SAFETY DATA SHEET

I. IDENTIFICATION PRODUCT IDENTIFICATION DAVIES LIQUID-TILE CAST

PRODUCT DESCRIPTION An acrylic solvent based cast for concrete and wood surfaces. It fills dents, nail holes, deep fill marks,
crevices and other deep surface imperfection. It is easy to apply with very good workability and is fast
drying. It also possess high resistance to abrasion, shrinkage, alkali, water and excellent surface adhesion.
PRODUCT CODE DV-5-900
DATE CREATED 13 October 2009
DATE REVISED 1 August 2020
SUPPLIER'S DETAILS
Supplier's name: Davies Paints Philippines, Inc. Telephone Number: (02) 8641-7101
Address: 1387 Mercedes Ave., San Miguel Mobile Numbers: 0917-5721458 / 0922-8886491
Pasig City, Metro Manila Email: customercare@daviespaints.com.ph
1600 Philippines Website: www.daviespaints.com.ph

A. EMERGENCY OVERVIEW
II. HAZARDOUS
IDENTIFICATION Highly flammable liquid and vapour
Harmful if inhaled
Causes skin irritation
Causes serious eye irritation
Suspected of causing cancer
May damage fertility or the unborn child
May cause harm to breast-fed children
Causes damage to organs (respiratory system, liver, central nervous system, kidney)
May cause drowsiness or dizziness (narcotic effects)
Cause damage to organs (respiratory system, nervous system) through prolonged or repeated exposure (Inhalation: lung)
Toxic to aquatic life with long lasting effects
B. POTENTIAL HEALTH EFFECTS
INHALATION Breathing high concentrations may be harmful. Mist or vapour can irritate the throat and lungs. Breathing this material
may cause central nervous system depression with symptoms including nausea, headache, dizziness, fatigue,
drowsiness, or unconsciousness. Breathing high concentrations of this material, for example, in an enclosed space or by
intentional abuse, can cause irregular heartbeat.
EYE CONTACT Can cause serious eye irritation with tearing, redness, or a stinging or burning feeling. Further, it can cause swelling of
the eyes with blurred vision. Effects may become more serious with repeated or prolonged contact.
SKIN CONTACT May cause mild skin irritation with redness and/or an itching or burning feeling. Effects may become more serious with
repeated or prolonged contact. It is likely that some components of this material are able to pass into the body through
the skin and may cause similar effects as from breathing or swallowing it.
INGESTION Swallowing this material may be harmful. Swallowing this material may cause stomach or intestinal upset with pain,
nausea, and/or diarrhoea. This material can get into the lungs during swallowing or vomiting. Small amounts in the
lungs can cause lung damage, possibly leading to chronic lung dysfunction or death. Swallowing this material may
cause effects similar to those described in the inhalation section (see "inhalation" above).

III. COMPOSITION / List of hazardous ingredient(s)

INFORMATION ON Chemical Name CASRN % Concentration
INGREDIENTS Xylene, all isomers 1330-20-7 1 - 10
Toluene 108-88-3 1 - 10
Ethylbenzene 100-41-4 1-5
Dioxotitanium 13463-67-7 0.1 - 1.0

List of ingredient(s) with no available hazard classifications

Chemical Name CASRN % Concentration
Limestone 1317-65-3 40 - 50
Talc 14808-96-6 15 - 25
Page 1 of 9 Other ingredients do not present health or environment hazard
 DAVIES LIQUID-TILE CAST

EYE CONTACT IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
IV. FIRST AID
Continue rinsing. If eye irritation persists: Get medical advice/attention.
MEASURES
SKIN CONTACT IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off
contaminated clothing and wash before reuse.
INHALATION IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor or physician if you feel unwell.
INGESTION Do not induce vomiting. Keep rest. Get prompt medical attention.
NOTES TO PHYSICIAN INHALATION: Inhalation overexposure can produce toxic effects. Monitor for respiratory distress. If cough or difficulty in
breathing develops, evaluate for upper respiratory tract and pneumonitis. Administer supplemental oxygen with assisted
ventilation, as required.

V. FIRE FIGHTING Flash Point and Method 4 ºC (ASTM D56-05)

MEASURES Flammability Limit, by volume (LEL-UEL) 0.8 - 6.7 %
Autoignition Temperature 422 ºC
GENERAL HAZARD:
Highly flammable liquid; may release flammable vapors when temperatures are at or over the flash point. Toxic gases will form upon combustion.
FIRE FIGHTING INSTRUCTIONS:
Allow fire to burn out under controlled conditions or fight fire from a safe distance, extinguishing with foam, dry chemical, carbon dioxide or dry
sand. Do not use directly "WATER" to extinguish to avoid the danger of fire spread that may be caused by floating flammable material on the
water surface. But if possible to do without hazard, use water spray to cool fire exposed surface and isolate material from heat.
EXTINGUISHING MEDIA:
Carbon dioxide, foam, dry chemical or dry sand.
FIRE FIGHTING EQUIPMENT:
Respiratory and eye protection required for fire fighting personnel. Full protective equipment (Bunker Gear) and a self-contained breathing
apparatus (SCBA) should be used for all indoor fires and significant outdoor fires. For small outdoor fires, which may easily be extinguished with
a portable fire extinguisher, use of an SCBA may not be required.
HAZARDOUS COMBUSTION PRODUCT:
Smokes, fumes and oxide of carbon.

VI. ACCIDENTAL Provide maximum ventilation. Personal protection should be used. Remove all sources of ignition. Contain spilled liquid with sand or earth. Avoid
RELEASE runoff into storm sewers and ditches which lead to waterways. Take up spilled material with vermiculite, dry sand (Don't use organic material to take
MEASURES up or wipe for example: sawdust, cotton cloth or paper which cause fire by spontaneous chemical reaction with air and paint and organic materials)
and place in a disposal container.

VII. HANDLING Handle in sufficiently ventilated areas.

AND STORAGE Handling in closed areas requires local exhaust ventilation with a minimum capture velocity of 0.5 m/sec, at the point of vapor evolution.
Keep container closed. Loosen closure cautiously before opening.
Store in a cool, well ventilated place away from incompatible materials.
Keep away from heat, sparks and flame. Protect material from direct sunlight.

VIII. EXPOSURE The face, eyes, head, hands, and all other exposed parts of the bodies of employees handling paints shall be protected. All footwear shall be non-
CONTROLS / sparking, such as rubbers, rubber boots or rubber soled shoes without nails. Coveralls or other outer clothing shall be of cotton. Rubber, rather than
PERSONAL plastic, gloves shall be used because of the danger of static sparks.
PROTECTION No matches, lighted cigarettes, cigars, or pipes, and no cigarette lighters or ferrous articles shall be taken into the area where work is being done. All
employees continuously in a compartment in which painting is being performed shall be protected by air line respirators in accordance with the
requirements of the Occupational Safety & Health Administration (OSHA) and by suitable protective clothing. Employees entering such
compartments for a limited time shall be protected by filter cartridge type respirators in accordance with the requirements of the OSHA. All
employees doing exterior paint spraying shall be protected by suitable filter cartridge type respirators in accordance with the requirements of the
OSHA and by suitable protective clothing.
Page 2 of 9 Do not eat, drink, or smoke while handling it. Thoroughly wash the hands with soap and water before meals and at the end of the work shift.
 DAVIES LIQUID-TILE CAST

EXPOSURE GUIDELINE:
Chemical Name Threshold Limit Value
Limestone 10 mg/m3 (TWA8, ACGIH)
Talc 2 mg/m3 (TWA8, ACGIH)
Xylene, all isomers 100 ppm (TWA8, ACGIH)
Toluene 50 ppm, 188 mg/m3 (TWA8; skin; ACGIH)
Ethylbenzene 20 ppm (TWA8, ACGIH)
Dioxotitanium 10 mg/m3 TWA8 (ACGIH)

IX. PHYSICAL AND Appearance Off-white liquid

CHEMICAL Odour Characteristic odour
PROPERTIES Odour threshold Not available
pH Not available
Melting point -94.9 ºC
Initial boiling point and boiling range 111 ºC
Flash point 4 ºC
Evaporation rate (butyl acetate = 1) 0.76
Flammability (solid, gas) Not applicable because product is liquid
Upper/lower flammability or explosive limits, % volume 0.8 - 6.7 %
Vapour pressure 0.8 - 1.2 kPa
Vapour density (air = 1) 3.1
Relative density (water = 1) 1.79
Solubility in water Negligible
Partition coefficient: n-octanol/water Not available
Auto-ignition temperature 422 ºC
Decomposition temperature Not available
Viscosity Not determined

X. STABILITY AND STABILITY

REACTIVITY (Conditions to avoid) Avoid open flame electrical equipment sparks and other sources of ignition which induce fire. This product is considered
stable under normal and anticipated storage and handling conditions.
INCOMPATIBILITY
(Specific materials to avoid) Acid and alkali which contact may cause reaction (polymerization with heat).

XI. TOXICOLOGICAL Limestone

INFORMATION ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, skin and/or eye contact.
SYMPTOMS: Irritation of eyes, skin, mucous membrane; cough, sneezing, rhinorrhea (discharge of thin nasal mucus); lacrimation (discharge of
tears)
TARGET ORGANS: Eyes, skin, respiratory system
ACUTE ORAL TOXICITY: Classification is not possible due to lack of data.
ACUTE DERMAL TOXICITY: Classification is not possible due to lack of data.
ACUTE INHALATION TOXICITY: Classification is not possible due to lack of data.
SKIN CORROSION / IRRITATION: Classification is not possible due to lack of data.
SERIOUS EYE DAMAGE / EYE IRRITATION: Classification is not possible due to lack of data.
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: Classification is not possible due to lack of data.
GERM CELL MUTAGENICITY: Classification is not possible due to lack of data.
CARCINOGENICITY: Classification is not possible due to lack of data.
REPRODUCTIVE TOXICITY: Classification is not possible due to lack of data.
EFFECTS ON OR VIA LACTATION: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible due to lack of data.
ASPIRATION HAZARD: Classification is not possible due to lack of data.
Page 3 of 9
 DAVIES LIQUID-TILE CAST

Talc
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, skin and/or eye contact.
INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when
dispersed.
SYMPTOMS: Fibrotic pneumoconiosis, irritation eyes
TARGET ORGANS: Eyes, respiratory system, cardiovascular system
EFFECTS OF SHORT-TERM EXPOSURE: Classification is not possible due to lack of data.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the lungs, resulting in talc pneumoconiosis.
Depending on the degree of exposure, periodic medical examination is suggested.
ACUTE ORAL TOXICITY: Classification is not possible due to lack of data.
ACUTE DERMAL TOXICITY: Classification is not possible due to lack of data.
ACUTE INHALATION TOXICITY: Classification is not possible due to lack of data.
SKIN CORROSION/IRRITATION: Classification is not possible due to lack of data.
SERIOUS EYE DAMAGE/IRRITATION: Classification is not possible due to lack of data.
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: Classification is not possible due to lack of data.
GERM CELL MUTAGENICITY: Classification is not possible due to lack of data.
CARCINOGENICITY: The American Conference of Governmental Industrial Hygienists (ACGIH) reported talc is not classifiable as human
carcinogen and the International Agency for Research on Cancer (IARC) concluded there is Animal & Human Inadequate Evidence (Group 3).
Therefore, it is not classified as a carcinogen.
REPRODUCTIVE TOXICITY: Classification is not possible due to lack of data.
EFFECTS ON OR VIA LACTATION: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible due to lack of data.
ASPIRATION HAZARD: Classification is not possible due to lack of data.

Xylene, all isomers

ROUTES OF EXPOSURE: Xylene can affect the body if it is inhaled, if it comes in contact with the eyes or skin, or if it is swallowed. It may enter
the body through the skin.
SYMPTOMS OF EXPOSURE: Dizziness, excitement, drowsiness, incoordination, staggering gait, impaired reaction time, impaired short-term
memory; headache; eye, nose, throat irritation; corneal vacuolization; anorexia; nausea, vomiting, abdominal pain; dryness and scaling of the
skin, dermatitis; reversible liver and kidney damage after exposure to sudden high concentrations.
INGESTION ACUTE: Burning sensation in mouth and throat; abdominal pain.
TARGET ORGANS: CNS, eyes, skin, respiratory system, GI tract, blood, liver, kidneys.
ACUTE EXPOSURE: The signs and symptoms of acute exposure to xylene include headache, fatigue, irritability, lassitude, nausea, anorexia,
flatulence, irritation of the eyes, nose, and throat, and motor incoordination and impairment of equilibrium. Flushing, redness of the face, a
sensation of increased body heat, increased salivation, tremors, dizziness, confusion, and cardiac irritability have also been reported.
CHRONIC EXPOSURE: The signs and symptoms of chronic exposure to xylene may include conjunctivitis; dryness of the nose, throat, and
skin; dermatitis; and kidney and liver damage.
ACUTE ORAL TOXICITY: Based on the rat LD50 (oral route) value of 3,500 mg/kg representing the lower of the two testing data, 3,500 mg/kg
and 4,300 mg/kg, it is classified as Category 5.
ACUTE DERMAL TOXICITY: No definitive value available, although the substance can be classified as Category 5 or not classified based on
the rabbit LD50 (dermal route) value of >4,350 mg/kg.
ACUTE INHALATION TOXICITY: Xylene is not classified based on the rat LC50 (4 hour inhalation exposure) value of 29.08 mg/L (equivalent to
6,700ppm) was lower than 90% of the saturated vapor concentration (8,000ppm) under a saturated vapour pressure of 0.8 kPa (20 ºC), the
substance was considered as "vapour containing substantially no mist" and was classified based on standard values expressed in ppm.
SKIN CORROSION / IRRITATION: Classified as Category 2 based on the description in the report on the rabbit skin irritation test: "moderate
irritant".
SERIOUS EYE DAMAGE / EYE IRRITATION: Classified as Category 2A based on the description in the report on the rabbit eye irritation test:
"moderate irritant".
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: Classification is not possible due to lack of data.
GERM CELL MUTAGENICITY: It is not classified based on the negative data on human multi-generation epidemiological studies and somatic
cell mutagenicity tests in vivo (micronucleus/chromosome tests) and the absence of data on heritable mutagenicity tests, germ cell mutagenicity
tests in vivo and germ cell genotoxicity tests in vivo.
CARCINOGENICITY: The IARC reported there is inadequate evidence in humans for the carcinogenicity of xylenes and there is inadequate
evidence in experimental animals for the carcinogenicity of xylenes. Therefore, xylenes are not classifiable as to their carcinogenicity to humans
Page 4 of 9 (Group 3).
 DAVIES LIQUID-TILE CAST

The United States Environmental Protection Agency (EPA) has classified mixed xylenes as a Group D, not classifiable as to human
carcinogenicity.
The ACGIH classified xylene as category A4 Not classifiable as a human carcinogen.
The United States National Toxicology Program (NTP) reported there was no evidence of carcinogenicity of xylenes (mixed) for male or female
F344/N rats given 250 or 500 mg/kg or for male or female B6C3F1 mice given 500 or 1,000 mg/kg. Due to these facts, xylene is not classified as
carcinogenic.
REPRODUCTIVE TOXICITY: Several human studies examined exposure to organic solvents (including mixed xylenes) and developmental
effects. An increased potential for spontaneous abortions among the wives of occupationally exposed men was reported. However, no
conclusions can be drawn from these studies because they all involved concurrent exposure to multiple chemicals. Mixed xylenes have been
shown to produce developmental effects, such as an increased incidence of skeletal variations in fetuses, delayed ossification, fetal resorptions,
and decreased fetal body weight in animals via inhalation exposure. Some studies observed maternal toxicity as well. Thus, xylene is classified as
presumed human reproductive toxicant (Category 1B).
EFFECTS ON OR VIA LACTATION: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Based on the human evidence including "throat irritation, severe pulmonary
congestion, alveolar hemorrhage, pulmonary edema, congestion accompanying hepatomegaly, centrilobular vacuolation of hepatocytes, nerve
cell damage associated with dot hemorrhage, swelling and disappearance of Nissl bodies, limb cyanosis, a transient increase in serum
transaminase activity, an increase in the blood level of urea, a decrease in endogenous creatinine clearance in the urine, liver damage, severe
kidney damage, amnesia, coma" and "pulmonary congestion, pulmonary edema, focal alveolar hemorrhage," it is classified as Category 1 Target
organ toxicant and the evidence from animal studies including "strong narcotic effect," it is classified as Category 3 Target organ toxicant. The
basis for the classification includes data on xylene with unknown composition or containing other substances.

SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Based on the human evidence including "eye/nose irritation, thirst" and
"chronic headache, chest pain, abnormal electroencephalogram, dyspnea, cyanosis of the hands, fever, a decrease in WBC count, discomfort,
impairment of pulmonary function, a decrease in working capacity, physical/mental disorders," it is classified as Category 1 Target organ toxicant.
The basis for the classification includes data on xylene with unknown composition or containing other substances.
ASPIRATION HAZARD: Classified as Category 2 Aspiration toxicant based on the report that aspiration of xylene or acute exposure to high
vapor concentrations of this substance may cause chemical pneumonitis, hemorrhage into the air spaces, and pulmonary edema. A worker
exposed to the vapors of a solvent containing 75 percent xylene (approximate airborne xylene concentration of 60 to 350 ppm) developed
giddiness, anorexia, and vomiting. After inhalation of high (not further specified) concentrations of xylene, workers may become flushed, feel hot,
and experience confusion, dizziness, tremors, and other signs or symptoms of central nervous system toxicity.

Toluene
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin and by ingestion.
INHALATION RISK: A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.
SYMPTOMS: Irritation of eyes, nose; lassitude (weakness, exhaustion), confusion, euphoria, dizziness, headache; dilated pupils, lacrimation
(discharge of tears); anxiety, muscle fatigue, insomnia; paresthesia; dermatitis; liver, kidney damage
TARGET ORGANS: Eyes, skin, respiratory system, central nervous system, liver, kidneys
EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes and the respiratory tract. The substance may cause effects on
the central nervous system. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. Exposure at high levels may
result in cardiac dysrhythmia and unconsciousness.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The liquid defats the skin. The substance may have effects on the central nervous
system . Exposure to the substance may enhance hearing damage caused by exposure to noise.
Animal tests show that this substance possibly causes toxicity to human reproduction or development.
ACUTE ORAL TOXICITY: The acute oral LD50 was determined to be >5000 mg/kg body weight of rats, hence, it does not warrant classification.
ACUTE DERMAL TOXICITY: Acute dermal toxicity in the rabbit was found to be low (LD50 >5000 mg/kg), thus, it is not classified.
ACUTE INHALATION TOXICITY: The LC50 exceeded 20 mg/L (25.7 mg/L in males, 30 mg/L in females), therefore, it is not classified.
SKIN CORROSION/IRRITATION: Toluene is considered to be irritating to rabbit skin is classified as Category 2.
SERIOUS EYE DAMAGE/IRRITATION: Based on the description that the subjects recovered from the damage within 7 days in rabbit eye
irritation test conducted in accordance with the OECD test guideline, which suggests that toluene causes mild eye irritation. Hence, it is classified
as Category 2B.
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: Based on the results of guinea pig maximization tests according to Guideline EU Method B.6 (Skin Sensitisation) suggesting
that toluene causes no skin irritation. Thus, toluene does not require classification for sensitzation properties.
GERM CELL MUTAGENICITY: Toluene was not mutagenic in the mouse lymphoma assay (with or without metabolic activation) based on
equivalent or similar to OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test). Toluene was was not genotoxic when tested with
and without Aroclor 1254 metabolic activation in Salmonella typhimurium strains TA98, TA100, TA1535 and TA1537 at concentrations up to 1000
µg/plate (limit of cytotoxicity) using a liquid preincubation procedure based on equivalent or similar to EU Method B.13/14 (Mutagenicity -
Reverse Mutation Test Using Bacteria). Toluene is not genotoxic in mammalian cells in vivo . For these reasons, toluene is not classified for germ
Page 5 of 9 cell mutagenicity.
 DAVIES LIQUID-TILE CAST

CARCINOGENICITY: Due to the fact that the substance is classified as Group 3 by IARC (1999), Category A4 by ACGIH (2001) and Category
D by EPA (2005), toluene was not classified for carcinogenicity.
REPRODUCTIVE TOXICITY: Based on the results of human epidemiological studies suggesting increased incidence of natural abortion after
toluene exposure, abnormal development and malformation of newborns caused by prenatal toluene abuse and decreased plasma
concentrations of luteinizing hormone and testosterone after toluene exposure, described in IRIS Toxiological review (2005), EU-RAR No.30
(2003), IARC 71(1999), IARC 47 (1989), EHC 52 (1986) and ATSDR (2000), the following conclusion by Ng et al. (1992) in EU RAR30 (2003):
"the study suggests an increased risk of late spontaneous abortions associated with exposure to toluene at levels around 88 ppm (range 50-150
ppm).

The results of this study are used as a basis for the risk characterisation of developmental toxicity in humans,"and the evidence of increased
incidences of foetal death and delayed ossification, a decrease and unossification of sternebrae, a shift in rib profile, excess ribs, retarded skeletal
development, delayed reflex response, learning disability and early vaginal opening and testes descent at dosing levels not toxic to dams from rat
and mouse teratogenicity tests. On that account, toluene is classified as Category 1A or Known human reproductive toxicant.
EFFECTS ON OR VIA LACTATION: According to Da-Silva et al.(1991), toluene was accumulated in breast milk, although no developmental
toxicity via lactation was observed, therefore, toluene can be classified as hazard category for effects on or via lactation.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classified as Category 1 (central nervous system) based on the human
evidence including "toluene is rapidly absorbed mainly through inhalation and acts on the central nervous system. Toluene causes fatigue,
sleepiness, dizziness and mild respiratory irritation at 50-100 ppm, excitement associated with paresthesia and nausea at 200-400 ppm and
central nervous system suppression leading to drunkenness, delirium and abnormal gait at 500-800 ppm" (CERI Hazard Data 96-4, 1997) and
categorized as Category 3 (respiratory tract irritation, narcotic effects) "irritation to the eyes, nose and pharynx" (EU-RAR No. 30, 2003) and the
evidence from animal studies including "anesthesia" (EU-RAR No. 30, 2003).

SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classified as Category 1 (central nervous system, kidneys, liver) based on
the human evidence including "Toluene induces drug dependency, and inhalant abuse of toluene causes chronic central nervous system damage
including restricted vision, headache associated with nystagmus and hearing loss, tremor, ataxia and amnesia. Cerebral atrophy was found in CT
tests, and renal dysfunction manifested as proteinuria and hematuria was also observed (CERI Hazard Data 96-4, 1997), "hearing loss, changes
in brain-stem auditory evoked potential" (ATSDR, 2000) and "hepatic toxicity associated with an increase in SGOT, fatty degeneration of hepatic
cells and lymphocytic infiltration (EU-RAR No. 30, 2003).
ASPIRATION HAZARD: Classified as Category 1 based on the fact that toluene is a hydrocarbon and has a dynamic viscosity of 0.65 mm2/s
(25 ºC) (calculated value).

Ethylbenzene
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, ingestion, skin and/or eye contact.
SYMPTOMS: Irritation eyes, skin, mucous membrane; headache; dermatitis; narcosis, coma
TARGET ORGANS: Eyes, skin, respiratory system, central nervous system
INHALATION RISK: A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.
EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes , the skin and the respiratory tract. Swallowing the liquid may
cause aspiration into the lungs with the risk of chemical pneumonitis. The substance may cause effects on the central nervous system. Exposure
above the occupational exposure limit (OEL) could cause lowering of consciousness.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: This substance is possibly carcinogenic to humans. The substance may have effects
on the kidneys and liver, resulting in impaired functions Repeated contact with skin may cause dryness and cracking.
ACUTE ORAL TOXICITY: The calculated LD50 (Rat, oral) was 3,500 mg/kg. Therefore, it was classified as Category 5.
ACUTE DERMAL TOXICITY : The dermal LD50 for ethylbenzene in New Zealand White rabbits was calculated as 15,415 mg/kg body-weight.
Hence, it is not classified.
ACUTE INHALATION TOXICITY: The acute inhalation LC50, vapor, 4 hours for ethylbenzene in Carworth Wistar rats was calculated as 17.8
mg/L (4,000 ppm) body weight. For this fact, it is classified as Category 4.
SKIN CORROSION/IRRITATION: Undiluted ethylbenzene has been shown to produce moderate irritation when applied to the uncovered skin of
rabbits. The application of undiluted ethylbenzene to the ear and to the shaved abdomen of rabbits up to 20 times during a 4-week period
resulted in moderate irritation. There was erythema and edema with superficial necrosis and exfoliation of large patches of skin. From this fact,
ethylbenzene is classified as Category 3 (Mild skin irritant).
SERIOUS EYE DAMAGE/IRRITATION: Drop application to rabbit eyes caused slight irritation and no corneal injury demonstrable by fluorescein
staining. Standard testing on rabbit eyes gave an injury grade of 2 on a scale of 10. Ethylbenzene is classified as Category 2B (mildly irritating to
eyes).
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible because the available data were insufficient to
warrant a classification.
Skin sensitization: Classification is not possible because the available data were insufficient to warrant a classification.
GERM CELL MUTAGENICITY: In a National Toxicology Program study, ethylbenzene was not mutagenic in Salmonella tests and did not
induce chromosomal aberrations or sister chromatid exchange in Chinese hamster ovary (CHO) cells in vitro, although it did induce trifluoro-
thymidine resistance in mouse lymphoma cells at the highest concentration tested (80 mg/litre). There was no increase of micronuclei in the
Page 6 of 9 peripheral blood of mice exposed to ethylbenzene. Based on these data, ethylbenzene is not classified as mutagenic.
 DAVIES LIQUID-TILE CAST

CARCINOGENICITY: IARC reported that there is inadequate evidence in humans for the carcinogenicity of ethylbenzene but there is sufficient
evidence in experimental animals for the carcinogenicity of ethylbenzene. Thus, ethylbenzene is possibly carcinogenic to humans (Group 2B).
ACGIH classified ethylbenzene as A3; Confirmed animal carcinogen with unknown relevance to humans. From these facts, ethylbenzene is
classified as Category 2 (Suspected human carcinogen).
REPRODUCTIVE TOXICITY: Based on the description of mice/rat teratogenicity tests: Toxic effects on the embryo (urinary malformation) are
observed at dosing levels not toxic to maternal animals, it is classified as Category 1B (Presumed human reproductive toxicant).
EFFECTS ON OR VIA LACTATION: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Single high exposures to ethylbenzene through inhalation cause irritation of the
mucous membranes and central nervous system effects (2,180 ppm). Ethylbenzene is classified as Category 2 (central nervous system) and
Category 3 (respiratory tract irritation).
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible because the available data were insufficient to
warrant a classification.
ASPIRATION HAZARD: Classified as Category 1 Aspiration toxicant based on the description in International Chemical Safety Cards (ICSC):
Ethyl benzene, if swallowed, may cause chemical pneumonia due to misswallowing. The substance is a hydrocarbon, the kinematic viscosity of
which stands at 0.6 mm2/s (25 ºC).

Dioxotitanium
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation.
INHALATION RISK: A nuisance-causing concentration of airborne particles can be reached quickly when dispersed.
SYMPTOMS: Lung fibrosis; [potential occupational carcinogen]
TARGET ORGANS: respiratory system
ACUTE ORAL TOXICITY: The acute oral LD50 for female rat is >5,000 mg/Kg body weight according to the OECD Guideline 425 (Acute Oral
Toxicity: Up-and-Down Procedure) and EPA OPPTS 870.1100 (Acute Oral Toxicity). Thus, dioxotitanium is not classified.
ACUTE DERMAL TOXICITY: The dermal LD50 of rabbit is greater than 10,000 mg/Kg body weight which is set as outside of the acute toxicity
hazard categories, thus dioxotitanium is not classified.
ACUTE INHALATION TOXICITY: The approximate LC50 of titanium dioxide in male rats exposed head-only for 4 hours, is >6.82 mg/L (the
highest test concentration practical). According to the criteria specified by GHS and subsequent regulations dioxotitanium requires no
classification, ergo, it is not classified.
SKIN CORROSION / IRRITATION: According to OECD Guideline 404 (Acute Dermal Irritation / Corrosion) as tested on New Zealand White
rabbits, dioxotitanium is no skin irritant and requires no classification.
SERIOUS EYE DAMAGE / EYE IRRITATION: Causes eye irritation and was set as Category 2B (mildly irritating to eyes).
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: It was put outside of the Category based on a not sensitizing result of a patch test in humans.
GERM CELL MUTAGENICITY: Taking note the negative results in a mouse bone marrow micronucleus test and a chromosomal aberration test
by intraperitoneal administration (in vivo somatic cell mutagenicity tests), dioxotitanium was not classified. As vital information, there is a
description of a negative Chinese hamster SCE test (in vivo somatic cell genotoxicity test). From in vitro mutagenicity tests, there are reports of
negative Ames tests and negative chromosomal aberration and mouse lymphoma tests.
CARCINOGENICITY: In International Agency for Research on Cancer (IARC) Monograph Volume 93 (updated on 10 March 2006), it is stated
that there is inadequate evidence in humans for the carcinogenicity of dioxotitanium but there is sufficient evidence in experimental animals for
the carcinogenicity of dioxotitanium. Dioxotitanium is possibly carcinogenic to humans (Group 2B). Moreover, no significant exposure to
dioxotitanium is thought to occur during the use of products in which dioxotitanium is bound to other materials, such as in paints.
The American Conference of Governmental Industrial Hygienists (ACGIH) stated that dioxotitanium is not classifiable as human carcinogen (A4,
“There are inadequate data on which to classify the agent in terms of its carcinogenicity in humans and/or animals”). Dioxotitanium is set outside
of the Category.
REPRODUCTIVE TOXICITY: Classification is not possible due to lack of data.
EFFECTS ON OR VIA LACTATION: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible because the available data were insufficient to
warrant a classification.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible because the available data were insufficient to
warrant a classification.
ASPIRATION HAZARD: Classification is not possible due to lack of data.

XII. ECOLOGICAL This has the potential to be toxic in environments. Do not leak or waste in the environments without adequate waste disposal handling.
INFORMATION

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XIII. DISPOSAL Empty containers and material (including waste thinner for cleaning and flushing of containers or application equipment) must be disposed in
CONSIDERATION accordance with government and local environmental control regulations.
Do not heat or cut empty container with electric or gas torch due to residue.

XIV. TRANSPORT UN Number: UN1263

INFORMATION UN Proper Shipping Name: PAINT
Transport hazard class(es): Class 3
Packing group: II
Environmental hazards:
Marine pollutant according to IMDG Code: No
Environmentally hazardous according to UN Model Regulations: No
Environmentally hazardous according to ADR: No
Environmentally hazardous according to RID: No
Environmentally hazardous according to ADN: No
Special precautions for user:
EmS Guide: F-E, S-E
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Y (containing xylenes/ ethylbenzene (10% or
more) mixture
IATA Dangerous Goods and ICAO Technical Instructions for the Safe
Transport of Dangerous Goods by Air ERG Code: 3L

XV. REGULATORY Philippines Inventory of All components of this product are registered in the Philippines Inventory of Chemicals and Chemical Substances
INFORMATION Chemicals and Chemical (PICCS).
Substances (PICCS)

TSCA Inventory List All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.

Montreal Protocol No component of this product is listed on the Montreal Protocol on Substances that Deplete the Ozone Layer.

Stockholm Convention No component of this product is listed on the Stockholm Convention on Persistent Organic Pollutants.

Rotterdam Convention No component of this product is listed on the Rotterdam Convention on the Prior Informed Consent Procedure for
Certain Hazardous Chemicals and Pesticides in International Trade.

1998 United Nations

Toluene is listed in the List of Substances in Table II of the 1998 United Nations Convention Against Illicit Traffic in
Convention Against Illicit
Narcotic Drugs and Psychotropic Substances but it was also recorded in the Report of the International Narcotic
Traffic in Narcotics Drugs
Control Board (INCB) for 2014 that Toluene's licit uses are as follows: industrial solvent; used in the manufacture
and Psychotropic
of explosives, dyes, coatings, and other organic substances and as a gasoline additive. This product is a coating.
Substances

XVI. OTHER Legend to abbreviations and acronyms used:

INFORMATION CASRN means Chemical Abstract Service Registry Number
LFL - UFL means lower flammability limit - upper flammability limit
TWA8 means 8-hour time weighted average
LD 50 means the amount of a chemical, given all at once, which causes the death of 50% (one half) of a group of test animals
LC 50 (50% lethal concentration) means the concentration of a chemical in air or of a chemical in water which causes the death of 50% (one
half) of a group of test animals
GHS means the Globally Harmonized System of Classification and Labelling of Chemicals
IUCLID means the International Uniform Chemical Information Database
HSDB means the Hazardous Substance Data Bank
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 DAVIES LIQUID-TILE CAST

EHC means the Environmental Health Criteria

OECD means the Organisation for Economic Co-operation and Development
ECHA means the European Chemical Agency
UN means the United Nations
IMDG Code means the International Maritime Dangerous Goods Code
ADR means the European Agreement concerning the International Carriage of Dangerous Goods by Road
RID means the Regulations concerning the International Carriage of Dangerous Goods by Rail
ADN means the European Agreement concerning the International Transport of Dangerous Goods by Inland Waterways
EMS Guide means the Emergency response procedures for Ships Carrying Dangerous Goods
MARPOL 73/78 means the International Convention for the Prevention of pollution from Ships, 1973, as modified by the Protocol of 1978
relating thereto, as amended
IBC Code means the International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk (International
Bulk Chemical Code)
IATA means the International Air Transport Association
ICAO means the International Civil Aviation Organization
ERG Code means the Emergency Response Drill Code as found in the ICAO document “The Emergency Response Guidance for Aircraft
Incidents Involving Dangerous Goods”

The information herein is given in good faith but we cannot guarantee that these are the only hazards which exist. Final determination of
suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.

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