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Electrochemistry Pyq

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274 views32 pages

Electrochemistry Pyq

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aspirantsougata
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PYQ Sourabh Raina Electrochemistry Vay shork amswe Legpe questions ClMorks) @ Nome He type of cll which was usec Ww Apollo spore proguammne™ C2020) Ans H,-O2 fuk kh: i: ge state “he coradag® pust Law eberto%pis ros: Are The amount of om substance Leposihod % Liberate at am ole bocke is duc cthy proportional quonkiey of elecrecity, parsed. teough eherrolyte wa oor amount of enbstantce caposthedk soe oar chosge 1 = 2° ela tocRemBeal evivalest: 63 Reprsent He Golvanée colt in whock, the seartion 2nts) + G2*caay) —> 2x bay) + Cuts? Lohe peoce? : €2013) ll Ga tay) |Gacs> ~cothnoke 2 Cz0ls? Znov jant . Anocke sat ge Define Secondary batteries They on eo Hore bateres whick con be aeckorgek ‘be passing, ehavaice cument XO them amd lead stovoge batlery. BS How o a a muck Raxge ts reaurecl fr He reducdio of, Imoke of 2y°t 0 2n®. 2 Ars Zreapt AE — 2nsD Imole & 2n* nequres ‘amoles 4 Lechon axge 72 F ee, qgsool= 19 3020C of wheck is betes Bs using & value o A ama B pred fer coating the auspoce of bor” : 2 £ Ec eet." ua) 2 prevent capri nd WEG” 2. 2-0 ole Ans cata e7® qv E@ TB es Metak Faxing Lower acduchon potential will be omtdasedk fast - metal A Ronirg Power seduction porontrol phen connecker wu Gow protet it from qnidation amd prenenk tgansiow- Sourabh Raina BT Define the Levm a Mo@or conductivity Cm) Gals? Ans MoLor conductivity ts He conductante shang solution cortauming, | moe of, dup oluedk when ploood a ‘fn parallel electodes ae cars sertion area Loage enough a ba fo ttn unt - S ont moh! a 08 how mony, coulombs oe gequurcdk 5% ontatedne Irvoe o H0 £0 O> : : os Avs H,0 aut +£0* ad : ett eho QP oh Ae ee AR aroles 4 2% eg eAKUSO® = 143008 c G4 F oblor mg sean’ a ’ » ocom, at cathode luring th Lovoalysis of ompeous ror cRimidhe olin e Aatcogy © Ag E'- 0.80V (gos) ptcoy) TE ab E72 0-00V : On basis of How stonolorct xecduction ele voce potential? CE ) which seathoris feoshe ak Cathode anh why . A> Reartion with Gigher tential occ ok cothode. Rearhon Bok aaa SS Define cuchile?, (2013, : Ay TEs eG One whisch Bernie 084 on combs Lor Of fucks Lhe methomoe converkock whe elevrical enrry’g: Sourabh Raina Shove answer zype L questions (2 Marks) GIl the standard beviocle potentio® fn Dantete Colhis I.lv. Caleulake the stan dort Cubbs encraa 4a He cell xeartion. CIF = 46,509 ¢ mo") 24 Cats> (2013? 2nCs) + CG tCoa,) — 2" Cam) t == ae mer Ecotee lly ee oe Beaont Eel = x d550e x LIV = 212 300 Smee ol Waite the mame of, Hee clk whick ts generally used im inverters. Wake He acattions taking ploce at Hie anode and He catbode of this cell (Z0!t Ars Lead storage baiterg Aiaot, csp + $04 Cay) ph sours +e see i codeay tHH't RE —— Ph Soy Cs? +QH,0( 4) 7 an te days of eisocbaion Cot) 0% ¥ a ‘ cekic netol 4 Us mMoLon condutincty CAm) & 34.08 somrut Gwen XCK) = 344.68 Som moe"! XCCH,Co emee! — C204 on”) = 40.4 Some R ° ° ee Acw,coou = ® ywttd CHO? : 2 349.68 +40-% = 390.58 somt ok . 340s - al : 34058 BIN reddit Hho product of electio? eb bssts of am soldron of Ou Lo, wh platinum wa ohm 2 Caiven EG2t/tn= *034¥ Ec guns) = 136% Cyt pugtg>,P = 200% £0 /H Avs At Cathoole + Tuo posite neavbion 2 2 5 oo Ly Cubtver 7 RCO Bis € 7 Ly Copprwe be deposikect becouse ve As Reger ste At omode ? 20 — a2 2H07 Op TAHT AIEN Lower eLevooke potentiol wt? be pregused brut due 4 over potenti? Of ony gen Blaine gs ts Leaked: (gore) Sourabh Raina Define Conducincts amt MoLon conduchivity fn the pobuhinn of om che rlyfic . Dig curs Us vocation wi concent ation”, c20!8? Conduterity ts defor 1 as condusomee Of, Lom Leng fk i ee urs 20Cb.0n sin gcc amo Lantng | om : e CACO, ith dablution becouse number % Evi Qrdion ab volume % MoLor. tondutenity 4 250 ne : “endl Ome vosen. | mole 4 elevoo ts olnsokvedt Ame 2 RXV > Te merenses with. dbulion becouie fetal Nobume V.0f s08ution conboimtna I mole 4 electrolyte. muenes. Cue ne ' fue pont of dif rence betieen eveite cKend di cZ020> amd eLevbra Syfix cee Ars Ars ELechachor Set, _Lechnlyte ohh 1 Tes a deve where haps isa device tok ee produce cfertuicok nergy ass enn Heronak sport ; 7 or cetons oneal ho veake a hemi coll xeniion : 2 Non sporeancor Tg acattion HUH 2 Spontameo! C one sean £kE P ° DaENE ae oe 3, Annde = *Ne cattode = XS 3. cathode ~* wt me are tu eLevtolytes . On delusion | conduckinicty of % imcreases AS tomes, whle thot V mere ares 25 Limes: Wick of, the elects ie why’ (202°) Ars yt weokeleuiolgte WHE dilubion a degree 5 Caer | Ne gent’ in in ULOAE Wo i: 4 duty x tere 0465 , cnn berg ions om avian. low RO O55 steep: Vo sting telat Only Eo nti isdpsose ove MOLD comdachnit oat oe Calcoukate the when a cus mors of A : enk 4 deposited F ld eg dace mop tt hi he ) AA 4 Ag Nog for 1S emi ie a 5 her IS minutes’. Cohen mol fe Ee an. marsd, Aa = 2A £eI8 minukts 1E = 96500 nag 084 hoage (8) isnbo = 49.2 secon (28th? > Let = 2K490° s a =1Goor Nee 108g 449 * lez 108 A4 ce lecaaas” Ay q6s0° le inoke poo = 108 K180° 650° 2 2.0149 of Ag 1g of larity 's ovens deport ime Ag Sourabh Raina oa Wade Hee mame of cell wheck ts general, used m hransisth lake He reactions Loleing place at anode : amol cathode of this cell’. Qolt fre Lechamcke Coll CDty okt? At anode oe ee At cothoole a ocoH)* NH Mn+ Nua * ea 020 The (o! : nui €: ——————— a nity Hod 02M eo ers seit kh o£ 298k On conduckinity ” Ans k= 0.025 Gar! MoLority = 0.aM - M plas.condudinit = kx loo? C Am) “aA = 9.025 x12? 0.2 = 125son™ a Bore answer type T Question (3 morkes> G21 Cobeukate EMF of He colt ak 298 & fe Cs) | fe tco.o01m) II 147C0-01M) | Ha cq9Clbar) | PEe>: 320-4F#l Given Hak Eceke = ONY (fog 220-3014 4 Bogle!) cae) Avs cope seatbinn 2 : Feegt2Acogy Fecayt Hace? Eceth o-H4v i _o.oras 2 > Ecedh = Cegth- 02053 Doge = out O° 8 To - oe cher = o.MU- 9.0288 Hoyle ea cut = O.WloS\ rea _o.ane 0-0245 Bog C2 2 cit) The eLeuty. a eee wolution eee a column of 0-0 : 5625 on is na ae amd area of ors Nave xlo faa in amd Moker conductivity” onkate esistovity ,dondavten leg Cg022? Ang 2= 0.625 em" Modarity 0-05" Re Sxlorn i a. 50m Concbuchitt Sy | : = 0.016 51 pe 8% £ = gps 2 0.016Si" poor, covclartini 2 Kx le? Bo RRA ue) i i gxi eX O82 6.05 . = 320 8 Om po ee ae ge mek ° solution contaimt e eLevinp Lateck usLng am acidic ~ 0s, according fo A036. 9 & fptlorams eopeation. Ea Si eet ee fe of cheomemsium tv Xl be cle chnploter by a we mb. How Long wit i& Lake to elevtap Lore, Ise using 125A cumen’!. CAtomemnars Os = en a pteee PACD TES 1p 24680 8 (018 Ans 03600) *6 ce is aque fo lapse Imobe 523 + ox SOP le GK9bSO? EX VBS OOC™ 524 le= 52 $2 Gx46S0° 1g = Ex agsoorkS c oe Sz Silhee by sgsroKl Sor & QM00% = GX46S0° ro ke Ex agsorart = | 36 2 lS ae = — sanles Aeconol 624 © The stanotorol Aibbs energy (DaG) fer the fo llaoe ~~ cetk reaction & —300 Komal. CoxG 4 i ° one 2n(5) + 2A9*Cay) — zn ‘cay)+ 24AgCs) Cakoubobe Eceee $n this aeadion CIF 96500 © mnt | Ans @ CTeamt | zncs) eae — 2n cay rt 2g cs> Qo2l-2>) | m2 oe = oth —300x 100 = 300% (002 E cere joke 2K 4SO° =LS5V © Colewlote the Xm of Mg L, 4 X velue foe Mg? ae ona (2 dons ane 106 Pkmae ‘and 46.3 Some moe” nespectivel’ As : fon Mg Wy > Amst ra har = Joo +2ax 46.3 log 1S2.6 el 58.6 sent B25 Fox the xeahion Cl asim) DA gts)+ BHC? : 42% CoM 2Ag hess tH, Ke) De: _usgooy ak 2S¢ Cc coloulake EMF of, Hhecete® (2018) Ars — QAg lc») + Hy, Cg) Laem anges +2ut Colm) +22 Co.1m) 2 “cell 41 os B caggoo = ~2x 96500 KEE Ecut= EC ~ 9.05" Bg Oe Eeote = 1360° E cone = 0.226¥~ “088 fog CHT" “ax 965°" 2 OHI 20.226 0.226 0.054 \ Bog aye 2 ye 0.226 40.054 = O28 Iv Sourabh Raina 926 The value 4 mm of ALz(S04 Iai BSE S omrmae™ while X sor” & G0 § omen. Caloulake Gmncting tore conduckniity of AL™ a (Cao? Ars am Ar Sq = 2 dm AL +3dm SO vice. amas as ag gse- 18° an ot eae Xmh2 = => ol 2 184 seme nel Wate Luo aolvamtoge of H-02 fuck cote one ondenoary coll” Exp Soin eheckodle eattion’ (2olu) Ay © Te 4os Bagh oppicteney 7°” ee oO H,o proolucco! com be wse o by $i. dainking pepo ostaon aus z _-»upolk +427 A t omode 2H,C3) +4oH Coy? 4H, (22> At ovo” OY At cohede > as 2H,0 +4 overall — aH,c4) 200% — c— you Cov) ) anp(2) G28 Define LevtioReme cal cath. . Woe Roppen if extemol potentio® appheot becomes meats. tam E cet of clerkn Remucalcoll”. (aolb) Ars The device Bak com convert chemical neg of chemical seathon fo elebucal energy & W&en a stead ok cumtnt of 2A 17 eile A oma. B otal, ely EB aso , ti sen 2g 4 Ca Heposite eo: amd ~ mows Card aee as a wot atomic, mor (20229 maanseizn - Equivalent woghe Ze Avs Cut 420° ao — Tek weight hs Maer = (ona, Eaprvole of : Sees om = MEET nx F ee a = 635824) aa Zz aGs0° zane 6SKe n= Gas wpe 249650" = 2038 63S “gocorel 2.04 eee Sourabh Raina (30 The condutrity, d, 0:20 mal 24 wLiction. of ke Les : Q.uvnls? Som! CoLeubate vfs amaler. conductority, ( wa! . es ? ee 2 degree o dumoviation (=) Selamat We TES Sim Ginen x =F ass (ap Ars kee QUBK IO Some | ie . MoLonity 7.) Rom k 2 = x ett we i Am ee tet Am = K x12? ise cee mM 9g uveld x1002 eet 2 a co oe 2 2A sont mat >08? Answer the following suestions ; By ts abternoting cunrent used. insteack f olirect current po measuring eststance of an ehetow lytic. solation.” i State koklrausch's Law of Enolepenctort ante ation. ob ton “ Depict the Galvanic ell in whe folboving aoaction Lakes place — Mags) + Cul¥coy>—> Metta) 4 0? Crevm i= 2°%), | Ars @ phect cument will couse eLevonbysis of 40 ution | 0 mare fons Will be produced: Hence we Use atkernatims cumenk 40 thot concentration of Lons nemains BamMe « © zt states hot Limiting omnbor conductintty of | an Levan lt com be repraseniteol as the Sum Of | Lndlintoluol contribution of he anion awk Cation. of ae i Aca = X,Na* +h al B31 — Arswer the following anes tions : ® Wayis abternoking cumnent used imeteack of olihect cument pr. measuring xesistamce of an clevtrn byte. solution”. © State koflrausck's Law of inolepenclert mig ation of ton © Depict the Galvamic lh in whe fobhowing xeation place — Mgts)-* Cub¥cayd —? MgMeny) + 0405? Cem 25 2, Lakes Ans © Cele cam be nepresennte o Os Mg IMge || G2" 1% Cobeulote the maximum. weak ond Cope fo he given aeaction at 29Bk- NtCs) + aby Coy) —— Ni tay) + 2Ag cs wml Qiven € Nit /Ni = -0.28V Eagt/ag= 0-Bov Tears 202), Ans (Eeote: Ctatiode- fo ioe : +h en Ne ae c-0.28? = 202650 = a. Ect 1.05% snp ECM hog ke ~ + ea at 248 D4 aR a6s0o% Los enn : = 202.650 Tmok i Logke = Foe eeH = 358 2 202.65 kSmoe™ r | O3> Conductivi Y | ity of axio?M methanol achd & Bk 10° | Cohoutoke it olor conduckivits, amd degree of as ndatin. i fn 4a methamole acta. is Yo ee ae C RNa? | Avs M = Ce axto? ke BIO s ’ 2. HCOOK yo $ ond mune” fen ae fen | 5 o you ae re | _ Re — Bx1o > 1 0 gone ree oo4 @ Mercury celts deliver a constamt potential aluriny Us Ute time. hive Reason © Calowlate te emg of the fobloing covls of 248k Fecs> | Fe**Co.01m) | H*cumy [Huey Clba> pees? 3025 Given Etegh+ o-uuv aMoul* An © Mercury colts delivers a constant potentio£ duning te Life time becouse tHe overall Aeation oloes noe bnvokve amy cond in olution whose concentration 2n CHa) o + 139° — 2n0Cs) + Hy (4) 1 634 © Us Ute time “hive Reason © Calculate He emg of the foblasing couls af 228 Fe.Cs> | Fe**C0-01m) | H¥cim) [Hucg Cl bax> P Given Etekh= o-44v | | = ® ce tcayy tH) ie Feet ve (orm Lbs ° 2t : —0.0s4! JCH4 Ecotl + Ect ~ 0:25! bo ae eth 20.44 - 0,054 b WwoX “8 Ent 9.44 — 0.0841 x-2 a Ewe = 0.4 toosrl = 0-494 y 0S) Mercury, cells deliver a constamt potontio£ using k 2023 3Movs

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