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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006
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SDS # : 31356
CALORIS 23

Date of the previous version: 2018-04-23 Revision Date: 2019-09-11 Version 3.03

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product identifier

Product name CALORIS 23

Number 10Q
Substance/mixture Mixture***

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Lubricating grease.

1.3. Details of the supplier of the safety data sheet

Supplier A - TOTAL UK LIMITED

183 Eversholt St, Kings Cross
London, NW1 1BU
UNITED KINGDOM
Tel: +44 (0)20 7339 8000
Fax: +44 (0)20 7339 8033

B - TOTAL LUBRIFIANTS
562 Avenue du Parc de L'ile
92029 Nanterre Cedex
FRANCE
Tél: +33 (0)1 41 35 40 00
Fax: +33 (0)1 41 35 84 71

For further information, please contact:

Contact Point A - HSE

B - HSE
E-mail Address A - rm.gb-msds@total.co.uk

B - rm.msds-lubs@total.com

1.4. Emergency telephone number

Emergency telephone: +44 1235 239670

***
UK: National Poisons Information Service (NPIS): NHS on 111 or a doctor

Section 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

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REGULATION (EC) No 1272/2008

For the full text of the H-Statements mentioned in this Section, see Section 2.2.

Classification
The product is not classified as dangerous according to Regulation (EC) No. 1272/2008

2.2. Label elements

Labelled according to REGULATION (EC) No 1272/2008***

Signal word
None

Hazard Statements
None

Precautionary statements
None

2.3. Other hazards

Physical-Chemical Properties Contaminated surfaces will be extremely slippery.***

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixture***

Chemical nature Mineral oil of petroleum origin.***

Hazardous components Do not contain hazardous substance nor substance with european workplace exposure
limits in concentration above regulatory thresholds

Additional information Product containing mineral oil with less than 3% DMSO extract as measured by IP 346.

For the full text of the H-Statements mentioned in this Section, see Section 16.

Section 4: FIRST AID MEASURES

4.1. Description of first aid measures

General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR

EMERGENCY MEDICAL CARE.***

Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Keep eye wide open while rinsing.***

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated

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clothes and shoes. Wash contaminated clothing before reuse. High pressure jets may
cause skin damage. Take victim immediately to hospital.***

Inhalation Remove casualty to fresh air and keep at rest in a position comfortable for breathing. If not
breathing, give artificial respiration.***

Ingestion Clean mouth with water. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician or poison control centre immediately.***

Protection of first-aiders First aider needs to protect himself. See Section 8 for more detail. Do not use
mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device.***

4.2. Most important symptoms and effects, both acute and delayed

Eye contact Not classified based on available data.

Skin contact Not classified based on available data. High pressure injection of the products under the
skin may have very serious consequences even though no symptom or injury may be
apparent.

Inhalation Not classified based on available data. Inhalation of vapours in high concentration may
cause irritation of respiratory system.***

Ingestion Not classified based on available data. Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhoea.***

4.3. Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.***

Section 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.***

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture

Special hazard Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may
be highly dangerous if inhaled in confined spaces or at high concentration. Combustion
products include sulphur oxides ( SO2 and SO3 ) and Hydrogen sulphide H2S, Mercaptans,
Nitrogen oxides (NOx), Zinc oxides.***

5.3. Precautions for fire-fighters

Special protective equipment for Wear self-contained breathing apparatus and protective suit.***
fire-fighters

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Other information Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

General Information Do not touch or walk through spilled material. Contaminated surfaces will be extremely
slippery. Use personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition.***

6.2. Environmental precautions

General Information Do not allow material to contaminate ground water system. Prevent entry into waterways,
sewers, basements or confined areas. Local authorities should be advised if significant
spillages cannot be contained.***

6.3. Methods and material for containment and cleaning up

Methods for containment If necessary dike the product with dry earth, sand or similar non-combustible materials.***

Methods for cleaning up Dispose of contents/container in accordance with local regulation. In case of soil
contamination, remove contaminated soil for remediation or disposal, in accordance with
local regulations.***

6.4. Reference to other sections

Personal protective equipment See Section 8 for more detail.

Waste treatment See section 13.

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling For personal protection see section 8. Use only in well-ventilated areas. Avoid contact with
skin, eyes and clothing.***

Prevention of fire and explosion Take precautionary measures against static discharges.***

Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the risk of
contact with the product. When using, do not eat, drink or smoke. Wash hands before
breaks and immediately after handling the product. Regular cleaning of equipment, work
area and clothing is recommended. Do not use abrasives, solvents or fuels. Do not dry
hands with rags that have been contaminated with product. Do not put product
contaminated rags into workwear pockets.***

7.2. Conditions for safe storage, including any incompatibilities

Technical measures/Storage Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep

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conditions container tightly closed. Preferably keep in the original container. Otherwise, reproduce all
the statutory information from the labels onto the new container. Do not remove the hazard
labels of the containers (even if they are empty). Design the installations in order to avoid
accidental emissions of product (due to seal breakage, for example) onto hot casings or
electrical contacts. Store at room temperature. Protect from moisture. Protect from frost,
heat and sunlight. Store in original container. Keep in properly labelled containers.***

Materials to avoid Strong oxidising agents.***

7.3. Specific use(s)

Specific use(s) Please refer to Technical Data Sheet for further information.

Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control parametres

Exposure limits Mineral oil mist:

USA: OSHA (PEL) TWA 5 mg/m3, NIOSH (REL) TWA 5 mg/m3, STEL 10 mg/m3, ACGIH
(TLV) TWA 5 mg/m3 (highly refined)
***

Legend See section 16.***

8.2. Exposure controls

Occupational Exposure Controls

Engineering measures Apply technical measures to comply with the occupational exposure limits. Ensure
adequate ventilation, especially in confined areas. When working in confined spaces (tanks,
containers, etc.), ensure that there is a supply of air suitable for breathing and wear the
recommended equipment.***

Personal protective equipment

General Information Protective engineering solutions should be implemented and in use before personal
protective equipment is considered. These recommendations apply to the product as
supplied.***

Respiratory protection None under normal use conditions. When workers are facing concentrations above the
exposure limit they must use appropriate certified respirators. Respirator with combination
filter for vapour/particulate (EN 14387). Type A/P1. Warning ! filters have a limited use
duration. The use of breathing apparatus must comply strictly with the manufacturer's
instructions and the regulations governing their choices and uses.***

Eye protection If splashes are likely to occur, wear:. Safety glasses with side-shields. EN 166.***

Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing. Type
4/6. Do not wear rings, watches or anything similar which can retain the product and may
cause a skin reaction. Extended and repeated contacts with skin can cause skin ailments
which may be aggravated by minor injuries or contact with soiled clothing.***

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Hand protection Hydrocarbon-proof gloves. Fluorinated rubber. Nitrile rubber. In case of prolonged contact
with the product, it is recommended to wear gloves complying with EN 420 and EN 374
standards, protecting at least for 480 minutes and having a thickness of 0,38 mm at least.
These values are indicative only. The level of protection is provided by the material of the
glove, its technical characteristics, its resistance to the chemicals to be handled, the
appropriateness of its use and its replacement frequency. Please observe the instructions
regarding permeability and breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local conditions under which the product is
used, such as the danger of cuts, abrasion, and the contact time. If used in solution, or
mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the EC approved gloves.***

Environmental exposure controls

General Information The product should not be allowed to enter drains, water courses or the soil.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Colour brown
Physical state @20°C solid
Odour characteristic
Odour Threshold No information available

Property Values Remarks Method

pH Not applicable
Melting point/range No information available

Boiling point/boiling range Not applicable

Flash point Not applicable

Evapouration rate No information available

Flammability Limits in Air

Upper No information available

Lower No information available
Vapour pressure No information available
Vapour density No information available
Relative density 0.880 @ 20 °C
Density 880 kg/m3 @ 20 °C
Water solubility Insoluble
Solubility in other solvents No information available
logPow No information available***
Autoignition temperature No information available
Decomposition temperature No information available
Viscosity, kinematic Not applicable
Explosive properties Not explosive
Oxidising properties Not applicable

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Possibility of hazardous reactions None under normal processing

9.2. Other information

Freezing point No information available

Section 10: STABILITY AND REACTIVITY

10.1. Reactivity

General Information None under normal processing.***

10.2. Chemical stability

Stability Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hazardous reactions No dangerous reaction known under conditions of normal use.***

10.4. Conditions to avoid

Conditions to avoid Keep away from open flames, hot surfaces and sources of ignition. Keep away from heat
and sparks.***

10.5. Incompatible materials

Materials to avoid Strong oxidising agents.***

10.6. Hazardous Decomposition Products

Hazardous Decomposition Products Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. Combustion
products include sulphur oxides ( SO2 and SO3 ) and Hydrogen sulphide H2S, Mercaptans,
Nitrogen oxides (NOx), Zinc oxides.***

Section 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity Local effects Product Information

Skin contact . Not classified based on available data. High pressure injection of the products under the
skin may have very serious consequences even though no symptom or injury may be
apparent.

Eye contact . Not classified based on available data.

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Inhalation . Not classified based on available data. Inhalation of vapours in high concentration may
cause irritation of respiratory system.***

Ingestion . Not classified based on available data. Ingestion may cause gastrointestinal irritation,
nausea, vomiting and diarrhoea.***

ATEmix (inhalation-dust/mist) 175.30 mg/l

ATEmix (inhalation-vapour) 279.60 mg/l

Acute toxicity - Component Information

Sensitisation

Sensitisation Not classified based on available data.

Specific effects

Carcinogenicity Not classified based on available data.

Mutagenicity .
Germ cell mutagenicity Not classified based on available data.

Reproductive toxicity Not classified based on available data.

Repeated dose toxicity

Target Organ Effects (STOT)

Specific target organ systemic Not classified based on available data.

toxicity (single exposure)

Specific target organ toxicity - Not classified based on available data.

repeated exposure

Aspiration toxicity Not classified based on available data.

Other information

Other adverse effects Characteristic skin lesions (oil blisters) may develop following prolonged and repeated
exposures (contact with contaminated clothing).***

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Not classified based on available data.

Acute aquatic toxicity - Product Information***

No information available.

Acute aquatic toxicity - Component Information

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No information available.

Chronic aquatic toxicity - Product Information

No information available.

Chronic aquatic toxicity - Component Information

No information available.

Effects on terrestrial organisms

No information available.***

12.2. Persistence and Degradability

General Information
No information available.

12.3. Bioaccumulative potential

Product Information No information available.***

logPow No information available***

Component Information No information available.***
12.4. Mobility in soil

Soil Given its physical and chemical characteristics, the product has no soil mobility.***

Air Loss by evaporation is limited.***

Water The product is insoluble and floats on water.***

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment No information available.***

12.6. Other adverse effects

General Information No information available.***

Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from residues / unused Should not be released into the environment. Do not empty into drains. Dispose of in
products accordance with the European Directives on waste and hazardous waste. Dispose of in
accordance with local regulations. Where possible recycling is preferred to disposal or
incineration. If recycling is not practicable, dispose of in compliance with local
regulations.***

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Contaminated packageing Empty containers should be taken to an approved waste handling site for recycling or
disposal.***

EWC Waste Disposal No According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application
for which the product was used. The following Waste Codes are only suggestions:. 12 01
12.***

Other information Refer to section 8 for safety and protective measures for disposal personnel. According to
the European Waste Catalogue, Waste Codes are not product specific, but application
specific. Waste codes should be assigned by the user based on the application for which
the product was used.***

Section 14: TRANSPORT INFORMATION

ADR/RID not regulated

IMDG/IMO not regulated

ICAO/IATA not regulated

ADN not regulated

Section 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture

European Union

REACH
All substances contained in this mixture have been pre-registered, registered or are exempt from registration in accordance with
Regulation (CE) No. 1907/2006 (REACh)***

International Inventories All the substances contained in this product are listed or exempted from listing in the
following inventories:
Canada (DSL/NDSL)
Europe (EINECS/ELINCS/NLP)
New Zealand (NZIoC)
China (IECSC)
Philippines (PICCS)
Korea (KECL)
Australia (AICS)
Japan (ENCS)
U.S.A. (TSCA)***

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Further information

No information available

15.2. Chemical Safety Assessment

Chemical Safety Assessment No information available

15.3. National regulatory information

The United Kingdom

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Section 16: OTHER INFORMATION

Abbreviations, acronyms
ACGIH = American Conference of Governmental Industrial Hygienists
bw = body weight
bw/day = body weight/day
EC x = Effect Concentration associated with x% response
GLP = Good Laboratory Practice
IARC = International Agency for Research of Cancer
LC50 = 50% Lethal concentration - Concentration of a chemical in air or a chemical in water which causes the death of 50% (one
half) of a group of test animals
LD50 = 50% Lethal Dose - Chemical amount, given at once, which causes the death of 50% (one half) of a group of test animals
LL = Lethal Loading
NIOSH = National Institute of Occupational Safety and Health
NOAEL = No Observed Adverse Effect Level
NOEC = No Observed Effect Concentration
NOEL = No Observed Effect Level
OECD = Organization for Economic Co-operation and Development
OSHA = Occupational Safety and Health Administration
UVCB = Substance of unknown or Variable composition, Complex reaction products or Biological material
ATE = Acute Toxicity Estimate
QSAR = Quantitative Structure-Activity Relationship
EL50 = median Effective Loading
NOELR = No Observed Effect Loading Rate
PAH = Polycyclic aromatic hydrocarbons
LOEC = Lowest Observed Effect Concentration
PVA = Polyvinyl alcohol
PVC = Polyvinyl chloride
ECOSAR = Ecological Structure Activity Relationships
CNS = Central nervous system
EPA = Environmental Protection Agency
ErL50 = effective loading on growth rate in algae test, to cause a 50% response
EbL50 = effective loading on growth with the control in algae test, to cause a 50% response

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DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
dw = dry weight
fw = fresh water
mw = marine water
or = occasional release

Legend Section 8

OEL = Occupational Exposure Limit

TWA: Time Weight Average
STEL: Short Time Exposure Limit
PEL: Permissible exposure limit
REL: Recommended exposure limit
TLV: Threshold Limit Values

+ Sensitiser * Skin designation

** Hazard Designation C: Carcinogen
M: Mutagen R: Toxic to reproduction

Revision Date: 2019-09-11

Revision Note *** Indicates updated section.
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
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This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the
user that any use of the product for purposes other than those for which it was designed entails potential risk.The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his
activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated
herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is
the user's responsibility to ensure that he is subject to no other obligations than those mentioned.

End of Safety Data Sheet

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