® P07-20

ADVANCED PATTERN PART TEST-4 (APT-4)

PAPER
TARGET : JEE (MAIN + ADVANCED)

2 COURSE : VIJETA (JP)

BATCH : 01JT(TCHP), 01JPA, 01JPB, 03JPAB
Time : 3 Hours Maximum Marks : 180
CODE

1 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

INSTRUCTIONS TO CANDIDATES
 Question Paper-2 has three (03) parts: Mathematics, Physics and Chemistry.
 Each part has a total eighteen(18) questions divided into two(02) sections (Section-1 and Section-2).
 Total number of questions in Question Paper-2 are Fifty Four(54) and Maximum Marks are One Hundred Eighty (180).
TYPE OF QUESTIONS AND MARKING SCHEMES
SECTION-1 (Maximum Marks : 36)

 This section contains TWELVE (12) questions. The answer to each question is NUMERICAL VALUE with two digit integer
and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO decimal placed.
 Marking scheme :
 Full Marks : +3 If ONLY the correct numerical value is entered as answer.
 Zero Marks : 0 In all other cases
SECTION-2 : (Maximum Marks : 24)
 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of which are
correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct answers, then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark

NAME OF THE CANDIDATE : ………………………………………………… ROLL NO. :………………..………………………..

I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator

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 INSTRUCTIONS FOR OPTICAL RESPONSE SHEET (ORS)
 Darken the appropriate bubbles on the original by applying sufficient pressure.
 The original is machine-gradable and will be collected by the invigilator at the end of the examination.
 Do not tamper with or mutilate the ORS.
 Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this
purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each
digit of your roll number.

DARKENING THE BUBBLES ON THE ORS :

 Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
 Darken the bubble COMPLETELY.
 Darken the bubble ONLY if you are sure of the answer.
 The correct way of darkening a bubble is as shown here :
 There is NO way to erase or "un-darkened bubble.
 The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles
are evaluated.
 Zero marks ‘0’ If none of the options is chosen (i.e. the question is unanswered).

FOR INTEGER TYPE QUESTIONS OMR LOOKS LIKE :

 For example, if answer ‘SINGLE DIGIT’ integer type below :
0 1 2 3 4 5 6 7 8 9
 For example, if answer ‘SINGLE DIGIT’ integer with positive / negative type below :
0
– 1
2
3
4
5
6
7
8
9
 For example, if answer ‘DOUBLEDIGIT’ integer type below :
0 0
1 1
2 2
3 3
4 4
5 5
6 6
7 7
8 8
9 9
FOR DECIMAL TYPE QUESTIONS OMR LOOKS LIKE :
COLUMN
1 2 . 3 4
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
6 6 6 6
7 7 7 7
8 8 8 8
9 9 9 9
 If answer is 3.7, then fill 3 in either 1st or 2nd column and 7 in 3rd or 4th column.
 If answer is 3.07 then fill 3 in 1st or 2nd column ‘0’ in 3rd column and 7 in 4th column.
 If answer is, 23 then fill 2 & 3 in 1st and 2nd column respectively, while you can either leave column 3 & 4 or fill ‘0’ in either
of them.

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 ADVANCED PATTERN
PART TEST-4(APT-4)
TARGET : JEE (MAIN+ADVANCED) 2021
COURSE : VIPUL | BATCH : (01JPA)
QUESTIONS, HINTS & SOLUTIONS
MATHEMATICS-I
PAPER-2
SECTION – 1 : (Maximum Marks : 36)
 This section contains TWELVE (12) questions. The answer to each question is NUMERICAL VALUE with
two digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO decimal
placed.
 Marking scheme :
 Full Marks : +3 If ONLY the correct numerical value is entered as answer.
 Zero Marks : 0 In all other cases
[kaM 1 ¼vf/kdre vad% 36)
 bl [kaM esa ckjg (12) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa]tks f}&vadh; iw.kkZad
rFkk n'keyo f}&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd VªadsV@jkmaM
vkWQ (truncate/round-off) djsaA
 vadu ;kstuk %&
 iw.kZ vad % +3 ;fn flQZ lgh la[;kRed eku (Numerical value) gh mÙkj Lo:i ntZ fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esa

2v  v  (iˆ  2 ˆj )  2iˆ  kˆ then value of 3 v is


1. If  be a vector which satisfies the condition

;fn  ,d lfn'k gS tks izfrcU/k 2v  v  (iˆ  2 ˆj )  2iˆ  kˆ dks larq"B djrk gS] rc 3 v dk eku gksxk &


Ans. 02.44 or 02.45

Sol. 2v  v  (iˆ  2 ˆj )  2iˆ  kˆ .......................................(1)
Dot with iˆ  2 ˆj
iˆ  2 ˆj ds lkFk fcUnq xq.ku ls
 v .(iˆ  2 ˆj )  1
ˆ ˆ
2

 v .(i  2 j )  1
 v .5.cos   1
2 2

 v 2 .5.sin 2   5 v 2  1 ..............................(2)
Taking mod in equation (1) using (2), we get
(1) o (2) ls ekikad ls
3v  6

| z1  z2 |max
2. If | z1 | 15 and | z2  3  4i | 5, then
| z1  z2 |min
|z z |
;fn | z1 | 15 vkSj | z2  3  4i | 5, rc 1 2 max dk eku gS&
| z1  z2 |min

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Sol. 05.00
We have, ;gk¡
| z1 | 15,| z2  3  4i | 5
Minimum value of | z1  z2 | is 15  10  5.
| z1  z2 | dk U;wure eku 15  10  5.
Maximum value of | z1  z2 | is 10  15  25
| z1  z2 | dk vf/kdre eku 10  15  25
1 3i
3. If z = 4 cos  (cos  + i sin ) and z1 = then difference between maximum and minimum value of
2
| z – z1 | is:
1 3i
;fn z = 4 cos  (cos  + i sin ) rFkk z1 = rc | z – z1 | ds vf/kdre o U;wure eku dk vUrj gS&
2
Ans. 04.00
Sol. x + iy = 4 – cos  (cos  + i sin )
x = 4 cos2  = 2 + 2 cos 2  …(i)
y = 4 sin  cos  = 2 sin 2  …(ii)
from (i) and (ii) (x – 2)2 + y2 = 4
(i) o (ii) ls (x – 2)2 + y2 = 4
centre C(2, 0); radius(r) = 2
dsUnz C(2, 0); f=kT;k (r) = 2
| z  z1 |max  CP  r
| z  z1 |min  CP  r
Difference vUrj = 2r = 4

dy
4. Equation of curve passing through (1, 1) and satisfying differential equation x  y(xex  n y) is
dx
x ny  ex (x  ) . Then  is equal to
dy
vody lehdj.k x  y(xex  n y) dks larq"V djus okys rFkk (1, 1) ls xqtjusa okys oØ dh lehdj.k
dx
x ny  ex (x  ) gS] rc dk eku gS&
Ans. 01.00
dy
Sol. x  y ny  yxex
dx
1 dy ny
  ex
y dx x
Let ekuk ny  t
dt t
  ex
dx x
1
 dx
I.F. = e x  e nx  x
 xt   xe x dx
x ny  (x  1)ex  c
This curve passes through (1, 1)
;g oØ (1, 1) ls xqtjrk gSA
c=0

1  x2  x  1 x2  x  1 
5. Let f () =  1
x
cot 1 
 2x  3x2


3  2x 
 dx


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 ln 
 | x 2  3x  2 |  | (x  1)(x  2) |  | x  1|  | x  1| 
and g () =  
1
| x  1|  | x  1|
 dx

ln


2 3  
where   (0, ) –  , ,1 . If f (200) – g (50) = a lnb , then find the value of (a + b)
 3 2  2
where b is a prime number and a N.


1  x2  x  1 x2  x  1 
ekuk f () =  1
x
cot 1 
 2x  3x2


3  2x 
 dx

ln 
 | x 2  3x  2 |  | (x  1)(x  2) |  | x  1|  | x  1| 
rFkk g () =  
1
| x  1|  | x  1|
 dx

ln


  2 3 
tgk¡   (0, ) –  , ,1 . ;fn f (200) – g (50) = a lnb , rc (a + b) dk eku gS&
3 2  2
tgk¡ b vHkkT; la[;k gS rFkk a N.
Ans. 04.00

1  x2  x  1 x2  x  1 
Sol. We have f() = 
1
x
cot 1 
 2x  3x2


3  2x 
 dx .....(1)

1 1
x=  dx = – dt
t t2
1
 
 t 2  t  1 t 2  t  1   1  1 1  t 2  t  1 t 2  t  1 
f() = 

t cot 1 
 2t  3

 2    dt =
3t  2t   t 2  1
t
cot 
 2t  3

 2
3t  2t 
 dt



1  2
1 t  t  1 t  t  1 
2 
=
t
1 

  cot 
 3  2t

2t  3t

2 
 

dt ....(2)

 On equation (1) + equation (2), we get


   1 
2f() = t
1
=   ln   ln    = 2 ln
   


f()   ln  
 
ln   
| x 2  3x  2 |  | (x  1)(x  2) |
Now g() = 
  | x  1|  | x  1|
 1 dx

ln  
1
 Odd function i.e. f(  x)  f(x) 
ln 
 1
g() = 
 1
1.dx = ln   ln   = 2 ln

g() = 2loge
ln 


Now f(200) – g(50) = ln(200) –  ln(50) =  ln 4 = 2ln 2
2

4
6. If  [sinx  cos x] dx = –, then find
0
. (where [.] denotes greatest integer function)

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 4
;fn  [sinx  cos x] dx = –, rc  dk eku gS (tgk¡ [.] egÙke iw.kk±d Qyu gS)
0
Ans. 02.00

2 A1 A2
–1 5 7 A3
4 4 A4
 3  2
Sol. 4 4
–1
– 2
–2
2
   
0

 = 2  2 sin x   dx
 4 
2


= 2 [ 2 sinx] dx
0

 = A1 – A2 – A3 – A4
3  
= – .3–
2 4 4
= – 2

sin 1 x 2
1

7. If the value the definite integral  2 dx is , where n is a natural number,

0
x  x 1 n
then the value of n/5 is ?
sin 1 x 2
1

;fn fuf'pr lekdyu 0 x 2  x  1 dx dk eku

n
gS tgk¡ n izkd`r la[;k gS rc n/5 dk eku gS?
Ans. 21.60
sin 1 x
1

Sol. Let I   dx .............(1)

0
x2  x  1
replacing x by 0 + 1 - x
x dks 0 + 1 – x ls gVkus ij
sin 1 1  x cos 1 x
1 1
I 2 dx   2 dx
0
x  x 1 0
x  x 1
.................(2)
On adding rquations (1) and (2), we get
(1) o (2) dks tksMus ij
1
 /2
2I   dx
0
x  x 1
2

 
2

3 3
 n = 108

x 2sec ²t
8. Let f(x) be a non constant continuous function defined in R such that f2(x) = 0
f(t).
4  tant
dt and

  m m
f(0) = 0, If f    n   , where m and n are relatively prime numbers, then is equal to......
 
4  
n n

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 x 2sec ²t
ekuk f(x), R esa lrr~ Qyu tks vpj ugha gS] bl izdkj gS fd f2(x) =  0
f(t).
4  tant
dt rFkk f(0) = 0, ;fn
  m m
f    n   , tgk¡ m vkSj n lgvHkkT; la[;k,¡ gS rc cjkcj gS -
 
4  
n n
Ans. 01.25
x 2sec ²t
Sol. We have, (f(x))²   f(t). dt
0 4  tan t
Differentiating both sides w.r. to x we get
2sec ²x sec ²x
 2f(x).f '(x)  f(x)   f '(x)dx   dx
4  tan x 4 tan x
 f(x) = log (4 + tan x) + C
Given, f(0) = 0 = log 4 + C  C= – log4
 f(x) = log (4 + tan x) – log4
  5 m
 f    log5 – log4  log    log (given)
4 4 n
 m = 5, n = 4  m + n = 9
x 2sec ²t
Hindi ;gk¡, (f(x))²  0 f(t). dt
4  tan t
x ds lkis{k nksuks rjQ vodyu ls
2sec ²x sec ²x
 2f(x).f '(x)  f(x)   f '(x)dx   dx
4  tan x 4 tan x
 f(x) = log (4 + tan x) + C
fn;k x;k gS, f(0) = 0 = log 4 + C  C= – log4
 f(x) = log (4 + tan x) – log4
  5 m
 f    log5 – log4  log    log (given)
4 4 n
 m = 5, n = 4  m + n = 9

9. If the area enclosed by the curve y  x and x   y, the circle x2  y2  2 above the x-axis is A,
15
then the value of A is

15
;fn oØ y  x vkSj x   y, o`Ùk x2  y2  2 dk v{k ls Åij izfrc) {ks=kQy A gS] rc A dk eku cjkcj

gS&
Ans. 07.50
Sol. Required area = Area of one quadrant of the circle   / 2
vHkh"V {ks=kQy = o`Ùk dk ,d prqFkk±'k dk {ks=kQy   / 2

   
3/2
4  x2 a  x2 . x2  b
10. If  x6
dx =
120 x5
+ C then a + b equals to :

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    
3/2
4  x2 a  x2 . x2  b
;fn  x6
dx =
120 x5
+ C rc a + b cjkcj gS&
Ans. 10.00
4  x2
Sol.  = dx Put x = 2 tan j[kus ij  dx = 2 sec2  d
x6
2sec .2sec 2  d 1 cos3  d
 =
2 4  sin6 
 =
26 tan6 
1  1  sin2  
= 4   cos  d put sin  = t j[kus ij  cos  d = dt
2  sin6  
1 dt 1 1  1 1  1  5sin2   3 
=
24 t 6
–
t4
dt =
16  3t 3  5t 5  + C = 16  15sin5   + C
   
x x
but ysfdu tan  = So blfy, sin  =
2 4  x2
 
 5x 2 
3 
    
 
 x2  4 3 / 2 x2  6
   + C
3/2
1  x2  4  1  2x  12 x2  4
2
 +C= 1 
=   +C =
16  15x 5  16  15x5  120  x5 
   
 
 x 2  4 5 / 2
 


1
1
 C7 .x 200 . 1  x  dx is equal to k , where k is a
11. If the value the definite integral 207 7

0
k
natural number, then the value of is ?
26

1
1 k
;fn fuf'pr lekdy
 C7 .x 200 . 1  x  dx dk eku k ds cjkcj gS tgk¡ k ,d izkd`r la[;k gS rc 26 dk
207 7

0
eku gS ?
Ans. 08.00
Sol. Integrating by parts
[k.M'k% lekdyu djus ij
 7 x
200 1
 1 7 
I  C7  1  x  .  
201 0 0 201
  
207 6 201
 1 x x dx
 
1
7
 1  x  x 201dx
6
 C7 .
207

201 0
Again integrating by parts 6 times, we get
iqu% 6 ckj [k.M'k% lekdyu djus ij
1
7!
201.202.203.204.205.206.207 0
I 207
C7 . x 207 dx

 1
208
 k = 208

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12. The area bounded by the curve y  f(x)  x 4  2x3  x2  3, x-axis and ordinates corresponding to
minimum of the function f(x) is
oØ y  f(x)  x 4  2x3  x2  3, x-v{k] f(x) ds fufEu"B ds laxr dksfV;ksa ls ifjc) {ks=kQy gS&
Ans. 03.03
Sol. f '(x)  4x3  6x2  2x  2x  2x(2x 2  3x  1)
 2x(2x  1)(x  1)
Since f is a differentiable function, for extremum
pawfd f, vodyuh; Qyu gS pje eku ds fy,
1
Points of f(x), we must have f '(x)  0 . Hence x = 0, ,1
2
1
f(x) dk fcUnq f '(x)  0 . vr% x = 0, ,1
2
Now vc f ''(x)  12x2  12x  2,f ''(0)  2,f ''(1)  2
and vkSj f ''(1/ 2)  3  6  2  –1
Thus the function has minimum at x = 0 and x = 1.
Qyu U;wure x = 0, x = 1 j[krk gSA
Therefore, the required area is blfy, vHkh"V {ks=kQy
1  x5 x 4 x3 1

 (x 4  2x 3  x 2  3)dx  
0  5


2

3
 3x 

0

SECTION – 2 : (Maximum Marks : 24)

 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct answers,
then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark
[kaM 2 : (vf/kdre vad : 24)
 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
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 nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk
x;k gS vkSj pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs

 
13. The vector c , parallel to the internal bisector of the angle between the vectors a = 7 î – 4 ĵ – 4 k̂ and
 
b = – 2 î – ĵ + 2 k̂ with | c | = 5 6 is
  
lfn'k c , nks lfn'kksa a = 7 î – 4 ĵ – 4 k̂ rFkk b = – 2 î – ĵ + 2 k̂ ds e/; dks.k dk vUr% v)Zd gS rFkk
 
| c | = 5 6 gS] rc lfn'k c gksxk&
5 5
(A*) ( î –7 ĵ + 2 k̂ ) (B) ( î + 7 ĵ – 2 k̂ )
3 3
5 5
(C*) (– î + 7 ĵ – 2 k̂ ) (D) (– î –7 ĵ + 2 k̂ )
3 3
7 î – 4 ĵ – 4k̂
9
Sol.
– 2 î – ĵ  2k̂
3
  7 î – 4 ĵ – 4k̂ – 6 î – 3 ĵ  6k̂ 
c =±  
 9 
 
  î – 7 ĵ  2k̂ 
c = ± 
 9 
 
  î – 7 ĵ  2k̂ 
c = ± 
 3 6 
 

5
5 6 c = ± ( î – 7 ĵ + 2 k̂ )
3
 
14. Let b and c are two non-collinear vectors such that
       
a .( b + c ) = 4 and a ×( b × c ) = (x2 – 2x + 6) b + (sin y) c , then
       
ekuk b rFkk c nks lfn'k gS tks lajs[k ugha gS rFkk a .( b + c ) = 4 dks lUrq"B djrs gSA ;fn a ×( b × c ) = (x2 –
 
2x + 6) b + (sin y) c , rc
 
(A*) x = 1 (B) x = –1 (C*) y = (4n + 1) , n  (D) y = (4n – 1) , n 
2 2

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     
Sol. a × ( b × c ) = (x2 – 2x + 6) b + sin y c
       
( a . c ) b – ( a . b ) c = (x2 – 2x + 6) b + sin y c
   
 a . c = x2 – 2x + 6 and a . b = – sin y
 x2 – 2x + 6 – sin y = 4
 (x – 1)2 + 1 = sin y

 x = 1, y = (4n + 1)
2
15. For complex number z1  x1  iy1 and z2  x2  iy2 , we write z1  z2 , if x1  x2 and y1  y2 . Then for
all complex numbers z with 1  z. (  , 2 , non real cube roots of unity) Given Img  > Img2
 1 z 
(A) 2  z (B)   z (C)  0 (D) All of these
 1 z 
lfEeJ la[;kvksa z1  x1  iy1 vkSj z2  x2  iy2 ds fy, z1  z2 ;fn x1  x2 vkSj y1  y2 rc lHkh lfEeJ
la[;kvksa z ds fy, 1  z. (  , 2 ,bdkbZ dk vokLrfod ?ku ewy gS) fn;k x;k gS Img  > Img2

 1 z 
(A) 2  z (B)   z (C)  0 (D) mijksDr lHkh
 1 z 
Sol. (AC)
z1  z2
 x1  x2 and vkSj y1  y2 for z1  x1  iy1 ds fy, vkSj z2  x2  iy2
Let ekuk z = a + ib and vkSj 1  z  1  a and vkSj 0  b
1 3
Now vc w 2   i , clearly Li"Vr;k 1/ 2  1  a
2 2
3 3
 1/ 2  a and vkSj  0b  b
2 2
 w 2  z holds goodlR; gksxh  (a) is true lR; gSA
1 3
Now vc w    i
2 2
3
Here 1/ 2  a but  b is not sure
2
3
;gk¡ 1/ 2  a ijUrq  b ugha gSA
2
 w  z does not hold good
w  z larq"V ugha gSA
 1  z   1   a  ib   1  a   ib 1  a   ib
Further iqu%    
 1  z   1   a  ib   1  a 2  b2
 1 z  1  a2  b2 1  a2  b2  
 Re     0 as a  1
 1  z  1  a 2  b2 1  a 2  b2
 1 z  2b
and vkSj Im    0 as D;kasfd b  0
 1  z  1  a 2  b2
 1 z 
  1  z   0 holds good larq"V gksrh gSA  (C) is also true lgh gSA
 

16. Solution of the differential equation (y + x xy(x + y))dx +(y xy(x + y) - x)dy = 0 is
vody lehdj.k (y + x xy(x + y))dx +(y xy(x + y) - x)dy = 0 dk gy gS&

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 x2 + y2 y x2 + y2 x
(A) + tan-1 =c (B*) + 2tan-1 =c
2 x 2 y

x2 + y2 x  2 xy 
(C) + 2cot -1 =c (D*) x2 + y2 + 2tan–1  =c
2 y  y–x 
 
Sol. The given equation is written as y dx  x xy (x  y)dx  (y xy (x  y)  x)dy  0
nh xbZ lehdj.k dks y dx  x xy (x  y)dx  (y xy (x  y)  x)dy  0 :i esa fy[k ldrs gSA
 ydx  xdy  (x  y) xy (xdx  ydy)  0
ydx  xdy  x  x   x 2  y 2 
    1  d     0
y2 y  y  2 
x
d 
x y 
2
 y   0  x  y  2 tan 1 x  c
2 2 2
 d 
 2   x  1 x 2 y
 
y  y
x
et
17. Let f :[1, )  R and f(x) = x  dt – ex, then which of the following is/are true?
1
t
(A*) f(x)is an increasing function
(B*) lim f ( x)  
x 
(C) f '(x) has a maxima at x = e
(D) f(x) is a decreasing function
x
et
ekuk f :[1, )  R vkSj f(x) = x  dt – ex rc fuEu esa ls dkSulk lgh gS ?
1
t
(A*) f(x) o/kZeku Qyu gSA
(B*) lim f ( x)  
x 
(C) f '(x), x = e ij mfPp"B j[krk gSA
(D) f(x) ákleku Qyu gSA

18. Area bounded between curve y = x2 &

1 2
(A*) x = 0 & x = 1 & x-axis is (B*) y = 0 & y = 1 & y-axis is
3 3
2 5
(C) x = 0 & x = 1 & x-axis is (D) y = 0 & y = 1 & y-axis is
3 3
oØ y = x2 vkSj
1
(A*) x = 0, x = 1 rFkk x-v{k ls ifjc) {ks=kQy gSA
3
2
(B*) y = 0, y = 1 rFkk y-v{k ls ifjc) {ks=kQy gksxkA
3
2
(C) x = 0, x = 1 rFkk x-v{k ls ifjc) {ks=kQy gksxkA
3
5
(D) y = 0, y = 1 rFkk y-v{k ls ifjc) {ks=kQy gSA
3
1
0
x 2
Sol: x = 0 & x = 1 & x-axis x dx

1 1 2
 & y = 0 & y = 1 & y-axis is 1  
3 3 3
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 1
0
x 2
Hindi x = 0, x = 1 rFkk x-v{k x dx

1 1 2
 & y = 0, y = 1 rFkk y-v{k 1  
3 3 3

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 ®
PATTERN CODE P7-20

TEST TYPE : ADVANCED PATTERN PART TEST-4 (APT-4)

TARGET : JEE (MAIN+ADVANCED) 2021
COURSE NAME : VIJETA (01JT (TCHP), 01JPA, 01JPB, 03JPAB)
FACULTY NAME : OP SIR –2
–1
TEST DATE : 13-12-2020 –1 TARGET DATE : 00-00-20
–2
Test Syllabus : Measurement error & Experiment, Modern Physics, Nuclear Physics,
–1
Wave Optics, Semiconductor, Circular motion, Centre of mass, RBD, –1
Fluid
–2
mechanics, Elasticity and Viscosity, Surface tension, Units and Dimensions,
–1
String Wave, Sound wave –1

APT-1 | PAPER-2 | PATTERN NO. 07-20

S.No. Subject Nature of Questions No. of Questions Marks Partial Marks Negative Total
1 to 12 Numerical type (2 digit, 2 decimal) 12 3 - 0 36
Maths
13 to 18 MCQ (Partial Marking) 6 4 +1 –2 24
19 to 30 Numerical type (2 digit, 2 decimal) 12 3 - 0 36
Physics
31 to 36 MCQ (Partial Marking) 6 4 +1 –2 24
37 to 48 Numerical type (2 digit, 2 decimal) 12 3 - 0 36
Chemistry
49 to 54 MCQ (Partial Marking) 6 4 +1 –2 24
Total 54 Total 180

Submit_(E + H) : 10-12-20_(OP Sir)

Final_(E + H) : 11-12-20_(OP Sir)

PAPER-2
SECTION – 1 : (Maximum Marks : 36)
 This section contains TWELVE (12) questions. The answer to each question is NUMERICAL VALUE with
two digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO decimal
placed.
 Marking scheme :
 Full Marks : +3 If ONLY the correct numerical value is entered as answer.
 Zero Marks : 0 In all other cases
[kaM 1 ¼vf/kdre vad% 36)
 bl [kaM esa ckjg (12) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa]tks f}&vadh; iw.kkZad

rFkk n'keyo f}&vadu eas gSA

 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd VªadsV@jkmaM

vkWQ (truncate/round-off) djsaA

 vadu ;kstuk %&

 iw.kZ vad % +3 ;fn flQZ lgh la[;kRed eku (Numerical value) gh mÙkj Lo:i ntZ fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esa

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19. A block is suspended at the end of a heavy string as shown. Find acceleration in m/s2 of a transverse
pulse created at bottom of the string. (Take g = 9.8 m/s 2)
n'kkZ;suqlkj ,d CykWd Hkkjh Mksjh ds ,d fljs ls vkyfEcr gSA Mksjh ds fuEure fljs ij mRiUu izxkeh LiUn dk Roj.k
dm/s2 esa Kkr dhft,A (yhft, g = 9.8 m/s2) [ST-VL]_(104) [M] [Easy]
[M.Bank_String Wave_Q.4.2.3.]

Ans. 49.00
Sol. If m = mass of block and  = linear mass density of string, at a distance x from block
;fn m = CykWd dk nzO;eku rFkk  = Mksjh dk js[kh; nzO;eku ?kuRo, CykWd ls x nwjh ij
(m   x )g
v=


 a = v· dv/dx
= g/2
= 4.9 m/s2
= 49 dm/s2 (decimeter/s2)

20. The only source of energy in a particular star is the fusion reaction given by -
32He4  6C12 + energy [M.Bank_ Modern Physics _4.15.2]
Masses of 2He4 and 6C12 are given [Made AJP Sir_2013-14]
m(2He4) = 4.0025u m(6C12) = 12.0000u
speed of light in vacuum is 3 × 108 m/s. Power output of star is 4.5 × 1027 watt. The rate at which the
star burns helium is n × 1013 kg/s. Here n is an integer. Find 3n. [MODERATE]

lay;u vfHkfØ;k esa fdlh fo'ks"k rkjs esa ÅtkZ dk dsoy ,d L=kksr fuEu izdkj fn;k tkrk gS -
32He4  6C12 + ÅtkZ
2
He4 rFkk 6C12 ds nzO;eku fn;s x;s gSA
m(2He4) = 4.0025u m(6C12) = 12.0000u
fuokZr esa izdk'k dh pky 3 × 108 m/s gSA rkjs dh fuxZr 'kfDr 4.5 × 1027 watt gSA rkjs esa ghfy;e ds tyus dh nj
n × 1013 kg/s gSA ;gk¡ n ,d iw.kkZad gSA 3n dk eku Kkr dhft,A
Ans. 24.00
Sol. Fraction of mass converted in energy ÅtkZ esa :ikUrfjr nzO;eku dk v{k
3  4 .0 0 2 5  1 2 .0 0 0 0 0 .0 0 7 5 R a te o f lo s s o f m a s s nzO;eku dh gkfu dk vuqikr
 =
3  4 .0 0 2 5 12 R a te o f b u rn in g tyus dh nj
12
Rate of burning tyus dh nj = 4
Rate of loss of mass. nzO;eku dh gkfu dh nj
75  10
12 P o w e r o u tp u t fuxZr ' kfDr
Rate of burning tyus dh nj = 4
 2
75  10 C C
2

27
12 4 .5  1 0
= 4
 8 2
75  10 (3  1 0 )

27
1 2  4 .5  1 0 54 2
= 12
= × 1015 = ×1015 = 8 × 1013 kg/s
75  9  10 9  75 25

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21. Intensity v/s wavelength of x-rays graphs are given for two different target elements. If number of
protons in an atom of target element-1 is 37 then number of protons in an atom of target element-2 will
be :
x-fdj.kksa dh rhozrk v/s rjaxnS/;Z ds e/; vkjs[k nks fHkUu /kkfRod y{;ksa ds fy, fn, x, gSA ;fn y{; /kkrq -1 ds
ijek.kq esa çksVkWu la[;k 37 gS] rks y{; /kkrq-2 ds ijek.kq esa çksVkWu la[;k gksxh : [Easy] [Made Kamal sir
2010-11] [M.Bank_Modern P._2.31] [M.Bank_ Modern Physics _4.7.2]

Ans. 19.00
Sol. By moseley's law, ekst+ys ds fu;e ls
 = a(z – b)
2 z1  1
=
1 z2  1

z1  1
2=
z2  1

36
2=
z2  1
z2 – 1 = 18
z2 = 19.

22. In YDSE distance between two slits is 1 mm. Distance of screen from two slits is 4 m. If light of wave

length 500 nm is used in experiment then what is distance (in mm) between 3 rd maxima and 5th minima

formed on same side of the central maxima :

[Easy] [HMS Sir Made 2015-16] [Used in 2015-16 TEST VIJETA (JP) 06-12-2015 (CT-4) P-1]

YDSE esa nks fLyVksa ds e/; nwjh 1 mm gSA insZa ,oa nks fLyVksa ds e/; nwjh 4 m gSA ;fn iz;ksx esa 500 nm rjaxnS/;Z

dk izdk'k mi;ksx esa ysrs gS] rc dsfUnz; mfPp"B ds ,d rjQ 3rd mfPp"B rFkk 5th fuEufu"B ds e/; nwjh ¼mm esa½

D;k gksxhA [M.Bank_Wave optics_ 4.2.1] [YE-YE]_(102) [E]

Ans. 03.00

3D
Sol. 3rd maxima mfPp"B =
d

9D
5th minima fuEufu"B =
2d

–7
3D 3  5  10  4
= = –3
= 3 mm
2d 2  10

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23. A constant force F is acting on the block of mass m = 2 kg which is moving vertically upward under
gravity. At time t = 0 upward velocity is 3 m/sec and at time t = 3 sec upward velocity becomes 6 m/sec.
Acceleration due to gravity is g = 10 m/sec2. Find the impulse provided by force F to block for time
interval of 3 seconds.
xq:Ro ds vf/kd Åij xfr'khy m = 2 kg nzO;eku ds CykWd ij fu;r cy F dk;Zjr gSA t = 0 ij Åij dh rjQ osx
3 m/sec rFkk t = 3 sec Åij dh rjQ osx 6 m/sec. gks tkrk gSA xq:Roh; Roj.k g = 10 m/sec2 gSA 3 sec. ds
vUrjky es CykWd dks cy F }kjk fn;k x;k vkosx Kkr djks &

[Moderate] [5 marks] [M.Bank_COM_4.5.4.] [History : Made SSP Sir, 2010-11]

Ans. 66.00 Ns
Sol. All impulse lHkh vkosx = mv2 – mv1
Ft – mgt = mv2 - mv1
Ft = mgt + mv2 – mv1
= (2) (10) (3) + (2) (6) – (2) (3)
= 60 + 6
Ft = 66 Newton second
= impulse by F }kjk vkosx

24. An old record player of 10 cm radius turns at 10 rad/s while mounted on a 30° incline as shown in the
figure. A particle of mass m can be placed any where on the rotating record. If the least possible
coefficient of friction  that must exist for no slipping to occur is , find 2 3 .
,d iqjkus fjdkWMZ Iys;j dh f=kT;k 10 cm gS tks fp=kkuqlkj 30° urry ij 10 rad/s ls ?kwe jgh gSA m nzO;eku ds
,d d.k dks ?kweus okys fjdkWMZ ij dgh Hkh j[kk tk ldrk gSA d.k o fjdkWMZ esa fQlyu ugha gksus ds fy, lEHko
U;wure ?k"kZ.k xq.kkad dk eku gS, rc 2 3 Kkr dhft,A

30°
[CM_CF] [103] [Moderate][M_Bank_CM_4.6.1.]
Ans. 06.00
Sol. f  mg sin  + mr2
µ mg cos  mg sin  + mr2

 r
2

or ;k µ  tan  +
g cos 

mg sin+ mr 2


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25. If angular acceleration of the uniform semi-circular disc just after release from rest position shown in
8g
figure is , then calculate N. (C is centre of semi-circular disc.) (2 = 10)
NR
fp=k esa n'kkZ;h xbZ fLFkfr ls fojkekoLFkk ls NksM+us ds Bhd ckn ;fn le:i v)Zo`Ùkkdkj pdrh dk dks .kh; Roj.k
8g
gS, rc N dh x.kuk dhft,A (C v)Zo`Ùkkdkj pdrh dk dsUnz gSA) (2 = 10) [Moderate]
NR
[RB_HT] [M.Bank_Rotation_Q.4.8.6]

[Made AKJ Sir_2013-14]

Ans. 30.00
Sol. Consider equation of torque about C
C ds lkis{k cyk?kw.kZ dh lehdj.k
2
 4R  mR

mg

= 
 3  2

8g 8g 8g
= = =
3R 2
3 R 30 R

26. A long capillary tube of radius r = 0.288 mm open at both ends is filled with water and placed vertically.

What will be the height of the column of water left in the capillary (in cm). The thickness of the capillary

walls is negligible. (surface tension of water is 72 dyne/cm, g = 1000 cm/sec 2 and density of water is 1

g/cm3) [M.Bank_Surface_Q.4.1.3]

r = 0.288 mm f=kT;k dh yEch ds'kuyh nksuks fljks ls [kqyh gS rFkk ikuh ls Hkjdj m/okZ/kj j[kh gSaA ds'kuyh esa

ikuh dh cph gqbZ Åpk¡bZ Kkr djksaA ds'kuyh dh nhokj dh pkSM+kbZ ux.; gSaA (ty dk i`"B ruko = 72 dyne/cm

rFkk g = 1000 cm/sec2) [ST_GE] [Easy]

Ans. 10.00

4T
Sol. = hg
r

4  72
= h × 1 × 1000
0 .0 2 8 8

2 T /r

2 T /r

h = 10 cm

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27. One end of a very long chain of linear mass density  is fixed to a cube of mass m and specific density
2/3 while the other end of chain is free. The cube attached with chain is immersed in deep water
container. If specific density of chain is 6, then find the height h (in mtres) above the surface of
container at which cube will float in equilibrium. (Given m/ = 50 metre) [Moderate]
[M.Bank_FL_Q.4.2.5.]
js[kh; nzO;eku ?kuRo  dh ,d yEch J`a[kyk dk ,d fljk nzO;eku m rFkk fof'k"V ?kuRo 2/3 ds ,d ?ku ls tqM+k
gS]rFkk nwljk fljk eqDr gSA J`a[kyk ls tqM+k ?ku ty ds xgjs ik=k esa Mqcks;k tkrk gSA ;fn J`a[kyk dk fof'k"V ?kuRo
6 gS, ?ku ds lkE;koLFkk esa rSjrs le; bldh ik=k dh ryh ls Å¡pkbZ h (ehVj ek=kd esa) Kkr dhft,A (fn;k x;k gS
m/ = 50 metre) [Made ABJ, 2009-10] [AB-OT-1 also]

Ans. 30.00
Sol. Weight of cube + straight chain = (m + h) g AIOT-XII (P,F,R)Q.57_Paper-2
 3m h 
Buoyant force =    g
 2 6 
At equilibrium, weight = Buoyant force
3m h
m + h = 
2 6
m 5h 3m
=  h=
2 6 5
Sol. ?ku + J`a[kyk dk Hkkj = (m + h) g
 3m h 
mRIykou cy =    g
 2 6 
lkE;koLFkk esa, Hkkj = mRIykou cy
3m h
m + h = 
2 6
m 5h 3m
=  h=
2 6 5

28. Bulk modulus for a material to used as a filament of an electric lamp is 4 × 1011 Pa. Modulus of rigidity
of this material is 3 × 1011 Pa. If ratio of young's modulus and poission's ratio is given by x 2 × 1011 Pa
then find the value of 3x. [SSI Sir Made 2015-16]
4 × 1011 Pa ds cYd xq.kkad ds nzO; dks ,d fo|qr ySEi rarq ds fy, O;ogkj fd;k tkrk gSA nzO; ds n`<+rk xq.kkad 3
× 1011 Pa gSA ;fn ;ax xq.kkad ,oa ikWbtu vuqikr x2 × 1011 Pa gS rks 3x dk eku Kkr dhft,A [SSI Sir Made
2015-16] [M.Bank_Elast._ Q.4.3.3]
Ans. 18.00
Sol. Young's modulus ;ax xq.kkad = y
Bulk modulus cYd xq.kkad = B
Modulus of rigidity n`<+rk xq.kkad = 
11 11
9B  9  4  10  3  10 36
 Then rc Y = = 11 11
= × 1011 Pa
3B   3  4  10  3  10 5
36 11
 10
Y 1
Poisson's ratio ikWbtu vuqikr  = –1= 5
11
1 =
2 2  3  10 5
36 11
 10
Y 5
 = 36 × 1011 = 62 × 1011
 1
5

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29. A cubical block of side 1 0 1 0 cm is connected to a smooth and uniform disc of mass 20 g through an
ideal string as shown. The block is placed on a thin liquid layer of thickness 0.2 mm. If center of the disc
move downward with constant speed of 2 cm/sec after the system is released. If coefficient of viscosity
x
of liquid is Pa-sec. then find 5x (Take g = 10 m/s2) [EC-GE] (104)
1000
[Moderate] [M.Bank_Viscosity_4.1.2]

Block
Thin liquid layer

Fixed surface

Disc
mg

1 0 1 0 cm Hkqtk dk ,d ?kukdkj CykWd 20 g nzO;eku dh ,d fpduh ,oae~ ,dleku pdrh ls fp=k esa n'kkZ;s
vuqlkj vkn'kZ Mksjh }kjk tqM+k gqvk gSA CykWd dks 0.2 mm eksVkbZ dh ,d iryh nzo ijr ij j[kk tkrk gSA fudk;
dks NksM+us ds i'pkr~ pdrh dk dsUnz uhps dh vksj fu;r pky 2 cm/sec ls xfr'khy gSA ;fn nzo dk ';kUrk xq.kkad
x
Pa-sec gSA rc 5x Kkr dhft,A (g = 10 m/s2 ysosaA)
1000

CykWd
nzo dh iryh ijr
fLFkj lrg
pdrh
mg

Ans. 25.00
Sol. By constraint relation, velocity of block is 2V. As acceleration for Block and disc is zero, for disc 2T =
mg
cfU/kr xfr ls CykWd dk osx 2V gSA pwafd CykWd o pdrh dk Roj.k 'kwU; gSA pdrh ds fy, 2T = mg gS %

a=0
2V
T
F
T T
V
a=0
mg

mg
T=
2
and for block T = f (rFkk CykWd ds fy, T = f)
mg 2V
 = A
2 d
m gd
   =
4AV
3 3
20  10  1 0  0 .2  1 0
= 3 4 2
4  10  10  2  10
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 = 5 × 10–3 NSm–2

7
30. If the ratio of the concentration of electrons to that of holes in a semiconductor is and the ratio of
5
7
currents is , then what is the ratio of their drift velocities ?
4
[AIEEE 2006] [M.Bank_Friction_Q.10.10.12]
7 7
fdlh v)Zpkyd esa bysDVªku o dksVj dh lkUnzrkvksa dk vuqikr gS o /kkjkvksa dk vuqikr gSA rc viogu osxksa
5 4
dk vuqikr D;k gksxk A [Physics for AIEEE(D.B.Singh)_Pg.814_Level-2_Q.45]
Ans. 01.25
Sol. I = neAvd
e n e  ( v d )e
=
h n h  ( v d )h

ne 7 e 7
Here, = , =
nh 5 h 4

7 7 ( v d )e ( v d )e 5 7 5
=   =  = .
4 5 ( v d )h ( v d )h 7 4 4

SECTION – 2 : (Maximum Marks : 24)

 This section contains SIX (06) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct answers,
then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark
[kaM 2 : (vf/kdre vad : 24)
 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk
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 x;k gS vkSj pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
 dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs

31. Consider a vernier caliper. Least count of main scale is 1mm. There are 20 equispaced marks on
vernier scale. When nothing is put between the jaws, zero of main scale lies between zero and first
division of vernier scale and and 15th division of vernier exactly coincide with one of the main scale
division. When zero of vernier is matched with zero of main scale, 20 th division of vernier exactly
coincides with 25th division of main scale. To measure the side of a cuboid, it is kept between the jaws
of vernier caliper, it is now observed that 18th division of vernier exactly coincides with 32 nd division of
main scale. Choose the correct option(s).
[Made by AJP Sir 2018-19] [MS-MS] [105] [M.Bank_ Measurement and Error _Q.2.1.5]
(A*) Least count of vernier scale is 0.25 mm
(B) Zero error is -0.25 mm
(C*) Side of cuboid is 10.25 mm
(D) Side of cuboid is 9.25 mm
,d ofuZ;j dsfyij iSekus ds eq[; iSekus dk vYiRekad 1mm gSA blds ofuZ;j iSekus ij cjkcj nwjh ij
20 Hkkx vafdr gSA tc blds tcM+ksa ds e/; dksbZ oLrq ugha gS] rks eq[; iSekus dk 'kwU;] ofuZ;j iSekus ds 'kwU; rFkk
izFke Hkkx ds e/; gS] ,oa ofuZ;j iSekus dk 15th Hkkx eq[; iSekus ds ,d Hkkx ds lkFk iw.kZ :i ls lEikrh gSA tc
ofuZ;j iSekus ds 'kwU; dks eq[; iSekus ds 'kwU; ls feyk;k tkrk gS] rks ofuZ;j iSekus dk 20th Hkkx] eq[; iSekus ds 25th
Hkkx ds lkFk lEikrh gksrk gSA ,d ?kukHk dh Hkqtk Kkr djus ds fy,] bldks ofuZ;j dsfyij ds tcM+ksa ds e/; j[kk
tkrk gS] rks ofuZ;j iSekus dk 18th Hkkx eq[; iSekus ds 32nd Hkkx ds lkFk lEikrh gks tkrk gS] rks lgh
fodYi@fodYiksa dk p;u dhft,A
(A*) ofuZ;j iSekus dk vYiRekad 0.25 mm gSA
(B) 'kwU; =kqfV –0.25 mm gSA
(C*) ?kukHk dh Hkqtk 10.25 mm gSA
(D) ?kukHk dh Hkqtk 9.25 mm gSA

0 5 10 15 20 25 Main scale

Sol.
Vernier scale

0 4 8 12 16 20
d d
2d 2d
3d 3d

d = 0.25 mm

LC = 0.25 mm

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 zero error 'kwU; =kqfV = – 0.75 mm

while taking the reading zero of vernier will be between 9th and 10th of main scale division.

ikB~;kad ysrs le; ofuZ;j iSekus dk 'kwU;] eq[; iSekus ds 9th rFkk 10th Hkkx ds e/; gSA
Reading = 9mm + 0.50 mm + 0.75 m = 10.25 mm
ikB~;kad = 9mm + 0.50 mm + 0.75 m = 10.25 mm

32. In the given figure a ball strikes a rod elastically and rod is hinged smoothly at point A. Then which of
the statement(s) is/are correct for the collision? [M.Bank_Rotation_5.3] [EASY]
fn;s x;s fp=k esa ,d xsan ,d NM+ ij çR;kLFk :i ls Vdjkrh gS vkSj NM+ fcUnq A ij ?k"kZ.kghu dhyfdr gS rks
VDdj ds fy, dkSulk@ls dFku lR; gS@gSa ? [M.Bank_Rotation_Q.2.7.1]

(A) linear momentum of system (ball + rod) is conserved

(B*) angular momentum of system about hinged point A is conserved
(C*) kinetic energy of system is conserved
(D) linear momentum of ball is conserved.
(A) fudk; (xsan + NM+) dk js[kh; laosx lajf{kr gSA
(B*) dhyfdr fcUnq A ds ifjr% fudk; dk dks.kh; laosx lajf{kr gSA
(C*) fudk; dh xfrt ÅtkZ lajf{kr gSA
(D) xsan dk js[kh; laosx lajf{kr gSA
33. Consider a string fixed at one end and attached to a ring on other end as shown. Ring is around a
smooth rod as shown such that it is free to move in y-axis. Two waves travel on this string. Equation of
the waves are :
Wave-1 : y = A sin (t – kx) [Moderate] [M.Bank_String Wave_Q.2.3.2.]
Wave-2: z = A sin (t – kx)
Both waves get reflected by the attached to the ring.
Then :
,d jLlh ftldk ,d fljk n`<+ fdyfdr gS rFkk nwljk fljk ,d oy; ls tqM+k gqvk gSA oy; ,d fpduh jksM esa gS
rFkk fp=kkuqlkj y-v{k ij pyus ds fy, Lora=k gSA nks rjaxsa jLlh ij pyrh gSaA rjax dh lehdj.k gS :
rjax-1 : y = A sin (t + kx)
rjax-2: z = A sin (t – kx)
nksuksa rjaxsa oy; ls Vdjkdj ijkofrZr gksrh gS
rc :
y

x
z
z-axis is out of plane of paper
(A*) No phase difference will be added in wave-1 due to reflection.
(B)  phase difference will be added in wave-1 due to reflection.
(C) No phase difference will be added in wave-2 due to reflection.
(D*)  phase difference will be added in wave-2 due to reflection.
(A*) rjax -1 esa ijkorZu ds ckn dksbZ dykUrj ugha gskxk
(B) rjax-1 esa ijkorZu ds i'pkr~ dykUrj vkrk gSA
(C) rjax -2 esa ijkorZu ds i'pkr~ 'kwU; dykUrj gksrk gS
(D*) rjax -2 esa ijkorZu ds i'pkr~  dykUrj gksrk gSA
Sol. (A) For wave (1) ring can slide up and down so if act like rare medium and no phase change.

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 (A)rjax (1) ds fy, oy; Åij ,oa uhps fQly ldrh gS] rFkk ;fn fojy ek/;e ds rjg O;ogkj djs rks dyk
vifjofrZr jgrh gSA
(D) For wave (2) oscillations are in z direction and ring can't move in z-direction. So if act like denser
medium and there is a phase change of  occures.
rjax (2) ds fy, z fn'kk esa nkSyu rFkk oy; z-fn'kk esa xfr ugha dj ldrh gSA vr% ;fn la?ku ek/;e dh rjg
O;ogkj djs] rks dyk ls cny tkrh gSA

34. Photons of energy 5 eV are incident on cathode. Electrons reaching the anode have kinetic energies
varying from 6eV to 8eV. [Moderate]
5 eV ÅtkZ ds QksVkWu dSFkksM+ ij vkifrr gksrs gSaA ,suksM ij igq¡pus okys bysDVªkWuksa dh xfrt ÅtkZ 6eV ls 8eV ds
e/; gS :- [M.Bank_ Modern Physics _2.1.1.]
[Made 2005 PKS]

(A*) Work function of the metal is 2 eV

(B) Work function of the metal is 3 eV
(C) Current in the circuit is equal to saturation value.
(D*) Current in the circuit is less than saturation value.
(A*) /kkrq dk dk;ZQyu 2 eV gSA (B) /kkrq dk dk;ZQyu 3 eV gSA
(C) ifjiFk esa /kkjk lar`Ir eku dh gSA (D*) ifjiFk esa /kkjk lar`Ir eku ls de dh gSA

Sol. KEmax = (5 – ) eV

when these electrons are accelerated through 5V,

they will reach the anode with maximum energy = (5 –  + 5)eV

 10 –  = 8

 = 2eV Ans.

Current is less than saturation current because if slowest electron also reached the plate it would have

5eV energy at the anode, but there it is given that the minimum energy is 6eV.

gy KEmax = (5 – ) eV

tc ;s bysDVªkWu 5V ls Rofjr fd;s tkrs gSa]

;s ,suksM ij igq¡psaxs vf/kdre ÅtkZ = (5 –  + 5)eV ls

 10 –  = 8

 = 2eV Ans.

/kkjk] lar`Ir /kkjk ls de gS] D;ksafd ;fn lcls /khek bysDVªkWu Hkh IysV ij igq¡prk gS rks bldh ÅtkZ ,suksM ij 5eV

gksrh ijUrq ;gk¡ U;wure ÅtkZ 6eV nh xbZ gSA

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35. A penguin of mass m stands at the right edge of a sled of mass 3m and legnth. The sled lies on
frictionless ice. The penguin starts moving towards left, reaches the left end and jumps with a velocity u
and at an angle  relative to ground. (Neglect the height of the sled)
[M.Bank_COM_2.2.3] [Moderate] [Made MP sir 2010-11]
m nzO;eku dk isafXou yEckbZ rFkk 3m nzO;eku dh flYyh ds Åij nka;s fljs ij [kM+k gqvk gSA flYyh ?k"kZ.kjfgr
cQZ ds Åij j[kh gqbZ gSA isafXou ck,a rjQ pyuk çkjEHk djrk gS rFkk ck,a fljs ij igq¡pdj u osx ds lkFk /kjkry
ls  dks.k ij Nykax yxkrk gSA (flYyh dh Å¡pkbZ dks ux.; ekusa)

(A*) Till the penguin reaches the left end, the sled is displaced by
4

(B) Till the penguin reaches the left end, the sled is displaced by
3
2
4 u s in 2 
(C*) After jumping, it will fall on the ground at a distance from the left end of the sled.
3 g
2
3 u s in 2 
(D) After jumping, it will fall on the ground at a distance from the left end of the sled.
4 g

(A*) isafXou ds ck,a fljs rd igq¡pus ij flYyh foLFkkfir gksrh gSA

4

(B) isafXou ds ck,a fljs rd igqp

¡ us ij flYyh foLFkkfir gksrh gSA
3
2
4 u s in 2 
(C*) Nykax yxkus ds i'pkr isfa Xou flYyh ds ck,a fljs ls nwjh ij /kjkry ij fxjrk gSA
3 g
2
3 u s in 2 
(D) Nykax yxkus ds i'pkr isafXou flYyh ds ck,a fljs ls nwjh ij /kjkry ij fxjrk gSA
4 g
m 1S 1  m 2 S 2
Sol. (A) Sm =
m1  m 2

(3 m ) (  x )  (m ) (  n)
0=
3m  m

x=
4
(C)

2u s in 
T=
g

1  u s in 2  
2
 u c o s    2 u s in  
Displacement of sled in this time =     =  
 3   g  3  g 


1  u s in 2  
2
 u c o s    2u s in  
bl le; esa flYyh dk foLFkkiu =     =  
 3   g  3  g 


4  u s in 2  
2

Total distance dqy nwjh =  

3  g 


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36. Which of the following are correct
(A*) According to wave theory of radiation, every radiation irrespective of wavelength will cause photo-
electric effect. [Easy] [M.Bank_ Modern Physics _2.2.1]
(B) x-ray photon are less energetic than visible light photon.
(C) Maximum kinetic energy of photo-electrons K.E.max is directly proportional to the frequency of the
incident radiation.
(D*) Einstein’s photoelectric equation is law of conservation of energy. [Made DKJ, 2009]
fuEu esa ls dkSu&lk lgh gS &
(A*) fofdj.k ds rjax fl)kUr ds vuqlkj çR;sd fofdj.k ds dkj.k] çdk'k fo|qr çHkko gksrk gSA (pkgs mldh
rjaxnS/;Z dqN Hkh gks)
(B) x–fdj.k QksVkWu n`'; çdk'k QksVkWu dh rqyuk esa de ÅtkZoku gSA
(C) QksVks bysDVªkWu dh vf/kdre xfrt ÅtkZ K.E.max vkifrr fofdj.k dh vko`fÙk ds lh/ks lekuqikrh gSA
(D*) vkbUlVhu çdk'k fo|qr lehdj.k] ÅtkZ laj{k.k dk fu;e gSA [Made DKJ, 2009]
Sol. Theoritical

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 ADVANCED PATTERN
PART TEST-4(APT-4)
TARGET : JEE (MAIN+ADVANCED) 2021
COURSE : VIJETA(JP) | BATCH : (JPA*,IP, PA1)
QUESTIONS, HINTS & SOLUTIONS
CHEMISTRY-III
PAPER-2
SECTION – 1 : (Maximum Marks : 36)
 This section contains TWELVE (12) questions. The answer to each question is NUMERICAL VALUE with
two digit integer and decimal upto two digit.
 If the numerical value has more than two decimal places truncate/round-off the value to TWO decimal
placed.
 Marking scheme :
 Full Marks : +3 If ONLY the correct numerical value is entered as answer.
 Zero Marks : 0 In all other cases

[kaM 1 ¼vf/kdre vad% 36)

 bl [kaM esa ckjg (12) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa]tks f}&vadh; iw.kkZad
rFkk n'keyo f}&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd VªadsV@jkmaM
vkWQ (truncate/round-off) djsaA
 vadu ;kstuk %&
 iw.kZ vad % +3 ;fn flQZ lgh la[;kRed eku (Numerical value) gh mÙkj Lo:i ntZ fd;k x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esa

37. 1 mol of a real gas obeys P(Vm – b) = RT; where 'b' and 'R' are constants. If the compressibility factor of
gas is 1.11 and occupied volume of the gas is Xb then determine value of X/2.
1 eksy okLrfod xSl P(Vm – b) = RT dh ikyuk djrh gS; tgk¡ 'b' vkSj 'R' fLFkjkad gSA ;fn xSl dk lEihM~;rk
xq.kkad 1.11 gS vkSj xSl }kjk xzg.k fd;k x;k vk;ru Xb gS rks X/2 dk eku Kkr dhft,A
Ans. 05.00
Pb
Sol. Z=1+
RT
Pb
or 1.11 – 1 =
RT
RT b
or 
P 0.11
b
or (Vm – b) =
0.11
or Vm = 10 b

38. 10% sites of a catalyst bed have adsorbed H2. On heating H2 gas is evolved from sites and collected at
0.03 atm and 300 K in a small vessel of 2.46 cm 3. Number of sites available is 5.4 × 1017 per cm2 and
surface area is 1000 cm 2. Find out the number of surface sites occupied per molecule of H 2 (R = 0.082
atm L/ mol K, NA = 6 × 1023)
,d mRizsjd fcLrj (bed) ds 10% LFky vf/k'kksf"kr H2 j[krs gSA xeZ djus ij H2 xSl LFkyks ls mRlftZr gksrh gS
rFkk bls 2.46 cm3 ds ,d NksVs ik=k es 0.03 atm rFkk 300 K ij laxzfgr fd;k tkrk gSA miyC/k LFkyksa dh la[;k
5.4 × 1017 izfr cm2 gS rFkk i`"Bh; {kS=kQy 1000 cm2 gSA H2 ds izfr v.kq }kjk ?ksjs x;s i`"Bh; LFkyks dh la[;k Kkr
dhft, (R = 0.082 atm L/ mol K, NA = 6 × 1023)A
Ans. 30.00

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 2.46
PV 0.03 
Sol. No of moles of H2 = = 1000 = 3 ×10–6
RT 0.082  300
Number of molecules of H2 = 3 × 10-6 × NA
=3 × 10-6 × 6 × 1023
= 18 × 1017
Total no. of sites available = 5.4 × 1017
10
No. of sites occupied by H2 = 5.4 × 1017 × 1000 × = 54 × 1018
100
54  1018
No. of sites occupied per molecule of H2 = = 30
18  1017
2.46
PV 0.03 
Sol. H2 ds eksyks dh la[;k = = 1000 = 3 ×10–6
RT 0.082  300
H2 ds v.kqvks dh la[;k = 3 × 10-6 × NA
=3 × 10-6 × 6 × 1023
= 18 × 1017
miyC/k LFkyks dh dqy la[;k = 5.4 × 1017
10
H2 }kjk ?ksjs LFkyks dh la[;k = 5.4 × 1017 × 1000 × = 54 × 1018
100
54  1018
H2 ds izfr v.kq }kjk ?ksjs LFkyks dh la[;k = = 30
18  1017

39. Given two separate reactions:

(I) (A)  Product
(II) (B)  Product,
Reaction (I) follows first order kinetics while reaction (II) follows second order kinetics. Both the
reactions have same half lives. When the initial concentration of (A) is ‘n’ times that of (B), then the rate
of reaction (I) is 1.386 times than that of rate of reaction (II) at the start of reaction. The value of n is:
nks i`Fkd vfHkfØ;k;sa nh x;h gS &
(I) (A)  mRikn]
(II) (B)  mRikn,
vfHkfØ;k (I) izFke dksfV cyxfrdh dk vuqlj.k djrh gS tcfd vfHkfØ;k (II) f}rh; dksfV cyxfrdh dk vuqlj.k
djrh gSA nksuksa vfHkfØ;k;sa leku v)Z vk;q j[krh gSA tc (A) dh izkjfEHkd lkUnzrk (B) dh 'n' xquk gS rks vfHkfØ;k
(I) dh nj vfHkfØ;k ds izkjEHk ij vfHkfØ;k (II) dh nj dh 1.386 xquk gSA n dk eku gS &
Ans. 02.00
Sol. For (A), rate = kA[A]
t1/ 2 A  0.693
kA
For (B), rate = kB[B]2
t1/ 2 B  1 , where a is the conc. of B at the start of reaction
a.k B
Since half-lives are same
0.693 1
 
kA a.k B
kA
  0.693a
kB
Since initial concentration of (A) is n times that of (B).
 [A] = na
rA k A na r
   2 , Given A = 1.386
rB k B a rB

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 na
 1.386 = 0.693 a ×
a2
1.386
 n 2
0.693
Sol. (A) ds fy, , nj = kA[A]

t1/ 2 A  0.693
kA
(B), ds fy, , nj = kB[B]2
t1/ 2 B  1
, tgk¡ a vfHkfØ;k ds izkjEHk ij B dh lkanzrk gSA
a.k B
pwafd v)Zvk;q leku gSA
0.693 1
 
kA a.k B
kA
  0.693a
kB
pwafd (A) dh izkjfEHkd lkUnzrk (B) dh n xquk gSA
 [A] = na
rA k A na rA
   , fn;k gS = 1.386
rB k B a2 rB
na
 1.386 = 0.693 a ×
a2
1.386
 n 2
0.693

40. The ratio of number of nuclei of 1H3 to 1H1 in a sample of water is 3 × 10–18 : 1. Tritium undergoes decay
to He having t1/ 2  12.3 years . Ratio of number of nuclei of 1H3 to 1H1 in 10 g of such a sample is
p × 10–20 after 24.6 year. Determine value of p.
ty ds ,d izkn'kZ esa 1H3 o 1H1 ds ukfHkdksa dh la[;k dk vuqikr 3 × 10–18 : 1 gSA fVªfV;e t1/ 2  12.3 o"kZ j[kus
okyk He esa {k; n'kkZrk gSA bl izdkj ds 10 g izkn'kZ esa 1H3 o 1H1 ds ukfHkdksa dh la[;k dk vuqikr 24.6 o"kZ ds
i'pkr~ p × 10–20 gSA p dk eku Kkr dhft,A
Ans. 75.00
Sol. ratio of number of moles = 1H1 : 1H
3

n : 3 × 10–18

n : 1.5 × 10–18

n : 0.75 × 10–18

Sol. eksyks dh la[;k dk vuqikr = 1H1 : 1H

3

n : 3 × 10–18
o"kZ
n : 1.5 × 10–18
o"kZ
n : 0.75 × 10–18

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41. 5.0 g of a sample containing (NH4)2SO4 and inert impurity (X) was boiled with excess of NaOH and the
NH3(g) so produced was absorbed in 200 ml of 0.5 M H 2SO4 solution in another vessel. The unreacted
H2SO4 required 400 ml of 0.4 M solution of NaOH for exact neutralization. Calculate weight % of
nitrogen in given sample.
5.0 xzke dk ,d uewuk tks fd (NH4)2SO4 ,oa vfØ; v'kq)h (X) ;qDr gS dks NaOH ds vkf/kD; ds lkFk xeZ fd;k
tkrk gSA ftlls mRiUu NH3(g) dks 200 ml, 0.5 M H2SO4 ;qDr ,d vU; ik=k esa vo'kksf"kr fd;k tkrk gSA bl
izdkj vuqi;ksxh H2SO4 dks iw.kZ:is.k mnklhu ds fy, 400 ml, 0.4 M NaOH dh vko';drk gksrh gS rks fn;s x,
uewus esa ukbVªkstu dk Hkkj % gksxkA
Ans. 11.20
Sol. (NH4)2SO4 + 2NaOH  Na2SO4 + 2NH3 + H2O
H2SO4 + 2NH3 (NH4)3SO4
H2SO4 + 2NaOH  Na2SO4 + 2H2O
400 0.4
m. moles of unreacted H2SO4 = = 80
2
m. moles of H2SO4 reacted with NH3 = 200 × 0.5 – 80 = 20
m. moles of NH3 reacted = 2 × 20
 m. moles of (NH4)2SO4 present in sample = 20;
moles of nitrogen in sample = 20 × 2 = 40
wt. of nitrogen = 40 × 10–3 × 14 = 0.56
0.56
% of nitrogen in sample = × 100 = 11.2
5

42. 1 g sample containing KO2 and some inert impurity is dissolved in excess of aqueous HI solution and
finally diluted to 100 ml. The solution is filtered off and 20 ml of filtrate required 15 ml, 0.4 M Na 2S2O3
solution to reduce the liberated iodine. If mass% of KO 2 in original sample is y % then find y/35.5 value?
KO2 rFkk dqN vfØ; v'kqf) ;qDr 1 g izkn'kZ dks tyh; HI foy;u ds vkf/kD; esa ?kksyk tkrk gS rFkk vUr esa
100ml rd ruq fd;k tkrk gSA foy;u dks Nkuk tkrk gS rFkk 20 ml Nfu=k dks fu"dkflr vk;ksMhu dks vipf;r
djus ds fy, 15 ml 0.4 M Na2S2O3 dh vko';drk gksrh gSA ;fn okLrfod izkn'kZ esa KO2 dk nzO;eku izfr'kr y%
gS rks y/35.5 eku Kkr dhft,A
Ans. 02.00
Sol. The balanced redox reaction is
2KO2 + 6H  2KOH + 2H2O + 32
meq. of hypo = 15×0.4 = 6 = meq of I2
Total I2 liberated = 15 m mol
m mol of KO2 in original sample = 10
mass % = 10×10–3 × 71 × 100 = 71% = y
Sol. larqfyr jsMkWDl vfHkfØ;k gSA
2KO2 + 6HI  2KOH + 2H2O + 3I2
gkbiks dk feyh rqY;kad = 15×0.4 = 6 = I2 ds feyh rqY;kad
fu"dkflr dqy I2 = 15 m mol.
okLrfod izkn'kZ esa KO2 ds feyheksy = 10
nzO;eku % = 10×10–3 ×71×100 = 71% = y

43. KMnO4 + HCl(conc.) 
In the given reaction when balanced with simplest integer coefficients, determine the sum of coefficients
of all Cl having substances.

KMnO4 + HCl(conc.) 
nh xbZ vfHkfØ;k dks tc ljyre iw.kk±d xq.kkadks ls lUrqfyr fd;k tkrk gS rks Cl ;qDr lHkh inkFkksZ ds xq.kkdksa dk
;ksx Kkr dhft,A
Ans. 25.00
Sol. 2KMnO4 + 16HCl 2KCl + 2MnCl2 + 8H2O + 5Cl2

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44. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using
alcoholic KOH is
,sYdksgkWyh KOH }kjk 3-czkseks-3-lkbDyksisf.VygsDlsu ds fogkbMªksczksfeuhdj.k ls lEHko lHkh ,Ydhuksa dh la[;k gSA
Ans. 05.00

Sol.

45. CH3O— —O— —O— —OCH3

How many moles of HI are consumed in above reaction?

(Report your answer by multiplying with 5)
mijksDr vfHkfØ;k esa HI ds fdrus eksy iz;qDr ¼[kpZ½ gksrs gSa \
(5 ls xq.kuQy ds i'pkr~ mÙkj crkb;s½
Ans. 10.00

Sol. CH3—O— —O— —O— —O—CH3

H H
(1) (2)
Benzene oxygen bond has partial double bond character.
csUthu vkWDlhtu ca/k] vkaf'kd f}ca/k xq.k j[krk gSA

46.

Double bond equivalent (DU) of D is :

OH
OH
ruq HNO3
A(vf/kd ok"i'khy) + B(de ok"i'khy)
(i) Sn/HCl
C D
(ii) NaNO2 / HCl {kkjh; ek/;e
D dh D.U. gS &
Ans. 09.00

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Sol. 
dil HNO3
 + 
(i)Sn / HCl

(ii)NaNO2 / HCl

HO N=N OH

Double bond equivalent of D is 9.

D dh D.U. 9 gSA


NaSH OH (X)
47. CH2–OH 
PCl5
 (X)       CH2–S–CH2
The number of times where SN2 reaction taken place in above reaction sequence is :
(Report your answer by multiplying with 5)
mijksDr vfHkfØ;k vuqØe esa fdruh ckj SN2 vfHkfØ;k lEiUu gksrh gS \
(5 ls xq.kuQy ds i'pkr~ mÙkj crkb;s½
Ans. 15.00

Sol. CH2–OH 

PCl5 NaSH
 PhCH2Cl   PhCH2SH

OH
  PhCH2S– 
(X)
 CH2–S–CH2

48. This question has 2 parts A and B, give answer as A + B.

bl iz'u esa nks Hkkx A vkSj B, A + B ds :i esa mÙkj nhft,A
(A) How many alkene/s react faster than propene with dil.H2SO4?
fuEu esa ls fdruh ,Ydhu] ruq H2SO4 ds lkFk izksihu dh rqyuk esa rhozrk ls fØ;k djrh gSa\
Ph
Ph CH3O
(a) (b) (c) (d)
Ph
O
(e) (f) (g) (h) Cl
(B) Consider all possible isomeric ketones, including stereoisomers of MW = 100. All these isomers are
idependently reacted with NaBH4 (Note: stereoisomers are also reacted separately). The total number
of ketones that give a racemic product(s) is/are
f=kfoe leko;oksa (stereoisomers) dks lfEefyr djrs gq, v.kq Hkkj = 100 okys lHkh leko;oh dhVksuksa ij fopkj
dhft,A bu lHkh leko;oksa dks NaBH4 ls Lora=k :i ls vfHkd`r fd;k x;k ¼uksV% f=kfoe leko;oksa dks Hkh vyx ls
vfHkd`r fd;k x;k½A jsflfed mRikn nsus okys mu dhVksuksa dh lEiw.kZ la[;k crk;saA
Ans. 06.00 + 05.00 = 11.00
Sol. (A) (a, b , c ,d , e , g)
rate of addition of E  stability of cation
E ds ;ksx dh nj  èkuk;u dk LFkkf;Ro
CnH2nO, MW = 12n + 2n + 16 = 100   14n = 84 n=6
Six such ketones exist : (N% fdVksu mifLFkr gS %)

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 O
O O
(B) C6H12O O O * O

OH OH
OH
* * * * *
* OH R S
OH OH
(+) & (–) (+) & (–) (+) & (–) (+) & (–) diastere.
(+) & (–) diaste.
(foofje:ih)
(foofje:ih)
Thus, 5 such ketones give a racemic mixture. (bl izdkj 5 fdVksu jslsfed feJ.k nsrs gSA)

SECTION – 2 : (Maximum Marks : 24)



 This section contains SIX (06) questions.

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct
 For each question, marks will be awarded in one of the following categories :
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen
and both of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and
it is a correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –2 In all other cases.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct answers,
then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A) and (D) will get +2 marks
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –2 mark

[kaM 2 : (vf/kdre vad : 24)

 bl [kaM esa N% (06) iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
 vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
 vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
 vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk
x;k gS vkSj pquk gqvk fodYi lgh fodYi gSA
 'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
 _.k vad % –2 vU; lHkh ifjfLFkfr;ksa esaA
 mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
 dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
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  dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
 dsoy fodYi (A) pquus ij +1 vad feysaxs ’
 dsoy fodYi (B) pquus ij +1 vad feysaxs ’
 dsoy fodYi (D) pquus ij +1 vad feysaxs ’
 dksbZ Hkh fodYi u pquus ij ¼vFkkZr~ iz'u vuqÙkfjr jgus ij½ 0 vad feysaxs vkSj
 vU; fdlh fodYiksa ds la;kstu dks pquus ij –2 vad feysaxs

49. Which of the following statement(s) according to the Arrhenius equation is/are correct ?
fuEu esa ls dkSulk@dkSuls dFku vkjsfu;l lehdj.k ds vuqlkj lgh gS@gSa \
(A*) When the activation energy of the reaction is zero, the rate becomes independent of temperature
 E / RT
(B*) The term e a represents the fraction of the molecules having energy in excess of the threshold
value
(C) Lower the magnitude of activation energy, stronger is the temperature dependence of the rate
constant
(D*) The pre-exponential factor is a measure of the rate at which collisions occur, irrespective of their
energy
(A*) tc vfHkfØ;k dh lfØ;.k ÅtkZ 'kwU; gksrh gS] rks nj rki ls Lo=kar gks tkrh gSA
 E / RT
(B*) in e a nsgyh eku ds vkf/kD; esa ÅtkZ j[kus okys v.kqvksa ds izHkktks dks iznf'kZr djrk gSA
(C) lfØ;.k ÅtkZ dk ifjek.k de gksus ij] nj fu;rkad dh rki fuHkZjrk izcy gksrh gSA
(D*) mudh ÅtkZ ij fopkj fd, fcuk] iwoZ&pj?kkrkadh xq.kkad (pre-exponential factor) VDdjksa dh nj (rate of
collisions) dk ekid gSA
 E / RT
Sol. (A) At zero activation energy k = A e a , k = A the rate becomes independent of temperature.
(B) true
(C) High activation energy reactions are more temperature sensitive. So higher the magnitude of
activation energy, stronger is the temperature dependence of the rate constant.
(D) fact
Sol. (A) 'kwU; lfØ;.k ÅtkZ ij k = A e Ea / RT , k = A nj rki Lora=k gks tkrh gSA
(B) lR;
(C) mPp lfØ;.k ÅtkZ vfHkfØ;k;sa vf/kd rki laosnh gSaA vr% lfØ;.k ÅtkZ dk ifjek.k mPp gksus ij nj fu;rkad
dh rki fuHkZjrk izcy gksrh gSA
(D) rF;

50. 
NaNO3 Solid (X) + Gas (A)

800ºC

Solid (Y) + Gas (A) + Gas (B)

Gas B, 
Mg   Product   Gas (C)
2 H O

Which of the following is/are correct ?

(A*) Gas B is diamagnetic in nature
(B*) Gas C is colourless gas
(C*) Potassium metal will form paramagnetic species as major product on heating with gas A
(D) All alkali metals form diamagnetic species on heating with gas B

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 
NaNO3 Bksl (X) + xSl (A)

800ºC

Bksl (Y) + xSl (A) + xSl (B)

xSl B, 
Mg  mRikn  H2O
 xSl (C)
fuEu esa ls dkSulk@dkSuls lgh gS@gSa \
(A*) xSl B izfrpqEcdh; izÑfr dk gSA
(B*) xSl C jaxghu xSl gSA
(C*) iksVsf'k;e /kkrq xSl A ds lkFk xeZ djus ij eq[; mRikn ds :i esa vuqpqEcdh; Lih'kht cuk;sxkA
(D) lHkh {kkj /kkrq xSl B ds lkFk xeZ djus ij izfrpqEcdh; Lih'kht cukrh gSaA
Sol. Gas A = O2 Gas B = N2 Gas C = NH3
xSl A = O2 xSl B = N2 xSl C = NH3

51. When N2 gas is adsorbed on the surface of metallic iron, electron transfer occurs from the metal to N 2.
The true statement(s) regarding this adsorbtion is/are :
(A*) N2 is chemisorbed.
(B*) N–N bond length is increased.
(C*) Occupancy of antibonding molecular orbitals in N2 is increased.
(D*) Entropy is decreased.
tc N2 xSl /kkfRod vk;ju dh lrg ij vf/k'kksf"kr gksrh gS] rks /kkrq ls N2 esa bysDVkWu LFkkukUrj.k gksrk gS] bl
vf/k'kks"k.k ds lanHkZ esa lR; dFku gS@gSa&
(A*) N2 dk jklk;fud vf/k'kks"k.k (chemisorbed) gksrk gSA
(B*) N–N ca/k yEckbZ c<+rh gSA
(C*) N2 esa izfrcaf/kr vkf.od d{kdksa dk vf/kxzg.k (Occupancy) c<rk gSA
(D*) ,UVªkWih ?kVrh gSA

52. A sample contaning 1 mol KHC2O4.H2C2O4 is titrated with different reagents. Select correct
statement(s)–
(A) 1 mol of KOH is used.
(B*) 3/2 mol of Ba(OH)2 is used.
(C) 4/5 mol of KMnO4 is used in alkaline medium.
(D*) 2/3 mol of K2Cr2O7 is used in acidic medium.
1 eksy KHC2O4.H2C2O4 ;qDr ,d izkn'kZ dks fofHkUu vfHkdeZdks ds lkFk mipkfjr djrs gS] rc lgh dFku pqfu;s&
(A) 1 eksy KOH iz;qDr gksrk gSA
(B*) 3/2 eksy Ba(OH)2 iz;qDr gksrk gSA
(C) {kkjh; ek/;e esa 4/5 eksy KMnO4 iz;qDr gksrk gSA
(D*) vEyh; ek/;e esa 2/3 eksy K2Cr2O7 iz;qDr gksrk gSA
Sol. Equivalent of KHC2O4.H2C2O4 as a acid = 3
and Equivalent of Ba(OH)2 = 3
Equivalent of KHC2O4.H2C2O4 as a reducing agent = 4
Equivalent of K2Cr2O7 = 4
Sol. vEy ds :i esa KHC2O4.H2C2O4 ds rqY;kad = 3
rFkk Ba(OH)2 ds rqY;kad = 3
vipk;d ds :i esa KHC2O4.H2C2O4 ds rqY;kad = 4
K2Cr2O7 ds rqY;kad = 4

53. Which of the following substrates is/are more reactive than ethyl bromide for SN2 reaction ?
fuEu esa ls dkSulk@dkSuls ;kSfxd SN2 vfHkfØ;k ds fy, ,fFky czksekbM ls vf/kd fØ;k'khy gksrs gS@gSa \
(A*) CH3–Br (B*) OHC–CH2–Br (C*) CH2=CH–CH2–Br (D*) Ph–CH2–Br

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54. In which of the following reactions benzaldehyde will form in final product.
fuEu esa ls dkSulh vfHkfØ;kvksa esa vfUre mRikn ds :Ik esa csUtsfYMgkbM cusxk\
CN CH3

SnCl2 HCl
(A*) 
H O
 (B)
KMnO

4

3 

OH

CO  HCl CO  HCl KOH/ 

(C*)     (D) + CCl4 
H

Anhyd.AlCl3 / CuCl futZy AlCl3 / CuCl
CN CHO

SnCl2 HCl
Sol. (A)  

CHO

CO  HCl / AlCl3
(C)  

OH OH
COOH
KOH/ 
(D) + CCl4 
 H

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