DBL7381 en 2021-01-01
DBL7381 en 2021-01-01
Foreword
This DBL specifies the requirements for the coating quality of coated metallic parts which are used in vehicle
exteriors, on the underfloor, and in the engine compartment, and describes the testing methods. These
coatings are final coatings. No further additional coating will be carried out in the receiving plant.
Changes
In comparison with edition 2020-11, the following changes have been made: Refer to Annex B
The product versions, which were not set to the status 'Not for new designs’ starting from this edition, are
listed in Annex C Table 25.
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Table of contents
1 Scope of application..........................................................................................................................3
2 Normative references........................................................................................................................4
3 Terms and definitions........................................................................................................................4
4 General requirements .......................................................................................................................5
5 Abbreviated material designation for documentation ........................................................................5
6 General properties of materials, raw materials and delivery condition .............................................5
6.1 All product versions...........................................................................................................................5
6.2 Changes (material, process) .............................................................................................................7
6.3 Assemblies........................................................................................................................................7
6.4 Mechanical pre-treatment method ....................................................................................................7
6.5 MAG- + MIG weld seams / heat-affected zone .................................................................................7
6.6 Punched and cut edges ....................................................................................................................7
6.7 CED material and pre-treatment .......................................................................................................7
6.8 Cavity coating ...................................................................................................................................8
6.9 Repair of faults in CED coating on SP body parts and SP component parts ...................................8
6.10 Layer thicknesses .............................................................................................................................8
6.11 Special considerations for product versions with light alloys as base material .................................8
7 Dimensions and tolerances/ form of supply ......................................................................................9
8 Technical Data ..................................................................................................................................9
9 Duties of the supplier ........................................................................................................................9
9.1 General requirements .......................................................................................................................9
9.2 Initial sampling ..................................................................................................................................9
Annex A (normative) Tests with set / target values ................................................................................11
A.1 Definition of the test method classes ..............................................................................................11
A.2 General requirements .....................................................................................................................11
A.3 Testing of paints in wet condition ....................................................................................................11
A.4 Processing tests..............................................................................................................................12
A.5 Visual inspections ...........................................................................................................................12
A.6 Technical-mechanical tests.............................................................................................................13
A.7 Climatic tests...................................................................................................................................16
A.8 Resistance to chemicals, test mixtures and test concentrates .......................................................28
A.9 Analytical tests ................................................................................................................................30
Annex B (informative) Changes in comparison with the last edition ......................................................31
Annex C (informative) Product versions with the status 'not for new designs' .......................................32
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1 Scope of application
This Standard applies to the Mercedes-Benz Cars & VAN divisions. It applies to all metallic base materials
on the exterior and underside of the vehicle and within the engine compartment, as well as for the actual
body, which receive an organic coating or are coated with a paintwork structure.
Depending on the purpose, the organic coatings or paintwork structures can be divided into exposure groups
that represent the respective product versions in this standard. An overview of the permissible product
versions can be found in Table 1 below.
This DBL does not apply to metallic component parts installed in the vehicle interior. DBL 7382 shall apply
to these.
This DBL does not apply to body replacement and follow-up drawn parts. DBL 7383 shall apply to these.
Decorative effect
Product version
The necessary additional coatings or cavity preservation should be documented in the data record for
product versions PV 10/20.
Components of product versions PV 10/20, which are documented with additional coatings or cavity
preservation in the data record, should be tested with and without additional measures and the respective
limit values should be considered, see Chapter 6.1.4
For product versions 20/22, the responsible specialist department for coating shall be contacted in the event
of a constant thermal load > 130 °C.
Single or multicoat finish: all common coating systems, provided that they comply with the requirements of
this DBL.
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2 Normative references
The following referenced documents are required for the application of this document. For dated references,
only the referenced edition applies. For undated references, the latest edition of the cited document
(including any changes) applies.
GE Gloss unit
OK Correct, corresponding to required quality
CED Cathodic dip paint (cathodic electro deposition)
CCT Corrosion cycle test
MAG Metal active gas welding
MIG Metal-inert gas welding
PES Polyester
PLP Production control plan
Rep. Paint repair
SQMS Supplier Quality Management System
TG Glass transition temperature
CASS copper-accelerated acetic acid salt spray
ZGS Drawing date
4 General requirements
To guarantee product safety and product quality, and to meet certification requirements, all relevant statutory
regulations and laws shall be complied with. In addition, the relevant requirements of the Daimler Group
shall apply.
In terms of components and recyclability, materials, process engineering, component parts and systems
shall comply with all applicable legal requirements.
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6.1.2 PV 30: Decorative and weather-resistant baked multicoat finish or powder coating, co-
extrudate, and other coatings
A painting system approval is required for this product version.
For coated co-extrudate, only the CASS test is carried out as part of this DBL; all other tests are checked in
accordance with DBL 5425.
Requirements for scratch resistance (Amtec / Crockmeter) in Table 5 as well as those for weather and
chemical resistance in Tables 20 and 21 are applicable for flat applied contrast colors on the outer car
body skin (e.g. in-mold coatings, foils, contrast colors for roofs, flaps).
6.1.4 PV 10/20: Single or multicoat finish, CED, powder, etc. with medium corrosion stress / CED
with heavy corrosion stress
Additional measures such as an additional coating on weld seams, edges and surfaces at a risk of
corrosion as well as areas with special stone chip stress or cavity preservation should be documented in
the data record of the component.
All materials used as additional coating for this PV shall have been approved according to DBL 7305 and
have a BQF.
All materials used as cavity preservation for this PV shall have been approved according to DBL 6905 and
have a BQF.
The following scopes shall be tested for initial material sampling of components with additional coatings or
cavity preservation:
1. Component only CED coated
2. CED coated component with documented additional measures according to the given BQF of DBL
7305 or DBL 6905
The Tier 1 supplier must ensure the adhesion between CED and any additional coating, document it and
prove it (see 9.2.1).
6.1.7 Substrates
For steel and galvanized steel substrate: CCT 2 (Tables 13 and 14) should be applied for new designs for
PVs 10, 11, 12, 20, 22, 30 and 31. CCT 1 can be used in exceptional cases in consultation with the specialist
department
For aluminum alloys: CCT 2 (Table 15) should be additionally applied for new designs for PVs 10, 11, 12,
20, 22, 30 and 31 as an approval-relevant corrosion test.
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6.3 Assemblies
Note that DBL 7381 can apply to the testing of either single parts or assemblies. Accordingly, the specified
tests shall also be carried out on either the single part or on the assembly. This shall be coordinated with
the specialist department.
Figure1: Coating defects occur due to silicate residues caused by MAG welding
The demonstration of a closed phosphate coat by analysis as well as the demonstration of monitoring
the pre-treatment and CED parameter should be attached with the ISIR (see 9.2.1).
6.9 Repair of faults in CED coating on SP body parts and SP component parts
6.9.2 PV 30: Decorative and weather-resistant baked multicoat finish or powder coating, co-
extrudate, and other coatings
Spot repair is not permissible, only complete repair.
For PV50: The minimum layer thicknesses and paint systems for wheels are stored in the “Implementation
regulation for surface treatment A 169 003 4299” or under document number “Paint surfaces for wheels” A
008 004 30 99 in DocMaster and shall be complied with in accordance with the drawing geometry status.
6.11 Special considerations for product versions with light alloys as base material
6.11.1 Extruded aluminum parts/ rolled aluminum/ cast aluminum (pressure, sand, ingot molds)
The CASS test (see Table 16) shall be performed as an approval-relevant corrosion test. In addition,
filiform corrosion test (see Table 17) can be required.
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8 Technical Data
For requirements of the approval-relevant tests with set values or target values, refer to Annex A.
Preliminary remark:
In addition to the quality of the coating material itself, the material, pre-treatment and shape of the parts to
be coated may also be crucial to compliance with the following requirements. The tests shall therefore be
conducted on finished parts. If necessary, the Global Material Sampling team shall be consulted prior to
testing.
If, due to their size, component parts are sawn into pieces, the cut surfaces shall be protected, e.g. with a
green polyester adhesive tape (source of procurement should be requested from the specialist department)
or with wax. The selected method shall reliably protect the edges from the moisture of the corrosive media
being drained without affecting the surrounding areas to be tested.
For underbody components, at least two parts shall be tested, the underside of the component parts in the
installation position forming the upper side in the test cell and vice versa. This is required in order to be able
to assess any effects resulting from the reverse situation.
A test angle of 70° is desirable for the main surface.
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- Object temperature curves (at full load), object temperature measuring points (illustrated documentation),
test frequency
- Illustrated corrosion test report, e.g. test position, storage/removal of the test parts in the/from the test
cell
- Adhesion test of overall paint system and individual coats
- Tests on adhesion of CED on the substrate as well as adhesion between CED and possible additional
coatings applied
- Repair paintwork: work instructions, coating materials with product and supplier name
- Corrosion test report for the repair concept (illustrated)
- Testing of CCT1 / CCT2 for steel and CASS / filiform test for aluminum wheels should be performed on
the entire wheels
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Annex A (normative)
Tests with set / target values
00 01 10 11 12 20 22 30 31 40 50
MBN 10494-1
According to the PLP and AAW drawing or approved sample with the tolerances typical of the material, as
X Layer thickness Non-destructive
documented in the ISIR.
layer thickness
Cross-section polish in Cross-section polish as per DIN 2808: Method 6a cross-section polish
X MBN 10494-1
the wedge process
: Horst Feldmann, 2022-09-15
00 01 10 11 12 30 31 50
High gloss:
High gloss:
Gloss ≥ 80
In accordance with drawing or approved sample. Gloss ≥80 GE (measuring MBN 10494-4
GE (20 °)
angle 20 °) Gloss
X Gloss evaluation Deviation with respect to reference sample 2-3 measurement
Matt: Gloss
Matt: using a
according to
No requirements for CED-Materials Gloss 23±7 GE (measuring reflectometer
color sample
angle 60 °)
(60 °)
Visual
Deviation with respect to reference sample 3-4 measuring technology: MBN 10494-4
inspection:
X Color assessment MBN 10473-2 MBN 10473-1
MBN
No requirements for CED-Materials visual: MBN 10476 MBN 10473
10476
According
MBN 10514-3 to MBN 10494-4
X Appearance
MBN 10514-4 approved MBN 10514-2
sample
: Horst Feldmann, 2022-09-15
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Uncontrolled copy when printed
OK: ≥ 6 (≥ 3,5*)
X X Cupping in mm conditionally OK: ≥ 5 (≥ 2,5*) 6 MBN 10494-5
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00 01 10 11 12 20 22 40 30 31 50
Scratch test
X X PV 20: K 2 MBN 10494-5
Cavity
*Paint repair structure 1: with additional coating documented in the data record of the
component
: Horst Feldmann, 2022-09-15
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Uncontrolled copy when printed
30 31 50
MBN 10494-8
Impact force adhesion on
Average value ≥ 45
X X aluminum surfaces:
No individual value ≤ 20
tempered, in N/cm2
: Horst Feldmann, 2022-09-15
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Uncontrolled copy when printed
00 01
X
steel
Corrosion cycle test on refer to Table 11. MBN 10494-6
X
galvanized steel
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Test
Preload
00 01 10 11 12 20 22 40 30 31 50
Condensed water
constant climate (CH)
X MBN 10494-6
Blistering/
X <2 (S2) <2 (S2) <2 (S2) 0 (S0) 0 (S0) MBN 10494-6
Degree of blistering (S)
OK: K 2 (K 2,5*)
X Scratch test after 24 h K2 K2 K2 conditionally OK: K K2 MBN 10494-5/-6
2,5 (K 3*)
OK: Gt 1 (Gt 1,5*)
X Cross-cut after 24 h Gt 1 Gt 1 Gt 1 conditionally OK: Gt 1 MBN 10494-5/-6
Gt 1,5 (Gt2*)
Multiple stone chipping test
X method B – overall damage PV 12, 101: 2 PV201: 2 2 MBN 10494-5
of component [grade]
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Evaluation
Preload
Test Test method
00 01 10 11 12 20 22 40 30 31
KR 2 KR 2
X Edge corrosion** KR 2 KR 1 MBN 10494-6
PV101: KR 1 PV201: KR1
SR 2 SR 2
X Weld seam corrosion SR 2 SR 2 MBN 10494-6
PV101: SR 1 PV201: SR 1
Subsurface corrosion around
X 1,5 2,0 1,5 1,5 MBN 10494-6
a scribe U/2 in mm
Blistering/
X <2 (S2) <2 (S2) <2 (S2) 0 (S0) MBN 10494-6
Degree of blistering (S)
component
**The limit values refer to one edge length. No integration across the whole component 2 with cavity preservation documented in the data record of the component
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Evaluati
Preload
Test Test method
00 01 10 11 12 20 22 40 30 31
on
Galvanized/ galvanized + organic coating / hot-dip aluminized substrates
Corrosion cycle test 1
The values indicated refer to zinc corrosion.
Galvanized steel
X No red rust shall occur in any case (does not apply to SR). MBN 10494-6
KR 3 KR 3
X Edge corrosion** KR 3 KR 2 MBN 10494-6
PV101: KR2 PV201: KR2
SR 2 SR 2
X Weld seam corrosion SR 2 SR 2 MBN 10494-6
PV101: SR1 PV201: SR1
Sub-surface corrosion
X 4,0 4,0 4,0 4,0 (4,0*) MBN 10494-6
around a scribe U/2 in mm
Blistering/
X <2 (S 2) <2 (S 2) <2 (S 2) 0 (S 0) MBN 10494-6
Degree of blistering (S)
**The limit values refer to one edge length. No integration across the whole component 2 with cavity preservation documented in the data record of the component
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Uncontrolled copy when printed
Blistering/
X 0 (S 0) MBN 10494-6
Degree of blistering (S)
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Evaluatio
Preload
Test Test method
10 11 12 20 22 30 31
n
Corrosion cycle test 2 Corrosion cycle test 2 must be used for new designs.
Steel substrates CCT 1 can be used in exceptional cases in consultation with the specialist department
X MBN 10494-6
Exposure time in cycles 6 6 6
KR 2 KR 2
X Edge corrosion** KR 1 MBN 10494-6
PV 101: KR1 PV 201: KR1
SR 2 SR 1
X Weld seam corrosion SR 2 MBN 10494-6
PV 101: SR 1 PV 201: SR 1
Sub-surface corrosion around
X 5,0 3,5 4,5 (4,5*) MBN 10494-6
a scribe U/2 in mm
Blistering/degree of blistering
X 1 (S1) 1 (S1) 0 (S 0) MBN 10494-6
(S)
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Evaluati
Preload
Test Test method
10 11 12 20 22 30 31
on
Galvanized/ galvanized + organic coating / hot-dip aluminized substrates. The given values refer to zinc
Corrosion cycle test 2 corrosion. No red rust shall occur in any case (does not apply to SR).
Galvanized steel Corrosion cycle test 2 shall be used for new designs. CCT 1 can be used in exceptional cases in consultation
X with the specialist department MBN 10494-6
KR 3 KR 2
X Edge corrosion** KR 1 MBN 10494-6
PV 101: KR2 PV 201: KR2
SR 2 SR 1
X Weld seam corrosion SR 2 MBN 10494-6
PV 101: SR1 PV 201: SR1
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Sub-surface corrosion
X 0,5 0,5 0,5 (0,53) MBN 10494-6
around a scribe U/2 in mm
**The limit values refer to one edge length. No integration across the whole component 3 ground
: Horst Feldmann, 2022-09-15
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Uncontrolled copy when printed
Evaluation
Preload
CASS test This test will be applied to all aluminum substrates (even cast).
Aluminum For aluminum alloys PV10,11,12, 20, see item 6.1.6.
X MBN 10494-6
Exposure time in h 96 168 240 240
KR ≤14
X Edge corrosion** KR 2 KR 1 MBN 10494-6
KR 05
Blistering/ 0 (S 0)
X <2 (S 2) 0 (S 0) MBN 10494-6
Degree of blistering (S) after 24 h
** The limit values refer to one edge length. No integration across the whole component 4 areas with 3 coats or fully painted
5 gloss of rotating edges
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30 31 50
X Visual assessment No gloss decrease, no color change in the original MBN 10494-4
Blistering/
X 0 (S 0) 0 (S 0) MBN 10494-6
Degree of blistering (S)
4,0
X Longest thread lF in mm 4,0 MBN 10494-6
6,03
: Horst Feldmann, 2022-09-15
** The limit values refer to one edge length. No integration across the whole component 3 ground
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30 31 50
Natural weathering with salt This test is not relevant for purchased parts.
X MBN 10494-6
Exposure time 12 months with light protection 12 months
Blistering/
X <2 (S 2) 0 (S 0) MBN 10494-6
Degree of blistering (S)
Steel
Sub-surface corrosion around
X a scribe U/2 in mm 2,0 2,0 MBN 10494-6
Zinc
Sub-surface corrosion around 1,0 1,0
X a scribe U/2 in mm MBN 10494-6
2,03 2,03
Aluminum
** The limit values refer to one edge length. No integration across the whole component 3 ground
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30 31 50
Florida test
MBN 10494-6
X
Test plates
Exposure time min. 3 years min. 2 years
X Visual color assessment Color deviation with respect to unexposed reference sample not greater than characteristic value 3-4 MBN 10494-4
X Visual color assessment Color deviation with respect to unexposed reference sample not greater than characteristic value 3-4 MBN 10494-4
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30 31 50
Resistance to chemicals
X Proof of compliance with these requirements by the paint supplier is sufficient (test results are part of the ISIR). MBN 10494-7
Gradient oven test method
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00 01 10 11 12 20 22 40 30 31 50
X Resistance to test fuels Proof of compliance with these requirements by the paint supplier is sufficient (test results are part of the ISIR). MBN 10494-7
X FAM test substance 23°C/10 min: no swelling or discoloration after regeneration time of 16 hours, scratch test: KR2 MBN 10494 part 7
00 01 10 11 12 20 22 40 30 31 50
X Wheel cleaner PV50: RT/16 h: no swelling or discoloration, no gloss change MBN 10494-7
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50
X Film-Tg Clear PES powder ≥ 67°C (15 min/170°C) (powder oven) MBN 10494-1
EP/PES hybrid primer ≥ 60°C (20 min/170°C)
Reactive EP/PES hybrid primer ≥ 60°C (17 min/150°C)
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DBL 7381:2021-01, page 31
Annex B (informative)
Changes in comparison with the last edition
In comparison with edition 2020-11, the following changes have been made:
- PV 21, 23 and 24. Cancelled and get new status: Not for new designs.
- Table 1: Columns “Cavity preservation” and “Stone-chip primer” deleted, for PV12 “with stone-
chip primer” adopted under “Type of coating”, for PV 20, changed from CED black to CED, for
PV31 “OEM body painting at the supplier” replaced by baked multicoat finish.
- Adopted in the area of use: The necessary additional coatings or cavity preservation should be
documented in the data record for product versions PV 10/20. Components of production
versions PV 10/20, which are documented with additional coatings or cavity preservation in the
data record, should be tested with and without additional measures, see Chapter 6.1.4
- Table 25 with PV ‘Not for new designs’ which had PV 21,23,24 was adopted
- Section 6.1.2.: Sentence for flat applied contrast colors on the outer body skin adopted.
- Section 6.1.4.: PV10/20 with and without additional coating, completely revised
- Section 6.1.5. adopted: Complete repair structures and scopes of test shall be agreed with the
specialist department. All the results should be documented exactly with values, illustrations,
graphs, etc., document number “Paint surfaces for wheels” A 008 004 30 99.
- Sec. 6.1.7. New: Substrate: Steel, galvanized steel and aluminum: Corrosion cycle test 2 shall
be used for new designs. CCT 1 can be used in exceptional cases in consultation with the
specialist department
- Section 6.5 Water jets adopted. The processes shall be selected so as to fulfill the requirements
of this DBL. In special cases, an additional coating on the weld seams is also possible. Process
optimization for weld spatters recorded in
- Section 6.7: The proof of a closed phosphate coat by analysis as well as the proof of monitoring
the pre-treatment and CED parameters should be attached with the ISIR. (see 9.2.1)
- Section 6.10. adopted: under the document number “Paint surfaces for wheels” A 008 004 30
99. in the future. Deleted: The other applicable document is the material approval list for alloy
wheel surfaces.
- Section 9.2.1 adopted: Proof of a closed phosphate coat by SEM image: An overview image at
a magnification of 500x as well as a close-up view at 2000x magnification, strict monitoring of
pre-treatment and CED process parameters, Filling Annex 1, Filling Annex 2, Filling Annex 3,
Adhesion test of overall paint system and individual coats, Tests on adhesion of CED on the
substrate as well as adhesion between CED and possible additional coatings applied, CCT1 /
CCT2 test for steel and CASS / filiform test for aluminum wheels should be conducted on the
entire wheels.
- Section 9.2.2: Filling Annex 1: Process data for pre-treatment, CED and painting, Filling Annex
2: Test report requirements
- Tables 6, 9, 10, 11: Specifications for PV10/20 with additional measures adopted
- Table 22: Values for resistance to test fuels specified
- Table 23: Brake fluid 10 minutes at 100 °C not applicable
- Table 24: Requirements adopted
- Deleted in all tables: Additional % corrosion surface in brackets to the corrosion evaluations (Ri,
KR, SR), “k.A.” information. Changed: Half grades of corrosion evaluations (Ri, KR, SR)
changed to full grades.
- For evaluation of edge corrosion: The limit values refer to one edge length. No integration
across the whole component.
- New tables 13, 14, 15 with CCT 2 requirements for PV 10,11,12, 20, 22, 30 and 31 for steel,
galvanized steel and aluminum.
- Annex A.1. deleted: Description of test method classes. Adopted: The WEB 2020+ process
shall be applicable. The WEB V 100, 300, 301, 500 documents should be followed.
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Annex C (informative)
Product versions with the status 'not for new designs'
The product versions, which were not set to the status ‘Not for new designs’ starting from this
edition, are listed in Table 25.
Table 25: Product versions with the status not for new designs, overview
Medium corrosive stress
Cavity preservation
Moderate corrosive
Stone-chip primer
Decorative effect
Product version
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