90 – 97 % MgO 97,7 – 99,3 %
CaO 1,2 – 2,2 % CaO 0,5 – 1,9 % CaO 0,5 – 1,1 %
SiO2 0,8 – 2,5 % SiO2 0,5 – 2,5 % SiO2 < 0,1 – 0,3 %
Al2O3 0,1 – 1,5 % Al2O3 0,1 – 1,5 % Al2O3 < 0,1 %
Fe2O3 5–7% Fe2O3 0,2 – 1,0 % Fe2O3 0,1 – 0,5 %
BD 3,05 – 3,45 g/cm3 BD 3,05 – 3,45 g/cm3 BD 3,40 – 3,45 g/cm3

22
Quality Criteria of Magnesia

 Chemical Composition

- Amount of Secondary Phases


SiO2, CaO, Fe2O3, Al2O3, MnO

- CaO/SiO2 ratio

- Boron content

 Periclase Crystal Size


Magnesite from Breitenau

 Bulk Density / Apparent Porosity

23
Influences on Final Brick Properties

24
Natural vs. Synthetic Sintered Magnesia

25
CaO/SiO2 ratio

CaO/SiO2 ratio
Short 1 1- 1,5 2
Name Formula Sm <1 1,5 – 2 >2
Notation (0,94) 1,5 (1,4) (1,87)
Periklas MgO M 2840 x x x x x x x
Magnesiaferrit MgFe2O4 MF 1715 x x x x x x x
Spinell MgAl2O4 MA 2135 (x) (x) (x) (x) (x) (x) -
Forsterit Mg2SiO4 M2S 1890 x - - - - - -
Monticellit CaMgSiO4 CMS 1492 x x x - - - -
Merwinit Ca3Mg[SiO4]2 C3MS2 1575 - - x x x - -
Dicalciumsilikat Ca2SiO4 C2S 2130 - - - - x x x
Dicalciumferrit Ca2Fe2O5 C2F 1449 - - - - - - x
Brownmillerit Ca2FeAlO5 C4AF 1415 - - - - - - x
Calciumaluminat Ca3[AlO3]2 C3A 1535 - - - - - - (x)
Periclase Crystal Size

Standard sintered magnesia

increased corrosion
BD: > 3,38 g/cm3

increased flexibility
Crystal size: 30-120 µm

resistance
LC-dead burned magnesia

BD: > 3,38 g/cm3


Crystal size: + 150µm

Fused magnesia

BD: > 3,38 g/cm3


Crystal size: > 350µm
1 Introductions

2 Raw materials Sintered Magnesia

3 Raw materials Spinel

4 Brick types and Lining Recommendation

28
Types of Spinels

The spinel group is a big mineral family with similar crystal structure but different chemical
composition:

General formula: AB2O4 or AO·B2O3


where : A: Mg2+, Fe2+, Mn2+, Zn2+
B: Al3+ = Aluminate spinel
Fe3+ = Ferrite spinel

Cr3+ = Chromite spinel

Important spinels:
MgO · Al2O3 Spinel (MA)
FeO · Al2O3 Hercynite (fA)
MnO · Al2O3 Galaxite
MgO · Cr2O3 Picrochromite MA67

FeO · Fe2O3 Magnetite


(MgO, FeO)(Fe2O3, Al2O3, Cr2O3) Chromite
Hercynite
Classification of Magnesia Spinel Bricks

 Classification according to type of sintered magnesia

• Synthetic sintered magnesia (AL-R1, AL-Z1,..)


• Natural sintered magnesia - low iron (AL-RE, AL-RC)
• Natural sintered magnesia - iron rich (AL-ZE, AL-ZE AF)

 Classification according to type of spinel used

Pre-reacted spinel In-situ spinel

• Spinel (AL R2, AL RE) • Spinel (AL R1)


• Hercynite (AL Z1)
• Galaxite (AL XE)
• Q-Series (AL QF)
• Chromite (AL SE)
Classification of Magnesia Spinel Bricks
Brick Types
Raw material combinations

80-95% Component A 5-20% Component B


Resistor Flexibilizer

MgO
Spinel Chromite
(SYNTHETIC) (NATURAL)

NATURAL SYNTHETIC
PREFABRICATED IN SITU
Electrofused During Burning Process:
or Sintered •Corundum
Low iron •Tabular Alumina
High iron •Calcined Alumina

MA FA MnA Q-Series
(Hybrid Spinel)
(„Standard“ Spinel) (fused Hercynite) (fused Galaxite)
1 Introductions

2 Raw materials Sintered Magnesia

3 Raw materials Spinel

4 Brick types and Lining Recommendation

33
Nomenclature
for basic cement rotary kiln bricks

ANKRAL R 2 CB XY

Code for different further


processing steps such as:
Pre-attached Cardboard attached on side B
R1…anti hydration treatment
R2…coating repellent impregnation
1, 2…Serial number for further distinction of different brands SS…special color marking as per
customer request
E… Economy grades

C…Products produced only in China

Type of spinel:
R – MA-spinel
Z – Hercynite
Q – Hybrid spinel technology
S – Chromium spinel

(all) basic cement


rotary kiln bricks are
named ANKRAL

34
Nomenclature MAGKOR

MAGKOR S 2

1, 2…Serial number for further distinction of different brands

Product lines:

Superior
Special products for extreme conditions

Top grade
MAGKOR: basic brick for cement rotary kilns
products for aggressive conditions

Standard
products for regular conditions

35
Product Range
for specific operation conditions

UTZ
CBZ

Outlet / LTZ

Central burning zone (CBZ)  bricks able to promote the formation of stable coating

Lower/Upper Transition Zone (LTZ, UTZ)  bricks with elevated resistance to


chemical attack, mechanical stresses and/or thermal load

36
Central Burning Zone (CBZ)

Alpine, sintered magnesia significantly promotes the formation of a stable


coating in the CBZ due to the unique properties of this raw material.

Properties
• outstanding ability to form stable protective coating
• high flexibility due to use of hercynite
• low thermal conductivity

Products
ANKRAL ZE
ANKRAL ZE AF
ANKRAL QE

37
Products for the Central Burning Zone (CBZ)
ANKRAL range
ANKRAL ZE ANKRAL ZE AF ANKRAL QE

Special features:

38
Products for the Central Burning Zone (CBZ)
MAGKOR range
MAGKOR A1 MAGKOR A2 MAGKOR A3

Special features:
MAGKOR A2

39
Transition Zones (LTZ/UTZ)

The transition zones can be particularly exposed to severe stresses.


For the selection of the best suitable refractory material the process conditions need
to be evaluated in regard to the predominant stress phenomenon.
The nature of these phenomena can be

Thermal Mechanical Chemical

Specially designed brick grades are available for specific conditions.

40
Thermal Load

In case of high thermal load refractories with a particular high content of MgO are
required. These products are also used for the lining of white cement kilns.

Due to the high MgO content these products are also very resistant to clinker melt
infiltration.

 ANKRAL Z1

 ANKRAL R1

 ANKRAL RN

41
High Thermal Load
Products for the LTZ / UTZ
ANKRAL Z1 ANKRAL R1 ANKRAL RN

Properties
• MgO content >90% 
• Low in Al2O3 and Fe2O3
• Refractoriness >1700°C

Special features

+ ANKRAL R1/RN

42
High Thermal Load
Products for the LTZ / UTZ
MAGKOR S7

Properties
• Addition of ZrO2
- improves hot properties
- improves resistance to clinker melt infiltration
• Refractoriness >1700°C

Special features

43
Mechanical Load

RHI has developed a complete new product range to withstand the critical
conditions often encountered in the tyre section or in areas with kiln shell
deformations. The so called hybrid spinel technology provides superior
flexibility and has proved excellent results in mechanically highly stressed
areas.

 ANKRAL QF
 ANKRAL Q1
 ANKRAL Q2/QC
 ANKRAL QE

44
High Mechanical Load
Products for the LTZ / CBZ /UTZ
ANKRAL QE Q2 Q1 QF
Properties
• Outstanding micro-structural flexibility
• Excellent refractoriness
• High to outstanding chemical
resistance

Special features

ANKRAL QE ANKRAL Q2 / Q1 / QF

45
Chemical Load

Chemical wear is characterized by two effects:

I. Corrosion of the
brick structure,
ceramic
bonding
Chemothermal
Load
II. Densification of
the brick structure,
loss of flexibility

46
High Chemical Load I

High chemical stresses by the infiltration of alkali salts requires the use of high purity
sintered magnesia, in order to reduce the impact of corrosion of the ceramic bonding.
RHI´s top grade basic bricks are based on synthetic sintered magnesia and therefore
provide excellent chemical resistance.

 ANKRAL Z1
 ANKRAL R1
 ANKRAL R2
 ANKRAL R8

47
High Chemical Load I
ANKRAL range
ANKRAL Z1 ANKRAL R1 ANKRAL R2 ANKRAL R8

Properties
 Excellent chemical
resistance
 Low amount of side phases
(SiO2 + CaO)

48
ANKRAL R8: Reference India
Kiln Details
Kiln:
FLS  4,35 x 66m
PC with grate cooler
4.300 tpd

Situation:

ANKRAL R8 lined in the LTZ between 0-8m. Before used ANKRAL Z1 and ANKRAL R2..

49
ANKRAL R8: Reference India
Results after a full campaign

Residual thicknesses of 205mm (orig. 220mm)


after a full campaign. Sample from LTZ rm 4.

50
ANKRAL R8: Reference India
Chemical Investigation

51
High Chemical Load I
MAGKOR range
MAGKOR B1 MAGKOR B2 MAGKOR B3

Properties
 Excellent chemical
resistance
 Low amount of side phases
(SiO2 + CaO)

52
High Chemical Load I
MAGKOR S2

Additionally to the use of synthetic sintered magnesia with high resistance to


chemical attack, MAGKOR S2 features a particularly low porosity and
permeability.
The low permeability hinders the penetration of volatiles in the brick by its
specially designed narrow pore structure.

53
High Chemical Load II

Besides the corrosion of the ceramic bonding, the infiltration of alkali salts
also severely reduces the structural flexibility of the refractory. The
implemented hybrid spinel technology significantly reduces this effect and
thereby significantly reduced the risk of crack formation and spalling.

 ANKRAL QF
 ANKRAL Q1
 ANKRAL Q2

54
High Chemical Load II

ANKRAL Q2 Q1 QF

Properties
 Outstanding micro-structural flexibility
 Excellent refractoriness
 Outstanding chemical resistance

55
Comparison Youngs Modulus
Modulus of Elasticity

Even when infiltrated ANKRAL Q2 shows a lower Young’s modulus than a


conventional MA spinel brick type (e.g. ANKRAL R2, ALMAG 85 or MA11).

56
ANKRAL QF
Reference Germany
Kiln:  5,2 x 87m SP with satellite coolers, 2.500 tpd
Lining area: UTZ tyre between rm 31,6 and 35,6
Tyre creep within campaign: about 40mm/rev

Fuels:
Main burner: bituminous coal, plastics, solvents (AF approx 70%)
Inlet: tyre chips

Situation:

The usual lining life until now has been limited to 4 months due to strong mechanical
and chemical load in the tyre section.

57
Results
after full campaign of 12 months

Brick shows nearly full residual thickness (205mm from original 220mm) with clear
signs of severe chemo-thermal and mechanical load (scratch marks and damages on
the cold face).
Furthermore there are reducing operation conditions.

58
Results
after full campaign of 12 months

Severe chemical attack and mechanical load !!


The colour is gone,
but nothing serious happened.
Increase of life time from 4 to 12 months !

59
Results
Chemical investigation Cusomter SPZ
Plant Germany
Aggregate Cement Rotary Kiln
Lining Area UTZ
Brick type ANKRAL QF ANKRAL QF
2-25 mm 75-100 mm 130-155 mm 180-205 mm
Data sheet
Sampling from hot face from hot face from hot face from hot face

LOI wt% 4,18 7,09 3,62 -0,08


1)
Oxides after ignition
MgO wt% 83,8 80,4 83,6 86,8 87
Al2 O3 wt% 9,69 9,73 8,8 9,26 9,3
SiO2 wt% 0,26 0,25 0,27 0,26 0,3
CaO wt% 0,83 0,74 1,3 0,76 0,7
MnO wt% 0,12 0,12 0,13 0,12
Fe2 O3 wt% 2,33 2,97 2,73 2,71 2,7

Bestimmung über Titration 2)


Cl wt% 1,84 3,24 1,51 0,07

Bestimmung mit Leco 2)


S wt% 0,01 0,24 0,24 0,05
SO3 wt% 0,03 0,6 0,6 0,13

Bestimmung mit ICP-OES 2)


Despite severe chemical
K2 O wt% 1,07 1,88 0,92 0,05
load no spalling or crack Na2 O wt% 0,05 0,08 0,11 0,05
formation. Molar alkali-sulphate-ratio 3)
(K2 O/94)+( Na2 O/62)-(Cl/71)
-43,92 -3,25 -1,3 0,23
(SO3 /80)
60
ANKRAL QF
Mineralogical Investigation

Microstructural detail from sampling area 2


showing severely densified brick structure but
no corrosion or degeneration of hercynite.
Formation of monticellite as corrosion product
of dicalcium-silicate.
Magnesia (1), potassium chloride (2),
monticellite (3), hercynite (4), complex spinel
(5).

61
High Chemical Load II

Besides the corrosion of the ceramic bonding, the infiltration of alkali salts
also severely reduces the structural flexibility of the refractory. The
implemented hybrid spinel technology significantly reduces this effect and
thereby significantly reduced the risk of crack formation and spalling.

 ANKRAL QF
 ANKRAL Q1
 ANKRAL Q2

62
Products for TZ with Moderate Chemical Stresses

For transitions zones without particular severe operation conditions and moderate
chemical stresses RHI provides basic bricks based on natural sintered magnesia.

 ANKRAL RE
 ANKRAL RN
 ANKRAL ZC
 ANKRAL RC

63
Products for TZ with Moderate Chemical Stresses
ANKRAL range
ANKRAL RE ANKRAL RN ANKRAL ZC ANKRAL RC

64
Products for TZ with Moderate Chemical Stresses
or higher loaded burning zones
MAGKOR A1

65
Coating Repellent Bricks

Frequent coating changes significantly increase the wear of refractory products. In


some areas process disturbing ring formation appears. For both cases coating
repellent brick types can be a solution.

 ANKRAL R2 (passive coating repellent)


Its pure raw material concept, and the reduction of
any coating providing additive results in coating repellent properties.

 REXAL 2S EXTRA R2 (active coating repellent)


An additional impregnation treatment provides coating repellent properties. The
impregnation treatment seals the pores of the hot face and reduces the adherence
of coatings.

66
BASIC BRICKS European production
Brand MgO CaO SiO2 Al2O3 Fe2O3 Cr2O3 BD AP CCS TSR RUL Raw material
Product overview basic bricks Air ta
% % % % % % g / cm3 Vol. % N / mm2 Cycles °C

Q-concept bricks

ANKRAL QF 87,0 0,7 0,3 9,3 2,7 --- 2,97 16,0 70 >100 > 1700 Magnesia fused Hercynite +

ANKRAL Q1 86,8 1,1 0,5 9,0 2,6 --- 2,97 16,0 70 >100 > 1700 Magnesia fused Hercynite +

ANKRAL Q2 86,3 1,6 0,8 9,0 2,3 --- 3,00 16,0 70 >100 > 1700 Magnesia fused Hercynite +

ANKRAL QE 81,4 2,0 0,6 9,0 6,5 --- 2,99 16,5 75 >100 1680 Magnesia fused Hercynite +

based on top quality sintered magnesia

ANKRAL Z1 91,8 0,8 0,3 3,4 3,8 --- 2,99 15,0 80 >100 > 1700 Magnesia fused Hercynite

ANKRAL R1 90,8 0,8 0,3 7,5 0,5 --- 2,96 15,0 70 >100 > 1700 Magnesia MA-Spinel

ANKRAL R2 87,9 0,8 0,3 10,5 0,5 --- 2,95 16,0 65 >100 > 1700 Magnesia MA-Spinel

ANKRAL R8 85,7 1,1 0,5 12,0 0,5 --- 2,92 16,0 70 >100 > 1700 Magnesia MA-Spinel

REXAL 2S Extra R2 85,9 0,8 0,2 12,5 0,4 --- 2,94 15,5 60 >100 > 1700 Magnesia MA-Spinel

based on high quality natural sintered magnesia

ANKRAL RE 86,8 1,7 0,8 10,5 0,2 --- 2,96 16,0 70 >100 > 1700 Magnesia MA-Spinel

ANKRAL RN 91,2 1,8 0,8 6,0 0,2 --- 2,94 16,5 75 >100 > 1700 Magnesia MA-Spinel

based on iron rich alpine sintered magnesia

ANKRAL ZE AF 87,8 2,0 0,9 3,0 6,3 --- 3,04 16,0 90 >100 > 1700 Magnesia fused Hercynite

Basic Brick85,9
ANKRAL ZE Types
2,0 1,0 3,0 8,0 --- 3,02 16,5 90 >100 1600 Magnesia fused Hercynite
BASIC BRICKS Mexican Production
Brand MgO CaO SiO2 Al2O3 Fe2O3 Cr2O3 BD AP CCS TSR RUL Raw material
Air ta
3 2
% % % % % % g / cm Vol. % N / mm Cycles °C

Q-concept bricks

ANKRAL QF 87,0 0,7 0,3 9,3 2,7 --- 2,97 15,5 70 >100 > 1700 Magnesia fused Hercynite +

ANKRAL Q1 86,8 1,1 0,5 9,0 2,6 --- 2,97 16,0 70 >100 > 1700 Magnesia fused Hercynite +

ANKRAL Q2 86,3 1,6 0,8 9,0 2,3 --- 3,00 16,0 70 >100 > 1700 Magnesia fused Hercynite +

based on top quality sintered magnesia

ANKRAL Z1 91,8 0,8 0,3 3,4 3,8 --- 2,99 15,0 80 >100 > 1700 Magnesia fused Hercynite

ANKRAL R1 90,8 0,8 0,3 7,5 0,5 --- 2,96 15,0 70 >100 > 1700 Magnesia MA-Spinel

ANKRAL R2 87,9 0,8 0,3 10,5 0,5 --- 2,95 16,0 65 >100 > 1700 Magnesia MA-Spinel

ANKRAL R8 85,7 1,1 0,5 12,0 0,5 --- 2,92 16,0 70 >100 > 1700 Magnesia MA-Spinel

REXAL 2S Extra 85,9 0,8 0,2 12,5 0,4 --- 2,94 15,5 60 >100 > 1700 Magnesia MA-Spinel

based on high quality natural sintered magnesia

ANKRAL RE 86,8 1,7 0,8 10,5 0,2 --- 2,96 16,0 70 >100 > 1700 Magnesia MA-Spinel
BASIC BRICKS Chinese production

Product
Brandoverview
MgO basic
CaO SiO bricks
Al O Fe O 2 2 3 2 3 BD AP CCS TSR RUL Raw material
Air ta
3 2
% % % % % g / cm Vol. % N / mm Cycles ta °C

ANKRAL Q-Series

ANKRAL QF 87,0 0,7 0,3 9,3 2,7 2,97 15,5 70 >100 > 1700 Magnesia fused Hercynite +

ANKRAL Q1 86,8 1,1 0,5 9,0 2,6 2,97 16,0 70 >100 > 1700 Magnesia fused Hercynite +

ANKRAL QC 85,4 1,5 0,7 9,3 3,1 2,90 17,0 60 >100 > 1700 Magnesia fused Hercynite +

based on top grade sintered magnesia

ANKRAL Z1 91,8 0,8 0,3 3,4 3,8 2,99 15,0 80 >100 > 1700 Magnesia fused Hercynite

ANKRAL R1 90,8 0,8 0,3 7,5 0,5 2,96 15,0 70 >100 > 1700 Magnesia MA-Spinel

ANKRAL R2 87,9 0,8 0,3 10,5 0,5 2,95 16,0 65 >100 > 1700 Magnesia MA-Spinel

ANKRAL R8 85,7 1,1 0,5 12,0 0,5 2,92 16,0 70 >100 > 1700 Magnesia MA-Spinel

based on high quality natural sintered magnesia

ANKRAL ZC 89,5 1,5 0,7 4,0 4,3 2,96 15,5 80 >100 > 1700 Magnesia fused Hercynite

ANKRAL RC 86,6 1,5 0,7 10,5 0,7 2,92 16,0 70 >100 > 1700 Magnesia MA-Spinel

69
Basic Brick Types
BASIC BRICKS Brazilian/European production
Brand MgO CaO SiO2 Al2O3 Fe2O3 ZrO2 BD AP CCS TSR RUL Raw material
Air ta

Product overview
% basic
% % bricks
% % % g / cm3 Vol. % N / mm2 Cycles °C

MAGKOR S-Grades

MAGKOR S2 86,5 0,8 0,30 11,5 0,5 --- 3,03 14,0 85 > 100 > 1700 Magnesia MA Spinel

MAGKOR S3 89,0 0,8 0,30 9,0 0,5 --- 2,95 16,0 79 > 100 > 1700 Magnesia MA Spinel

MAGKOR S7 84,5 1,0 0,30 11,0 0,4 1,80 3,00 15,0 70 > 100 > 1700 Magnesia MA Spinel

MAGKOR B-Grades

MAGKOR B1 85,9 0,8 0,20 10,5 0,5 --- 2,94 16,0 65 > 100 > 1700 Magnesia MA Spinel

MAGKOR B2 87,9 0,8 0,30 10,5 0,5 --- 2,95 16,0 65 > 100 > 1700 Magnesia MA Spinel

MAGKOR B3 90,8 0,8 0,30 7,5 0,5 --- 2,96 15,0 70 > 100 > 1700 Magnesia MA Spinel

MAGKOR B5 91,5 0,8 0,40 6,5 0,6 --- 2,95 16,0 60 > 100 > 1700 Magnesia MA Spinel

MAGKOR A-Grades

MAGKOR A1 86,6 1,5 0,70 10,5 0,7 --- 2,92 16,0 70 > 100 > 1700 Magnesia MA Spinel

MAGKOR A2 87,1 0,5 1,30 7,5 2,2 --- 2,87 19,7 64 > 100 > 1700 Magnesia MA Spinel

MAGKOR A3 87,0 0,6 1,20 8,5 1,4 --- 2,90 18,0 65 > 100 > 1700 Magnesia MA Spinel

70
Basic Brick Types
Get in touch
Roland Krischanitz
Head of Technical Marketing
Wienerbergstrasse 9
1100 Vienna Austria
Phone: +43 50213 6720
E-mail: roland. krischanitz@rhimagnesita.com
rhimagnesita.com

Important notice:

These materials do not constitute or form part, or all, of any offer of invitation to sell or issue,
or any solicitation of any offer to purchase or subscribe for, any securities in any jurisdiction
in which such solicitation, offer or sale would be unlawful, nor shall part, or all, of these
materials form the basis of, or be relied on in connection with, any contract or investment
decision in relation to any securities.

These materials contain forward-looking statements based on the currently held beliefs and
assumptions of the management of RHI Magnesita N.V. or its affiliated companies, which are
expressed in good faith and, in their opinion, reasonable. Theses statements may be
identified by words such as “expectation” or “target” and similar expressions, or by their
context. Forward-looking statements involve known and unknown risks, uncertainties and
other factors, which may cause the actual results, financial condition, performance, or
achievements of RHI Magnesita N.V. or its affiliated companies to differ materially from the
results, financial condition, performance or achievements express or implied by such forward-
looking statements. Given these risks, uncertainties and other factors, recipients of this
document are cautioned not to place undue reliance on these forward-looking statements.
RHI Magnesita N.V. or its affiliated companies disclaims any obligation to update these
forward-looking statements to reflect future events or developments.

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