CHEMISTRY laevorotation, this

the mixture show

hydrolysis
1. Sucrose is dextrorotatory but after fructose.
because of dextrorotation of
morethan
(A) Laevorotation of glucose is
(B) Sucrose is a non-reducing sugar.
(C) Recemic mixture is formed. dextrorotation ofglucose.
than
P) Laevorotation of fructose is more
is :
column Xand column Y
2. The correct order of match between
X Y

I Vitamin A i. Muscular weakness

II. Vitamin D ii. Increased blood clotting time
III. Vitamin E iii. Night-blindness
IV. Vitamin K iv. Osteomalacia
(A) I-iv, II iii, III ii, IV i
(B) Iii, II i, III iii, IV -iv
(C) I-ii, II ii, III iv, IV -i
D I-iii, II iv, III - i, IV - ii

3. In the reaction :

NH; P N;CI N,BF4 R NO2

P, Qand R respectively are:
AA NaNO, +dil. HCI, HBE, Cu +NaNO,
(B) NaN0, + con.HCI, F,. Cu + NaNO,
(C) NaN0, +dil.HC1, BF,, Cu + NaNO,
(D) NaNO, +dil. HCl, F,, Cu +NaNO,

Thyroxine produced in the thyroid gland is an iodinated

(4) threonine (B) lysine derivative of
ertyrosine (D) tryptophan
 S.
Which one of the following is a non-narcotic analgesic ?
(A) Heroin (B) Codeine Ae) Aspirin (D) Morphine

6.
Keceptors are proteins and crucial to body communication process. These receptors
embedded in
A Cell membrane (B) Protein (C) Endocrine gland (D) Chromosome
7. Which of the following monomers form biodegradable polymers?
(A) Ethylene glycol and pthalic acid
(B) Caprolactum and 1, 3 - Butadiene
(C) Phenol and formaldehyde
AD) 3-hydroxybutanoic acid and 3-hydroxypentanoic acid

8. Match the List-Iwith List-1l in the following:

List-I List-II
1. Caprolactum (a) fCH, -CH),
CH,
2. Vinyl chloride (b) fCH,-CH,
CHs
3. Styrene (c)
{CH,-CH,
CI

4. Propene (d)

(A) 1-c, 2-d,3-a, 4-5 (B) 1-a, 2-d, 3-c, 4-b

(C) 1-d. 2-c. 3-a, 4-b ) 1-d, 2-c, 3-b, 4-a
 9. The correct order of first ionisation enthalpy of given elements is
SLi< B Be <C (B) Be<Li<B<C (C) C<B< Be <Li (D) Li < Be <Re.

10. Which of the following statement is INCORRECT?

(A) Bond length ofO, >Bond length of O; SB) Bond order of O, < Bond order of o.
(C) Bond length of O, <Bond length of 0, (D) Bond order of O, > Bond order of 0

11. Agas at a pressure of 2 atm is heated from 25 °C to 323 °C

and simultaneously
to
,rd
of itsoriginal value. Then the final pressure is compressed
A 1.33 atm (B) 6 atm (C) 2 atm (D) 4 atm
12. Lattice enthalpy for NaCl is + 788 kJ mol and AH°
Hyd
=-784 kJ mol-. Enthalpy of solution
of NaCl is
(A) + 572 kJ mol-l (B 4 kJ mol (C) -572 kJ mol-! (D) 4 kJ mol-!
13. At 500 K, for a reversible reaction + B2e) 2ABg) in a closed
Kr =2x 10. In the presence of catalyst, the equilibrium container,
is attaining 10 times faster.
equilibrium constant Kç in the presence of catalyst at the The
(A) 2x104
same temperature is
(B) 2 x 106
(C) 2 x10-10 4) 2x 10-5
14. Aweak acid with pk, 5.9
and weak base with pK, 5.8 are
of the resulting solution is mixed in equal proportions. pH
A1.005 (B) 7.5
(D) 7.05
15. Temperature of 25 °C in
A 77°F and 298.15K Fahrenheit and Kelvin scale respectively are
(C) 45 °Fand (B) 17 °F and 298.15 K
260.15 K (D) 47 °F and 312.15 K
16. The
number of protons, neutrons and electrons in the ion 322
6S respectively are
(A) 16, 18, 16
BY16, I6, 18 (C) 18, 16, 16 (D) 16, 16, 16
Space For Rough Work
 17. Apair of amphoteric oxides is
(A) Al,0, Li,0 (B) BeO, BO, () BeO, Mg0
(D) BeO, Zn0
18. The composition of water gas is
(A) CO) t N,o (B) CHA (C) COp +H,Opy )
19. JUPAC name of the compound is
COey t H,

A) 2, 3-
dimethylbut-2-ene
(C) 1, 1,2, 2 - tetra (B) 2, 3 -dimethyl
methylethene (D) 2, 3 - dimethyl butyne
20.
Among the following : butene

II
IV
The set which
(A) I, Iland IIIrepresents aromatic species is
(B) III, IVand V
(C) II and III
21. Which one of AÐ) I, Il and IV
the following gases converts
(AF CO
(B) O, haemoglobin into carboxy haemoglobin ?
(C) NO
22. What is the (D) CO,
oxidation number of Sin
(A) +5
(B) +4 H,S,0?
(C) +7
23. A30%
(A) '30 solution of hydrogen peroxide is
(C) '50 volume' hydrogen peroxide
volume' hydrogen (B) 10 volume'
peroxide B)'100 volume hydrogen peroxide
hydrogen peroxide
Space For Rough Work
 The ratio of radii in simple
Z4. | 'a' atanda lor the cdye length of the cubic syslem
body centered cubie andface centered cubic unit cells is cubic,
(A) la Via y2a (B) ;44 22 a

2
V2

25. Dimerisation of solute molecules in low dielectric constant solvent is due to :

A Hydrogen bond (B) Covalent bond
(C) Co-ordinate bond (D) lonic bond
26.
The swelling in feet and ankles of an aged person due to sitting continuously for long
during travel, is reduced bysoaking the feet in warm salt water. This is hours
(A) Reverse Osmosis B because of :
Osmosis (C) Edema (D) Diffusion
27. A sample of water is found to contain 5.85% of AB (molecular mass 58.5) and
9.50% XY, (molecular mass 95). Assuming 80%
of XY,. the freezing point of ionisation of AB and 60% ionisation
water sample is [Given : K, for
Freezing point of pure water is 273K and water 1.86 K kg mol-!,
A, B and Y are
(A) 264.25 K By 265.56 K monovalent ions)
(C) 280.44 K
(D) 281.75 K
28.
Match the column A(type of
crystalline solid)with the column B
P
A
B (example for each type):
Molecular Solid SiC
lonic Solid
R. Mg
Metallic Solid iii.
S. H,0
Network Solid iv. My0
(A) P-iii, 0-i, R-ii, S-iv
(CO) Pii, Q-iv, R-ii, S-i (B) P-iv, Q-iii, R-ii,
S-i
29,
A metal
DP-ii, Q-iv, R-ii, S-i
crystallises in a body
volume of the unitcell in m' is centered cubic lattice with the
(A) 64y J0 29 (B) 4 10 29 metallic radius y3 A. The
G6.4 10-29
Space For Rough Work (D) 4x 10-10
 0. 1 M weak
acid IHA nductivity cell is 2x 10 Ohm. The cell
in a conductivity
resistance of
30. The
cell is 0.78 C m and m of acid HA 0s 390 Scm² mol. The pH of the
COnstant of the
solution is
AY33
(B) 4.2 (C) 5 (D) 3

mol L-!-9
1 In which one of thefollowing reactions, rate constant has the unit
CH,COOCH,
A Acid catalyscd hydrolysis of
(B) CHCI, Cl, CCI, + HCI ( mot it

2NO2)
D) Decomposition of HIon the surface of Gold

12 For a reaction, the value of rate constant at 300 K is 6.0 x 10 s-,

The value of Arrhenius
factor Aat infinitely high temperature is :
(A) 6x 105 xe-Ea3 00R (B) e Ea/300R
6 10-5 Ae
300 tb) 6 x 105

33. The rate constants k, and k, for two toe

1 0 e1000T different reactions are 10l6 x e-2000/T and
2000
respectively. The temperature at which k, = k, is :
K
2303 (B) 2000 K x 1000
(C) 2.303 K
(D) 1000 K
34. During the
clectrolysis
(A) 0. liberates of brine, by using
at anode inert electrodes,
(C) Na deposits on (B) H, liberates at anode
cathode P) CI, liberates at anode
35.
Consider the following 4
A: Ag' electrodes
(0.0001 My/Ag,.:
C. Ag (0.01 B: Ag' (0.1 M)/
A8s)
Then reduction MyAE D:Ag' (0.001 M) / ABsyi
(A)
B>C> D> A potential in volts of
the electrodes in the EAg'/Ag = +0.80 V
yA DC>B order
(B) C > D> A> B
(D) A>B>C>D
Space For Ro
 36. gives a sol X When FeCI is added to
When FeCl, is added to excess of hot water
NaOH,0) Solution, gives sol Y.
X and Y formed in the above processes respectively are
A) Fe,0, xH,0/ OH and Fe,0, xH,O/Fe"
(B) Fe,0, xH,0/H' and Fe,O, xH,O/Na
(C) Fe,0, xH,0/CI and Fe,O, xH,O/OH
(D) Fe,0, xH,0/ Fe and Fe,O, xH,0/0H

37. The reducing agent in the given cquations :

4 Ag,,+8 +2H,O(aq)
+8 CN0)t O:,0 ’ 4|Ag(CN),Jag) t 4OHag)
2|Ag(CN),Jaa) t Zn,(Zn(CN)J) 2Ago)
AS Zn (B) O, (C) H,O (D) CN

38. For the formation of which compound in Ellingham diagram AG° becomes
negative with increase in temperature ?
more and more
(B) FeO (C) ZnO (D) Cu,0
39. Which of the following compound does not give dinitrogen on
(A) Ba(N,), heating ?
(B) NH,NO, erNH,NO, (D) (NH), Cr,0,
40.
Aqueous solution of raw sugar when passed over beds of
colourless. Pick the correct set of terminologies that can be animal charcoal, it becomes
used for the above example.
Adsorbent Adsorbate
(A) Solution of Sugar Process
(B) Animal Charcoal Animal Charcoal Sorption
ej Animal Charcoal Solution of Sugar Absorption
(D) Colouring Substance Colouring substance Adsorption
Animal Charcoal
41.
Adsorption
For Freundlich
Theslope of lineadsorption isotherm, a graph of log (x/m) Vs. log (P) gives a straight line.
and its Y-axis
(A) log K intercept respectively are
n log K (C) log log K (D); n

Space For
42. In solid
state, PCL, is a/an
(A) Octahedralstructure
(B) lonicsolid with (PCI1 and [PCI,)
es lonic solid with |PCI]' and [PCI,]
(D) Covalent solid present in the form of P,Clo
does not have (n-1)d ns?
*3. In which one of the following pairs, both the elements
configuration in its elementary state? ey Hg, Cn (D) Cu, Zn
(A) Zn, Cd (B) Cd, Hg

transition element ?
44. Which of the following is CORRECT with respect to melting point of a
AA) V> Cr (B) Cr > Mn (C) Mn> Fe (D) Ti > V

45. aMnO, +bS,0; +H,0’ xMnO, +ySo, + zOH

a and y respectively are
(A) 8;3 BY8; 6 (C) 3; 6 (D) 8; 8

46. Which formula and name combination is INCORRECT ?

(A) K,[AI(C,0,),]- Potassium trioxalatoaluminate(D)
(B) (P(NH,), CI(NO,)] - Diamminechloridonitrito - N- platinum (1l)
t [CoCl,(en),JC1 - Dichloridodiethylenediammine cobalt (Il) chloride
(D) (Co(NH,), (H,0)CiHCI, - Tetraammineaquachloridocobalt (II) chloride

Which of the following system in an octahedral complex has maximum unpaired electrons ?
(A) d' (high spin) (B) d°(low spin) (C) d (low spin) ) d (high spin)
48. Thecorrect decreasing order of basicity of hydrides of Group-15 elements is
AA) SbH,> AsH, > PH, >NH, (B) PH, > AsH, > SbH,> NH,
(C) AsH, > SbH, > NH, > PH, P) NH,> PH,>AsH, >SbH,

0 Which one of the following oxoacids ofphosphorus can reduce AgNO, to metallic silver 9
(A) H,P0, (B) HP,0, (C) HP,0% ) H,PO,
 are
50. Apair of compounds havingthesame boiling points
(A) cis but-2-ene and trans but-2-ene
(B) n-hexane and neo-hexane
(C) benzene and naphthalene
P) ()butan 2- ol and (-) butan 2-0l

51. Identify A, B and C in the sequence :

KCN LIAIH, B
HNO;
CH,CH,Br alc 0°C
CH,CH,CH,OH
A CH,CH,CN, CH,CH,CH,NH,
CH,CH,CH,NH,
(B) CH,CH.NC, CH,CH.OH,
(C) CH,CH,CN,C,H,OH, C,H,,CI
(D) CH,CH,CN, CH,CH,NH,, C,H,OH
PCC
CH, - CH= CH- CHO
52. CH, - CH =CH - CH,0OH
the above reaction
Hybridisation change involved at C-1 in (D) sp to sp
(C) sp² to sp
(A) sp' to sp Bf sp to sp²
2 - diamine is progressively added in the molar ratio
If a didentate ligand ethane -1, are
aq solution, following co-ordination entities
53.
en : Ni :: 1:1, 2:1, 3 : 1to [Ni(H,0),}
formed.
1. [NiH,0),en] (aq) pale blue VTeGYoR

I1. [Ni(H,0);(en),]*(aq) -blue/purple

Violet
III. [Ni(en),] (aq) -
light absorbed in case of I and III are respectively
The wavelength in nm of
(B) 300 nm and 475 nm
A)475 nm and 310 nm
Dt 600 nm and 535 nm
(C) 310 nm and 500 nm

an organometallic compound ?
Which ofthe following isHfCH,CH,
54. MgBr
(A)CH,COONa (O(CH,COO,Ca
For Rough W,
(D) CH,0Na
55. Abetter aldehyde is:
reagent to oxidize primary alcohols into
(B) Alkaline KMnO4
AS PCC
(C) Acidified K,Cr.0, (D) CrO,

56. In the reaction :

() SnCl, + HCI con.KOH
C,H,CN. ’X
Y+Z.
(i1) H,0*
Formation of X, formation off Y and Z are known by
(A) Rosenmund reduction, Cannizaro reaction. CHta-CH= CH,
reaction.
(B) Clemmensen reduction, Sandmeyer
(C) Wolff-Kishner reduction, Wurtz reaction.
B) Stephen reaction,Cannizaro reaction.
reaction are
57. Compounds P and R in the following
’R
CH,CHO
() CH, MgBr conc.H,SO, o
() H,0*
heat (1)B,H,
(ü)H,0,0H
(B) Functional isomers
(AT Position isomers (D) Identical
(C) Metamers

58. Aniline does not undergo

(B) Sulphonation
(A) Nitration (D) Bromination
(G Friedel-Craft reaction

heating of phenyl methyl ether with HI produces an aromatic compound A which on

59. The respectively are.
treatment with con. HNO, gives B. A and B
acid (B) Picric acid, Phenol
(A) Methanol, Ethanoic
lodobenzene, 1-lodo-4-nitrobenzene
(C)
DPhenol, Picric acid

OH
NaOH
’ A
) CO;, 0CHY(Major product)
(i) H B
(ii)
60. (ii) H

is
Y inthe above reaction (C) Cumene
(A) SalicylaldehydeB) Aspirin (D) Picricacid
ce For Rough Work