JEE MAIN

FULL TEST SOLUTIONS

STANDARD ANSWER KEY
o<o<<a A
1 2 3 4 5 6 7 8 9 10 14 12 13
3 4 14 15
1 2 3 1 4 4 2 3 3 1
16 17 3
18 19 20 21 22 23 24 25 26 27 28
A 4 2 29 30
3 2 3 7 2 6 9 5 3 5 5
31 32 3 5
33 34 35 36 37 38 39 40 41 42 43 44
1 4 45
2 4 2 2 1 1 4 4 1 1 2
46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A 1 3 2 3 1 7 2 6 2 6 7 30 9 3 2
Q 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
A 3 1 1 3 4 4
2 3 1 1 3 3
Q 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A 1 2 2 2 2 2 4 5 5 3 3 4 1
 Hg(0Ac)yH,0 -H
+
HO
was |2.
NaBH4/OH CH;
structure. hybridisation
vessel
-3H,
(X)
Major
closed OH CH; giant HCI
d
c, +Clh(g)
0
c b,
No
b, + (c)
CIO
0CI
tetrahedral
a, a,
|L
Ph Ph H,PO, compound
(2)(4)in Planar
but
Non-polar
PCl;(g)PCl,(g)
H0 Cr;0,/V,Os
kept climination
EtOEOH
X
K (E3 linear. ’
PCI, -H,
600°C
- HOH
(B) lonic mol 3-x
(A) sp sp
of CH;CHH
- - +
CO,SiO, PCL,
AIF;- 3
mol CI
HO H CIZ
=0
Att equil.
at
(4). (4).
00 (10)
(2). (3). (3).(a) (d) (1).
% Ph CH3 CH,
Q.13 (8) (9) (11) (12) (13)
Me Me chain
amylopectin. 2
Achiral
mixture =50
year
Et branchedincorrcct. B.M. Dispersed
Dispersion ug/year
starch. B.M. Medium Liquid
Me Me Intraolecular and
H AlCIa ICratt Solid Malachite:
Cu(OH),.CuCO 2x0.05
Gas Kaolinite
:AL(OH),Si,o, Hg/year
Alkylation a-amylose [V(H,0)JC,; 3.89
only ’
[Co(H,0)|Cl, 3.89
fidel
Cr
animal is only =0.05
reaction
(1) =
spin = Sug
1S 1111
statement
moment spin
moment Liquid
Phase SolidFeCO Calamine:
Liquid ZnCO,
(K)order
Gives
CO2 an Amylopectin 3d e, 3d?
is of e,
polysaccharide
consists unpaired constant
A
Glycogen Magnctic unpaired
Magnetic Zero
’ [Ar]1s [Ar]1s : Siderite
ACOOH H3C:
Hence
V2t Co2+ Milk Smoke
Cheese K
mcansIW2
lt Rate =
(3). Me B-keto
acid 3 3
(4). (1). (2). (4).
Me (3). (1).
(1) Et, (2) (3) (4) (5) (6) (7)
 (d+)
cquil1brium 300)
-/RxT,_Rx R
addition
in t6)
Chalcocite,
(D.U.
=S)
(240
-300) 2100 carbon in
V) Mo
I H,T K - X=7.
.:. syn
K Propane-1,2,3-tricarbonitrile.
300
xx0.0821 (V,- 240 = crowded and
380 (-1500R) through Calamine,
Barytes.
’ = (i) (i)
H,02/OH
BH3/THF -3
at calculate 1.2 Fluorspar,
equilibrium
HNO, Pext.
g/mol (2%) T, 1.2 5T) T, SR 2 in
(N
300 100- .. placeless
3
=- x
10 2100R
R x
Cm dil. w -T) (T,-300)
Cy
= 6 =
=-1500
product. ,O40
at the
major NazCrO4
HzS04
11x
0.9 10
13/6 10 v.
13.6x
76
M AU= = takesgoes
then -CN
CH, CH-CN RT CRT
=
hdg x t I500 =1600 AT 5
= R= (NH);AsMo,
=9.
(3). -CN
CH, nCy AU
attain
=Cx 11x
0.9 25.2Mg (T,
q=0’ boron(23)
Reaction 6.Magnesite,
Argentite,
-3
hHg nCy -ST, =y 300
to1.80 |
= Mn 20T, AU= 12 OH
M 3 AH Xx and
T So,
(2). (3).
7. 9.
K (22)
2. (25)
5.
(18) (19) (20) (21)
(24)
=24.84
4.98
-1.8 3
> factor})
LE.
Rbt electrons
xt
96500
2
4x|x(-5.4) M 4
96.5
xxt C < > NH2 valency seconds.
-1.8+24.84L.59
... 4x2=
-bt/D power
= clectrolysed
mnolar 2p > of
[CI,]
2x1 -0.10) B Lit exchange
=
396500
x reducing =2 x105
1.59
=M 0.025 2s2 Order
2p! Li<B<
Be<C ’ 96500
[PCl,]|Cl,1 (1.8) 1 H.R. 0 NaOH/Brn 0 Ixt
[PCl;) x² =0 M, (0.20 x/xt52 Be size > 1.93
5.4 = 1.59Crt+t 0.10
= « dataPo
formnmediumlonic
mobility molecule
=
3-x - =b-4ac 159
XXX x 10-3 = Li >
per Te
H W E 2
=
1.8 1.8x 9650052 gaseous çO-NH, x
2a = = of x x
H;'o?1 f=
xmole t=96500
- 3.18 [PCI] =0.250
Molar250 E x t=75
s 2s! as Se>
’
1.80 5.4 x+ 0.025 (3).
2 IE,
= In
aq. {from
K D = CstEAS>
X = in
(4). (16) (2).
(4).
(14) (15) (17)
 x1.6
was
10x(0.1+0.9)
10-3
vessel R=100 R-29
3enr -In
(5)
closcd 10s
= (5)
=
In
at
lL cauilibrium
B²2
5000 R-0.12
-ett)
(l'o Pdrds?
s0.016 resistance
102
in 2m oscillation
of
No, 20 7
W
i=i,(1-e) Req ofwire)
kept R
V10
2n/ F0.992 1-et
=
0.8 1/5 L = m
(new =
Ao 104 9x16 = t=tIn10-2
(5)
= R,
PCI,attain 2m M36 L=10mH 0.2 p? AD
b 7 x 1252 22,
of For
A t=y= = 1.6 p2
Rc
to
molallowed
To 80 100et t= R=
(2).
(36) R= = R,
< (4).
(34) 1
Q.133.00 (35)
(2).
4
3.
(monobasic) H=CE?
+H..
be
will CaHPO, 2
1000200 ’AIPO4
|A] 75.45 figuresK.E.
/2M Na NaH,PO, cm
3 O-S-S-S-S-0 60
dil
NaO1} h 20 V4
Averagc
titre
valuc
25.0 significant
MNeNe
= E-(CE'-o)
(CE)
> Ry. =
15
mL MHeTHe ’ Ca(OH),
H,PO,
+
Al(OH), V10
H

+
25.25 =25.2 mV «
h
T)
VMT
For
twO
gases,
NaOH
(monobasic) H
AU+
(0.5-D
R
x
4
f= 2
3 h= K.E.1
of Since, e-t/y
+ Number + + (dibasic)
HC
H
CH.
25.2 25.15 (Since +5
H,PO, H,PO,
(tribasic) 1/21/8 2r
m
=Age
A
He = =
Na" Whh T,
3.
=
(27)
5. (1).
(49.
(2) f 15 (2).
5.
3.
5.
(26) (28) (29) (30) (31) (33)
 was
vessel V fm =f-fm =173.29
100 1100 4 + k'r'dt variable
as
c,dclosed (Vo= 400 f
= Hz ù=0
neglected (UBF)
(LBF)
(2)a,
b,
c b, 400V (Vo
(Vmdo = is to
a, lL Hz,
10 Q
200
= X (dv acceleration =f,- perpendicular
(4)in =0.25 x
frequency
=2 a,
be Fox = frequency Q
=100 XË
kept can
10* (V,),
=0.55
H
= »
(d'+x',3/2 = GHz,Modulation
Index 2f 1000.5 + dt dt P
v0;
PCI, -2KQqx
-2KQqxMHz
d,x' (40)
(4).
m=p4rr'dr Z=JR²+X
V=1Z’Z= =00)² As, K²r centripetal
band =
bandLBF 100 v2
« t° always
of 100f=300 m vocV4nK
=4TKR J4rK
X
=
01 K²r. - c
<< 2T 173.2
Za,
c,d mol -
UpperLower
UBF R V
100 dv
200
3
a. a, =f,
So, as so
x = 0 (41)
(1).
R= So L= = is
for F=
Q.13300 f. T R a, | P, f,
(4). (4).
(39) (42)
5
3egAKg (1) K,K,)
...
(2)
d
". £oK3A
3d +
K,K, (a?+x',32
dil
NaOlH W3 d/3 K,K;) =
C3
/3
+
9K,K,K3 X 2KQx
2KQ
3egAK,K,K3 -(K,+
K,+K;) (K;K3 r
+
K,Kg
E
d 3d
Ky) cos
= E=
+ +C
2 10
+2
T0x (K,K, + 2KQx
+C; Kz 2KQ
El_2 +
Reu d 3d =C 3d 2
(K} di
di
E Q F=
1.
(37)
(1).
C= Tcq Ceg E
C (38)
(1).
 -b
emfof on towards
point (Vo
>Vp)
=12:>2of that =2 V4R'-v'?
V- B h
cellthan (2) <x<l) theorem)
2
E, therefore
the shift volt
length
null =(-5)
E, for should =6
0 2T
transfer
potentiometer.
point (for 25-16x4 +
>E,. shortestthe V,m Vm-V,, Po
E, 1);:
power=
wire (80)
E,
null cell
Ej.
Thus, +
mË
m, 200
+
80 =
E,
> R
P, dgh values
Substituting
+ x }| V4x : +
thattheat potentiometer (2) ms-
= =-7 (for V4mEo OV
be
of givenTherefore,
’
Vm=-5
m/s Vmy 2E, /2mE B)- R [=
VB
(PQ) 2T =P,
=2(max.
(200) 2Eg =|(Tx 0.25
case must left
ofC. h h P
-
=
Vcm Now, =
K.E. = KE=
R
=4x
62 =P P,Also,
In As E, [ VB
(1). R, P,
=
7. 2. (53)
6. 2.(54) 6.
(50) (51) (52)
(55)
-P,v-vË)
scparately,
eV
0.49
=
of
photoelectrons isochoric
m[-5i-i) WpA
theorem) m/s² eV
=2.49 1200]
and -[M°L?TO)
=
MLT- Hz metal=2eV WRCt0+
move m) isobaric
=0.5 1014 Dare Tp) 600-
Bernoulli'swill (v-v)= by
received Wcp0 (T -Tp] -
P, ’a m, +j-(3i+2j) x m/s C’
=6 volt10-34 are +
difference block by Impulse
received
by ML-IT-2 the energy 10 W=0+
uR 800 kJ
a
30 m received =P ML2T
ke ML2T-2 lightelectron
x 10-19
x1.6 = and DA T =40
6.63 of kinetic t
1SN =
to M=-(impulse 30° -
(According = Ap
both15
=m[Si+
j) L of function B 0and and Tg) + [2200800
Pressure = m[-2i
therefore and >x
Frequency cos m/s ’ T
BCwork(Tc-
Impulse
Impulse in 10' -
Since l Energy ..Maximum V, 20 A uR[Tc
25 x
= AB Process 25
V, Process
30
kg total
B=P 6x Work Given= 3
B = ke = W
So uR =6Xx
(4). (44)
(1). (2). So = = =2
(46)
(1). (3). (48)
(2). (3).
(43)
(45)
(47)
(49)
 is gR²)
surtace second
R = is
= GM hyperbola 12
h =| b²-
carths height
Change
in
PE
(":: per 4N2
unit 2t 7 4,
X-MXIS
’a²=
at
energy energy
at GMm
gR´m
mgR
2
-102 -10
25 2/5 dx
Jp
(2+t) - of
V2 equation
-2
=0
dy dt rate al
to
(4,6) -y
hR potential potential equal 2x
tangent
GMm GMm As Suppose ’²=3a2
e=2
=U-U,2R
W
work
done at Shortest
distance
2R -10
dx 5 deceases dy through
passing
R
MR = (9/4,
P
1/2) of
Initial Final 2R x
at .2y y X-=1
Equation
U, U,
ay dt Ordinate
o0,0) dx ’t=
1/2 us
dy dt Let x 2 2
(60)
2. (3). (62)
(1). (1).
’
(61)
(63)
10(|
x10')xl0 6 30.fromof conductivity
respectively 7
first 40-10=
the
flowmasses
t.
time 0°C
energy
=-my'
401 heatthein
rotations= tmLsteam
- kinetic
40.75 9 in
melted cross-section t=
thermal mLice =7
10
rotations of be (1-x) 10'-3J
40 amounts
m 800°C
4 m in
cm x
resolution
x6
0;taor = of Let ice the
change
=(1/9) 100)
6
m= 1.22
rad
10-7
2r
10=a(3)
x N
407
(6)7a
9 numbert. and
Q, be
800-0))700
1-x
800-
2
my².
(20x
time of =
x required
4T rdg
10-
of 1.22A x en =
make
Seconds.
36 N227 and
Required
any
formed A area
and of
or
Q, Dividing, Final
kA|
= KE
=0 2
KE x
=
=kA/
Initial
|A
KE|=3J
h=. =6xLimit =3.66=2 it 2TN: the
the
rod. |-x=8x =x100
Q steam 100°C
k
Let Let in Let and , Work
30. P 3
7. Or
Or 9.
(S6) .
or 3.
(57) (58)
(59)
 1Ons o1 |C, & .
rocnnni .als

(64) (3). Let f () is

periodic with
then cos (x +T)- = cos x period cqual to T
xe R n!
(x +T)°-x?)
2|sin (x+T) +x?) =0
(r-1)!(n-r+1)!
n
2
r!(n-)!
(x t T)-x=n xE R 2
or (x + T)² + x n+ X E R n-r+] 15
which is
false because these 15r =2n -2r2
quadratic equation are 17r =2n+ 2
f(x) is notequation
but not identity
(65) (4). Vectors AB,periodic. 15
AC. AD = Coplanar 70
[AB AC AD] = 0
-3 r!(n-)! 3
-2 -1 -3 =0
n
14
-1 -1 -1-À (r+l)! (n -r-1)!
I+1 3
-3
n-r 14
-2 -1 -3 =0 14r + 14= 3n -3r
-4-2 3n -17r= 14
’ (-4-2) (-1 + 2) =0 2n - 17r=-2
(66) (2). y = x+ ax - b »=-4
n= 16
(1,-5) lies on the curve 17r =34., r=2
-5 =1 +
Also,
ab’a-b=
y' =3x + a
-6
. (i)
16C, 16C,
y' (1,-5) =3 + a (slope of 1Ûc, -°C, +°C; 16+120- 560
This tangent is l to tangent)
(3 + a) (1) =-1 -x+y+4=0 680+16 696
a =4 3
-= 232
3
...(ii)
By (i) and (ii) : a =4, b=2 (69) (3). P ’(-~pvr)
y=x³-4x - 2. -Pv(qvr)
(2,-2) lies on this curve. -p’F| p’I
(67) (4). lim 1+f(3 +x)-f (3) ) -q’Fq
I’F I’F
(1* form)
x0\1+f(2-x)-f (2) (70) (2). det (A-)=0
f (3+x)-f (2-x)-f (3}+f (2)
lim 3-2 0 3
x (l+f (2-x)-f (2))
0 3-2. 0 =0
Using L'Hopital 3
f (3+x)+f" (2-x) 3-.
lim
eX0f(2-x)+(1+f (2-x-f2)) (3-.)³-9(3-) =0
f(3)+f(2) (3-2) [(3- -3=0
1 =1 3- =0 or 3-)-3 =0 or 3--3=0
’ À=0. 3 or 6
(68) (4). nCl 2
15
 /2
(71) (3). I= sin' x X
Sin x t COS X
-dx (75) (3). dx + ex/y dx + exy dy - xy dy =0
xdy)
dx + eN'y dy + ex'y (ydx -
T/4
Sin" x + cos X
dx
Sin x t cos X
T/4
0
’ dx + exy dy + yd (e'y) = 0
’ dx + d (yexy) =0
= | (|- sin x cos x) dx ’ xt yeX/y =c
a. +1
Tt/4 (76) (1). Let
sin x T-1 a-1

2 4 4 4 |a+i| =|z| 1=|z|

a-il|
(72) (1). Ef= 20 =2x2 +2x -4 Circle of radius 1.
’ x'+ 2x -24 =0 (77) (2). 'C4 x (De-arrangement of 3 things)
x=3, 4(rejected) 35 x 2 =70 =7C, x 2
X Exf -= 2.8 (78) (2). np =6, npq =3
q= 1/2, p= 1/2, n = 12
(73) (1). Let other end is (h, k), then centre equal to So required probability
(p+h q+k a+i|
= 12Co p° ql? + 12C, p' ql! = |a-i| =|z|
2 2
Because circle touches X-axis hence radius 4 4
(79) (2). Let cos-! =A ’ cos A
5
=

2 2
2 tan-l =B’ tan B=
3
-p)² +(k-q' =2 tan A + tan B
3
4 3
+
2
17
tan (A + B) =
’ (x-p)' =(y + q)- (y- )² 1- tan Atan B 1-
32 6

’ (x- p)= 4qy 43

(74) (3). (80) (1).
80m 2(sin x - sinx) +(sin x-sin x)
f(x) = 2(sin x - sin'x)- (sin x - sin x)| 2
20m

X*
(:: sin x > sin x in (0, ))
By similar triangle
80 =3; X =
.(1)
X X+ X2
h 20 Now f(x) -3 ;
..(2)
X+X2 =3 ; X =
By (1) and (2)
2 4 or X, = 4x| differentiable at x =
f(x) is continuous &

80 or h= 16m
XË 5x
 (81) 2. f(x)= tan
sin x -cOS X (87) 3. lá-6+|6- + -a =9
Sinx tcOS X
6- 22 ä.b=9’£áb = - .. 1)
= tan lan x -1 2
tan x +)
tan tan x
J+b+c20 i?+2E b 20
3
X -
-:f()=x
Its derivative w.r.t. x
X
is
For equality
-= 2
2 1/2 l +b+|=0>ä+b+=0
(82) 2. =3 Sb+ 5 = -5 : 2ä +5b+ 5 =-3£
|-r
|2 +5b +Sc|= 3| |=3
a³ 27 27(1-r)_27 (88) 3. y=-/-x y'=- X
1-r 19 19
where x & y both (- ve
’ 6r- 13r + 6=0
’ r = 2/3 asr|<1
x=--y ’ x'=-y
where x &y both () ve
|A|
(83) 4. |A. | B|=8 and B
=8 ’|A |=4 Hence, A=
16ab

and | B|= 1/2

111
det (BA-1.B) = 4 16

(84)
(85)
5.
5.
17-,1;B=5
-8 3
DR'S of 1ine are 2, 1, -2 where a =b= 1/4 .. A = 1/3

Normal vector of plane is i -2j- kk (89) 4.

Sin a =
(2i+j-2k)-(i-2j-kk)
3V1 +4+k?
2k
Sin a = ...1
)
3Vk?+5 lim P(x)’ 0 and lim P(x)’0

242 Minimum number of zeroes using IVT is

..2)
3 4. Hence, R>4
(12+ (2) = l»k? =5/3 The roots using lie in
1. We have P (A) = P (7) =6/36, (-o, 0); (0, 1); (1, 2) :(2, )
(86)
P (B) = P (4)= 3/ 36 (90) 1. y²- 5y = 3x - 6
Since equal throws are disregarded, for point of intersection with y-axis, i.e.
x =0
Hence in cach throw A is twice as likely to y'- Sy +6=0 ; y=2, 3
Win as B.
A(0. y). B(0, y,)
Let P(B) =p, P(A) = 2p AB=y - y| -|3-2 |= 1
3p =1p= 1/3

10