SEMICONDUCTORS
SEMICONDUCTORS
PHYSICS, CLASS 12
ELECTRONIC DEVICES
1. Metals They possess very low resistivity or high conductivity.
ρ ~ 10-2.10-8 Ωm, σ ~102. 108 Sm-1
2. Semiconductors They have resistivity or conductivity intermediate to metals and
insulators.
ρ ~ 10-5. 106 Ωm, σ ~ 10+5 .10-6 Sm-1
Types of Semiconductors Types of semiconductors are given below:
(i) Elements Semiconductors These semiconductors are available in natural form, e.g.
silicon and germanium.
(ii) Compound Semiconductors These semiconductors are made by compounding the
metals, e.g. CdS, GaAs, CdSe, InP, anthracene, polyaniline, etc.
3. Insulators They have high resistivity or low conductivity.
ρ ~ 1011 . 1019 Ωm, σ ~ 10-11. 10-19 Sm-1
4. Energy Band In a crystal due to interatomic interaction, valence electrons of one atom are
shared by more than one atom in the crystal. Now, splitting of energy level takes place. The
collection of these closely spaced energy levels are called an energy band.
5. Valence Band Valence band are the energy band which includes the energy levels of the
valence electrons.
6. Conduction Band Conduction band is the energy band above the valence band.
7. Energy Band Gap The minimum energy required for shifting electrons from valence band
to conduction band is called energy band gap (Eg ).
8. Differences between conductor, insulator and semiconductor on the basis of energy bands
are given below:
9. Fermi Energy It is the maximum possible energy possessed by free electrons of a material
at absolute zero temperature (i.e. 0K)
10. On the basis of purity , semiconductors are of two types:
(i) Intrinsic Semiconductors It is a pure semiconductor without any significant dopant
species present
ne = nh =ni
where , ne and nh are number densities of electrons and holes respectively and ni is called
intrinsic carrier concentration.
An intrinsic semiconductor is also called an undoped semiconductor or i-type
semiconductor
(ii) Extrinsic Semiconductors Pure semiconductor when doped with the impurity, it is
known as extrinsic semiconductor.
Extrinsic semiconductors are basically of two types: (a) n-type semiconductors
(b) p-type semiconductors
NOTE: Both the type of semiconductors are electrically neutral.
11. In n-type semiconductor, majority charge carriers are electrons and minority charge
carriers are holes, i.e. ne> nh .
Here, we dope Si or Ge with a pentavalent element, then four of its electrons bond with the
four silicon neighbours, while fifth remains very weakly bound to its parent atom.
Formation of n-type semiconductor is shown below:
12. In p-type semiconductor, majority charge carriers are holes and minority charge carriers
are eletron i.e. nh > ne .
In a p-type semiconductor, doping is done with trivalent impurity atoms, i.e. those atoms
which have three valence electrons in their valence shell.
pn junction
Forward biased
A P-N junction diode is said to be forward biased when the positive terminal of a cell or
battery is connected to the p-side of the junction and the negative terminal to the n side.
When diode is forward-biased the depletion region narrows and consequently, the potential
barrier is lowered. This causes the majority charge carriers of each region to cross into the
other region. The electrons travel from the n-side to the p-side and go to the positive
terminal of the battery. The holes that travel from the p-side to the n-side combine with the
electrons injected into the n-region from the negative terminal of the battery. This way the
diode conducts when forward-biased.
1. A high AC voltage is applied to the primary side of the step-down transformer. The
obtained secondary low voltage is applied to the diode.
2. The diode is forward biased during the positive half cycle of the AC voltage and
reverse biased during the negative half cycle.
3. The final output voltage waveform is as shown in the figure below:
Full wave Rectifier
A simple full way rectifier consists of two transformers mutually inducted and two diodes
which filter the negative cycle of alternating current. At any instant the voltage at A(input
voltage of diode 1) and end B (input voltage of diode 2) of the secondary with respect to the
centre tap will be out of phase. Suppose during a positive half cycle of Ac input, the end A
is positive and end B is negative with respect to the centre tap. Then diode 1 gets forward
biased(allows the flow of current) and diode 2 gets reversed biased(does not allow the flow
of current). Hence the current flows through the diode 1 towards the centre tap along the
path AXY as shown in the above diagram. Similarly, during the negative half cycle of Ac
input the end B becomes positive and end A becomes negative.
Advantages of Full Wave Rectifier
• The rectification efficiency of full wave rectifiers is double that of half wave
rectifiers. The efficiency of half wave rectifiers is 40.6% while the rectification
efficiency of full wave rectifiers is 81.2%.
• The ripple factor in full wave rectifiers is low hence a simple filter is required. The
value of ripple factor in full wave rectifier is 0.482 while in half wave rectifier it is
about 1.21.
• The output voltage and the output power obtained in full wave rectifiers are higher
than that obtained using half wave rectifiers.
The only disadvantage of the full wave rectifier is that they need more circuit elements than
the half wave rectifier which makes, making it costlier.
Ripple factor
The ripple factor is defined as The ratio of the RMS value of an alternating current
component in the rectified output to the average value of rectified output.
Potential barrier: The potential difference created due to the diffusion of charge
carriers across the junction is called the potential barrier.
Since, n2i = ne nh
(1.5 × 1016)2 = ne (4.5 × 1022)
Therefore, ne = 5 × 109
Given nh = 4.5×1023
⇒ nh >> ne
Therefore, the semiconductor is p-type and ne = 5 × 109 m-3.
11. Why is the valence band in semiconductors partially empty, and the
conduction band is partially filled at room temperature?
In semiconductors, the conduction band is empty, and the valence band is
completely filled at zero Kelvin. No electron from the valence band can cross over to
the conduction band at this temperature. But at room temperature, some electrons
in the valence band jump over to the conduction band due to a small forbidden gap,
i.e., 1 eV.
14. Draw a labelled diagram of a full wave rectifier circuit. State its working
principle. Show the input-output waveforms. (All India 2009)
Answer:
p-n junction diode as full wave rectifier
A full wave rectifier consists of two diodes and special type of transformer
known as centre tap transformer as shown in the circuit. The secondary of
transformer gives the desired a.c. voltage across A and B.
During the positive half cycle of a.c. input, the diode D1 is in forward bias and
conducts current while D2 is in reverse biased and does not conduct current.
So we get an output voltage across the load resistor RL.
During the negative half cycle of a.c. input, the diode D1 is in reverse biased
and does not conduct current while diode D2 in forward biased and conducts
current. So we get an output voltage across the load resistor RL.
NOTE: This is a more efficient circuit for getting rectified voltage or current.
15. Draw V-I characteristics of a p-n junction diode.
Answer the following questions, giving reasons:
(i) Why is the current under reverse bias almost independent of the applied
potential upto a critical voltage?
(ii) Why does the reverse current show a sudden increase at the critical
voltage.
Name any semiconductor device which operates under the reverse bias in the
breakdown region.
(All India 2012)
Answer:
(i) In reverse bias of p-n junction diode the small current is due to minority
carrier and hence resistance is also very high. Increase in voltage leads to a
very-very small increase in reverse bias currents so we conclude that in
reverse bias reverse current is almost independent of applied potential upto a
critical voltage because after this critical voltage, current increases suddenly.
(ii) In reverse bias, reverse current through junction diode is due to minority
charge carriers. As reverse bias voltage is increased, electric field at junction
becomes significant. When reverse bias voltage becomes equal to zener
voltage, electric field strength across junction becomes high. Electric field
across junction is sufficient to pull valence electrons from the atom on p- side
and accelerate them towards n-side. The movement of these electrons across
the function account for high current which is observed at breakdown reverse
voltage. Zener diode and photo diode operate under reverse bias.
16. Write any two distinguishing features between conductors, semiconductors
and insulators on the basis of energy band diagrams. (All India 2012)
Answer:
Distinguishing features between conductors, semiconductors and insulators :
(i) Insulator. In insulator, the valence band is completely filled. The conduction
band is empty and forbidden energy gap is quite large. So no electron is able
to go from valence band to conduction band even if electric field is applied.
Hence electrical conduction is impossible. The solid/ substance is an
insulator.
(ii) Conductors (Metals). In metals, either the conduction band is partially
filled or the conduction and valence band partly overlap each other. If small
electric field is applied across the metal, the free electrons start moving in a
direction opposite to the direction of electric field. Hence, metal behaves as a
conductor.
(iii) Semiconductors. At absolute zero kelvin, the conduction band is empty
and the valence band is filled. The material is insulator at low temperature.
However the energy gap between valence band and conduction band is small.
At room temperature, some valence electrons acquire thermal energy and
jump to conduction band where they can conduct electricity. The holes left
behind in valence band act as a positive charge carrier.
(i) In n-type semi conductors an extra energy level (called donor energy level)
is produced just below the bottom of the conduction band, while in the p-type
semiconductor, this extra energy band (called acceptor energy level) is just
above the top of the balanced band.
(ii) In n-type semiconductors, most of the electrons come from the donor
impurity while in p-type semiconductor, the density of holes in the valence
band is predominantly due to the impurity in the extrinsic semiconductors.
(iii) At absolute zero temperature conductivities of both types of semi-
conductors will be zero.
(iv) For equal doping, an n-type semiconductor will have more conductivity
than a p-type semiconductor, at room temperature.
18. Explain the two processes involved in the formulation of a p-n junction diode.
Hence define the term ‘barrier potential’. (Comptt. Delhi 2017)
Answer:
(a) Two important processes that occur during the formation of a p-n junction
are
(i) diffusion and
(ii) drift.
(i) Diffusion: In n-type semiconductor, the concentration of electrons is much
greater as compared to concentration of holes; while in p-type semiconductor,
the concentration of holes is much greater than the concentration of
electrons. When a p-n junction is formed, then due to concentration gradient,
the holes diffuse from p side to n side (p ➝ n) and electrons diffuse from n
side to p-side (n ➝ p). This motion of charge carriers gives rise to diffusion
current across the junction.
(II) Drift: The drift of charge carriers occurs due to electric field. Due to built in
potential barrier an electric field directed from n-region to p-region is
developed across the junction. This field causes motion of electrons on p-side
of the junction to n-side and motion of holes on n-side of junction to p-side.
Thus a drift current starts. This current is opposite to the direction of diffusion
current.
19. (a) Explain the formation of depletion region for p-n junction diode. How does
the width of this region change when the junction is
(i) forward biased,
(ii) reverse biased?
Answer:
(a)
As soon as a p-n junction is formed, the majority charge carriers begin to
diffuse from the regions of higher concentration to the regions of lower
concentrations. Thus the electrons from the n-region diffuse into the p-region
and where they combine with the holes and get neutralised. Similarly, the
holes from the p-region diffuse into the n-region where they combine with the
electrons and get neutralised. This process is called electron-hole
recombination.
The p-region near the junction is left with immobile -ve ions and n-region near
the junction is left with +ve ions as shown in the figure. The small region in
the vicinity of the junction which is depleted of free charge carriers and has
only immobile ions is called the depletion layer. In the depletion region, a
potential difference VB is created, called potential barrier as it creates an
electric field which opposes the further diffusion of electrons and holes.
(i) In forward biased, the width of depletion region is decreased.
(ii) In reverse biased, the width of depletion region is increased.
20. (a) Define the terms ‘depletion layer’ and ‘barrier potential’ for a p-n junction.
How does
(i) an increase in the doping concentration and
(ii) biasing across the junction, affect the width of the depletion layer?
Answer:
(a) (i) Depletion layer. The layer containing unneutralized acceptor and donor
ion across a p-n junction is called depletion layer. It is called depletion layer
because it is depleted of mobile charge carriers.
(ii) Barrier potential. The electric field between the acceptor and donor ions is
called the barrier. The difference of potential from one side of the barrier to
the other side is called barrier potential.
(i) The increase of doping concentration will reduce width of depletion layer in
semi conductor.
(ii) depletion layer widens under reverse bias and vice versa.
1. SEMICONDUCTOR :
A pure semiconductor germanium or silicon, free of every impurity is called intrinsic
semiconductor. At room temperature, a pure semiconductor has very small number of
current carriers (electrons and holes) .Hence its conductivity is low. When the impurity
atoms of valance five or three are doped in a pure semiconductor, we get respectively n-
type or p- type extrinsic semiconductor. In case of doped semiconductor ne nh=ni2. Where
ne and nh are the number density of electron and hole charge carriers in a pure
semiconductor. The conductivity of extrinsic semiconductor is much higher than that of
intrinsic semiconductor
Q (2). The impurity atoms with which pure Si should be doped to make a p- type
semiconductor is
a. Phosphorus
b. Boron
c. Arsenic
d. Antimony
a. Intrinsic semiconductors.
b. Ionic Solids
c. p- type semiconductors
d. Metals
a. Non- metal
b. Metal
c. Insulator
d. None of these
Answers 1. (c) The majority Charge carriers in n-type semicond as holes 2. (b) BORON 3. (c)
p-type semiconductors 4. (c) Insulators
Two statements are given – One labeled assertion (A) and other labeled reason (R).
Select the correct answer to these questions from the codes (a), (b), (c) and (d) as
given below:
a) Both A and R are true and R is the correct explanation of A
b) Both A and R are true but R is not the correct explanation of A.
c) A is true but R is false.
d) A is false but R is true.