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Lecture # 24& 25 - Week # 15

This document provides information on the Chemical Reaction Engineering course taught by Dr. Muhammad Haris Hamayun at COMSATS University Islamabad, Lahore Campus. The course contents include kinetics of homogeneous and heterogeneous reactions, analysis of batch reactor data, and design of different reactor types. The recommended textbooks are also listed. The course learning outcomes are mapped to program learning outcomes and include understanding fundamentals, applying knowledge, analyzing data, and designing reactors. Assessment methods are also discussed in the context of outcome-based education. Examples provided cover topics like selectivity in parallel reactions and reactor selection case studies.

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Sufyan Khan
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48 views20 pages

Lecture # 24& 25 - Week # 15

This document provides information on the Chemical Reaction Engineering course taught by Dr. Muhammad Haris Hamayun at COMSATS University Islamabad, Lahore Campus. The course contents include kinetics of homogeneous and heterogeneous reactions, analysis of batch reactor data, and design of different reactor types. The recommended textbooks are also listed. The course learning outcomes are mapped to program learning outcomes and include understanding fundamentals, applying knowledge, analyzing data, and designing reactors. Assessment methods are also discussed in the context of outcome-based education. Examples provided cover topics like selectivity in parallel reactions and reactor selection case studies.

Uploaded by

Sufyan Khan
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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Chemical Reaction Engineering

Course Code: CHE 331


Course Cr. Hrs.: 4(3,1)

Course Instructor:
Dr. Muhammad Haris Hamayun
Assistant Professor,
Department of Chemical Engineering,
COMSATS University Islamabad, Lahore Campus.
Contact Email: mhhamayun@cuilahore.edu.pk
1
Course Contents

Kinetics of homogeneous reactions: rate of reaction, variables affecting the rate of


reaction, order of reaction, rate constant; searching for a mechanism of reaction,
activation energy and temperature dependency. Interpretation of batch reactor data for
single and multiple reactions. Integral method and differential method of analysis for
constant volume and variable volume batch reactors, search for a rate equation. Design
of homogeneous reactors, Batch, Mixed flow, Plug flow reactors, Comparison of single
reactor, multiple reactor systems in parallel/series. Temperature and pressure effects.
Adiabatic and non-adiabatic operations. Surface phenomenon and catalysis,
Heterogeneous reaction systems, rate equations for heterogeneous reactions, fluid
particle reactions, determination of rate controlling steps. Catalysis desorption
isotherms, kinetics of solid catalyzed reactions. Catalyst deactivation and regeneration.
Design of fluid-solid catalytic reactors.

2
Recommended Books

1) H. Scott Fogler, Elements of Chemical Reaction Engineering, 5th edition, Prentice


Hall, 2016.

2) H. Scott Fogler, Elements of Chemical Reaction Engineering, 4th edition, Prentice


Hall, 2006.

3) Octave Levenspiel, Chemical Reaction Engineering, 3rd edition, Wiley India Pvt.
Limited, 2006.

4) Elsie Perkins, Chemical Reaction Engineering, WILLFORD Press, 2022.

3
CLOs and Mapping with PLOs

Understand • Describe the fundamentals of chemical reaction


(C2, PLO1) engineering.

Apply • Apply the fundamentals of chemical reaction


(C3, PLO1) engineering.

Analysis • Analyze the kinetic data using different methods of


(C4, PLO2) data analysis.

Design • Design isothermal and nonisothermal reactors (e.g.,


(C6, PLO3) Batch, CSTR, PFR, PBR etc.)

4
OBE in a Nutshell

◼ What do you want the students to have or able


to do? ◼ Knowledge, Skill, Affective

◼ How can you best help students achieve it?


◼ Student Centred Delivery

◼ How will you know what they have achieved it?


◼ Assessment

◼ How do you close the loop


◼ Plan, Do, Check, Act (PDCA)
5
Lecture # 24 & 25 (CLO # 1 and 2)

• Chapter # 8: Multiple Reactions


✓Relationship between Instantaneous and Overall Selectivity for CSTR

✓Selectivity for Parallel Reactions

✓Example # 8.2

6
Example # 1 (4th Edition)

Problem Statement:

Develop a relationship between SD/U and S෠ D/U for continuous stirred tank reactor (CSTR).

Solution:
kD
For two parallel reactions:
A D
kU
A U

Instantaneous Selectivity:
rD
SDΤU =
rU

Overall Selectivity:
~ FD
SD U =
FU
7
Example # 1 (4th Edition)

Mole Balance on CSTR for Product D: FD = rD V

Mole Balance on CSTR for Product U: FU = rU V

Overall Selectivity will be equal to FD rD


S෠ D/U = = = SD/U
FU rU
Instantaneous Selectivity:

8
Selectivity – Parallel Reactions

9
Selectivity – Parallel Reactions

10
Selectivity – Parallel Reactions

11
Selectivity – Parallel Reactions

12
Reactor Selection and Operating Conditions

13
Reactor Selection and Operating Conditions

14
Reactor Selection and Operating Conditions

15
Reactor Selection and Operating Conditions

16
Example 8.2 – Case 1

17
Example 8.2 – Case 2

18
Example 8.2 – Case 3

19
Example 8.2 – Case 4

20

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