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Quantum Mechanics 2

time independent pertibation

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114 views41 pages

Quantum Mechanics 2

time independent pertibation

Uploaded by

4utiktehp
Copyright
© © All Rights Reserved
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    & ay <2 flviye = Oe siqa t Eom cage | according i ptthensemal condilioo ee dee iyeyse ar ° Sty ye © Lal Pal @ dEn Sm ny Soe CoE | _ enw ql . ey | ale hn] be - | e pe —a f= En cat, ee, S amlithay AN bat \ R bo RP Ey? En + | Ate e| FE alors eebbld at ogi) Falong the gears yy ve a posfon | elecbae pid. | haefore eleebve dipole moment = [= — 2% chavat si the elon additions) potential Emap es ule op © aoe (> sotaredio! | = os. FE wse (7Ds=Z) Woe e€z the —ce yl ke* ae > Csclnodiinger wan eq? fet 8 ) » = comprert oleae | Bevo UNE ? termitiviliy CE FD at Pevmiabstity a-F) |4* ordexe , correctin term (€) | Fist ondue Stk erbert “ m te ak | orlve Ener comedian tem . = 24,14 | Qook | 1S >) vu speed Sate lion ptegal As = Ly gl eercose] Pod owing lnniks OFM vanishes eB) =o That is gerst order Stark effect not Shevo fas will not shew Gromd Stale H-atom wail Skevck ef pect . : ws x ode Stak epfect ow on optsatos 1 Operales Opals oy tet woe joneher Fare ® ——@ [grant emaclroscat operates elif cures ) dso sO : oy WO my) Hees@ed 2 Ey Gy tM —@ sub @ @ 0.8 gee) _ agg etre, = En Hey PY oy 2a) Ny? 6, ate ' ; We FBTR OS BM + Ey Hips Hep? rly? ety, Fewer n'y —O© Fab an quombinedoniicel opeteles amd follows connate aula ne mm 2. but, vey) 2 F Vyo ager 4 avy, VF —@ VE) = pene. et YTFVy l= HF + 2v9)0F o, Eo ey*\e = och : ( Fv )y, 9 VF 4 2vy VF “iw Meweduty fp COrmmrbtion —gyloe Boece wh ( ye vi ear) \ ah )VFt 2VP, Pw ye —@® But vr Ww 2 OF 2 op a 398 ao Bt ye CERRO —@® | C 24 © fren Uivovew potential ) On Odi dp solv 24” a ler Fa fs): Re Leqender polynomial avd _. Fa c£(Z4+%) 5 cory de coected MY tevrn = A? = 2yPlHlel 7 oe bev fumeen in Gand B Se by gubstikikney | Solvio’ &) aynardvoet le sto affect EY & calewtatico g polersveabnlity of nydsegen alors | Dipole momesturo pe ae Pola yrcalei ity | | Jnondee Le Degemnale — ovarepy uals. By considssuing, — linear of dedenerate jenactino » det Let \G-06-202,5 0° Vnwsdon combinadine Ceail- eR > Wwe fold oq emote puntlion - qoaclions ave tire yoand we ace amcions, ° i values ey ond E, eigen a = tia junction er) Ruaaltort poner 2 Oph TONE —o aie PCG TS ovdex correction fern ” « Oa ee ts), 0) age rie? = Ht mR, —© ip, temo Those pote, athe caleulate 15 order cossecliva tase ur be Aeplaud with ‘Tne fomrdio ‘b w S > a Ey [cata eeuPLT +e by, +C,8U + Hen = -® ° Ye, [4 mubliplying <¥A) of a @ > Pee Ca SROL HL YY SPALHLRLY + eyphitits = » n Ec Lp} we w Gy SPY EMC CuPLWy 4 ES LUSTY T Cl eee) ene rely + GSIINLYLY + En § A wy = Sapuiaia, Soe puasicheprrcamerscea=T \ ‘ 874 EME cw hy2y 4 EP Kw Hy Een & Yaa? + En G Ey ") BY adopting namalicalieo Conditier ) atsy 2 Clty Com, wolute 6, and oe v) By evaluate Cn awd, one tan calewtal E, and E Heliww vtomion Gownd tabs: Frida Helin Connick of ao olechone aie ordi Ju calculate She qromed Stale omngy of | Belin clon, espedatid fren a, and} ar tuo elickowie wane fuaselion THe Canta of goo oft do (3) awe normalized feectver Let He (Ee nee ac ; + aé[ 4] a by =_% a 18 LY 22g\ CR THEE NOH + LON o> veoh ea ze] gy atest 2a) ze[3,*5,) lar > 48) zefe4 )le7 + 2g4,\-2 (4,7 6 — | the fast deren amd S200r4 term tog’ © is | y a wy TmEe —_ 5 aie , om [eve] —O Ee ak | | eer HO we This Validity (appximation> Wondition fox WKB 4) Classically explanele vee ws 18 Oh high, potiobal vis sloulp qurntizo othawtde of funny point R, J oscillatory aero terms goer Baa, Tisiny pomnt WKB kee Om edu b esate the complele asian ate wee ib ws possible by connecting Ab broring owt: & Sine Va) slowly, ehounging jontlion Tt Gan be expomded i fas of Tosgloe Somes vea) = VO) +() (ae#) oon det VUE)z€ tru sehrolbigos 69” 23 [wA- wre 2 _ a 7 =d ay a (ee v Fe 4) _6 ae Tn regi00 LEK : ® ' t tuo Sdulieo exist Aaqyon Ly kaamme's solulion (3) Bonnie guight te the Faring potnt (a) 3 , a 68 frac «te -[3ae a 5 ye is 1 k pS (Jeg a >t sa ( fou K 1) Baur Te te the tuming point x a els free > = at kde ~ Nu) K | a i « 4 7s exp fa) <_ aM sin ( J ne %) | Bin etm Ave connected to opponent fy HUreasey | | Gevvslins ped —cotin fers caer egpovenbiak duotnes | Yee Todi cates having >=" Sqn Jn creawrng, yotectia! | L inpime state - wWke appprrienalions is hee The Aig’ by phase | established at the barrier 4 Bly in the eaprombiors ) , é) Alpha enwivien — Lek the aading 9} dow wacltory ert aalphor particle attraction ws upto * Is lon, he | Columbic pontial ap wk | D | Ee = 2ke % —o | at ae > | a WV | put the Solution of P= exp((8.ds) a am(VeO-E) jadi * = | Vwi, add YO 7% Me | * wo ( (288 -E = | [uar- (#2) | (F \ar © % | by going ony” @ ow om etalat, — the tremsnwame. sar gud -panonr Avy constevak “A Tb priscies nee -2 ( ade 7 mE gy jon Theory Tine Dep andeut Pevlirbali hme deporottul pobusbalon theory, form wow furarchion (Pp) -iEt ylsd = px) ep (+ oO whore yo) satispirs time incependands Sched onegy equation fet Hp e)= E HL) — HG,t) = wea hon) Tec) His) = potasbeti pleat) = wnperlorloed whew, petiurbed hawniltenian slime depemdrat ond pestinsled howniltoniow 5 Bie wndepencliut- dik tinne, diperdluut Scliodige 04% vis hae, = ' Je oe HOvt) Ble) ® foe ot will be the plalionamy alli oud yf wvpasbialoed bowel Lorin « we Hee (SsE) Feet —@ In tens + petuubation theory awe fhe wove fumchioo Cy Yun) = = oy, —Q) ETRY tune, framchinn com Le Asprecented by | Taeax Combination rf 4% poo OO WCr, bE) = = c,ce) p exp (eet ) —© whe Cy is & coppicaot ©P cemtant Oat) = BCH = Zc.) wy O) exp (= | By Substilubing abowe aqj inte 29) i ‘ c a ihe Eq COYL) Cap (4=") = PH) ZC) yo Dexp a) : —@ Wwe dee poerp(St) = 2.6,c0 Hep’ exp (G&S) ERY suttliphy WHEN ZL both sidlus and Aearronnspeng thagew = = c,ce) & Le = an jes am le ( ae els * a Few e Feo) Ha ALO 0) HL e a Wye a ae (7 8) > oy YW -2i8 & Sho (Wun) € ay 2-24, © —— + (Weg 7) = at Le, Premnistuen —proteeilily eguall “lo | | wo ol> ‘ Pt cl = ATM AL. sie” Cw 2) ‘he ES anes ais nie i wae —© “Thin iw keown os tamiiion probability from hook coe oI “2 cw) 4 F sea pupottion to 518 (ord th hes mk re bramistion prbrbiliky Oscstlales belwen avd « iy , chase tine t- bah ws 4 states amd probally ee oe af oy pot vis clave bebowen Prox | Pao | # the mmx pte | high oceans ayi'|> a aVBidth } fie peck, igh maar, 7 is on les pena ae) +- = t a Pree wwdee the peck (oordoy the depends ef oper Home ArThe probability of adpmes peck decreases wy —vo Trowsistion fee Conttinuons Stale @) Stale @) (Ferris Golden Rade) Teridue tewwishions a continnons porn dissent fo Continua Contin rum Trowwyslion axe Contineons from [ky Se, Jet dewalt, ws SLED; No-oh onceny Stetlés of Continnons — laehoten, EE +de is Continuous thowkiien « [ese GE RE condor | Stute ws PE dé, Energy beloeen continous “otal Finumy Pao babilile pO=, 5 m Tease | FIOM the ah with ee pt w voy luge thab (peck), beome gral amd jrambitiion become Viewed gg tet as Wont “(Bete -) & | - + | de = ty ag. freer Gi) prpabilily ; Prep [ SBE te pts) = 2 Wed bh owe | ped = ANEW FEO __@ _ > Ben 2 mabe element rowstioa elumam A porpostion a fp square of wanting teburannl od — duasby states beloeen w én Ey ® ie called ars Ferm -y dt we sed ‘0 couche phupics [Neubono caer” “me eel ‘6 qoder Rule - “| Einsteins p.B& Coeppedob » desis Ain excited cooleules O morules pe lowe state do yttited state can be £yplevinad by pillows Celvatin 24) picorbhoo = Emniesort € wawnon Cstirutaled) tspenkemneens) bamsistion This ghanonencn Com be cmdusstind bp poll Uy Alo, nt Le ol hk inte te state tidak oon oh Vivuke, CCoApre ok Nay be 10-4 aan peitively , soak iyi stun gece (owes, state : sae le nN vs Tramsithico sal. f°? profesional do cawity Slots (sapbyern) jg thamsistina sale ef otsergluo N. Me bos luk, stale & pled) (lower rp Jt $(05) > B + Pw) nan) Brom Etnttin Coefbiceints fer thduced absesphes stl the dromviition Yom Wom States i.e » EME Bm ste) —O nom wlan oN, is ho» ef pasticlts [atoms|wroltuds occu, at wel “n’. : Siewillaaty Tnewvistions from m—on stats eAnbent —B i cppith Fe Where ogg “ Eintlin’s coeffiaot fer stimulated tinony At Uhasenale tgytlibiuey Jf Uhue oa ot neh teemshe | a wanttay they NaSa-om ftw) = Nip Bman Se (ak therm quilher the KE mo din petere emttany( no aninceny wo for ft he, Be it n= Oa | phen he, Aedig to MB didhabition Lana the banal) pally 1k wi OC export 2 2 = 5etnn | 3 Wan * Ea Gy m6 Ny = ela a | We | ‘ho re a) . a de moe an additise teeo which dovt dept ee Tras addition ers @ Upon wanistnon (earthionk ged) as Agere Dw Bron? Ne Amon —©® | Amon + ban fw) 2 ee i by =! tere, = Pe et eS) y _© | Bee Cait =") | ° — ~ a -O1- 2022 Aman” Baan er) 1] fad —® ct According do pownck \ypothests Aectiahion hom Wing) = on Wen 1 _ _®@ men exp Been Ym, ay 4 by Sulotatitliney ag "@»© rar tn ital] Sey, 2: -B x ZH me mY) re = abel ne = yh * enn wn 3 Amen . 8Ah Uma —@) Om—ss5, ce he sctio of emusion ord alcosbhoo) Ey® can aloo expe > clipoler approximatinn accerding Lis Hipole eappavxirnction Bron a 2 Jone” . am (Me e &miviny) 7s | edmly|ny|~ —@ 3 By sub 649 inte and solving Aman = 2b Im , BOS fT ch AR exnindayt ®- 3 = embVin yy 2% \egmisiny|? 5S 3he 3 = mn e> Lemirinol” ; } ane? k A, = 4 dw? : nn) Wry | geole|ny] > whee ae” Aree I ch BF Creislein coe}fuint ir trons etme combnt © Dipole appanximadion « i ald “Ut The vatio belmeen Gpenttows ewission te sharilal i sages eB : i { | | | Ten Spon * awe oO sham ewwwnod Aon Bayo mm $CP ened 2 (= s)"| HF y Sf w << KE Lhe equilibaum 5 Abe stumlaled ewwixren 8 exceeds (morte) i) pttieymal eapisliboura = W077 KT they Spontemnonw> quviethon — otceeels of Rodialtoo whe Ag ase vecbor g scalo potentials | According te plow aludrorvaguobic wre equetion | i sereudl oA =8 ern ae ond AW) eK =O 5 wreck whe “kK we a propagation | thn tw Solution of 4" © | AGn A) = Aocoleep Ciky 3) a eap (“ik sot) | -® ey a a ® © O eledine velo e-2 3, [peer one eupC-iks +iotd)] A0(-1) [extCiny-iot) ~ exp Cake swe) | 1 [exp Ciky-iwt)- exploiket ier] wea oe of Drage clube field (Pe 2 [ng i = ae ay Gresgy dewalp = few) mal = ad 0) a x = 2 (pg Han lhonian Operatex . 4 The hovrsiian “H! of a chatge paabicl. in an Clee tbiorogny field He Lc p-= 2p): ed a) oy who bg, veclae 4 Scalar potarstials But hawitonian porter van ole capressed| Os He i's ich - A-VHe [pl> —e: “sm "5.8 omc €4"@ ws asrived by colwing P= ~ihv elechorie motion cam be explored ay sme wits Welp¢ a® ok ss v evo) feb ot —® me Bul, He HEH @ by apotion® ¢ O op feos. RY AVG) Hoe 4teh Av mC Te ut tern of 4" @ explewing abeut potenti’ ve) - Elecbawte dipole appeorivnation By the, elechiovmegubic zpedhors vonbiney Ahan te ecanelangth of la feytlran wench exp sikh) =1 s on Mmaen, then the — vector paantial Abe, t)= [Pot Jenpeint teapl wd] dus | por hamiltonian operilan ule cieh piv 5 | <= Av —@ } by Sb? © inte © | iwi] wade 8 ne vice flageal[exp ie) soap wwe VA wv 4 cong onl af ¥ oaploders a diediion of She prpeantes (poleriscalion) . BU ich 2K Ivpiny f (expe seapeit)) AY) “ot —® 6] H! | = HO = whee XKIRINZ wuld elomwat On Coot it iS cost an dipole wnownent - gn orden dn sthuts 2a (the yeti alemuint Ahodd be oat Actordaig Jo er" odo Comnubtico dtlobans te] . (| [ae = na [oth “pe 21 wr [oP] A yo S - iy wo) vo aK | We |7 © But del ca ]|n ye <4) ¥ yypy - Sine wo operates ae Inawiltorion then the Ald ou alan trsmilloviany ‘Crew, poodiunts ane.) | Homi bes crrtwor agen product q two hovmi tien then ib os luwwibion + ds Atal 04-09-2024 F by vsing "© wos dey -8 Baa aghoir = GSK Lene = Ey SKIT eq@ we wilid i chomvation ies Le\v\ny7 = es Ce{-t alent -@ Cr PY quoutum operates one writin ) wim oes Bh) ——______ catevaler = = Baw & Kets INT @ Ths & WS al kmoon ay dipote dwornsediuuan approvinection - B® iv ale pape o | unle veeY . = Be Maen v % " Bo? = NS Bee) _— et ae ae tO od sg @ Ais spodal Coordin ate Gs a tenger and 2. kepresent Ae eee | Ze ict Te z* (4 Coordinate) vag tnteoduted by Minos ka fom @& eq)" (oe chomae’) Hines ] 1) &y ®* Toverieut vader Lorenli, tLamafesmetion | Conditions a Space cooadinate . : | Eq) ® is not dnvarient unde gute thomsfetnatin conditions eae WD EGO & a second onler a iforetic! aqrotion in terms of Space coordinals iy) det hawilfowian fe a fees postide in tems | gf setalivisbic ome d-g 7 t [Perot \ » aes) —© . schnodinger eqnation | & (Pernt) ye iBY a) | 20 [Ce epomter cansit be and Ue) Spore, root ) | The drew backs 4 © » and - Sign of o poxalers and Sqynave stot of | oyoralises | an ons ato Owexcome, fla dfiadtice og”@ bs & [bes -modipced THs rodied 447(@) ve Kwoven ow Klein gordon eqration - Nye 1K BY oe Hy at leet “Hon both sides | fy = 4Uib22) Since operators Hom 2 can be Interchoupble By = RA COD edhe = —th die aS at This wise Somyple Fe~m yf Klein gqoden eq clio Bat pom © PS Picea eh ls Pa | = RR Pct —@ | Sus eg? @m @®D ve ger | KR VER ete) Re ~s oc —@® | Pele SH on comm sole | oe a | wo Ce): oe Se ve Cc. -* -D*) cs 2 De Alanbels priatiple —c Eq” aepececile io ewe Sf Klein Qerdan apaler | ) fey a a ~ Tae aw of Joe’ ed Cr tte door ¢

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