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STPM 2016 Sem 1 Real Ms

This document contains a marking scheme for a chemistry exam with several questions. It provides the answers and explanations for each question worth a total of 20 marks. The questions cover topics like drawing molecular structures, calculating molar ratios from empirical formulas, acid-base titration curves, and gas equilibrium constants. Answers are provided in sentence or point form with clear labeling of marks awarded for each part.

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1K views2 pages

STPM 2016 Sem 1 Real Ms

This document contains a marking scheme for a chemistry exam with several questions. It provides the answers and explanations for each question worth a total of 20 marks. The questions cover topics like drawing molecular structures, calculating molar ratios from empirical formulas, acid-base titration curves, and gas equilibrium constants. Answers are provided in sentence or point form with clear labeling of marks awarded for each part.

Uploaded by

sliong1020
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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REAL MARKING SCHEME

STPM SEMESTER 1 2015


20 / 16 962 / 1 (CHEMISTRY
CHEMISTRY)
Section B and C
2
16.a) i Draw structure (must have diatom) [3] 19. a) i. - C is sp hybridised [1]
3
ii. Curve [1] label with sublimation [1] - N is sp hybridised [1]
- C form 1 π-bond and 3 σ-bond
bond [1]
- N form 3 σ-bond
bond with one lone pair electrons [1]
- Structure at excited state [1]
Carbon Nitrogen
↑ ↑ ↑ ↑ ↑↓ ↑ ↑ ↑
2s 2p 2s 2p
-
ii. Lewis structure : C N [1]
b) - since Y2 has greater molecular size than X2 @
iii. - Since C-N
N in peptide has single bond [1]
- weak Van Der Waals forces of Y2 is greater than X2 [1]
0 - while C-N N in cyanide ion has triple bond [1]
- X2 is a liquid / vapour above - 7.2 C [1]
0 - bond length of C-N in peptide is longer than in cyanide
- Y2 is a solid below 113.8 C [1]
ion. [1]
17 a) vapour pressure exerted by a mixture of solution is - as the C-N N in cyanide contain 2 π-bond and 1 σ-bond
the mol fraction multiply with the pure vapour pressure.[1] while -CONH- consist of 1 σ-bond
bond [1]
b) - mixture of H2O and HF shows negative deviation [1]
- both H2O and HF are hydrogen bonding [1] b) - BaCl2 has higher
her melting point than BeCl2 [1]
- since the intermolecular forces of mixture (electrostatic - BaCl2is held by strong
trong ionic bond / electrostatic
attraction forces) is stronger than in H2O and HF [1] attraction forces. [1]
c) 10% of HF and 90% of H2O [1] - BaCl2 is an ionic compound [1]
0
d) 120 C [1] - BeCl2is simple covalent molecule [1]
e) liquid and vapour [1] - hold by weak Van Der Waals' forces [1]

18. a) mass of O = 1.00 - (0.198 + 0.0250 + 0.116) @ 20. a) 2 H2O (g) ↔ 2 H2 (g) + O2 (g)
= 0.6610 [1] Initial / mol 1.0 0 0
- calculate mol [1] - ratio [1] Dissociation - (1.0)(0.02) + (1.0)(0.02) +1/2(1.0)(0.02)[1]
Element C H N O At equilibrium 0.98 0.02 0.01 [1]
Mass / g 0.198 0.0250 0.116 0.6610 Total mol = 0.98 + 0.02 + 0.01 = 1.01 mol [1]
Mol 0.0165 0.0250 0.00829 0.0413 PH2O = (0.98/1.01)(1.0)
8/1.01)(1.0) = 0.9703 atm
Ratio 2 3 1 5 PH2 = (0.02/1.01)(1.0) = 0.0198 atm
- Empirical formula : C2H3NO5 [1] PH2 = (0.02/1.01)(1.0) = 0.0099 atm [1]
- (C2H3NO5)n=121 @ (2(12)+3(1)+1(14)+5(16))n = 121 [1] (PH 2 ) 2 (PO 2 ) (0.0198) 2 (0.0099) [1]
- Molecular formula : C2H3NO5 [1] KP = 2
@
b) Formulae of species (1 - 4√ :1m ; 5 - 7√ 7 :2m ; 8√ :3m) (PH 2 O ) (0.9703) 2
+ +
m/e = 16 ; O m/e = 32 ; O2 KP = 4.1 x 10 atm
-6
[1]
+ +
m/e = 35 ; 35Cl m/e = 37 ; 37Cl ii. - As T increase, KP increased [1]
+ +
m/e = 51 ; (35ClO) m/e = 53 ; (37ClO) - very small KP value ; formation of water is favoured /
+ +
m/e = 67 ; (35ClO2) m/e = 69 ; (35ClO2) equilibrium shift to the left [1]
+
c) - He has 1 electron / single electron system [1] b) Axis [1] plotting [1] curve [1] [3]
- electron absorbed energy and excite to higher level [1] 12
- electron at excited state is unstable [1]
- as e- fall from higher level to lower, excess energy is 10
released / electromagnetic wave emitted / photon energy
is released [1] 8
pH

- E = hf / E = hc / λ [1]
- Energy (1) Spectra [1] [2] 6
n=∞
n= 5 4
n= 4
2
n= 3
0
n= 2 0 5 10 15
3 20
VNaOH / cm
3
ii. - equivalent point at 15.6 - 16.0 cm [1]
n= 1 - pH at 1/2 V = pKa = 3.9 [1]
-4 -3
- Ka = 1.3 x 10 mol dm [1]
M A VA a M A (10.00) 1 [1]
= @ =
M B VB b (0.0500)(16.00) 1
-3
MA = 0.080 mol dm [1]
Section A 1 B 2 C 3 B 4 A 5 D 6 D 7 D
8 B 9 C 10 A 11 A 12 C 13 D 14 C 15 A

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