Safety data sheet

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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

1. Substance/preparation and manufacturer/supplier identification

Product name:
Lutensol® TO 8

Use: Raw material for the chemical-technical industry

Manufacturer/supplier:
BASF (Thai) Limited
23rd Floor, Emporium Tower, 622, Sukhumvit 24 Rd.,
Klongton, Klongtoey, Bangkok 10110, THAILAND
Telephone: +66 2624-1999
Telefax number: +66 2664-9254
E-mail address: Thailand-SDS-info@basf.com

Emergency information:
International emergency number:
Telephone: +49 180 2273-112

2. Hazard identification

Classification according to UN GHS 2009

Classification of the substance and mixture:

Acute toxicity: Cat.4 (oral)
Serious eye damage/eye irritation: Cat.1
Hazardous to the aquatic environment - acute: Cat.2

Label elements and precautionary statement:

Pictogram:
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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

Signal Word:
Danger

Hazard Statement:
H318 Causes serious eye damage.
H302 Harmful if swallowed.
H401 Toxic to aquatic life.

Precautionary Statements (Prevention):

P280 Wear eye and face protection.
P273 Avoid release to the environment.
P270 Do not eat, drink or smoke when using this product.
P264 Wash contaminated body parts thoroughly after handling.

Precautionary Statements (Response):

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or physician.
P330 Rinse mouth

Precautionary Statements (Disposal):

P501 Dispose of contents and container to hazardous or special waste
collection point.

Other hazards which do not result in classification:

No specific dangers known, if the regulations/notes for storage and handling are considered.

This classification is based on the current CESIO recommendations. This surfactant complies with
the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to
support this assertion are held at the disposal of the competent authorities of the Member States and
will be made available to them at their direct request or at the request of a detergent manufacturer.

3. Composition/information on ingredients
Chemical nature

Substance nature: Substance

Poly(oxy-1,2-ethanediyl), .alpha.-tridecyl-.omega.-hydroxy-, branched

CAS Number: 69011-36-5

4. First-Aid Measures
General advice:
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a
corticosteroid from a controlled/metered dose inhaler.
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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Note to physician:
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11., (Further) symptoms and / or effects are not known so far
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

5. Fire-Fighting Measures

Suitable extinguishing media:

water spray, dry powder, foam

Specific hazards:
harmful vapours, carbon oxides
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.

Special protective equipment:

Wear a self-contained breathing apparatus.

Further information:
The degree of risk is governed by the burning substance and the fire conditions. Collect
contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
Contaminated extinguishing water must be disposed of in accordance with official regulations.

6. Accidental Release Measures

Personal precautions:
Use personal protective clothing. Information regarding personal protective measures, see section 8.

Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater. Inform authorities in the event of product spillage to water courses or sewage
systems.

Methods for cleaning up or taking up:

For large amounts: Dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material.
Dispose of absorbed material in accordance with regulations.

Additional information: High risk of slipping due to leakage/spillage of product.

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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

7. Handling and Storage

Handling
Keep container tightly sealed. Wear suitable protective clothing and eye/face protection.

Protection against fire and explosion:

No special precautions necessary.

Storage

Suitable materials for containers: High density polyethylene (HDPE), Low density polyethylene
(LDPE), Stove-lacquer RDL 50, Stainless steel 1.4301 (V2), Stainless steel 1.4306 (V2A), Stainless
steel 1.4361, Stainless steel 1.4401, Stainless steel 1.4439, Stainless steel 1.4539, Stainless steel
1.4541, Stainless steel 1.4571
Unsuitable materials for containers: Paper/Fibreboard
Further information on storage conditions: Keep container tightly closed and dry; store in a cool
place.

Storage stability:
Storage temperature: <= 70 °C

The packed product is not damaged by low temperatures or by frost. Bulk must be protected from
solidification.
Protect from temperatures above: 70 °C
Properties of the product change irreversibly on exceeding the limit temperature.

8. Exposure controls and personal protection

Components with occupational exposure limits

No substance specific occupational exposure limits known.

Personal protective equipment

Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Particle filter with medium efficiency for
solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)

Hand protection:
Chemical resistant protective gloves
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN ISO 374-1):
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures:

Wearing of closed work clothing is recommended. No eating, drinking, smoking or tobacco use at the
place of work. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

Form: liquid
Colour: colourless
Odour: product specific
Odour threshold: not determined

pH value: approx. 7 (DIN EN 1262)

(20 °C)

solidification temperature: approx. 10 °C (DIN ISO 2207)

(1,013 hPa)
Boiling point: > 250 °C

Flash point: approx. 200 °C (ISO 2592)

Evaporation rate:
Value can be approximated from
Henry's Law Constant or vapor
pressure.

Flammability (solid/gas): hardly combustible

Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: > 300 °C

Thermal decomposition: > 350 °C (DTA)

Self ignition: not self-igniting

Self heating ability: It is not a substance capable of

spontaneous heating according to
UN transport regulations class 4.2.

Explosion hazard: not explosive

Fire promoting properties: not fire-propagating
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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

Vapour pressure: < 0.1 hPa

(20 °C)

Density: approx. 0.97 g/cm3 (DIN 51757)

(70 °C)
approx. 1 g/cm3 (DIN 51757)
(20 °C)
Relative density:
No data available.
Relative vapour density (air):
not determined

Solubility in water: soluble

Miscibility with water:
miscible in all proportions
Partitioning coefficient n-octanol/water (log Pow):
not determined
Surface tension: 26.8 mN/m (DIN EN 14370)
(23 °C; 0.5 g/l)

Viscosity, dynamic: approx. 150 mPa.s (DIN 51562)

(23 °C)
approx. 20 mPa.s (DIN 51562)
(60 °C)

Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.

10. Stability and Reactivity

Conditions to avoid:
See SDS section 7 - Handling and storage.

Thermal decomposition: > 350 °C (DTA)

Substances to avoid:
caustics, halogens, Alkalines, acids, reactive chemicals

Corrosion to metals: Corrosive effects to metal are not anticipated.

Hazardous reactions:
No hazardous reactions when stored and handled according to instructions.

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

Chemical stability:
The product is stable if stored and handled as prescribed/indicated.
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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

11. Toxicological Information

Routes of exposure
Acute oral toxicity
Experimental/calculated data:
LD50rat (oral): > 300 - 2,000 mg/kg (OECD Guideline 423)
Literature data.
Acute dermal toxicity
LD50 rat (dermal): > 2,000 mg/kg (OECD Guideline 402)
Literature data.
Assessment of acute toxicity
Of moderate toxicity after single ingestion.
Symptoms
Information, i.e. additional information on symptoms and effects may be included in the GHS labeling
phrases available in Section 2 and in the Toxicological assessments available in Section 11.
(Further) symptoms and / or effects are not known so far

Irritation

Assessment of irritating effects:

Risk of serious damage to eyes. Not irritating to the skin.

Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)
Literature data.

Serious eye damage/irritation rabbit: irreversible damage (Draize test)

Literature data.

Respiratory/Skin sensitization

Assessment of sensitization:
Based on the structure, there is no suspicion of a skin-sensitizing potential.

Germ cell mutagenicity

Assessment of mutagenicity:
Based on the structure, there is no suspicion of a mutagenic effect.

Carcinogenicity

Assessment of carcinogenicity:
Based on the structure there is no suspicion of a carcinogenic effect.

Reproductive toxicity

Assessment of reproduction toxicity:

Based on the ingredients, there is no suspicion of a toxic effect on reproduction.
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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

Developmental toxicity

Assessment of teratogenicity:
Based on the ingredients, there is no suspicion of a teratogenic effect.

Specific target organ toxicity (single exposure)

Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

The information available on the product provides no indication of toxicity on target organs after
repeated exposure.

Aspiration hazard

No aspiration hazard expected.

12. Ecological Information

Ecotoxicity

Toxicity to fish:
LC50 (96 h) > 1 - 10 mg/l, Leuciscus idus (Fish test acute, static)
Literature data.

Aquatic invertebrates:
EC50 (48 h) > 1 - 10 mg/l, Daphnia magna (Daphnia test acute)
Literature data.

Aquatic plants:
EC50 (72 h) > 1 - 10 mg/l, Scenedesmus sp. (DIN 38412 Part 9)
Literature data.

Microorganisms/Effect on activated sludge:

EC10 (17 h) > 10,000 mg/l (DIN 38412 Part 8)

Chronic toxicity to fish:

No data available.

Chronic toxicity to aquatic invertebrates:

No observed effect concentration (21.0 d), > 1 mg/l, Daphnia magna (OECD Guideline 202, part 2,
semistatic)
Literature data.

Assessment of terrestrial toxicity:

No data available concerning terrestrial toxicity.
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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

Mobility

Assessment transport between environmental compartments:

The substance will not evaporate into the atmosphere from the water surface.
Adsorption to solid soil phase is possible.

Persistence and degradability

Elimination information:
> 60 % CO2 formation relative to the theoretical value (28 d) (OECD 301B; ISO 9439; 92/69/EEC,
C.4-C) (aerobic, activated sludge, domestic) Readily biodegradable.

Bioaccumulation potential

Bioaccumulation potential:
Accumulation in organisms is not to be expected.

Additional information

Add. remarks environm. fate & pathway:

Treatment in biological waste water treatment plants has to be performed according to local and
administrative regulations.

Other ecotoxicological advice:

Inhibition of degradation activity in activated sludge is not to be anticipated during correct
introduction of low concentrations. Do not release untreated into natural waters.

13. Disposal Considerations

Must be disposed of or incinerated in accordance with local regulations.

Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.

14. Transport Information

Domestic transport:
Not classified as a dangerous good under transport regulations
UN number or ID number Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Sea transport
IMDG
Not classified as a dangerous good under transport regulations
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BASF Safety data sheet
Date / Revised: 21.09.2022 Version: 5.0
Product: Lutensol® TO 8
(30044015/SDS_GEN_TH/EN)
Date of print): 19.06.2023

UN number or ID number: Not applicable

UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number or ID number Not applicable
Proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

15. Regulatory Information

Other regulations

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

16. Other Information

This product is of industrial quality and unless otherwise specified or agreed intended exclusively for
industrial use.This includes the mentioned and recommended usage.Any other intended applications
should be discussed with the manufacturer.In particular this concerns the application for products
that are the object of special standards and regulations.

Vertical lines in the left hand margin indicate an amendment from the previous version.

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.