Scribd
Upload
44 views2 pages

Tutorial 2

This document provides example problems for calculating various properties related to electromagnetic radiation absorption and transmission, including: 1) Calculating wavelengths of signals transmitted at various frequencies. 2) Calculating wavelength and energy of a 220 MHz signal. 3) Identifying units for absorptivity given different path lengths and concentrations. 4) Converting between absorbance and percent transmittance. 5) Calculating molar absorptivities from transmittance data. 6) Additional examples involving constructing calibration curves to determine unknown concentrations.

Uploaded by

ariff udin
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
44 views2 pages

Tutorial 2

This document provides example problems for calculating various properties related to electromagnetic radiation absorption and transmission, including: 1) Calculating wavelengths of signals transmitted at various frequencies. 2) Calculating wavelength and energy of a 220 MHz signal. 3) Identifying units for absorptivity given different path lengths and concentrations. 4) Converting between absorbance and percent transmittance. 5) Calculating molar absorptivities from transmittance data. 6) Additional examples involving constructing calibration curves to determine unknown concentrations.

Uploaded by

ariff udin
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

Tutorial 2

1. 24-7. Calculate the wavelength in centimeters of


a. an airport tower transmitting at 118.6 MHz.
b. a VOR (radio navigation aid) transmitting at 114.10 kHz.
c. an NMR signal at 105 MHz.
d. an infrared absorption peak with a wavenumber of 1210 cm-1

2. 24-11. Calculate the wavelength and the energy in joules associated with a signal
at 220 MHz.

3. 24-13. What are the units for absorptivity when the path length is given in
centimeters and the concentration is expressed in
a. parts per million? Anw ppm-1 cm-1
b. micrograms per liter?
c. mass-volume percent?
d. grams per liter?

4. 24-14. Express the following absorbances in terms of percent transmittance


a. 0.0356 Anw 92.1%
b. 0.895
c. 0.379

5. 24-15. Convert the accompanying transmittance data to absorbances.


a. 27.2% Anw 0.565
b. 0.579
c. 30.6%

6. 24-19. A solution containing 4.48 ppm KMnO4 exhibits 85.9 %T in a 1.00-cm cell at
520 nm. Calculate the molar absorptivity of KMnO4 at this wavelength.

7. 24-20 Beryllium(II) forms a complex with acetylacetone (166.2 g/mol). Calculate the
molar absorptivity of the complex, given that a 2.25 ppm solution has a
transmittance of 37.5% when measured in a 1.00-cm cell at 295 nm, the wavelength
of maximum absorption.

8. *24-23. A solution containing the complex formed between Bi(III) and thiourea has
a molar absorptivity of 9.32 x 103 L cm-1 mol-1 at 470 nm.
a. What is the absorbance of a 5.67 x 10-5 M solution of the complex at 470 nm in
a 1.00-cm cell?
b. What is the percent transmittance of the solution described in (a)?
c. What is the molar concentration of the complex in a solution that has the
absorbance described in (a) when measured at 470 nm in a 2.50-cm cell?
9. 24-24. The complex formed between Cu(I) and 1,10-phenanthroline has a molar
absorptivity of 7000 L cm-1 mol-1 at 435 nm, the wavelength of maximum absorption.
Calculate
a. the absorbance of a 6.17 x 10-5 M solution of the complex when measured in a
1.00-cm cell at 435 nm.
b. the percent transmittance of the solution in (a).
c. the concentration of a solution that in a 5.00-cm cell has the same absorbance
as the solution in (a).
d. the path length through a 3.13 x 10-5 M solution of the complex that is needed
for an absorbance that is the same as the solution in (a)
10. 24-26 A compound X is to be determined by UV/visible spectrophotometry. A
calibration curve is constructed from standard solutions of X with the following
results: 0.50 ppm, A 5 0.24; 1.5 ppm, A 5 0.36; 2.5 ppm, A 5 0.44; 3.5 ppm, A 5
0.59; and 4.5 ppm, A 5 0.70. Find the slope and intercept of the calibration curve,
the standard error in Y, the concentration of the solution of unknown X
concentration, and the standard deviation in the concentration of X. Construct a
plot of the calibration curve and determine the unknown concentration by hand
from the plot.

You might also like

pFad - Phonifier reborn

Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


Alternative Proxies:

Alternative Proxy

pFad Proxy

pFad v3 Proxy

pFad v4 Proxy