Material Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Cetus® DE 100
Product Use: Compressor Oil
Product Number(s): 42079
Company Identification
Chevron Marine Products LLC
44 South Broadway
White Plains, NY 10601
United States of America

Transportation Emergency Response

CHEMTREC: CHEMTREC (800) 424-9300 or (703) 527-3887
Health Emergency
ChevronTexaco Emergency Information Center: Emergency Information Centers are located in the USA.
International collect calls accepted. (800) 231-0623 or (510) 231-0623
Product Information
Product Information: 914-285-7300
MSDS Requests: 914-285-7300

SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS

This material contains no ingredients requiring disclosure under the regulatory criteria for this jurisdiction.

SECTION 3 HAZARDS IDENTIFICATION

IMMEDIATE HEALTH EFFECTS

Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Not expected to be
harmful to internal organs if absorbed through the skin. High-Pressure Equipment Information:
Accidental high-velocity injection under the skin of materials of this type may result in serious injury. Seek
medical attention at once should an accident like this occur. The initial wound at the injection site may
not appear to be serious at first; but, if left untreated, could result in disfigurement or amputation of the
affected part.

Ingestion: Not expected to be harmful if swallowed.

Inhalation: Not expected to be harmful if inhaled. Contains a synthetic hydrocarbon oil. May cause
respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at
airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation
may include coughing and difficulty breathing.

SECTION 4 FIRST AID MEASURES

Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and
flush eyes with water.
Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if
contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing
and shoes or thoroughly clean before reuse.
Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get
medical advice.
Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the
air, move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort
occurs.
Note to Physicians: In an accident involving high-pressure equipment, this product may be injected
under the skin. Such an accident may result in a small, sometimes bloodless, puncture wound.
However, because of its driving force, material injected into a fingertip can be deposited into the palm of
the hand. Within 24 hours, there is usually a great deal of swelling, discoloration, and intense throbbing
pain. Immediate treatment at a surgical emergency center is recommended.

SECTION 5 FIRE FIGHTING MEASURES

Leaks/ruptures in high pressure system using materials of this type can create a fire hazard when in the
vicinity of ignition sources (eg. open flame, pilot lights, sparks, or electric arcs).

FIRE CLASSIFICATION:
OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible.

NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0

FLAMMABLE PROPERTIES:
Flashpoint: (Cleveland Open Cup) 200 °C (392 °F) (Min)
Autoignition: 385 °C (725 °F)
Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not
Applicable

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

PROTECTION OF FIRE FIGHTERS:

Fire Fighting Instructions: This material will burn although it is not easily ignited. For fires involving this
material, do not enter any enclosed or confined fire space without proper protective equipment, including
self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic
compounds will be evolved when this material undergoes combustion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.

Spill Management: Stop the source of the release if you can do it without risk. Contain release to
prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible,
observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as
applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove
contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner
consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at
(800) 424-8802 as appropriate or required.

SECTION 7 HANDLING AND STORAGE

Precautionary Measures: DO NOT USE IN HIGH PRESSURE SYSTEMS in the vicinity of flames,
sparks and hot surfaces. Use only in well ventilated areas. Keep container closed.

General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling
this material. To minimize this hazard, bonding and grounding may be necessary but may not, by
themselves, be sufficient. Review all operations which have the potential of generating and accumulating
an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling,
tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations)
and use appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR
1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77,
'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API)
Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray
Currents'.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode
and cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities,
and other substances in the work place when designing engineering controls and selecting personal
protective equipment. If engineering controls or work practices are not adequate to prevent exposure to
harmful levels of this material, the personal protective equipment listed below is recommended. The user
should read and understand all instructions and limitations supplied with the equipment since protection is
usually provided for a limited time or under certain circumstances.

Special note: Do not use in breathing air apparatus or medical equipment.

ENGINEERING CONTROLS:
Use in a well-ventilated area.

PERSONAL PROTECTIVE EQUIPMENT

Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields as a good safety practice.
Skin Protection: No special protective clothing is normally required. Where splashing is possible, select
protective clothing depending on operations conducted, physical requirements and other substances in
the workplace. Suggested materials for protective gloves include: Neoprene, Nitrile Rubber.
Respiratory Protection: No respiratory protection is normally required.
If user operations generate an oil mist, determine if airborne concentrations are below the occupational
exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection
from the measured concentrations of this material. For air-purifying respirators use a particulate
cartridge.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.
Color: Colorless to yellow
Physical State: Liquid
Odor: Faint or Mild
pH: Not Applicable
Vapor Pressure: No data available
Vapor Density (Air = 1): >1
Boiling Point: >300°C (572°F)
Solubility: Negligible
Freezing Point: Not Applicable
Density: 922 kg/m3 - 962 kg/m3 @ 15°C (59°F) (Typical)
Viscosity: 28.8 cSt @ 40°C (104°F) (Min)

SECTION 10 STABILITY AND REACTIVITY

Chemical Stability: This material is considered stable under normal ambient and anticipated storage
and handling conditions of temperature and pressure.
Incompatibility With Other Materials: May react with strong acids or strong oxidizing agents, such as
chlorates, nitrates, peroxides, etc.
Hazardous Decomposition Products: None known (None expected)
Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

IMMEDIATE HEALTH EFFECTS

Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product
components.
Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product
components.
Skin Sensitization: No product toxicology data available.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar
materials or product components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or
product components.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar
materials or product components.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
The toxicity of this material to aquatic organisms has not been evaluated. Consequently, this material
should be kept out of sewage and drainage systems and all bodies of water.

ENVIRONMENTAL FATE
This material is not expected to be readily biodegradable.

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. Oil collection services are available for used
oil recycling or disposal. Place contaminated materials in containers and dispose of in a manner
consistent with applicable regulations. Contact your sales representative or local environmental or health
authorities for approved disposal or recycling methods.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate
Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-
specific or quantity-specific shipping requirements.

DOT Shipping Description: PETROLEUM OIL, N.E.C.; NOT REGULATED AS A HAZARDOUS

MATERIAL FOR TRANSPORTATION UNDER 49 CFR
Additional Information:NOT HAZARDOUS BY U.S. DOT. ADR/RID HAZARD CLASS NOT
APPLICABLE.

IMO/IMDG Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR

TRANSPORTATION UNDER THE IMDG CODE

ICAO/IATA Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR

TRANSPORTATION UNDER ICAO

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: NO

2. Delayed (Chronic) Health Effects: NO
3. Fire Hazard: NO
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:

01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

No components of this material were found on the regulatory lists above.

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), EINECS (European Union), ENCS (Japan), IECSC (China), KECI (Korea), PICCS
(Philippines), TSCA (United States).

NEW JERSEY RTK CLASSIFICATION:

Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to
be identified as follows: (Lubricating oil)

WHMIS CLASSIFICATION:
This product is not considered a controlled product according to the criteria of the Canadian Controlled
Products Regulations.

SECTION 16 OTHER INFORMATION

NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0

HMIS RATINGS: Health: 1 Flammability: 1 Reactivity: 0

(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or
published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint
and Coating Association (for HMIS ratings).

LABEL RECOMMENDATION:
Label Category : INDUSTRIAL OIL 1

REVISION STATEMENT: This revision updates the following sections of this Material Safety Data Sheet:
1,2,5,9,14,16
Revision Date: 01/17/2006

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:

TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
CAS - Chemical Abstract Service Number
ACGIH - American Conference of Government IMO/IMDG - International Maritime Dangerous Goods
Industrial Hygienists Code
API - American Petroleum Institute MSDS - Material Safety Data Sheet
CVX - ChevronTexaco NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on OSHA - Occupational Safety and Health Administration
Cancer

Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI
MSDS Standard (Z400.1) by the ChevronTexaco Energy Research & Technology Company, 100
Chevron Way, Richmond, California 94802.

The above information is based on the data of which we are aware and is believed to be correct
as of the date hereof. Since this information may be applied under conditions beyond our control
and with which we may be unfamiliar and since data made available subsequent to the date
hereof may suggest modifications of the information, we do not assume any responsibility for the
results of its use. This information is furnished upon condition that the person receiving it shall
make his own determination of the suitability of the material for his particular purpose.