SRI MARUTHI PU-COLLEGE HOSKOTE II-PUC

Monthly Test (November-2023)

Sub: Chemistry(34)
Time: 3.15 Hours Max marks: 70

I. Select the correct option from the given choices. 15 x 1 =15M

1. Which of the following is independent of temperature?
a) Lowering of vapour pressure
b) Vapour pressure
c) Relative lowering of vapour pressure
d) Osmotic pressure

2. Given EClo   1.36 V, E o Cr 3 / Cr  0.74 V

2 / Cl

o
ECr O 2 / Cr 3
 1.33V, E o MnO  / Mn2  1.51V
2 7 4

The correct order of reducing power of the species  Cl  , Cr 3 , Mn   will be

a) Mn 2   Cl   Cr 3  Cr b) Mn 2   Cr 3  Cl   Cr

c) Cr 3  Cl   Mn 2   Cr d) Cr 3  Cl   Cr  Mn 2 
3. How much faraday of electricity is required to deposit one mole of silver from silver chloride?
a) 3F b) 1F c) 3F d) 4F
4. The reaction A  B follows second order kinetics if [A] is increased by 3times, the rate of
formation of B will be
a) increased by 6 times b) increased by 9 times
c) decreased by 6 times d) decreased by 9 times
5. The metal ion not form coloured compound is
a) Chromium b) Manganese c) Zinc D) Iron
6. Which of the following hybridisations has square planar geometry?

a) sp 3d b) dsp 3 c) dsp 2 d) sp3

7. 3 alkyl halides are practically inert to substitution by SN2 mechanism because of

a) Insolubility b) Instability c) Inductive effect d) Steric hindrance
8. Ethanol on warming with Conc. H 2 SO4 at 413 K gives

a) ethene b) diethyl ether c) dimethyl ether d) all

9. Identify the product when anisole react with HI

a) CH 3OH b) C6 H 5OH c) C6 H 5 I d) all

10. Aldehydes and ketones both are identified by
a) Tollen’s reagent b) Fehling’s solution c) Benedict’s solution d) 2,4-DNP
11. Benzoyl chloride on reduction with H2/Pd, BaSO4 produces
a) Benzoic acid b) Benzyl alcohol c) Benzoyl sulphate d) Benzaldehyde
12. During nitration of aniline, amino group is protected by
a) Acetylation b) hydrolysis c) Saponification d) Sulphonation
13. N-ethyl benzene sulphonamide is soluble in alkali because
a) Hydrogen attached to nitrogen in sulphonamide is strongly acidic
b) Hydrogen attached to nitrogen in sulphonamide is strongly basic
c) Sulphonyl group attached to nitrogen atom is strong electron withdrawing group
d) Sulphonyl group attached to nitrogen atom is strong electron donating group
14. Identify optically inactive amino acid
a) Alanine b) valine c) Glycine d) Leucine
15. Which of the following acids is a vitamin?
a) Aspartic acid b) Adipic acid c) Ascorbic acid d) Glutamic acid

II. Fill in the blanks by choosing the appropriate answer from those given in
bracket. 5x1=5
(Chloroform, unaltered, temperature, pressure, increases, decreases)
16. Molality is independent of _______________
17. If initial concentration of first order reaction is doubled then half-life period is ___________ .

18. As we proceed from La  OH 3 to Lu  OH 3 , basic strength __________ .

19. __________ is a polyhalo compound.

20. The boiling point of primary amines ________ with increase in number of carbon atoms.
III. Answer any three of the following. 3x2=6
21. Name the phenomenon involved.
a) a piece of raw mango in salt solution shrinks. 1M
b) When pressure greater than osmotic pressure is applied on solution side.1M
22. a) What is Pseudo-first order reaction? 1M
b) Write Arrhenius equation. 1M
23. What are ambident ligands? Give an example.
24. Explain fittig’s reaction.
25. How is Benzene converted into benzaldehyde by Gattermann-Koch reaction? Write equation.
26. Name the two hormones which regulate the glucose level in the blood.
IV. Answer any three of the following. 3x3=9
27. Explain the preparation of potassium permanganate from MnO 2.
28. a) Calculate spin only Magnetic moment of M 3+ ion (Z = 24) 2M
b) Explain why Cu+ ion is not stable in aqueous solution. 1M
29. What is Lanthanoid contraction? Mention two of its consequences.
30. Using valence bond theory, account for the hybridisation Geometry and Magnetic property of
 NiCl4 
2
. [Given, atomic number of Ni = 28].

31. Draw the energy level diagram for the crystal field splitting in tetrahedral complexes. Write the
relation between  0 and  t for the complexes having same metal, same ligand and metal ligand
distances.
32. Predict the type of isomerism for the following complexes.

I)  Pt Br  NH 3 3  SO4 II) Co Cl2  en 2  III)  Pt  NH 3  4   Pt  Cl4  

V. Answer any two of the following . 2x3=6

33. a) How does solubility of a gas in liquid vary with temperature and pressure? 2M
b) 10 ml of liquid ‘A’ is mixed with 10 ml of liquid ‘B’ the volume of the resultant solution is 19.9
ml. What type of deviation is expected from Raoult law? 1M
34. State Kohlrausch law of independent migration of ions. Mention two applications of it.
35. a) How does conductivity and molar conductivity vary with concentration of electrolytic solution?
2M
b) Name the gas evolved at anode during the electrolysis dilute H 2SO4. 1M
36. Derive an integrated rate equation for a first order reaction.
IV. Answer any four of the following. 4 x 5 = 20
37. a) Explain SN1 mechanism for the hydrolysis of 2-bromo-2-methylpropane. 2M
b) Complete the following reactions

I) C2 H 5 Br  KCN 

II) C6 H 5 N 2Cl 

Cu2Cl2 / HCl
2M

c) Define sereocenter? 1M
38. a) Write the mechanism of acid catalysed dehydration of ethanol to ethene. 3M
b) Among phenol and alcohol which is more acidic? Give reason. 2M
39. a) An aromatic hydrocarbon ‘A’ having molecular formula C 9H12 is oxidised in presence of air gives
compound ‘B’. The compound ‘B’ is treated with dilute acid gives two organic compounds C and D.
The compound C forms white precipitate ‘E’ with Bromine water. Write the chemical reactions with
names A, B, C and E. 4M
b) Give an example for unsymmetrical (mixes) ether. 1M
40. a) Write the structures of A and B.

CH 3CHO  CH 3OH 

dry HCl
 A 
CH 3OH
B 2M

b) Explain Aldol condensation with an example. 2M

c) Arrange the following in increasing order of their reactivity towards HCN.
Acetone, acetaldehyde, formaldehyde, Acetophenone. 1M
41. a) Explain the esterification reaction with an example 2M
b) Name the reagent used in clemmenson’s reduction. 1M
c) Mention the role of dry HCl in the addition of alcohols to carbonyl compounds. 1M
d) What type of carboxylic acids undergo HVZ reaction? 1M
42. a) Identify X, Y, and Z in the following reactions.

3M
b) Give reasons:
I) Aniline does not undergo Friedel Craft’s reactions. 1M
II) Aniline with conc; HNO3 forms meta nitro compound in significant amounts. 1M
43. a) Draw the Haworth structure of maltose 2M
b) Deficiency of which vitamin causes the disease Rickets. 1M
c) How many peptide bonds present in hexapeptide? 1M
d) Name the type of linkage between two nucleotides in nucleic acid. 1M
VII. Answer any three of the following: 3x3=9
44. 450 cm3 of an aqueous solution of a protein contains 1 g of the protein the osmotic pressure of such
at solution of 310 K is found to be 3.1104 bar. Calculate molar mass of protein [R = 0.083 L bar
mol-1 K-1].
45. At 200C the vapour pressure of pure liquids A is 22 mm of Hg and that of pure liquid B is 75 mm of
Hg. What is the mole fraction of these two components in a solution that has a vapour pressure of
48.5 mm of Hg at this temperature.

46. The conductivity of 0.01 M solution of acetic acid at 298 K is 1.65 104 S cm1 . Calculate
dissociation constant for acetic acid. (Given  om for acetic acid = 390 S cm2 mol-1).

 
47. Calculate the cell EMF at 250C for the cell Zn Zn20.0004 M
Cd20.2 M
o
Cd . Given Ecell values at 25C ;
Zn 2 / Zn  0.763V and Cd 2 / Cd  0.403 N , F  96,500 C , R  8.314 J K 1 mol 1 .

48. The rate of a reaction doubles when the temperature changes from 270C to 370C. Calculate the value
of Ea.
49. The three fourth of a first. Order reaction is completed in 32 minutes. What is the half-life period of
the reaction?