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SAFETY DATA SHEET FOGO-001

Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, GHS & 1272/2008/EC Standards SDS Revision: 1.0 SDS Revision Date: 11/13/2019

1. PRODUCT & COMPANY IDENTIFICATION

1.1 Product Name:
FOGO FIRE ZERO – FIRE EXTINGUISHER SPRAY
1.2 Chemical Name: Aerosol
1.3 Synonyms: FZ 02/03
1.4 Trade Names: FOGO Fire Zero Fire Extinguisher Spray
1.5 Product Use: Aerosol Fire Extinguishing Spray
1.6 Distributor’s Name: MGS USA, LLC
1.7 Distributor’s Address: 11711 Oakspine CT, Ellicott City, MD 21042 USA
1.8 Emergency Phone:
###################################
1.9 Business Phone / Fax: 1 (310) 770-5209 / +1 (917) 770-6635 / +1 (443) 864-4986

2. HAZARDS IDENTIFICATION
2.1 Hazard Identification: This product is classified as a HAZARDOUS SUBSTANCE and as DANGEROUS GOODS according to the classification
criteria of NOHSC: 1088 (2004) and ADG Code (Australia).
WARNING! PRESSUIRZED CONTAINER MAY BURST IF HEATED. CAUSES EYE IRRITATION.
Classification: Aerosol 3; Eye Irrit. 2
2.2 Label Elements: Hazard Statements (H): H229 – Pressurized container may burst if heated. H320 – Causes eye
irritation.
Precautionary Statements (P): P210 – Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking. P251 – Do not pierce or burn, even after use. P261 –
Avoid breathing fume/gas/mist/vapors/spray. P264 – Wash hands and exposed skin areas with
soap and warm thoroughly after handling. P305+P351+P338 – IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 – If eye irritation persists get medical advice/attention. P410+P412 – Protect from
sunlight. Do not expose to temperatures exceeding 50 °C (122 °F).
2.3 Other Warnings: KEEP OUT OF REACH OF CHILDREN.

3. COMPOSITION & INGREDIENT INFORMATION

EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH NOHSC OSHA
ppm ppm ppm
ES- ES- ES-
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. % TLV STEL TWA STEL PEAK PEL STEL IDLH OTHER
7732-18-5 NA 231-791-2 ≥ 90 NA NA NF NF NF NA NA NA
WATER (AQUA/EAU)

112-34-5 NA 203-961-6 1-5 NA NA NF NF NF NA NA NA

GLYCOL ETHER DB
Eye Irrit. 2A; H319
PROPRIETARY MIXTURE OF NA NA NA 1-5 NA NA NF NF NF NA NA NA
DETERGENTS
107-21-1 KW2975000 203-473-3 ≤1 (100) NA NF 10 NF (50) NA NA
ETHYLENE GLYCOL
Acute Tox. (oral) 4; H302
NA NA NA ≤1 NA NA NF NF NF NA NA NA
FLUOR ALKYL SURFACTANTS

4. FIRST AID MEASURES

4.1 First Aid: Ingestion: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of water or milk
IMMEDIATELY. If the patient is vomiting, continue to offer water or milk. Never give water or milk to an
unconscious person. Contact the nearest Poison Control Center or local emergency number. Provide an
estimate of the time at which the material was ingested and the amount of the substance that was
swallowed.
Eyes: Splashes are not likely; however, if product gets in the eyes, flush with copious amounts of lukewarm water
for at least 15 minutes. If irritation occurs, contact a physician.
Skin: If irritation occurs and product is on the skin, rinse thoroughly with lukewarm water, followed by a thorough
washing of the affected area with soap and water. If irritation, redness or swelling persists, contact a
physician immediately.
Inhalation: Remove victim to fresh air at once.
4.2 Effects of Exposure: Ingestion: If product is swallowed, may cause nausea, vomiting and/or diarrhea.
Eyes: Moderately irritating to the eyes. Symptoms of overexposure may include redness, itching, irritation and
watering.
Skin: May be irritating to skin. The product can cause allergic skin reactions (e.g., rashes, welts, dermatitis) in
some sensitive individuals.
Inhalation: None expected.
4.3 Symptoms of Overexposure: Overexposure in eyes may cause redness, itching and watering. Symptoms of skin overexposure may include redness,
itching, and irritation of affected areas. The product can cause allergic skin reactions (e.g., rashes, welts, dermatitis) in
some sensitive individuals.
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SAFETY DATA SHEET FOGO-001
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, GHS & 1272/2008/EC Standards SDS Revision: 1.0 SDS Revision Date: 11/13/2019

4. FIRST AID MEASURES – cont’d

4.4 Acute Health Effects: Moderate irritation to eyes.
4.5 Chronic Health Effects: No harmful or chronic health effects are expected to occur from a single accidental ingestion.
4.6 Target Organs: Eyes
4.7 Medical Conditions Pre-existing dermatitis, other skin conditions, and disorders of the HEALTH
Aggravated by Exposure:
1
target organs (eyes, skin, and respiratory system).
FLAMMABILITY 0
PHYSICAL HAZARDS 0
PROTECTIVE EQUIPMENT B
EYES SKIN

5. FIREFIGHTING MEASURES
5.1 Fire & Explosion Hazards: PRESSURIZED CONTAINER MAY BURST IF HEATED. Level 1 Aerosol (NFPA 30B). Aerosols
may burst at temperatures above 120 °F. Cool uninvolved containers to prevent possible bursting.
Aerosols may be projectile hazards when bursting. If aerosols are bursting, stay clear until bursting
is complete. Containers may rupture and release liquids or/or exposed gases if exposed to the
heat of fire. Keep containers cool by spraying them with water until the fire has been extinguished.
Keep away from heat, lit cigarettes, sparks & open flame. Keep container closed.
5.2 Extinguishing Methods: Product is an extinguishing media. Water, Foam, CO2, Dry Chemical.
5.3 Firefighting Procedures: As in any fire, wear MSHA/NIOSH approved self-contained breathing apparatus (pressure-
demand) and full protective gear. Keep containers cool until well after the fire is out. Use water
spray to cool fire-exposed surfaces and to protect personal. Fight fire upwind. Prevent runoff from
fire control or dilution from entering sewers, drains, drinking water supply, or any natural waterway.
Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained
breathing apparatus to protect against potential hazardous combustion or decomposition products
and oxygen deficiencies.

6. ACCIDENTAL RELEASE MEASURES

6.1 Spills: Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective
Equipment (PPE).
For small spills (e.g., < 1 gallon (3.8 L)) wear appropriate personal protective equipment (e.g., goggles, gloves).
Maximize ventilation (open doors and windows) and secure all sources of ignition. Remove spilled material with
absorbent material and place into appropriate closed container(s) for disposal. Dispose of properly in accordance with
local, state and federal regulations. Wash all affected areas and outside of container with plenty of warm water and
soap. Remove any contaminated clothing and wash thoroughly before reuse.
For large spills (e.g., ≥ 1 gallon (3.8 L)), deny entry to all unprotected individuals. Dike and contain spill with inert
material (e.g., sand or earth). Use ONLY non-sparking tools for recovery and cleanup. Transfer liquid to containers for
recovery or disposal and solid diking material to separate containers for proper disposal. Remove contaminated clothing
promptly and wash affected skin areas with soap and water. Keep spills and cleaning runoffs out of municipal sewers
and open bodies of water.

7. HANDLING & STORAGE INFORMATION

7.1 Work & Hygiene Practices: Do not eat, drink, or smoke while handling this product.
7.2 Storage & Handling: Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans). Keep away from excessive
heat and open flames. Keep in temperature between 5-40 ºC (41-104 ºF).
7.3 Special Precautions: Spilled material may present a slipping hazard if left unattended. Clean all spills promptly.

8. EXPOSURE CONTROLS & PERSONAL PROTECTION

8.1 Exposure Limits: ACGIH NOHSC OSHA OTHER
ppm (mg/m3) ES- ES-
CHEMICAL NAME(S) TLV STEL ES-TWA STEL PEAK PEL STEL IDLH
ETHYLENE GLYCOL (100) NA NF 10 NF (50) NA NA
8.2 Ventilation & Engineering General mechanical (e.g., fans) or natural ventilation is sufficient when this product is in use. Use local or general
Controls:
exhaust ventilation to effectively remove and prevent buildup of vapors or mist generated from the handling of this
product. Ensure that an eyewash station, sink or washbasin is available in case of exposure to eyes.
8.3 Respiratory Protection: No special respiratory protection is required under typical circumstances of use or handling. If
necessary, use only respiratory protection authorized per U.S. OSHA's requirement in 29 CFR
§1910.134, or applicable U.S. state regulations, or the appropriate standards of Canada, its provinces,
E.C. member states, or Australia.
8.4 Eye Protection: Avoid eye contact. Protective eyewear recommended. Wear protective eyewear (e.g., safety glasses
with side-shield) at all times when handling large quantities (of this product. Always use protective
eyewear when cleaning spills or leaks. Contact lenses pose a special hazard; soft lenses may absorb
and concentrate irritants.
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SAFETY DATA SHEET FOGO-001
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, GHS & 1272/2008/EC Standards SDS Revision: 1.0 SDS Revision Date: 11/13/2019

8. EXPOSURE CONTROLS & PERSONAL PROTECTION – cont’d

8.5 Hand Protection: None required under normal conditions of use. However, may cause skin irritation in some sensitive
individuals. If anticipated that prolonged & repeated skin contact will occur during use of this product,
wear latex or rubber gloves for routine industrial use. If necessary, refer to U.S. OSHA 29 CFR
§1910.138, the appropriate standards of Canada, of the E.C. member states.
8.6 Body Protection: No special body protection is required under typical circumstances of use and handling. If necessary,
refer to appropriate standards of Canada, the E.C. member states, or U.S. OSHA.

9. PHYSICAL & CHEMICAL PROPERTIES

9.1 Appearance: Aerosol, yellowish liquid
9.2 Odor: Characteristic
9.3 Odor Threshold: NA
9.4 pH: 6.5-8.0
9.5 Melting Point/Freezing Point: NA
9.6 Initial Boiling Point/Boiling
Range: NA
9.7 Flashpoint: NA
9.8 Upper/Lower Flammability
Limits: NA
9.9 Vapor Pressure: NA
9.10 Vapor Density: NA
9.11 Relative Density: 1.00-1.10
9.12 Solubility: NA
9.13 Partition Coefficient (log Pow): NA
9.14 Autoignition Temperature: NA
9.15 Decomposition Temperature: NA
9.16 Viscosity: NA
9.17 Other Information: NA

10. STABILITY & REACTIVITY

10.1 Stability: This product is stable.
10.2 Hazardous Decomposition
Products: Oxides of carbon (CO, CO2) and sulfur (SO2).
10.3 Hazardous Polymerization: Will not occur.
10.4 Conditions to Avoid: Open flames, sparks and high heat. Protect from frost.
10.5 Incompatible Substances: High heat

11. TOXICOLOGICAL INFORMATION

11.1 Routes of Entry: Inhalation:YES Absorption: YES Ingestion: NO
11.2 Toxicity Data: This product has NOT been tested on animals to obtain toxicology data. Toxicology data, found in scientific literature, is
available for some of the components of the product.
11.3 Acute Toxicity: See Section 4.4
11.4 Chronic Toxicity: See Section 4.5
11.5 Suspected Carcinogen: No.
11.6 Reproductive Toxicity: This product is not reported to produce reproductive toxicity in humans.
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
11.7 Irritancy of Product: See Section 4.2
11.8 Biological Exposure Indices: NE
11.9 Physician Recommendations: Treat symptomatically.

12. ECOLOGICAL INFORMATION

12.1 Environmental Stability: There are no specific data available for this product.
12.2 Effects on Plants & Animals: There are no specific data available for this product.
12.3 Effects on Aquatic Life: There are no specific data available for this product.
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SAFETY DATA SHEET FOGO-001
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, GHS & 1272/2008/EC Standards SDS Revision: 1.0 SDS Revision Date: 11/13/2019

13. DISPOSAL CONSIDERATIONS

13.1 Waste Disposal: Waste disposal must be in accordance with appropriate Federal, state, and local regulations.
13.2 Special Considerations: U.S. EPA Waste Number: D001 (characteristic - ignitable).

14. TRANSPORTATION INFORMATION

The basic description (ID Number, proper shipping name, hazard class & division, packing group) is shown for each mode of transportation. Additional
descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND): CONSUMER COMMODITY, ORM-D (IP VOL ≤ 1.0 L) – until 12/31/20
UN1950, AEROSOLS, 2.2 (LTD QTY, IP VOL ≤ 1.0 L)
14.2 IATA (AIR): ID8000, CONSUMER COMMODITY, 9 (IP VOL ≤ 820 mL)
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2 (LTD QTY, IP VOL ≤ 1000 mL) or
14.3 IMDG (OCN):
UN1950, AEROSOLS, 2.2 (LTD QTY, IP VOL ≤ 1.0 L)
14.4 TDGR (Canadian GND):
UN1950, AEROSOLS, 2.2 (LTD QTY, IP VOL ≤ 1.0 L)
14.5 ADR/RID (EU):
UN1950, AEROSOLS, 2.2 (LTD QTY, IP VOL ≤ 1.0 L)
14.6 SCT (MEXICO):
UN1950, AEROSOLES, 2.2 (CANT. LTDA., IP VOL ≤ 1.0 L)
14.7 ADGR (AUS):
UN1950, AEROSOLS, 2.2 (LTD QTY, IP VOL ≤ 1.0 L)

15. REGULATORY INFORMATION

15.1 SARA Reporting Requirements: This product does not contain any substances subject to SARA Title III, section 313 reporting requirements.
15.2 SARA TPQ: There are no specific Threshold Planning Quantities for the components of this product.
15.3 TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
15.4 CERCLA Reportable Quantity: NA
15.5 Other Federal Requirements: This material does not contain any hazardous air pollutants. None of the components in this product are listed as
priority pollutants under the CWA. None of the components in this product are listed as toxic pollutants under the CWA.
15.6 Other Canadian Regulations: This product has been classified according to the hazard criteria of the CPR and the MSDS
contains all of the information required by the CPR. The components of this product are listed on
the DSL/NDSL. None of the components of this product are listed on the Priorities Substances List.
WHMIS A, D2B (Compressed Gas, Other Toxic Effects)
15.7 State Regulatory Information: No ingredients in this product, present in a concentration of 1.0% or greater, are listed on any of the following state
criteria lists: California Proposition 65 (CA65), Delaware Air Quality Management List (DE), Florida Toxic Substances
List (FL), Massachusetts Hazardous Substances List (MA), Michigan Critical Substances List (MI), Minnesota
Hazardous Substances List (MN), New Jersey Right-to-Know List (NJ), New York Hazardous Substances List (NY),
Pennsylvania Right-to-Know List (PA), Washington Permissible Exposures List (WA), Wisconsin Hazardous Substances
List (WI).
15.8 Other Requirements: This product does not contain any chemicals known to the State of California to cause cancer or other reproductive
harm. For more information go to www.P65Warnings.ca.gov
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SAFETY DATA SHEET FOGO-001
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, GHS & 1272/2008/EC Standards SDS Revision: 1.0 SDS Revision Date: 11/13/2019

16. OTHER INFORMATION

16.1 Other Information: WARNING! PRESSUIRZED CONTAINER MAY BURST IF HEATED. CAUSES EYE IRRITATION. Use only as
directed. Discontinue use if irritation develops. Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Do not pierce or burn, even after use. Avoid breathing fume/gas/mist/vapors/spray.
Wash hands and exposed skin areas with soap and warm thoroughly after handling. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists,
get medical advice/attention. Protect from sunlight. Do not expose to temperatures exceeding 50 °C (122 °F).
KEEP OUT OF REACH OF CHILDREN.
16.2 Terms & Definitions: See last page of this Safety Data Sheet.
16.3 Disclaimer: This Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR §1910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & MGS USA LLC.’s
knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy, suitability or
completeness is not guaranteed and NO WARRANTIES OF ANY TYPE, EXPRESSED OR IMPLIED, ARE PROVIDED
INCLUDING THE WARRANTIES OF MERCHANTIBILITY AND FITNESS FOR A PARTICULAR PURPOSE. The
information contained herein relates only to the specific product(s). If this product(s) is combined with other materials, all
component properties must be considered. Data may be changed from time to time. Be sure to consult the latest
edition.
16.4 Prepared for: MGS USA LLC.
11711 Oakspine CT
Ellicott City, MD 21042 USA
Tel: +1 (310) 770-5209
Tel: +1 (917) 770-6635
Tel: +1 (443) 864-4986
Email: umetzler@mgs-beauty.com
16.5 Prepared by: ShipMate, Inc.
P.O. Box 787
Sisters, Oregon 97759-0787 USA
Tel: +1 (310) 370-3600
Fax: +1 (310) 370-5700
http://www.shipmate.com
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SAFETY DATA SHEET FOGO-001
Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, GHS & 1272/2008/EC Standards SDS Revision: 1.0 SDS Revision Date: 11/13/2019

DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a SDS. Some of these that are commonly used include the following:

GENERAL INFORMATION: NATIONAL FIRE PROTECTION ASSOCIATION: NFPA

CAS No. Chemical Abstract Service Number FLAMMABILITY LIMITS IN AIR:

RTECS No. Registry of Toxic Effects of Chemical Substances Number Autoignition Minimum temperature required to initiate combustion in air with no other source
EINECS No. European Inventory of Existing Commercial Chemical Substances Number Temperature of ignition
LEL Lower Explosive Limit - lowest percent of vapor in air, by volume, that will
EXPOSURE LIMITS IN AIR: explode or ignite in the presence of an ignition source
UEL Upper Explosive Limit - highest percent of vapor in air, by volume, that will
ACGIH American Conference on Governmental Industrial Hygienists explode or ignite in the presence of an ignition source
IDLH Immediately Dangerous to Life and Health
NOHSC National Occupational Health and Safety Commission (Australia) HAZARD RATINGS:
OSHA U.S. Occupational Safety and Health Administration
PEL Permissible Exposure Limit 0 Minimal Hazard
STEL Short Term Exposure Limit 1 Slight Hazard
TLV Threshold Limit Value 2 Moderate Hazard
TWA Time Weighted Average 3 Severe Hazard
4 Extreme Hazard
FIRST AID MEASURES: ACD Acidic
ALK Alkaline
CPR Cardiopulmonary resuscitation - method in which a person whose heart has
stopped receives manual chest compressions and breathing to circulate blood COR Corrosive
and provide oxygen to the body. W Use No Water
OX Oxidizer
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: HMIS TREFOIL Radioactive

HEALTH, FLAMMABILITY & REACTIVITY RATINGS: TOXICOLOGICAL INFORMATION:

0 Minimal Hazard HEALTH LD50 Lethal Dose (solids & liquids) which kills 50% of the exposed animals
LC50 Lethal concentration (gases) which kills 50% of the exposed animal
1 Slight Hazard FLAMMABILITY ppm Concentration expressed in parts of material per million parts
2 Moderate Hazard PHYSICAL HAZARDS TDlo Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
3 Severe Hazard PERSONAL PROTECTION
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or toxic effects
4 Extreme Hazard TC, TCo, LClo, & LCo
IARC International Agency for Research on Cancer
PERSONAL PROTECTION RATINGS: NTP National Toxicology Program
RTECS Registry of Toxic Effects of Chemical Substances
A G BCF Bioconcentration Factor
TLm Median threshold limit
log KOW or log KOC Coefficient of Oil/Water Distribution
B H
REGULATORY INFORMATION:
C I WHMIS Canadian Workplace Hazardous Material Information System
DOT U.S. Department of Transportation
D J TC Transport Canada
EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
E K NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
Consult your supervisor or SOPs for
F X special handling directions.
TSCA
EU
U.S. Toxic Substance Control Act
European Union (European Union Directive 67/548/EEC)
WGK Wassergefährdungsklassen (German Water Hazard Class)

WORKPLACE HAZARDOUS MATERIALS IDENTIFICATION (WHMIS) SYSTEM:

Face Shield &
Safety Glasses Splash Goggles Gloves
Protective Eyewear

Protective Clothing
Boots Protective Apron Dust Respirator
& Full Suit Class A Class B Class C Class D1 Class D2 Class D3 Class E Class F

Compressed Flammable Oxidizing Toxic Irritation Infectious Corrosive Reactive

Dust & Vapor Half- Full Face Airline Hood/Mask

Full Face Respirator CLP/GHS (1272/2008/EC) PICTOGRAMS:
Mask Respirator Respirator or SCBA

OTHER STANDARD ABBREVIATIONS:

Carc Carcinogenic
Irrit Irritant
NA Not Available
NR No Results GHS01 GHS02 GHS03 GHS04 GHS05 GHS06 GHS07 GHS08 GHS09
ND Not Determined
Harmful Health
NE Not Established Explosive Flammable Oxidizer Pressurized Corrosive Toxic Environment
Irritating Hazard
NF Not Found
SCBA Self-Contained Breathing Apparatus
Sens Sensitization
STOT RE Specific Target Organ Toxicity – Repeat Exposure
STOT SE Specific Target Organ Toxicity – Single Exposure