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1st Chem File 2 - Compressed

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Versatile Master Key ( 244 ) Solved Chemistry 1, Year 5. (a) Define Limiting reactant and how it is identified by different steps. ,notespk.com (b) Explain Millikan's oil droplet experiment for determination of charge on electron. notespk.cdm 6. (a) There is a mixture of Hydrogen, helium and methane occupying a vessel of volume 13dm’ 37 °C and | atm. The masses of H, and He are 0.8 g and 0.12 g respectively, Calculate the mole fraction of ear gas? What is’Galvanic sell. Give the construction of Zn - Cu Galvanic cell. Briefly explain composition of electrodes and chemical reactions at electrodes. notespk.com Define electron affinity. Enlist factors influencing Electron Affinity. How it varies in groups and periods? E ° 3 2 (a (b) State First law of thermodynamics. Prove that AE = 4, . 8. (a) What are liquid crystals? Give their four applications in daily life. notespk.co (b) The solubility of CaF, in water at 25 °C is found to be 2.05x 10“ moldm™. Calculate the value of X,, at this temperature. notespk,com 9. (a) Explain the depression of the freezing point of a solvent by a solute with the help of a graph. > (b) What are enzymes? Give examples in which they act as catalyst. Mention the characteristics of enzyme catalysis. SAHIWAL BOARD 2022 PAPER CHEMISTRY PART-I (G - I) Time: 20 Min. (Objective Part) Marks: 17 Note: You have four choice for each objective type question as A, B, C and D. The choice which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles. Cutting or filling two or more circles wilt result in zero mark in that question. (i) For which svstem. does the equilibrium constant K, has units of (concentration) '? 4 potespk.co™ east 32H, (a) Nagy +3 aig) 2M ayay(b) Haay + Lg) 2M notesok.com ee Versatile Master Key (245 ) ‘Solved Chemistry 1, Year (ii) (iii) (iv) wv) wi) (vii) (0) 2NOy) = NOy) vg) PHF) Ayo) t Fr The change in heat energy of a chemical reaction at a Constant temperature and pressure is called: ,9tesok.¢o™ (a) Enthalpy change ¥ (b) Bond energy (c) Heat of sublimation (d) internal energy Acetone and chloroform are soluble into each other due to: (a) Intermolecular hydrogen bonding ¥ (b) lon dipole interaction (c) _ instantaneous dij (a) Allofthese =. notesP.c: Quantum number values fot 2p orbitals are: (@) n=2/=1v (b) n=1,/=2 () n=1,/=0 (d) n=2,/=0 ! The type of hybridization in molecule of ethene (CH, = CH,) Is: (a) Sp (b) sp’ ©, 2 Y (d) Dsp Which of ‘the given will have same number of molecules at STP? >" tesppi.com (vi), Which one is pseudo solid? nee (a) CaF (b) Glass“ (c) NaCl (d) All these (vii) The molecules of CO, in dry ice form: (a) Ionic crystal (b) Molecular crystal ~ a [ersatie Masier Key. (78) Sonea Oromia 2, Yoo? (c) Covalent crystal (d) Mettalic crystal (viii) Quantum number values for 2p orbitals are: yu co™ (@) n=2¢=1¥ (bt) n=26=0 oct (ce) n=2 €=2 () n=1e=2 °° (ix) When 6d orbital is complete, the entering electron goes into: (a) 7p (b) 7s ¥ (c) 7d (d) 7E (x) Which one has unpaired electron in antibonding molecular orbital? not ~ @ 8 ~& Mv «| B w & (xi) Which one has zero dipole moment? (a) NH, (b) CHCl, (c) HO (d@) BF, ¥ (xii) Caloric is equivalent to: (a) 0.4184 (b) 41.843 (©) 4184 Y (d) 418.4 (xiii) The pH of 10-M of an aqueous solution of H,SO, is: (a) 3.2 (b) 2.7¥ (c) 2.0 @) LS (xiv) Molarity of pure water is: notespk.com (ay i (b) 18 (©) S555¥ (d) 6 (xv) ‘Stronger the reducing agent greater is the: (a) Oxidization potential ¥ (b) Reduction potential (©). Redox potential (d) EMF of cell (xvi) In zero order reaction the rate is independent of: (a) Temperature of reaction (b) Concentration of reactants Vv (c) Concentration of products (d) None of these (xvii)How many times Na atom is heavier than H-atom? (a) 11 times (b) 46 times (c) 32 times . (d) 23 times “ porespk.com Section! stecpk com 2. Attempt any EIGHT short questions. (8 «2 = 16) (i) What is stoichiometry? Which laws are obeyed during stoichiometric calculations? (ii) What is Molar volume? Give example. (iii) Calculate the gram atoms in 0.1g of Sodium. (iv), What is Gooch crucible? o (v) How crystals are dried in vacuum desiccator? (vi) What is ether extraction? (vii) Calculate the value of R in S.I uni o of Versatile Master Key (254) __Solyed Chemistry 1,, Year (vili)Give difference between effusion and diffusion. (ix) Why gases are ideal at low pressure and high temperature? (3) Whats law of Mass action? noispe br (xi) What is relationship between K, and K,? (xii) What is Kw? How does its value change with increase in temperature? 3. Attempt any EIGHT short questions. (8 x 2= 16) (i) Why HF is weaker acid than HCC? otespk.co™ (it) Define Molar heat of sublimation. °°” (ii) Differentiate between Amorphous and Crystalline solids. (iv) What is meant by Habit of Crystal? (v) Differentiate between orbit and orbital. (v1) Define frequency and wave number. - (v1) Write down any two postulates of Plank’s quantum theory. (viii) Write down electronic configuration of Cu-29; Cr-24 (ix) What is meant by hydration energy? (x) Define molality. Also write its units. (xi) What is activation of catalyst? Give example. (xii) Differentiate between Average and Instantaneous rate. m ores notespk.com 4 Attempt any SIX short questions. (6*x2=12) (i) Define ionization energy. Why is the second ionization energy higher than that of first? notespk.com (ii) Define electrotiegativity. How do the electronegativity values vary in the periodic table? Notespk.com (iii) Write down two postulates of VSEPR Theory. (iv) Why is CS, molecule linear while SO, molecule is bent or angular? notespk.com (v) Define standard enthalpy of combustion. Give an example. (vi) Give two examples of exothermic reactions. (vii) What is the difference between heat and temperature? (viii)Calculate the oxidation number of Cr in K,Cr,0, and CrCl, (ix) Write down the electrode reactions in silver oxide battery. oes (8% 3 = 24) 5. (a) Define and explain limiting reactant with the help of two examples. (b) Derive the equation to calculate the radius of revolving electron in nth orbit. 6. (a) Calculate the mass of tdm’ of .NH, yas at 30°C and 1000mm Hg pressure, considering that NH, is behaving SS el Versatile Master Key (255) Solved Chemistry 1, Year ideally. notespk.com (b) Describe a galvanic cell explaining the function of electrodes and the salt bridge. (a) Describe postulates of valence shell electron pair repulsion theory (VSEPR). (b) State Hess's law of constant heat summation. Explain this law with the help of two examples. 8. (a) Explain manometric method. for measurement of vapour + pressure, ntespk.com (b) The solubility of CaF, in water at 25°C is found to be 2.08x10‘moldm™. What is the value of KX, at this temperature? _ notesnk.com 9. (a) Differentiate betweeh ideal and non-ideal solutions. (b) How does Arrhenius equation help us to:calculate the energy of activation of a reaction? MULTAN BOARD 2022 RAPER CHEMISTRY PART-I (G - I) Time: 20 Min. . (Objective Part) Marks: 17 Note: You have four choice for each objective type question as A, B, C and D. The choice which you think is correct; fill that circle in front of that question number, Use marker or pen to fill the circles, Cutting or filling two of more circles will result in zero mark in that question. (i) 27g of Al will react completely with how much mass of O, to produce Al,O,? . notespk.com (a) 32g of oxygen (b) 24g of oxygen “ (c) 16g of oxygen (d) 8g of oxygen (ii) Solvent extraction method is a particularly useful technique for separation when the product to be separated is: (a) Volatile or thermally unstable (b) Non-volatile or thermally stable “ (c) Volatile or thermally stable (d) Non-volatile or thermally unstable (iii) The change in heat energy of a chemical reaction at constant temperature and pressure is called: (a) Internal energy change (b) Bond energy (ce) Enthalpy change ¥ (d) Heat of sublimation (iv) The number of moles of CO, which contains 8.0g of oxygen is: (a) 0.50 (b) 0.25 VY (ce) 1.0 0 nores™ 0 d) 1.50 [Persatile Master Key ~~ (256) Solved Chemistry 1, Year (v) Which of the following compounds has the highest percentage of ionic character? notespk.com (a) HCI (b) HI (c) HBr (d) HF ¥ (vi) Which Pair of the following can be separated by sublimation? (a) NaCl and sand (b) J, and Naphthalene (c)_ Naphthalene and sand v, (d) KC¢ and NaCé (vii) Quantum number values for 3d orbitals are: (a) n=3,¢=2 (6) nr2, ¢=3 (ce) n=3,0=3v (d) n=3,2=0° (viii) Which of the folowing species has unpaired electrons in antibonding molecular orbitals? notesnk.co -@) OF ) Ov (©) *F, (d) By (ix) When water freezes at 0°C, its density decreases due to: (a) Cubic structure of ice (b) Change of bond lengths (c). Change of bond angles ——_gotespk.co™ (d) Empty spaces present in the structure of ice V (x) The order of rate of diffusion of gases NH,,SO,,Cl, and CO, is: (a) Cl,>S0,>CO,>NH, (b) NH, > SO, > Cl, >€0, (c) NH,>CO,>Cl,>SO, (a) NH,>CO,>S0,>Cl, v (xi) Splitting of spectral lines when atoms are subjected to strong electric field is called: notespk.com (a) Photoelectric effect (b) Zeeman effect (c) Stark effect V (d) Compton effect Gil) Which of the following will have the same number of gmolecules at S.T.P? - S(a) 280m’ of CO, and 280cm' of NO, ¥ Bb) 11.2dm’ of O, and 32g of 0, oot co Zc) 44g0f CO,and11.2dm’ of CO = (d) 28gof N, and 5.6dm: of oxygen (xiii) In order-to keep the boiling point of water at 110°C, the external pressure should be: o (a) Between 760 torr and 1200 torr Vv rose (b) Between 200 torr and 760 torr 00} (c) 765 torr (d)_ Any value of pressure (xiv) Stronger the oxidizing agent, greater is the: (a) Reduction potential = (b) emf of the cell (c) Oxidation potential (d) Redox potential (xv) The unit of the rate constant is the same as that of the rate of reaction in: : —_—_—_—_— Versatile Master Key (a) Third,order reaction ‘Solved Chemistry 1, Year (b) | Second order reaction (c) First order reaction (d) Zero order reaction ¥ (xvi) Molarity of pure water is: notespk.com (a) 1 (b) 6 () 555” 9 (d) 18 (xvii)Ann excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration. ‘What are the main ions in the filtrate? (a) Ag"! and NO;' only (b) Ba’ and NO,' only (c) Ba?‘ and NO; and Ct! (@)_—- Ag" and Ba®* and NO,‘ v ive Part) Section I , 2. Attempt any EIGHT short questions. (8 x 2 = 16) (i) How the limiting reactant can be identified? (ii) -What is percentage yield? notespk.com (iii) Define stoichiometry and give its assumptions. (iv) What are the uses of chromatography? (v) How the 8, values of components can be determined? (vi) What is the difference between stationary and mobile phase’? (vii) What is Joule Thomson effect? (viii) Write two causes for deviation from ideality. (ix) Throw some light on the factor 1/273 in Charles's Law (x) How the acidic buffer can be prepared? (xi) Define common ion effect. Give an example. (xii) What is the effect of common ion on solubility? 3. Attempt any EIGHT short questions. (8 * 2 = 16) (i) What is London dispersion forces? In which type of molecules these forces are present? (ii) What are the advantages of vacuum distillation? (iii) How the rate of evaporation depends upon the surface area? (iv) Write two properties of ionic solids. (v) Write two properties of neutrons. ; (vi) What are defects of Rutherford Atomic Model? (vii) Calculate the mass of electron by using its value of charge and ¢/m values. (viii) What is the prigin of hydrogen spectrum? (ix) Boiling points of the solvents increase due to the presence of solute. Justify. (x) Define consulate temperature. Give one example. (xi) What is promoter or activator? eo™ (xii) Define catalytic poisoning with example. °° 4, Attempt any SIX short questions. (6*x2=12) OO —————————————_— notespe.com notespk oo cot Versatile Master Key ( 258°) Solved Chemistry 1,, Year (i) Define chemical bond and give cause of chemical combination of elements: notespk co! (ii) What is meant by electron affinity? Give a suitable example. (iii) What do you mean by co-ordinate covalent bond, give example. (iv) Differentiate between bonding and antibonding molecular orbitals. (v) How is aluminium anodized in an electrolytic cell? (vi) What are secondary cells? Write names of any two such cells. (vii) State Ist law of thermodynamics. Also write its equation. (viii) Define enthalpy of combustion with a suitable example. (ix)_ Burning of natural gas is a spontaneous process, justi ao 5. (a) Explain concept of mole in four different ways, with examples for each case. notespk.com (b) Discuss defects of Bohr's atomic model. 6. (a) 250cm" of the sample of hydrogen effuses four times as rapidly as 250cm’ of an unknown gas. Calculate the molar mass of unknown gas. Describe the electrolysis of molten NaCé. Explain the geometry of CH, using hybridization. How do you measure the heat of combustion of a substance by Bomb calorimeter? notespk.com 8. (a) Define liquid crystal. Also give its three applications. (b) Ca(OH), is sparingly soluble compound its solubility product is 6.5x10°*. Calculate the solubility of Ca(OH), 9. (a) Explain graphically elevatidn of boiling point. Also write down its mathematical form. notesnk.com (b) Write down any four characteristics of enzyme catalysis. BAHWALPUR BOARD 2022 PAPER CHEMISTRY PART-I (G - I) Time: 20 Min. (Objective Part) Marks: 17 Note:You have four choice for each objective type question-as A, B, C and D. The choice which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles. Cutting or filling two or more circles will result in zero mark in that question. (i) During the process of Crystallization, the hot saturated solution no . (a) is Cooled very slowly to get large sized crystals (b) is cooled at a moderate rate to get medium sized crystals “ (c) Is Evaporated to get the crystals of the product Notaspk.com see Versatile Master Key (259) Solved Chemistry 1,, Year (a) _ is mixed with an immiscible liquid to get the pure crystals of product (ii) The number of moles of CO, which contains 8.0g of Oxygen (a) 0.25 Vv (b) 0.50 (c) 1.0 (d) 150 (iii) The mass of one mole of electron is: - (a) 1.008 mg (b) 0.55 mg ¥ (c) 0.184mg (d) 167mg Gy) Solvent Extraction is an equilibrium process.and it is controlled by: notesPr- (a) Law of Mass Action (b) Amount of Solvent used (c) Distribution/Law v (d) The amount of Solute (vy) The molecule of CO, in Dry Ice form the : (a) Ionic Crystals (b) Covalent Crystals . (©) Molecular Crystals ¥ (d) Allthese (vi) Equal Masses of Methane and Oxygen are mixed in an empty container at 25°C. The fraction of total pressure exerted by Oxygen is: (a) 13Vv (b) 8/9 (c), 1/9 (d) 16/17 (vii) Which of the following will have the same number of Molecules: (a) 280cm? of CO, and 280cm’ of NO, ¥ A + (b) 11.2dm’* of O, and 32g of O, (©) 44gof CO, and 11.2dm’ of CO (a) 28gof N, and 5.6dm’ of oxygen (viii) When water freezes at ooc , its density decreases due to : (a) Cubic Structure of Ice (b) Empty Spaces present in the structure of ice “ (c) Change of Bond Length “www. notesnk. tom (d) Change of Bond Angles Fyratlonce of Know'ed qe (ix) The number of Bonds in Nitrogen Molecule is : (a) One % andone * (b) One © and two 7 ¥ (c) Three Sigma Only (d) Two © andone * (x) The wave number of the light emitted by a source is 2x 10°m' The Wavelength of this light will be : (a) 500nm¥ (b) 500m (©) 200nm = (d)_ 5x10'm (xi) The nature of the positive rays depends on: of (a) The nature of the electrode vest © (b) The nature of the discharge tube neo el [ratte Master Rey { 280.) Soved Chemisty 3, Yea] (c) The nature of the residual gas V (4) All these (xii) The Paramagnetic Property of ©, is well explained on the basis of . (a) VSEPR’ ¢ (b) VBT (Valence Bond Theoty) (©) MOT (Molecular Orbital Theory) (d) None of these (xiii) The molal boiling point constant is the ratio of the elevation in boiling point to: " (a) Molarity _ (b} Moyality (c) Mole Fraction of Solvent (d), Mole Fraction of Solute (xiv) The rate of Reaction : (a) ‘Increase as reaction proceed (b) Decrease as reaction proceed V * (c) Remain the same'as the reaction proceed . (d) None of these www.notespk.com (xv) Calorie is equivalent to: Excellence of Knowledge | (a) 0.4184) (b) 41.843) (©): 4.18434 (d) 418.4) (xvi) The Cathodic Reaction in the p Bleciealyss of dil. H,S0, with Pt Electrode is; (a) Reduction ¥ ‘ 6) Oxidation (c) Both Oxidation and Reduction cot (d) None of these : ete” (xvii)The pH of 10 dm of an aqueous solution of H,S0, is: (a) 3.0 (b) 27% ° © 20 (d) 15 mn ores (Sub, Section I 2. Attempt any EIGHT short questions. (8 x 2=16) (i) What is the function of Magnetic field in Mass Spectrometer? (ii) Differentiate between Molecular and Empirical Formula. (iii) Define Gram Atom with one example. co™ (iv) Define R,. What are its units ? oreo (v) , State Boyl's Law. Also write its (vi) How Saturated Solution is prepared for mathematical for Crystallization ? _—_— Versatile Master Key Solved Chemistry 1, Year (vii) How is Plasma formed ? (viii) Describe Sublimation Process. (ix) Differentiate between Diffusion and (x) What is meant by lonic Product of Water ? Effusion. (xi) How Acidic Buffer can be prepared ? tespk.com : WWW.NOTE SP cage (xii) Define PA. and PK, ahaa of Kno% 3. Attempt any EIGHT short questions. (8 x 2= 16) (i) Define Isomorphism. Give one example. Gi) One feels sense of cooling under the fan after bath . Give the reason. www.notesnk. com (iit) Whatis Aufbau Principle? _ Excelience of K Toatednas (iv) What are Zeeman Effect and Stark Effect? (v). What is Spin Quantum Number? Give its (vi) What do you mean by Inhibitor? Give an two values example (vii) What are Dipole Induced Dipole Forces? . (viii)Evaluate the mass of Electron. notespk.com (ix) What is Fractional Crystallization? How is it useful? (x) Define Activation Energy and Activated Complex. (xi) Calculate the Mass of Urea in 100 g of H,0 in 0.3 Molal Solution. (xii) How. can the Vacuum Distillation be employed to avoid decomposition of a sensitive liquid? 4. Attempt any SIX short questions. (6x 2=12) (i) Why the Second lonization Energy is greater than First lonization Energy? (ii) Define Octet Rule. Give an example. notespk.com (iii) Why CO, and CS,- have linear structure? (iv) Throw light on the term Bond Order. (v) Define Enthalpy of Formation (aH® Sf ) and give an example. (vi) Define Exothermic Reaction by giving an example. (vii) What do you know about State Function ? ‘ (viii)Calculate the Oxidation Number of Manganese in KMn0, . (ix) What is the funetion of Salt Bridge? 5. (a) Explain Isotope with their relative abundance. (b) Explain Rutherford's Model of Atom. Give its defects, 6 (a) Calculate the mass of tdm’ of NH, gas at 30°C and 1000 mm Hg pressure, considering that NH, is behaving ideally (b). Briefly explain the working of Galvanic Cell. —_—— ee Teer (a) Explain the Geometry of Ethene (CH, =u) using Hybridization : (b) State and explain First Law of Therinodyaninies. 8 (a) How Vapor Pressure is measured by Manometric Method? (b) The Solubility gf POF, at 25°C ig WWW.) ciespl “ceri of POF, FE xcellence at Knowledge Calculate Ksp 9. (a) How will you define Raoult's Law in three different forms with Mathematical Expression? _potespk.co™ (b)_What is Catalysis ? Give its types with examples. BAHWALPUR BOARD 2022 PAPER CHEMISTRY PART-I (G - II) Time: 20 Min. (Objective Part) Marks: 17 Note: You have four choice for each objective type question as A, B, C and D. The choice which you think is correct; fill that circle in front of that question number, Use marker or pen to fill the circles. Cutting or filling two or more circles will result in zero‘mark in that question. (i) If the salt bridge is not used between two half cells, then the voltage: notespk.cO} (a) Decrease rapidly (b) Decrease slowly (c) Does not change (d) Drops to zero¥ (ii) If the rate equation of a reaction 24+8— products is, rate = K[ A] [B] and A is present in large excess, then order of reaction is: notesPk 0! (a) 1¥ (b) 2. (). 3 (d) 15 (iii) The angle between sides 'b' and 'c' is : (2) Beta (b) Alpha (c) Theta (d) Gamma (iv) Isotopes differ in: “ (a) Properties which depend upon mass¥ ee? (b) Arrangement of electrons in orbitals oe (c) Chemical properties * (d) The extent to which they may be affected in electromagnetic field (v) The number of atoms in 1.79g of gold and g of sodium are equal. natesnke cam (a) 0.023% (b) 23 () 230 (4) 2300 (vi) The comparative rates at which the solutes move in paper chromatography depend on: [Versatile Master Key (263) Solved Chemistry Z, Year (a) R, vatues of solutes¥~ (b) The size of paper ay (ec) Temperature of the experiment (d) Size of the chromatographic tank used 0° (vii) Equal masses of methane and oxygen are mixed in an empty container at 28°C. the fraction of total pressure exerted by methane is; 0 69) ores ' 2 1 8 (iy 4% (by) () 9 (d) 9 (viii) The molar volume of CO, is maximum at: (a) 127°C and LatmY — (b)_ 0°C. and 2 atm (c) STP (d) 273°C and 2 atm (ix) Intermolecular forces present in ammonia are (a) Hydrogen bonding (b) fon - dipole forces (c) Dipole - induced dipole forces (4) London - dispersion forces” é (9) Quantum number values'for '3d' orbitals will be: (a) »=3,6=0 (b) »=3/0=1 é (ce) 7=3,0=2v (d) n=3,0=3 e (xi) Orbitals having same energy are called: , (a) Valence orbitals (b) Hybrid orbitals (c) d-orbitals (d) Degenerate orbitalsY (xii) Bond order of helium molecule is : (a) Two (b) One —(@) Zero (a) Three (xiii) Berylium dichloride follows hybridization: @ pw Oe OF "@ (xiv) The Born-Haber cycle is the application of law. (a) Hess's¥ (b) Le-chatlier (c) Coulomb ~ ==). Pascal (xy) The pH of 0.001 moldm®? of an aqueous solution of H,SO, is: (a) 3 (b+) 27% (ce) 20“) :5 (xvi) The pH of human blood is maintained at 3 (a) 7 (b) 7.35% (c) 7.95 (a) 8.00 (xvii) The mola boiling point constant is the ratio of the elevation in boiling point to: com (a) Molarity (b) MolatityY notes? (c) Mole fraction of solvent (d) Mole fraction of solute Section I - Attempt any EIGHT short questions. (8 x 2=16) (i) 180 g of Glucose and 342 g of Sucrose have the same number of Molecules. Justify it (ii) No individual Neon Atom in the sample of the glement has a mass of 20. 18 amu, Give reason, notes (ui) Why is the Actual Yield mostlv less than the Theoretical Yield ? (iv) What is Retardation Factor (&,)? Why it has no unit ? (v) How are undesirable colours removed (m) Pilots feel uncomfortable breathing at higher during crystallization? altitudes, why? (vii) What is Solyent Extraction? notespk.co™ (viii)Define Diffusion, Give example, (ix) What is Critical Temperature (TC)?.Give au example. (x) How is basic Buffer Solution prepared ? Give an example. (xi) What is Common lon Effect ? Give an example pa Define pH and pOH. 3. Attempt any EIGHT short questions. (8 x 2 = 16) (i) How Aquatic Animals owe their lives under blanket of ice in Winter? notespk.com (ii) Justify Earthenware Vessels keep water cool. (iii) Ionic Crystals are highly brittle . Justify it. (iv) Why Electrical Conductivity of metal decreases with rise of temperature ? . (v) . Why it is necessary to decrease pressure in a discharge tube to get Cathode Rays ? , (vi) Give any two properties of Neutron. potespk.com (vii) Define Hund's Rule. with an example. (viii) Differentiate between Zeeman Effect and Stark Effect. (ix) In summer, the antifreeze solution pratect the liquid from boiling over. Give reason. . (x) Why in Hydrates Cation attracts more water molecules than anion? (xi) The radioactive decay is always First Order Reaction. Justify it. (xii) Sum of Co-efficients of Balanced Equation is not necessarily important to give order of reaction. Explain: 4. Attempt any SIX short questions. (6x 2=12) (i) What is Octet Rule? Give two examples in, Sv hista Octet Rule is not obeyed? notesPk (ii) -Size of Anion is larger than its Neutral Atom, why? (iii) What is ionization Energy? Give units. (iv) What is Ammonium lon? How it is formed? (v) What is the difference between Internal Inergy and Enthalpy (vi) What is Hess's Law of Constant Heat Summation?” (vii) Burning of Candle is spontaneous process, why? 60 (viii)Calculate the Oxidation Number of Chromium in &,Cr,0, ‘onduction? Give saspe com 5. (a) What is a Limiting Reactant? How does it control the quantity of product in a chemical reaction? Give two examples. antespk com (b) Explain the Millikan's Oil Drop Experiment to determine the ~ » charge of an Electron. 6 (a) 260cm? of the sample of Hydrogen Effuses four mes as rapidly as 250cm’ of an unknown gas. Calculate the Molar Mass of Unknown Gas. (>) Explain the measurement of Electrode Potential of Zine (Zn) 7. (a) Explain AB, Type with no lone pair of electron and with multiple bond according to VSEPR Theory (b) What do you mean by Enthalpy? Also prove that AM = 4, 8. (a) How Boiling Point and External Pressure are related? Discuss . applications also. notespk cO™ (b) The solubility product of Ag,CrO, is 2.6% 10? at 25% Calculate solubility of the compound 9. (a) What do you mean by Elevation of Boiling Point ” Explain Landsberger's Method for its measurement (b) Discuss Half Life Method and method of large Excess to find order of a reaction. notespk.cam D.G. KHAN BOARD 2022 PAPER CHEMISTRY PART-I (G - |) Time: 20 Min. (Objective Part) Marks: 17 Note:You have four choice for each objective type question as A, B, C and D. The choice which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles. Cutting or filling two or more circles will result in zero mark in that question. (i) * The solvent commonly used in solvent extraction is (a) Methyl alcohol (b) Diethyl ether / (c) Liquid ammonia (d) Hydrochlonic acid (ii) How should the conditions be changed te prevent the volume ST [Versatile Master Key ( 266-) Sowved Chemistry 1, Year of a given gas from expanding when its mass is increased? (a) Temperature is lowered and Pressure is increased ¥ (b) Temperature is increased and pressure is lowered g (c)_ Temperature and pressure both are lowered oo (d) Temperature and pressure both are increased & (iti) The order of the rate of diffusion of gases NH,,S0,,Cl, and CO, is: (a) Ch >S0,>CO,>NH, (by NH, > SO, > Cl, > CO, ¥ (c) NH,>CO,>Cl,>SO, (4) NH, >CO, > SO, >Ch, (iv) In order to raise the boiling point of water upto 110 °C, the external pressure should be oo (a) Between 760 torr and 1200 torr V oon (b) Between 200 torr and 760 torr oot? (c) 765 torr (d) Any value of pressure (vy) Tonic solids are characterized by (a) Low melting points (b) Good conductivity in solid state (c) High vapour pressures(d) Solubility in polar solvents (vi), When 6 d orbital is complete , the entering electron goes into (a) 7£ (b) Is¥ © 7p (d) 7d (vii) Rutherford's model of atom failed because (a) The atom did not have a nucleus and electrons ‘ (b} It did not account for the attraction between protons and neutrons notespk.com (c) It did not account for the stability of the atom (d) There is actually no space between the nucleus and the electrons | notespk.com (viii) Which one has perfectly triangular shape?’ . (a) SnCt, (b) CO, @ SO,v (dd) NA, (ix) Which of the hydrogen halides has the highest percentage of ionic character? (a) HCl (b) HBr (c) HFY (d). HI (x) If an endothermic reaction is allowed to take place very rapidly in the air, the temperature of the surrounding air (a) Remains constant (b) Increases (c) Decreases ¥ (d) Remains unchanged (xi) An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration. What are the main ions in the filtrate? (a) Ag’ and NO, only (b) | Ba®’ and NO; only V —— Solved Chemistry 1 ir (c) Ag’, Ba" and NO, (d) Ba’ ,NO, and C1 (xii) 18 g glucose is dissolved in 90 g of water. The relative lowering of vapour pressure is equal to (a) 1/5 (b) 5.1 (ce) W514 (dy 6 (xiii) 13 Ifa strip of Cu metal is placed in a solution of FeSO, (a) Cu will be deposited (b) Fe is precipitated out (c) Cuand Fe both dissolve — (d) » No reaction takes place / (xiv) In the rate equation of a reaction 2A + B ~ products is , rate = k [A] [B], and A is present in large excess, then order of reaction is: . nme (a) 1v : (by 2 Totespke (c) 3 (d) None of these (xvy The largest number of molecules are present in (a) 3.6g of H,0 v (b) 4.8 g0f C,H,OH (©) 28g0fCo (d) 54gof N,O (xvi) Many elements have fractional atomic masses. This is because (a) The mass of the atom is itself fractional (B) Atomic masses are average masses of isobars (c) Atomic masses are average masses of isotopes (d) Atomic masses are average masses of isotopes Proportional to their relative abundance ¥ (xvii) The comparative rates at which the solutes move in paper chromategraphy , depend on (a) The size of paper (b) Rye values of solutes “ (c) Temperature of the experiment (d) Size of the chromatographic tank used 0t25?' com Section I 2. Attempt any EIGHT short questions. (8 x 2=16) (i) Law of conservation of mass has to obeyed during stoichiometric calculations. Give reason Why elements have fractional atomic masses? (iii) Why we use the term relative atomic mass? _(iv) Why regular air cannot be used by sea divers? (v) Real Gas show non ideal behavior Why? iS (vi) Give any two applications of plasma é (vii) Define Rf value and why it has no unit? ———————— Versatile Master Key (268) Solved Chemistry 1., Year (viii) Differentiate between stationary and mobile phase (ix) Give applications of paper chromatography (x) Draw out and Labelled the Bomb calorimeter (x1) Burning of candle is spontancous process. Justify it (xn) Justify Hess's law with an example. 3. Attempt any EIGHT short questions. (8 «2 = 16) (1) Define hydrogen bondigg www. notespk com (11) Why evaporation causes cooling? Excellence of Knowledge} (in) What is meant by anisotropy? . (vv) Differentiate between Allotropy and Polymorphism <¥) State Hund's rule with example _* (vi) Why e/m value of cathode rays is equal to electron? (vii) Differentiate between fast and slow neutrons ‘ (viii)Positive rays are also called canal rays why? (ix) What are hydrates? Give one example (x) Describe continuous solubiljty curve with graph and example (xi) What is negative catalysis. Give example (xii) Define half life period. What is its importance? 4. Attempt any SIX short questions. (6*%2=12) (i) Differentiate between Vonding' molecular orbital and antibonding molecular orbital (ii) Why do the lone pairs of electrons occupy more ‘space than the bond pairs.? (iii) The dipole moments of CH, and CO, are zero but.that of H,0 is 1.85 D. Why? (iv) The size of anion is larger than its parents neutral atom. Give the reason notespk.co! (v) Define standard enthalpy of neutralization. Give an example (vi) Differentiate between spontaneous and non-spontaneous process (vii) Why is it necessary to mention the physical states of the reactants and products in thermochemical equations? (vill) viii How can copper be purified electrolytically? ’ (ix) Differentiate between electrolytic and voltaic cell. 5. (a) Define the following terms and give two examples of each (i) Gram Formula (ii) Gramion (ii1) Gram atom (iv) Percentage yield (b) Explain Planck's quantum theory of radiations and derive the “relation E = hev notasok.com ———————

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