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Assignment 3 Hydrocarbon

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Assignment 3 Hydrocarbon

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SENG corner” (aa ‘Text Based Objective and Exemplar Problems NCE 1 Arrange the following in decreasing order of their (@) 3, 6-Diethyl-2-methyloctane boiling points. (b) 5-Isopropyl-3-ethyloctane A) n-butane (©) 3-Ethyl-S-isopropyloctane (©) 2-methylburane (@ 3-1sopropyl-6-ethyloctane (©)n-pentane 5. The addition of HBr to 1-butene gives a mixture of (D) 2, 2-dimethylpropane Products A,B and C (@)A>B>C>D ()B>C>D>A Br Br ()D>C>B>A @)C>B>D>A c. © @ - nef cx, cw fon 2. Arrange the halogens F, ,Cl2,Br,12,in order of their 4 Cals increasing reactivity with alkanes. w o (@)1, HBr > HI (b) HBr > HI > HCL (HI> HBr> HCl (4) HCL> I> HBr 8. Arrange the following carbanions in order of their decreasing stability. (HS—C=C @B)H—c=c” (QH3C— CH (®A>B>C ®B>a>c (OC>B>A @C>A>B Arrange the following alkyl halides in decreasing order of the rate of B- elimination reaction with alcoholic KOH, H over, —¢—ci,er Hs (®)CH, — CH, —Br (OCH, —CH, —CH, — Br (@A>B>C (bt) C>B>A (B>c>A (@A>C>B 10. Which of the following reactions of methane is incomplete combustion? (a) 2CH, +0, —Sus28Ri1000 0c ,OH (0) CH, +0, “2°, HCHO + H,0 (OCH, +0, —> C(s)+2H,00 (CH, +20, —+ CO3(g) +2H,00 4. (a) A parent chain with larger number of substituents is preferred, rere eee CH,CH,—CH—CH,CH,—CHtCH,CH, CH,CH, sa CH, crf, Hy ‘Bygone (Wrong numberisig> aie es CHsCHy—C—CHCH,— CHC, CH, ow CH,CH, chi cH, 3, 6Diey.2-neylcane (Correct numbering) 5. (a) Addition of HBr to 1-butene occurs in accordance with Markovnikov’s rule giving I as the major and Cas the minor product. Be Cac —cHmce, > CH,CH,—CH—CH + CH,CH,CH,CH,—Br Br “ 1 Compound I contains a chiral carbon. Therefore it exists in two enantionmers (A and B) which are mirror images of each other hai aa ‘Thus, the mixture consists of A and B as major and Cas minor product. 8. (b) sp-Hybridized carbon is more electronegative than, a sp*-hybridized carbon and accommodates the negative charge better. Therefore, (B) is more stable than (C), CH, group has +Leffect. Therefore CH group intensifies the negative charge and makes A less stable. Thus, sta decreases in the order : B > A> C. 9. (d) Greater the stability of alkene formed, greater jg the reactivity of alkyl halide. Alkene obti from (A) is CH, C= CH, CH This alkene is most stable, Therefore, reactivity towards p-elimination decreases in the order ; A>C>B. 10. (¢) Combustion is done with air orO,. In combustion, CO, and water is formed. Reaction (©) is incomplete combustion. PEDER eosic Problems | —— © << 1. Which of the following alkanes has a meso stereoisomers ? © < 2. Among the following, the compound which has y Br highest boiling point is C~ ah Product: Br Cai wo Br. MgBr gy BrMg._~_-MaBr @n~w~ ox @®\~ o 8. Propane can be best prepared by the reaction : foc,—-ca—c, @ZX (@) CH,CH,I+ CHyI+Na—B2 + 8 Which of the following methods of alkane synthesis (b) CH,CH,COONa + CHyCOONa #2 involves the electrochemical oxidation of alkanoate ecropee ion? (© CH,CH,Br + (CH,),CuLi "2 5 (a) Kolbe's method (b) Wurtz method (@ CH,CH,CH,COONa — "0H (©) Frankland method _ (@) Corey-House method 08 9. The reactivity of alkyl halides for Wurtz reaction is 4, Me ;CMgClon reaction with D,0 produces (@) > 2°>3° (0) 3°> 2° 1° (@) MescD (@) Me,CoD Oras (rs3%5 2 (©) (CD3)30D (@) (CD3),COD 10. Which of the following is planar and cannot form 5. Which of the following carboxylic acids undergoes conformational isomer ? decarboxylation most easily on heating ? (@) CH,CH,COOH wll wA @ @ oO ° 11. Which statement is incorrect about free radical (6) CH, —C— COOH halogenation of alkanes ? oO t (a) The number of product molecules formed by one (0 Gis Ct, 08 pont ivy hih (b) If 0, is added, initially the rate of reaction decreases, then it increases. (©) Inhibitors combine with free radical and terminate the chain reaction (4) Presence of Ph—C —O —O—C —Ph inhibit il the free radical reaction, 9, 13, 4, 18. 16. 17. The correct order of heat of combustion of the following hydrocarbon is : Pent-I-ene Pentane Neopentane _Isopentane @) @ ® © (@ P>Q>R>8 0) Q>S>R>P (© P>Q>S>R @S>R>Q>P Formation of free radical is easiest in : @~a (0) Br o-~r @™ ‘What is the chief product obtained when n-butane is treated with Br, in the presence of light at 130°C ? (a) “Tt ©) >a ir © . @) ~~ ‘The number of possible enantiomeric pairs that can be produced during monochlorination of 2-methyl butane, is : @3 0) 4 2 @1 How many total products will be obtained by ‘monochlorination of 2-methyl butane and how many can be separated by fractional distillation ? @64 054 62 42 Cine: How many monobrominated products will be obtained by above reaction ? @6 we os 3 CH, I 18. Be CHs cH, I @ a (b) CHCl, CH; 19. (©) both (a) and (b) (4) none of these How many alkane of molecular weight 100 are chiral ? (a1 (b)2 3 @4 Ph— CH Cll, —GHy + CH; a1. 24, No of produets and no. of factions ae respon - NCERT Chemistry Booster @65 (0) 6,4 54 6,3 ‘The relative reactivity of 1°,2° and 3° hydrogens ig chlorination reaction has been found tobe 13g. In the reaction, a “ + >< + aul © © tthe ratio of the amount of Ute product (4),(8),(c) and (D) is expected to be : (a) 1:3.8:5:1 (b) 3: 7.6 (© 3:7.6:5:3 @ 6: L\ + Hor Product: @ Aa oo) ~~ Br © @—~s Br A SPS HB major produc the ‘major product is : OS™ ewe major product, the ‘major pre ‘uct is : A, iy (a) ® @Q~ne © A pdrocarbons 25 27. 28. 29. 30. 31. Z™, — ~ Bi rac, the product is (a) a of os (@Hyc=c=cH, . The method of estimation of active hydrogen in a compound by reaction with CH ,Mgl is known as : (a) Zerewitinoff method (b) Hinsberg method (©) Zeisel method (d) Victor Meyer's method Consider the following reaction : PhyC—O—O—cPh. AQ + 60, OO, ‘The major products formed in this reaction are : @ >< gandcuct, ou © 4t and <8 A oy Find out number of monochlorinated products (including stereoisomers) which are possible in the above reaction. (a2 (be) 3 ‘CHy Products of the above reaction will be : and CHCl (d)no reaction o4 @s (b) diastereomers @ structural isomer (@) racemic mixture (©) meso D CK "4 product D W,02 D fas oD ) att D A D CGE — ommarantco D HC. _, - Ni D7 SCH; Product of above reaction will be : (@) racemic mixture _(b) diastereomers © meso (@) constitutional isomers 35. 36. 37. oa. (2H meu CL ” BroH,c~ CH,—Br @ cmg © (@) none of these HMO, product: (a) Cr ) Cx eG (€) none of these BRAS cc CH Br _ w/the aor product: Br- »DOG Ds E © ~Orm oy Arrange the following alkanes in decreasing order of their heat of combustion & CH —CHy >~ aa CH3 oo mw @® (a X>Y¥>Z (b) Z>X>Y ()Z>¥>x X>Z>Y Se conn ‘HO. @ AN mL Caras @ hy oO In the reaction, CHP Br CSO ‘The major product obtained is : cS _ i certt wrA- ork HH 38. On apa: ox wr ox (@) none of these 39. [ cr, on SHPO 5 Major product: @[ ec, w[_)-cn, © oO @ > 40. The major product of the following reaction is Br A nee, @ oT oo © oS 41. Operete @ () Py (©) both (a) and (b) @ j cooH - CH — CH —CH — CH, — product 42. Cll, —CH—CH— CH, > produ COOH bv, Ale KOH {) WN, produce + 46. 47. CH Hy / oO ——> [_) reagent used for the reaction : (@) iAH, (© NaBH, HN (@H,, Pa —Baso, beeen iS. ‘Which reagent will be used for the above conversion? (@) Na/L.iq.NH (b) H,, Pd—caco, (© Li, Ph—NH, @Hy,Pt Which of the following has zero dipole moment ? Go) HaHa Cs Boo Ny CHC eH HO Nc cH, CH, © Scace* H7 “H CH eH c=: Oyen G,, Which of the following is correct order of stability of alkene ? (@ CH, —CH=cH, <\/< OK () cH, —cH=cH,<\ << x Hydrocarbons 0 SKS Aa Br i : : @ot hhh, ‘Major product : H,C—CH—CH) NZ Br I 0) Bf (a) wc0-{_ cri, crc, ° (¢) HxC —CH—CH, — Br ¥ (@) None of these © ,co-{ CHACH,—CH, 50. Consider the following reaction : CH, (©) both (a) and (b) in same amount ! (@ none of the above H,C—C—CH =CH, +HCL—> | 53, H,C=CH —C=CH +HCI—>X; * CH; f ‘The major product obtained in the reaction is : @Hc—cH—c=cH cl CHy + ()H,C=CH—C= CH, (a) H,c—C—CH—CH 1 | a a CH, dia (© CH, —CH—C=cH I a (b) Hjc—C —CH —CH, | a ° (@cH,—ca—c=cH, CHy I a cH; 54, ZH Heel), Major product : I (Q H,cC—C—CH, — CH, —Cl Br JS | are on CHy (@) none of these 51. on-{_\)-cr cca, Hol of (@) None of these ‘Major product : —_—_ 55. The reactivity of alkene, s HyC—CH=CH, ; cmc 3 Hy H=CH, HyC 3 oo ) @ towards hydrogen i (a) X>¥>z (b) ¥>X>Z (0 2>X>¥ (Y>2>Xx 3 I 56. HyC—Cm cp HH Ha Pt 80804 Product : 5 ite ‘CH (@) an optically active compound (©) an optically inactive compound (©) a racemic mixture a a diastereomeric mixture eae, Aand B are respectively : CH, @ Ox * both ‘OH © Crcu.cn both © ( and On ‘OH @ ()-aH01 and Ox ‘OH 58. What reagent is needed to accomplish the following synthesis ? MES moc a (H80 (6) Kuno, 0H (©) 05,20/H,0 (4) Ph—COH 59. Which compound will yield 5-keto-2-methyl hexanal upon treatment with O ? Hy @ & CH © & CH, ae NOERT Chemistry Booster, Hy s © @ wy iH 60, a S86 HePO4 Major product: 61. 62. of 0 © Cx @ iS) wre = CCH, T2284, Major produc: (@) None of these HC — CH =CH, + HCl". product, the intermediate of reaction is : (0) CH, — cH, —CH, @ @ CH; — CH, —CHy 2 —CH-CH, 1,CHy (©) CHs NBS, Ale KOH pHa, CHIH 7 pr: NaBit OF CH=CH, gets ICH, ) é carb a CH,—CH,—O—CH,—Ph © CH=CH, @ O-CH,—Ph Ni “© “fmt: ) © © (@) no reaction 65. Choose the reaction sequence that would best accomplish the preparation of 2-methylcyclohexanol : fi “0 HO, H,$04, oO Hig (OAe)», 1,0, NaBH, OF BH, THF Bhi, THE =e @ Teo NaH HO, NeOH xH-cl @n——cel, CH 67. Give the major product of following reaction, Major product : on ‘OH (© Ph—CmeC—CH Br @ © CA. I 0 ‘OH 1 0, © Ay @ 68. Which of the following products is not formed in following reaction ? Oy Br @ OK w*™ 0K om 6s. CY a+ Mar ett: NaBb 208 oko ' woKe 3 70, TSc=CH-CHy HMR HE Major product : cH 3 a,c ges Phy __-CH—CH, Phy __-CHy—CHs » cH SH ®@ cao Phy _/-CHy—CHly c © curSoc, Nate ofthese CH, 1. chy HEMACHOH . 71. Gp CCH, HRA Major product: Cy CHD © cySon 32) Phy cH, Sal , : 72, chy Do= cH, S22 + Major product : Ph_-OH Phy cl ©) ou oN cue » cr cH,—on Ph. _-CH;—Cl Ph g-GHty-OH © ara cH SH Pay 78. (C= CHCH, —¥4_+ Major product: i Heya OH Pho -CHieCHly Po CHC CH;~ “SoH cH SH J oH > Phy -CHCH, Phy, CHC, © ca Np cH SoH 74. Which would produce chiral molecule after treatment with Lindlar catalyst ? (@ ar ot | os ory 75. Which of the following compounds was starting ‘material for the oxidation shown below ? OH Compound —##24/#®, Ho +00, ‘OH oO @ or ® ‘or © oy oo 76. The product of following reaction can be best described as in (a) a racemic mixture (b) a single enz _ (© a pair of diastereomers (4) an achiral molecule Te AF A x BOY ths 232 ¥ 2 Hy @ o e~oQ 78. Product of following reaction can be best described as. oe ws (a) meso product (b) a pair of enantiomers (©) structuralisomer (4) apair of diastereomers 79. Which of the following reactions results in the formation of a pair of diastereomers ? HG oH HG oH o Oe, @ Me B® Hi, Hj oH HCG OH z oe athe © Se ee 80. Anon —BalS2_5 Major product : Br oH o AANA» Arn Br Br CH. 5 81. BA Major product : 82. a> HEH, Major product : r © @ ak Hg a b) (CH: _ Cnet 7 BLL 1, GC a, on «O val? CHy ae, Major product : Stereochemistry of the product are : i, (@) diastereomers ©) meso @ Kon 7. (© racemic mixture (d) pure enantiomers ‘OH ‘OH #5. Ph—CH = CH —Ph—S2> xia, Cee é Hi y—Harecae0s 7 [on Llu Identify product (Z) of the reaction. Ph H Pho Ph nop J Some — —2i(0802_, Major product : @ ome My, 2a, 2H i © omer (@ Ph—C=C—Ph @ © cr Excess CFCO4H OH, 86. © @ of Ce Ht 91. oO es Comment on optical nature of product. (a) Racemic mixture (b) Enantiomer (© Diastereomer (@) Optically inactive oa. ca product on on Tur Le 98. What is the final product of the following reaction ? 94. Which of the following is not formed in given ro or ot Ot ate a @ 95. Choose the best reagent to carry out the following transformations : HjC—C = C—H—> Ca (@) Lindlar catalyst; NaNH,/NH, (0, 1-bromopro- pane (b) NaNH,/NHy (©, L-bromopropane; Lindlar catalyst (© NaNH,/NH, (0, 1-bromopropane; Li/NH; (0 (d) All of the above 96. Which of the following will be most reactive in the addtion reaction with HBr ? (a) CH, —C=m=C— CH, (b) AA © oO oS W 97. Compound (x) 242, H + o 0 Find the structure of (X). (@) both (a) and (b) HC. CH; omc: SH @ eV © Pn cH, 100. THY, Product : ll (© R— C—aH, —cHy cH, HCN A @ yo Nery es of hydration ofthe following alkenes are : 01. at 10 sO —CH=CH,; F—CH=CH,; ) @ CH, —CH=CH, Qenay © (a) P>Q>R>S (b) S>R>Q>P (© P>S>R>Q (@R>S>P>Q 02. Rates of hydrohalogenation of the following alkenes of); a-ana-() @ \ CHy—E— CH= as CH, —CH =CH—CH, 6 CH, ® (a) P>Q>R>S (dD) Q>P>R>S (Q>P>S>R (@P>Q>S>R 108.3CH, —C=CH—ESE > curate @ oO ) CH, b a a m @ a, 2 HAC tf. ci,cH,c—c uyio , _ cHscHaBe Ni (2) CH,CH,CH =CH — CH (b) CH,CH,CH = CH CH CH, C=C! © y= Nerycr, CH,CH, —_-CH,CHy Oey 9° ll 108. CH,CH,CH, —C—H +H, —ComcH > AX @ (7% ae ) oe Nery OH c Py oe ctl, IH nae oH 106, The produets of the following I and I sequences a=° related as : 1, PaaS, 3 /, ®, CHy—C = C—CHy i, TP (@) diastereomers (6) identical (© enantiomers (@ geomertical isomers 107. The order of reactivity of alkyl halides in Wrz reaction is : (@) R-I>R-Br>R—C1 (b) R-ER-I>R-C! (d) RA>R—Cl>R—Br 108, Ware reaction on a mixture of ethyl halide and isobutyl halide gives: (@) Butane and isobutane (b) Butane and 2,5~dimethylhexane (c) Butane, 2,5-dimethylhexane and isohexane (@ Butane and isohexane 109. The Corey-House alkane synthesis is carried out by ‘treating an alkyl halide with: (@) Lithium metal (0) Copper metal (©) Lithium metal followed by reaction with cuprous iodide and then treating the product with an alkyl halide (@ Cuprous iodide followed by reaction with alkyl halide ust Be 110. 11. 112, 113. 114, 115. 116. 117. 118. Which of the following acids on decarboxylation sives isobutane: (a) 2,2-Dimethyl butanoie acid (b) 2,2- dimethyl propanoic acid (©) 3-Methy! pentanoic acid (@ 2-methyl butanoie acid ‘The volume of methane evolved by treatement of 16.6 g of methyl magnesium iodide with water at S.TRis: (@) 224 mL. (b) 2.241. (© 0.2241, @ 2241 Which of the following compound is not suitable to obtain from wurtz reaction? (@) ethane (b) butane (© isobutane @ hexane ‘When ethyl chloride and n-propyl chloride underoges ‘wurtz reaction which is not obtained: (@) n-butane (b) n-pentane © whexane (@) isobutane How many acids can be taken to obtain isobutane from decarboxylation: @4 3 ©2 @5 Give reactivity order for decarboxylation? (D CH, — CH, — COOH; @) CH, = CH — COOH; (i) CH =¢—CooH @i>0>m @)m>u>1 (©m>1>n @u>1>m Which of the following reagent can be used for following conversion : HOC Goss H0-(-y ye. (@) Zn —Hg/HC (© NH, —NH, /°0H (b) Red P+ HI @ All of them Which of the following does not give alkane with RMgx (@) Ph—OH (© CH,COOH () CNH, @ Hel - Which of the following reaction can not be used to obtained propane: (@) Wurtz propane () Corey-house reaction (© Decarboxylation of acid salt (@) Allof them 119. (A) CH, — CH— COOH BPH, OH “B' looses its optical activity because of: (@) Chirality of the molecule destroyed (b) Symmetry of molecule is destroyed (© Spatial arrangement is changed (@) Recemic mixture is formed Hs 120, Gil, — CH MgCl + CHy—¢—O8 —vqy, Hy cH, What is‘Q’? (@) isobutane (b) isopropane (©) tert. butyl chloride (4) propane 124, (De ecante convenes ol) ; (a) Red P+HI (b) Wolf kishner reduction (© Clemmensen reaction @a ou 122, (CH,)¢—Br OE A aigigige 7B “Bis: (@) CH,(CH,),C(CH,), (0) (CH), —C(CH,) (© CH4(CH,),CH, (@) (CH,),(CH,)C(CH5), Which of the following reactions does not involve a —C bond formation ? (@) Hydrolysis of a Grignard reagent (b) Combination of two allyl free radicals (© Corey-House synthesis of alkanes (@ RNa +R —Br—+R-R +NaBr 123, 124. The highest boiling point is expected for : @) Isooctane (b) 2,2,3,3-tetramethyibutane (© noctane @ n-butane 125. Alkane reacts with which of the following halogensi dark @F, ©) cd, Oh @ Br, 126, Pyrolysis of alkanes is a : (a) Nucleophilic addition reaction ydroet 437 128. 129. 130. 131. 133. 134, 135. 136. () Free radical substitution reaction (© Electrophilic addition reaction (@ Free radical elimination reaction ‘The nitrating agent for the nitration of alkanes is: (@) Cone. HNO, (b) Mixture of conc. HNO, and cone, HS0, (© Acetyl nitrate (@ HNO, vapours at high temperature ‘The antinock compound is : (TEL (b) Diethylzine (©) Dimethyleadmium (4) Tetramethyl in ‘The chain propagating step is fastest in the reaction of an alkane with : (@) Fluorine free radical (b) Chlorine free radical (©) Iodine free radical _(@) Bromine free radical 10 litre of an alkane X require 35 litre of O, for complete combustion, X forms only one monochloro derivative ¥. The action of alcoholic KOH on ¥ yields : (@) CH,CH,CH,ON —(b) CH, = CH, (QcHCH=CH, @ CH — GH Cy OH ‘Which of the following reactions of alkanes involves free radical intermediates ? (@) Halogenation (b) Pyrolysis (© Nitration (@) All of the above (CH) sCMgCl on reaction with D0 produces: (@ (CH,),CD (6) (CH) 30D ((@D,),0D (@ (CD,),0D ‘The compound with the highest boiling point is (@) mhexane (b) mpentane (© 2,2-dimethyl propane (4) propane Photochemical chlorination of alkane is initiated by a process of : (@) pyrolysis () substitution (c) Homolysis (d) Peroxidation Isomerization in alkane may be brought about by using: @) ALLO (6) Fe,05 (© AICI, and HCl (@) Concentrated H,SO, Bromination of an alkane as compared to chlorination proceeds : (@) Ata slower rate (b) Ata faster rate (© With equal rates (@ With equal or different rate depends upon the temperature 187, Halogenation of alkanes gives ‘mixture of monohalo products. The ease of substitution follows the order: (@) Tertiary H > primary H > secondary H () Primary H< secondary H < tertiary H (© Primary H> secondary H_ > tertiary H (@) Secondary H>tertiary H > Primary H 138. The halogenation reaction of alkanes with different halogens is fastest in the case of : @L @) a, OF @ Br, 139. In the nitration of propane, the product obtained in maximum yield is {@) I-nitropropane _—_(b) 2-nitropropane (©) Nitroethane (@ Nitromethane 140. Only two isomeric monochloro derivatives are possible for : (a) n-butane (b) 2,4-dimethyl pentane (©) benzen (@ 2-methyl butane 141. What is the chief product obtained when n-butane is treated with bromine in the presence of light at 130°C? (a) CH, —CH, — CH, —CH, —Br (0) CH, —CH, — CH — Br CHa (9 CH,— CH —CH, —Br cH, cH, | @ CH;— t —CH,—Br cH, 142. The number of different substitution products possible when ethane is allowed to react with bromine in sunlight are : @9 m6 @8 @s 143. Which of the following reactions of methane is incomplete combustion: (@) 2CH , +0, SSH tue. 90H OH (b) CH, +0, “#3 5 HCHO+H,0 (0 CH, +0, —>C(s)+2H,00) (@) CH, +20. —>C0,(g)+2H,0(), C™~ Sa 144, 148. 146. 147. 148. 149. 150. 151. Ethane is formed during the formation of chloromethane by chlorination of methane because : (a) higher members of the hydrocarbons are generally formed during reactions (b) two methyl free radicals may combine during chlorination to give ethane (© two chloromethane molecules react to form ethane (@) chlorine free radical reacts with methane to give ethane Which of the following compounds gives methane on reaction with water ? (@) Cac, BC sic @ ALC, ‘Chlorination of alkanes is a photochemical process. It is initiated by the process of : (@) heterolysis, (b) homolysis © pyrolysis (@) hydrolysis Which one of the following gives only one monochloro derivative ? (@) neo-Pentane (b) n-Hexane (© 2-Methylpentane (4) 3-Methylpentane The number of chain isomers possible for hydrocarbon CH. is (@)3 )5 4 @6 Which of the following isomeric heptanes can yield seven different monochlorinated products upon free radical chlorination ? (a) 2,2-Dimethylpentane (b) 2-Methylhexane (©) 3-Methylhexane (4) 2,4-Dimethylpentane ‘Which of the following compounds will react with Na to form 4,5-diethyloctane ? (@) CH,CH,CH,CH,Br (b) CHyCH,CHy — GH —CHCH,Br CHs (© CH,CH,CH CH, — GA—CHy Br © GH,GH,cH, cH = "CHCH, Br What happens when methane reacts with cone. HNO, at high temperature ? (a) Nitromethane is formed. (b) Methanol is formed. (©) CO, and H,0 are formed. (d) CO and H,0 are formed. 182. During halogenation of alkanes the halogen alkane is mpi trend. Which of the follown’ statements is not correct ? (a) The reactivity of halogens is in the order Fy > Cl, > Br, >Ip- For a given halogen the reactivity of ° isin che order of P> 2°51", % *docatbn (© Bromine is less reactive than chlorine towards g particular alkane. (@) On chlorination monosubstituted product ig formed while on bromination disubstituted products are formed. 153. Which alkane is produced when sodium salt of butanoie acid is heated with soda lime (@) CHCH, (b) CH,CH,CH,cH, (cH, (@ CH,CH,CH, 184, Match the column I with column II to identify the products of oxidation of alkanes and mark the ae | @ | HCOOH +H,0 (@) | cH, +20, 24, (B) | 2CH, +0, BK, Gi) co, +2H,0 | | iil), 2cH,0H ry | i | | [@) cH, +30, -Seeonme, ©) cH, +0, MP2, (iv)| HCHO +H,0 @ (A) > @, 8) > @, © > did, D> @w ©) A) Gi), B > GD, > Ww), 4.0 © (A) Gv), 8) > Gi), (©) > Gi), > 0 @ (A) Gi, @) > 0, © > @, > 185. A mixture of 1-iodoethane and 1-lodopropane i treated with sodium metal and dry ether to carry out ‘Wurtz reaction. Which of the following hydrocarbons will be formed ? (a) Propane + Hexane (b) Ethane + Propane (©) Butane + Propane (@) Butane + Pentane + Hexane ‘which ofthe following is the most stable free radical? (@ CHSCHa (b) CH,CHCH, (@ CHACHCSHs (@ CoHsCH,CH, ‘which of the following has the lowest boiling point ? (@ 2Methylbutane (b) 2-Methylpropane (© 22-Dimethylpropane (4) n-Pentane which step is chain propagation step in the following ‘mechanism ? @a,—sar scr Gi) Cl" + CH, —> “CH, +HICL aycr +cr—+ (j) "CH, + CL —> CHC @@ &) Gd © Gi @ 459, Hydrocarbon which is liquid at room temperature i (@ pentane (b) butane (© propane (@) ethane 160. Which of the following statements is true ? (@) Soda lime is a mixture of sodium hydroxide and potassium hydroxide, (b) Methane can be prepared by Wurtz reaction. (© In alkanes all carbon atoms are sp* hybridised. (@) neo-Pentane yields three different monochloro derivatives. 161, Match the column I with column II and mark the appropriate ch —\ (A) | n-Butane —> | @ Free radical | 2-Methylpropane | substitution |® ca, +c, cH,c1 jan | warts reaction | |(© | RCOONs + soda lime —> RH Gi) Isomerisation | (19) Decasboxgtaton | ee @ (A) > Gid, @) + ©, © > Gv), O) > GD ©) A> WO, @ > Gv), > @, O) > Gd © A> @, B) > Gi, ©) > Gv), O) > Gd @ A&W), B) > W, © > Gid, O) > 162. In the given reactions : (Pex sna © cago SEE, 38 y HE, 2 40 cH ,cooH MH, MOH, y_ Bz Identify X,¥ and Z. x Y Zz @ cH, cH,Br CHCH (ii) CHjCOONa CH;CH, CH,CH,Br @) OCH,CH, CH, CHBr Gi) CHyCOONa CH, CH,CH,CHs (© @CHCH,Br CH,CH, CH,CH,CH Gi) CHyCOONa CH, CHBr (@ (@CH.CH, — CH,CH,Br CH,CH,CH.CHs Gi) CH,COONa CH, CHBr 163. Chlorination of methane does not occur in dark because : (@) methane can form free radicals in presence of sunlight only. (b) to get chlorine free radicals from Cl, molecules energy is required. It cannot happen in dark. (©) substitution reaction can take place only in sunlight and not in dark. (@) termination step cannot take place in dark. It requires sunlight. 164, An alkyl halide X reacts with sodium to form 3,8-dimethyldecane. What is X ? CHC, — G4 —GHHCHACL cH, (b) CH,CH,CH,CH,Cl CH) H (© CH, —¢—C—cH, — cH, — CH, — CHC hai, CH (d@) CH, —C—CH,CH,Cl ots 165. An alkane CgH,, gives two monochloro derivatives on chlorination. Its possible structure is : (a) CH,CH,CH,CH.CH2CHs (bcs — GH—GHCH.CH, CHy © CH, —GH—CHaCHs CH,CHs CHy CHs @ cH, —CH—CH—CH, ga) . . 166, The major constituent of natural gas is (a) methane (®) propane (©) butane (@) hexane 167. Wurtz reaction may be used to unite : (@) two alkyl halides (b) two aryl halides (©) alkyl and aryl halides @ two benzene units 168. Which of the following products is formed when n-heptane is passed over (Al,0,, + Cr,0) catalyst at 773K? (@) Benzene (b) Toluene (© Polyheptane (@) Cycloheptane Alkenes 169. Geometrical isomerism is caused : (@) by restricted rotation around C=C bond (b) by the presence of one asymmetric carbon atom (© due to the different groups attached to the same functional group (@) byswing of hydrogen atom between two divalent atoms 170. Which of the following compounds will show cis-trans isomerism ? (a) (CHy),C=CH— CH () H,C=Ccl, (© CH,HC=CCICH, (@) HCIC=cH, 171. How many geometrical isomers are possible for the given compound ? CH — CH=CH —CH=CH— C,H, (a) Four (b) Three © Two @ Five 172. The alkene that exhibits geometrical isomerism is : (@) propene (b) 2-methylpropene (© 2-butene (@) 2-methyl-2-butene 173. 2-Bromopentane is treated with alcoholic KOH solution. What will be the major product formed in this reaction and what is the type of elimination called ? (@) Pent-L-ene, f-Elimination (b) Pent-2-ene, f-Elimination (©) Pent-L-ene, Nucleophilic substitution (@) Pent-2-ene, Nucleophilic substitution 174, An alkene X is obtained by dehydration of an alcohol Y.X on ozonolysis gives two molecules of ethanal for every molecule of alkene. X and ¥ are : NCERT Chemistry Boo; (a) X =3-hexene, ¥ =3-hexanol (b) X =2-butene, ¥ = 2-butanol (©) X = L-butene, ¥ = 1-butanol (d) X =1-hexane, ¥ = 1-hexanol 178. Arrange the following alkyl halides in decreas, order of the rate of B-elimination reaction i] alcoholic KOH. H I WOH, —C—CiiBr GG, — CH, ay CH, (ii) CH, — CH, — CH, —Br @ > @> Gi) — ©) Gi) > > @ OW>G>Q WW> Gid> 176. Which of the following reactions does not show the correct products of the reaction ? (@) CH, —CH=CH, > CH, —CH, — CHa a (b) CH, —CH=cH, S_, CH, —CH, — cH, Br @et,—ct—cr, cn, Lact, (@) CH, — CH=CH, "cH, — cH—cH, a 177. The products for the following reactions are : ia @ CH, —C—CH, —CH, + ale. KOH > X (i) CH, —CH—cH=cH, 57 +z (a) X=(CH,),C=CH,,Y =CH,CH,CHO, Z=CH,CH,CHO (b) X=CH —~',,Y =CH,CHO,Z =CH,COOH (© X=CH, —CH=CH—CH,, CH, | Y =CH, — CH —CHO, Z =HCHO Hy — CH =C(CH,),,¥ =HCHO CHO 478. The mechanism of the reaction in terms of intermediates or type of reaction is given below. Mark the incorrect option. Hs (a) CHy —C=CH, + HBr —> Carbocation intermediate cH, erode () CH, — C=CH, + HBr Free radical intermediate (© Yemc€ + X;— Hleropilcntemediat Domed + 04+ Oronide Presence of unsaturation in organic compounds can 179. bbe tested with : (@) Fehling’s reagent _(b) Tollens’ reagent (© Baeyer's reagent (4) Fittig's reaction 180. Propanal-1 and pentan-3-one are the ozonolysis products of an alkene. What is the structural formula of alkene ? @ cHyCH, —G=CH —CH.CHs CH,CH; HCH, I (b) CH,CH, — CH=CH — CH —CHy Gictty (CH; —C=C—CHs | CH,CH, (@) CH,CH,CH,CH, — CH=CH — CH,CHs 181. An alkene 3-thylpent-2-ene will give which of the following produets on ozonolysis ? (@) HCHO + CH,CH,CH,CHO ertyeno oc” ‘CH, CH, (@) CH ,CH,CHO + CH ,CHCH,CH,CHO 182. What is the order of reactivity of hydrogen atoms attached to carbon atom in an alkene ? (@) 3°> P>2° (b) 2°> 13° (320 @ P>2°>3° 183. 184. 185. 186. a1) ‘Answer the following questions (189-185) based on the given paragraph. Dehydrohalogenation involves removal of the halogen atom together with a hydrogen atom from @ carbon atom adjacent to the one with halogen atom Akceholie KOH is used for dehydrohalogenation. ‘According to Saytzeff’s rule, when two alkenes may be formed, the alkene which is most substituted is the major product. the following alkyl halides in decreasing ‘Arrange Order of the rate of B-elimination reaction with alcoholic KOH. CH,CH,CH,Br Hy — GH — CHB @ cH, wo tty — cH, — GH Hs Br w @ >i) > O © Gi) > GD >O (© @> > Gd (@ G>@>GiD ‘The ease of dehydrohalogenation for different halogens isin the order (a) iodide > bromide > chloride (bromide > iodide > chloride (© chloride > bromide > iodide (@ iodide > chloride > bromide What are the products of dehydrohalogenation of 2-iodopentane ? (a) 2-Pentene (major), 1-Pentene (minor) (B) 1-Pentene (major), 2-Pentene (minor) (© 2-Pentene (50%), 1-Pentene (50%) (@) None of these ‘An unsaturated hydrocarbon was treated with ozone ‘and resulting ozonide on hydrolysis gives 2-pentanone and acetaldehyde, What is the seructure of alkene ? (@) CH, — CH =CH—CH; CH,’ NCH, Hy Call co FS cace 5 Hy’ NCH CoH CH, @ MS cacg Hs cry? “So, a ee. 187. A compound X decolourises Br. water and reacts slowly with conc. H SO , to give an addition product. ~ X reacts with HBr t6 form ¥.Y reacts with NaOH to form. On oxidation Z gives hexan-2-one. X,Y and Z in the reactions are : x72", Decolourisation [ow 1,80, Addition product xB y 08, 7 ©), cH cHcH, — cacittls ° exane-fone (@) X =CH,CH,CH =CHCH,, Y =CH,CH,CH(Br)CH(Br)CH,CH,, 2=CH,CH,CH, (b) X=CH,CH =CHCH,, Y =CH,CH(r)CH(Br)CH,Z =CH,CH,CH,OH (© X =CH,CH,CH =CHCH,CH,, Y=CH,CH, — FH CH,CH,CH, Br CHsCH, Cit, — CH — CHC, OH (@) X =CH,CH,CH,CH=CHCH,, Y =CH,CH,CH,CH,CH,CH,Br, CH,CH,CH ,CH,OH 188. An organic compound C gH, (X) on reduction gives CeHyy (¥). X on ozonolysis gives two aldehydes C;H,0 (1) and C,H,0 (ID. Identify the compounds X,Y and aldehydes (D and (1D. (@) X =CH,CH =CHCH,CH,CH,, Y =CH,(CH),CHs, (@ =CH,CHO, (11) =CH(CH,),CHO (b) X =CH,CH,CH =CHCH,CH,, Y =CH,(CH,)4CHa, (@ =CH,CHO, (I) =CH,CHO (© X =CH,CH,CH,CH,CH =CH,, ¥ =CH3(CH)3CH,, (@ =HCHO, (11) =CH,(CH,),CHO @ X=CH,CH, — C= CH— Gh, cH =CH, (CH) CH, @ CH;CHO, (I) =CH,CH,CHO NCERT Chemistry Booster.xj 189. The compound formed when alcoholic solution gp ethylene dibromide is heated with granulated zine. (@ ethene () ethyne (© ethane (@) bromoethane 190. CH,CH,CH0H SFE» 2-5 Aand B are : (a) A=CH,CH,CH,, B =CH,CH,CH,CI (b) A=CH,CH =CH,,B =CH,CICH=cH, (¢) A=CH, =CH, B =CH,CH,Cl (@ A=CH,CH,CH,,B =CHjCH=CH, 191. Hydrolysis of ozonide of but-1-ene gives : (@ ethylene only (b) acetaldehyde and formaldehyde (©) propionaldehyde and formaldehyde (@) acetaldehyde only 192. Pentene-1 with HCl gives : (@) 3-chloropentane —_(b) 2-chloropentane (© L,2-dichloropentane (4) 1-chloropentane 193. Ozonolysis of 2,3-dimethylbut-1-ene followed by reduction with zinc and water gives (@) methanal and hexanoic acid (b) methanoic acid and butanone (© methanal and 3-methylbutan-2-one (@) butanoic acid and 2,3-dimethylbutanoic acid Alkynes 194. What happens when calcium carbide is treated with water ? (@ Ethane is formed. (®) Methane and ethane are formed. (© Ethyne is formed. (@ Ethene and ethyne are formed, 195. How many structures are possible for CsH, with one triple bor? @4 3 2 @1 196, The most acidic hydrogen atoms are present in: (@ ethane (b) ethene (©) ethyne (@) benzene we 197. Choose the correct reagents used in the conversion. » Gy =H, GH, Gy Os cH, cB Br Br ©, crac” oO - q r s (a) Br, ale.KOH NaOH ~— ALO () HBr ale.KOH Ca, KMn0, (HBr ale.KOH NaNH, —redhotirontube (@Br, al.KOH —NaNH, _redhotiron tube 198. The ozonolysis product(s) of the following reaction is(are) : ac 0° cHcH, — Gmc 822, Products) (@) CH,COCH, (&) CH,COCH, + HCHO (© CH,COOH + HCOOH (@ CH,CH,COOH + HCOOH 399+ Compete he following rection by {identifying X and y, cHcr,cacn Ms xy (a) X =CH,CH,COONa,Y =CH,CH,CH =CH, (b) X =CH,CH,C =CNa, ¥ =CH,CH,C=CC.Hs (@) X =CH,CH,CH,CH Na, ¥ =CH3CH,CH,CH 202. Match the column I with column II to give the cot (A) CHs(CHz), —CH—(CHz)sCHs CH —(CH,)sCHs fe cH, —CcH—C=C—CHy © Cpon—ai,—ciat |e] ex — came — Gai — Gt | | CoHs _ @ A>, B) > Ww), © > GH, D) > GHD (b) (A) + Gv), B) > 4, (> GHD, D) > 201. rect IUPAC names and mark the appropriate choice. (@ X =CH,CH,CH =CNa, ¥ =CH,cH, —GH— CH, CH; Which of the following alkynes is most acidic ? (a) CH,;C=CH (b) CH,C CCH (CH,CH,C=CH (CH=CH Which of the following reactions does not show the acidic nature of ethyne ? (a) Acetylene reacts with sodamide to form sodium acetylides. crtemcet + Na My cH mCNa + SH (&) When passed through ammoniacal cuprous Chloride solution, a red precipitate is formed. cle ct + Cu,Cl, + NHOH—> ‘CuC=CCu + 2NH {Cl +2H,0 o Acetylene reacts with chlorine in the dark to form dior tetachlorides. cH =cH + cl, “> cHcl=cHCL “Seana, — cela (2) Acetylene when passed through ammoniacal silver nitrate gives a white precipitate. CH=CH +2AgNO, +2NH,OH—> "AgC=CAg + 2NH NO, +2H,0 id tL © A) > Gi), @) > O, (© > Gv), 0) > GD @ A) > Gd, B) > Gi), ©) @, () > Gv) 203. One mole of 1,2-dibromopropane on treatment with ~S__X moles of NaNH, followed by treatment with ethyl bromide gave a 2-pentyne. The value of X is : (a) one (b) two (© three (@) four ‘Which of the following alkynes can be identified and distinguished from the rest of the alkynes on reaction with ammoniacal silver nitrate to gave a white 204. precipitate ? (a) CHj,C=C—CH, (0) CH,CH,C=CH (© CH,CH,C=CcH, (@) CHyC=CCH,CH,CH, 205. Identify the product for the following reaction : CH=CH + Hoa (@) C1,CHCHO (b) CH(OH) =CHC! (© CICH,CH,OH @ CH,Cocl 206. When 1-butyne undergoes oxymercuration with the help of HgSO,+H,SO,, the product(s) formed is/are : (@) CH,CH,COOH + HCOOH (b) CH,CH,COCH, (© CH,CH,CH COOH (@) CH,CH,CH,CHO 207. Which of the following does not represent polymerisation of alkenes and alkynes ? (@) nCH=CH—+ CH=CH —CH=CH}, () 3cH aC) —CH= Ch £E— CH CH (@ nCH=CH,—+ €CH, —CH =CH—CH,3, 208. Which of the following will give 2,2-dibromopropane on reaction with HBr ? (@CH,—CH=CH, (6) CH,C=cH } (CH,CH=CHBr —(d) CH=CH Identify X and Y in the following reaction. Hat G+ Kon AES x SE Br Br (@) X =CH,CHBr, Y =CH, =CH, (b) X =CH,OH — CH,OH,Y =CH, =CH, (© X=CH, =CHBr,Y =CH=CH @ X=CH=CBr,Y =CH=cH oN NCERT Chemistry Booster-xy 220, The correct trend of acidic nature of alkynes is: the folowing (@) C= cHt> cH —C—CH> cHscmocy, () City —CmCH> CH mCH> CH,Comccy, (©) CHyCm CCH > CH — CmCHt> CH cy (@ CH= CH> CH,C=CCH, > CH,Carcy ‘dent the reagent from thefllowing ist which ag va easily distinguish between I-butyne and 2-buryne (@) Bromine water (b) Baeyer’s reagent (© Dilute 50, + HgS0, (@) Ammoniacal CuCl, 212. Ozonolysis products of | 2-pentyne afer decomposition of ozonide with water and subsequen, oxidation are : (a) ethanoic acid and propanoic acid (b) ethanoie acid and propanone (©) ethanoic acid (@) formic acid and glyoxal Aromatic Hydrocarbons a 213, Which of the following names is not correctly writen in front of the compound ? CH,CL @ 1-Chloro-1-phenylmethane HBr, & 4-Bromo-1,1-dibromo-1-phenylmethane Br a o Chloro-4-phenylmethane CH, CH;CH,CI @ or 1-Chloro-2-phenylethan® 214, The correct structure for triphenylbromomethane Br ee rly Br o © © {\ CH ‘Br CH,Br COO sn, Which ofthe following reactions snot an example of electrophilic substitution in benzene ring ? a ch o@ oO + 3Cl, a a a SO,H oGj1.—-O) 216, Although benzene is highly unsaturated it does not undergo addition reactions. The explanation of this can be suggested as : (a) seelectrons of benzene ring are delocalised () since electrons are present inside the ring, addition cannot take place (6 eydlie structures do not show addition reactions (@ benzene is not a reactive compound 217. Mark the incorrect statement from the following (@) Benzene has a planar structure. () Benzene is an unsaturated hydrocarbon and shows addition reactions lke alkenes. (6 In benzene carbon uses two p-orbitals for hybridisation. (@ Aromatic hydrocarbons contain high percentage of carbon hence burn with sooty flame. A. 218. Name the products of the following reactions. (0 Goll reacts with methyl ehloride in presence of AIC. CU) Ggtig reacts with acetyl chloride in presence of Aly. (ID Celt, reacts with fuming nitric acid in presence of cone. H,80,. (IV) CH is catalytically hydrogenated. 1 0 m1 Vv (@) Chloro- Toluene Nitro» n-Hexane methane benzene (0) Methyl Chloro- Phenyl ‘Trimethyl- benzene _ benzene nitrite benzene (© Benzyl —‘Trimethyl-Trinitre- Toluene chloride benzene toluene (@) Toluene —Aceto--—‘Trinitro- _Cyclo~ phenone benzene hexane 219. Identify the unknown compounds. CH,CN CHs a Gh © OxO2-2O (@) A> CH,COCL, B+ CHCl, C 4 NaCN (0) A> CH,CI, B > CoH CH2,C > KCN (© A> CH,,B > CgHsCHCI, 6 > AgCN (@) A> CH,CI,B > CeH1gCOCI, C+ KCN 220. Identify the unknown compounds. TES A sae? ® ar ©) te) (a) A Nitrobenzene, B > Dinitrobenzene, C+ p-Bromoaniline (b) A> CcH,S0,H,B > m-Benzenesulphonic acid, C— m-Benzenesulphonate (©) A>CgH,NO,,B> m-Bromonitrobenzene, C+ m-Bromoaniline (@ A- p-Nitrobenzene, B—> m-Trinitrobenzene, C—> m-Bromoaniline 221. Coal tar is the main source of : (a) aromatic compounds (b)alicycic compounds (© aliphatic compounds (€) nitro compounds 222. What isthe carbon-carbon bond length in benzene? @ 120Aand1.31A (b) 1.39A (Q139Aand120A (4) 1.20A L~» 1) 224, 227. 229. Nitration and chlorination of benzene are : (a) nucleophilié and electrophilic substitution respectively (b) electrophilic respectively (© electrophilic substitution in both the reactions (@) nucleophilic substitution in both the reactions. ‘The following reaction is known as : Aids CoH + CHCl Zi CoH sCHy + HCl (a) Wurtz-Fittig reaction (b) Friedel-Crafts reaction (© Rosenmund reaction (d) Sandmeyer reaction Nitration of benzene is carried out with conc. HNO in presence of conc. H,S0 4. The role of conc. H SO, isto provide : (a) nucleophile during the reaction (b) free radical during the reaction (©) electrophile during the reaction (@) catalyst during the reaction and nucleophilic substitution 3. Which of the following species is aromatic ? oO @|,.] @) Q o sof Which of the following species aromaticity ? @ UW OQ ol] of) Which of the following groups is o-p directing but deactivates benzene ring for electrophilic substitution? (@) —CH; () —NH, @-a (@) —No,, In halogenation of aromatic hydrocarbon, a halogen carrier is used which is generally a Lewis acid. The ‘main function of this reagent is to generate the species : (@)x x" does not show (b) (b) x (d) x" NCERT Chemistry Booster.x, a0. Match the column I with column Hand mag yy appropriate choice. (A) | Alkyl halide+Sodium in @ | Sulphonation | presence of dry ether | (w)| Arene-+Acid halide in| (i) | Wurtz reaction presence of AICI (©) Arene+Fuming (i) Catalytic | sulphuric acid | hydrogenation | (p)| Arene-+Hydrogen in | (iv) | Friedel-Crafts reaction presence of Ni @ A) 0, B) > Gi), © > GW, D)+ Gy ©) A) WW), B > @, ©O> GH, +O © @)> Gi, @ > 0, OW, 0) @ @ A) @), 8) > @), © O, ©) > Gi 231. Which of the following steps is not correct in the 232, mechanism of electrophilic substitution of benzene ? (a) Generation of electrophile like X*,R*,RC*O, NO} ete. (©) Attack of electrophile resulting in the formation. of arenium ion in which one of the carbon is sg? hybridised. (© Addition of proton on benzene ring. to ge carbocation. (q@) Removal of proton from sp? carbon atom to restore aromatic character. Benzene easily shows : (@) ring fission reactions since itis unstable. (b) addition reactions since itis unsaturated. (© electrophilic substitution reactions due to stable ring and high x-electron density. (@) nucleophilic substitution reactions due to stable ring and minimum electron density. ‘The correct order of reactivity towards substitution is (a) benzene>phenol>benzoic acid>chlorebenzem® (b) phenol>benzene>chlorobenzene> benzoic ao (© chlorobenzene>benzoic acid>phenol>" | (€) benzoic acid> chlorobenzene> benzene 223. 224. 225. 226. 227. 229, Nitration and chlorination of benzene are: (@) nucleophilié and electrophilic substitution respectively (b) electrophilic and _nucleophil respectively (© electrophilic substitution in both the reactions (d) nucleophilic substitution in both the reactions. ‘The following reaction is known as : substitution CoH + CHC ASS CoHgCHs + HCL (a) Wurtz-Fittigreaction (b) Friedel-Crafts reac (© Rosenmund reaction (4) Sandmeyer reaction. Nitration of benzene is carried out with conc. HNO, in presence of cone, H SO. The role of conc. H,SO is to provide (a) nucleophile during the reaction (b) free radical during the reaction (© electrophile during the reaction @ catalyst during the reaction Which of the following species is aromatic ? oQ oY Oo Which of the following species does not show aromaticity ? @ oO J . of] NY H Which of the following groups is o-p directing but deactivates benzene ring for _ electrophilic ‘substitution? (@)—cH, (b) —NH, @—-a (@) —NO, In halogenation of aromatic hydrocarbon, a halogen carrier is used which is generally a Lewis acid. The ‘main function of this reagent is to generate the species : @x @x* (b) x~ @x* 230, Match the column 1 with column Hand mark thy appropriate choice. [roe of dry ether | (B) Arene+Acid halide in (i) | Wurtz reaction | presence of ICL, \ (© | Arene+Fuming 9) Catalytic | sulphuric acid hydrogenation |) Arene+Hydrogen in| (iv) Friedel-Crafts | reaction | presence of Ni @ A) @, B)> Gi), © > Gi, D) > iv) (b) (A) > Gv), (@) > Gi, (©) > Gi), D) + © @)> Gi, @) > ©, © > Ww), D> Gi @ @) > @, > W),O > 0, ©) > Gi Which of the following steps is not correct in the mechanism of electrophilic substitution of benzene ? (a) Generation of electrophile like X*,R*, RC*O, NO} ete. (b) Attack of electrophile resulting in the formation of arenium ion in which one of the carbon is sp? hybridised. (© Addition of proton on benzene ring to give carbocation. (d) Removal of proton from sp? carbon atom to restore aromatic character. Benzene easily shows : (@) ring fission reactions since itis unstable. (b) addition reactions since it is unsaturated. (© electrophilic substitution reactions due to stable ring and high r-electron density. (@) nucleophilic substitution reactions due to stable ring and minimum electron density. ‘The correct order of reactivity towards electrophilic substitution is : (a) benzene>phenol>benzoic acid> chlorobenzene (b) phenol>benzene>chlorobenzene>benzoic acid (© chlorobenzene>benzoic acid> phenol>benzené (d) benzoic acid>chlorobenzene>benzene>phenol 232, 233, complete the reaction with suitable reagents and (@ (A) ~CH,COCI, (B) - Celt sCHO, nds. ’ “gall (C) -CgHgCOONa, (D) ~ AICls 238. Similar to alkenes and alkynes benzene also ‘undergoes ozonolysis. In the sequence of the given CH; w oxidation , (gy Na Oo ‘AGS Oo om oT reaction identify X and ¥. (a) (A) -CH,, (B) -CgH1 CHO, (C) -CgH,COONa, Ce. x ey (D)-CH, (&) (A) -CH,CL,(B) -CgHsCOOH, (C) -CgH,COONa, (D) -ale.KOH (© (A) -CH,Cl, (B) -C.H COOH, (©) -CgH,COONa, (D) -NaOH + CaO (a) X =Triozonide, Y = Glyoxal (b) X =Diozonide, ¥ = Succinic acid (c) X =Monoozonide, ¥ =Benzoic acid (@ X =Triozonide, ¥ =Benzaldehyde = ‘Answers : i 7 mer fs fone @ 5 C6 @ 7% Os @% 10. (b) ne @ 2 we. @ 4 © @ 16 @ 7. Oj © (1. @ 20. @ a. 22, Was, am. 25. | 26 G27 ©) [2 D0 Te SL @ 32. 0) 32. O34 & 35. © 96. (37 O98 (99 40. @) ee ee ee es ec ee Ca CC a ae si. @ 52. @) 53. @ 54 @ 5S @ 56 @ 57 © @ (5%. @ 6. © 6. @ 62. © 6. BH 64. © 6. @ 66. @ 67 @ 69. @ 7. © 1. 72. @ 73 C47 G75 @) 76 177 O @ 7. @ % @ o. 82. @ 83. @ 8 @ 85. @ @6. (87 [O @! 89. @ 9. @ 1. @ 92. © 93 © 94 @I9. OH 9 © “97. (a) 98 (9 9% (@) 100. (@) vous 102. a) 108. (9-104. (29 108. (@)= 106. (0) 207. fa) 208. (@)_ | 109. (I) 220. © an, BAG 12 (ie na aad ave (ce) 106. (BY 26. |p 197. |B 218. ha 229. ad 20. FS tan, (Pel na ley 8 fd 204 | 2. te 226. DE x27. yg) 220. (2) 229. (Gg 290. 51, (VR 192 fae 300. (gg © 334 CQ, 236, [fe 296. alg) 297. 9} 120. ag x5. UE 240. sax, 0a gg 24. (Get! 24, 248, (C246. (| 147.) 140. 0) 14. a0. (152, @)_ 153. (@) 154. (155. (| 186. (0 197. @)) 158, () 189. (HS 260. tea, (Qh 162 Gay | 368. (gy 264. (a) 2 268. |) | 166. a) 267 eg 268. (169. alg 370. fe v7 ge v7. (@gth 173. Ve x74. 3175.06) 176. NG) 977. el 7378. Ya) 179. GS x80. Hap ton, (Qf 102. (@) 105. (py 204. (a) 108. (a) 206. (90) 207. (GF 108. (a) 109. 4G 290. () 191, fg) 192. @) 193. (9194. @ 195. @) 196. @ 197. 198. (@)_ 199. ® 200. (@) 201. (py 202. ge 203. fg 204. (G9 205. (a) | 206. [BNR 207. (HT 208. al 209. TE! 220. Hal 231, (dg, 212 fds 233. el 9 204 a) 205.) 216. (ig) 297- Pg] 216- fe) 219.) 220. Ve) 221. f@)ig 222. |) 223. (@) 224. (b) 225. (ce) 226. (@) 227. (d) 228. (©) 229. (@) 230. @) 231. (@) 232. (@) _ 233. (b) 234. (©) __ 285. (a) 151.

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