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Topic : MOLE CONCEPT & ATOMIC STRUCTURE.
1. Which of the following is correctly matched 6. Calcium carbonate reacts with aqueous HCl to
*
according to S.I. unit ? give CaCl2 and CO2 according to the reaction
CaCO3 + 2HCl(aq) → CaCl2 + CO2(g) + H2O(ℓ)
(1) Mass : gram What mass of CaCO3 is require to react with
(2) Distance : kilometer 500 ml of 2 M HCl ?
(3) Volume : (meter)3 (1) 100 g (2) 50 g (3) 150 g (4) 200 g
*
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(4) Density : g/ml See S.I. unit 7. On heating, calcium carbonate dissociates into
CO2 and CaO. What volume of CO2 will be
2. Which of the following prefix is correctly produced at 1 atm and 273 K on heating 50 g
matched with their multiples ? CaCO3 sample ?
(1) micro = 106 (2) mega = 10–6 (1) 11.2 ℓ (2) 22.4 ℓ
(3) nano = 10–9 (4) giga = 10–12 (3) 50 ℓ (4) 5.6 ℓ
3. Which of the following does not follow law of 8. On heating Calcium carbonate, CaO(s) and
NCERT definite proportionation with other three ?
U
CO2(g) is produced. What mass of residue is left
behind on heating 200 g of CaCO3(s) ?

a
d
(1) Rain water (2) Well water
(1) 56 g (2) 44 g
(3) River water (4) Heavy water
(3) 112 g (4) 88 g
4. "Equal volume of gases at the same 9. In nature iron is found in three isotopic forms
temperature & pressure should contain equal Fe54, Fe56 and Fe57 and - natural abundance of
number of molecule". It is :- these isotopes are 5%, 90% and 5% respectively.
(1) Law of Multiple proportion What will be the atomic mass of iron ?
(1) 56 (2) 55.95 (3) 56.5 (4) 55
(2) Avogadro's law
(3) Law of Gaseous volume
10.
88
1 amu is AIIMS PUQ
*
(1) 1.67 × 10–21 mg (2) 1.67 × 10–28 kg
(4) Law of Definite proportion
5. Which of the following is a pure substance ? (3) 1.67 × 10–23 g (4) All are correct

T
11. If radius of earth is 6400 Km. Which value is
(1) Tap water
correct according to S.I. unit for the diameter of
(2) Air earth ?
(3) CH4(g) NCERT (1) 64 × 105 m (2) 128 × 105 m
Line
(4) All are pure substance (3) 128 × 107 cm (4) 64 × 107 cm
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12. What will be the formula mass of NaCl ?
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17. Which of the following is correct relation
(1) 58.5 g (2) 58.5 u between molarity (M) and molality (m) if
density of solution is 1 g/ml ?
(3) 23 u (4) 234 u
(1) M = m
13. Which of the following will be equivalent to 1 mol ?
X (2) M > m
* (1) Number of O atoms in 32 g O2 sample
conceptual (3) Number of O molecules in 16 g O sample
(2) Number of C14 atoms in 12 g C14 sample
(3) M < m
(4) We can't predict without Mw (solute)
2 2
18. Which statement is correct for the reaction
(4) Number of H atoms in 1 g H2 sample Al N2(g) + 3H2(g) → 2NH3(g)
14. For which of the following reaction law of (1) 10 g N2 and 30 g H2 will produce 40 g NH3
mass conservation is not valid ?
(2) 10 ℓ N2(g) and 30 ℓ H2(g) will produce 40 ℓ NH3(g)
(1) C + O2 → CO2
(3) 10 ℓ N 2(g) and 30 ℓ H 2(g) will produce
(2) CaCO3(s) → CaO(s) + CO2(g)
20 g NH 3(g) at any temperature and
(3) Photosynthesis reaction pressure
235
(4) 92U + 0n1 → 36Kr91 + 56Ba142 + 30n1 (4) 28 g N2 and 100 g H2 will produce 34 g NH3(g)
15. How many significant figure are there in the 19. Which of the following combination will
0.02856 298.15 0.112 * produce the largest amount of HCl according to
answer of
0.5785
the reaction
(1) 3 H2 + Cl2 → 2HCl
(2) 4 (1) 2g H2 and 71 g Cl2
(3) 5 (2) 1 g H2 and 72 g Cl2
(4) Any number according to round off (3) 36.5 g H2 and 36.5 g Cl2
16. A2 reacts with B2 according to the reaction (4) All will produce equal amount of HCl
A2 + 2B2 → 2AB2
20.
Which of the following will have the largest
In which of the following condition B2 will be A
* Revise this
left behind in the container ? number of atoms ?
CONCEPT
(1) 1 mol A2 and 1 mol B2 (1) 1 g atom of Na
(2) 1 g atom of Li Curr Imp)
-

(2) 1 mol A2 and 2 mol B2

(3) 2 mol A2 and 1 mol B2 (3) 1 g atom of K
(4) 1 mol A2 and 4 mol B2 (4) All have same number of atoms
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21. Which of the following will have largest 25. Which of the following observations could not
number of atoms ? be explained with the help of electromagnetic
(1) 1 g Au(s) (2) 1 g Na(s) theory (classical physics)
(3) 1 g Li(s) (4) 1 g Cl2(g) (1) Black-body radiations and photo-electric
22. Which of the following compounds contain effect
same percentage of carbon ? (2) Variations of heat capacity of solids as a
(a) Glucose function of temperature
(b) Fructose
(3) Line spectra of atoms
(c) Acetic acid
(d) Ethanol (4) All of these
(1) a and b only 26. Which concept was used by Bohr to explain
structure of hydrogen atom and its spectra :
(2) b and c only
(1) Wave nature of light
(3) All have equal percentage of C
(2) de-Broglie hypothesis
(4) a, b and c
(3) Planck's concept of quantisation
23. Which of the following compounds will have
(4) Heisenberg's uncertainty principle
same empirical formula ?
27. What is number of photons of light with a wave
(a) Glucose Y
length of 4000 pm that provide 100 J of energy?
(b) Fructose
(1) 2 × 1019
(c) Acetic acid
(2) 2 × 1027
(d) Ethanol
(3) 2 × 1018
(1) a and b only (2) All
(4) 2 × 1017
(3) b and c only (4) a, b and c
28. Electromagnetic radiation of wavelength 248 nm
24. Which particles will be produced on V is just sufficient to ionise the sodium atom.
bombarding a thin sheet of beryllium by
*
α -particles : Ionisation energy of Na(g) is : (NA = 6 × 1023)
(1) Proton (1) 120 kJ/mol
(2) Beta-particle (2) 296 kJ/mol
(3) Neutron (3) 132 kJ/mol
(4) Positron (4) 480 kJ/mol
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29. Life times of the molecule in excited state are often 33. "Every object in motion has a wave character".
measured by using pulsed radiation source of This statement is given by :
duration nearly in the nanosecond range. If (1) Heisenberg
radiation source has the duration of 2 ns and the
number of photons emitted during the pulse source (2) de-Broglie
is 2.5 × 1015 J. Calculate the energy of the source. (3) Bohr
(1) 3.28 × 10–11 J (4) Schrodinger
(2) 8.28 × 10–10 J 34. How many quantum numbers are enough to
(3) 5.28 × 10–12 J explain the line spectrum of multi-electron
atom.
(4) 8.28 × 10–9 J
(1) 1
30. Neon gas is generally used in the sign boards. If
it emits radiation of 600 nm. Maximum distance (2) 2
traveled by this radiation in one minutes. (3) 3
(1) 4 × 107 m (4) 4
(2) 7.8 × 108 m 35. Total number of nodal surfaces in 3p orbital are :
(3) 4.2 × 109 (1) 0 Torn
in all
(4) 1.8 × 1010 m (2) 1 Orbitals .

31. An element has mass number 84 and it has 10% (3) 2

more neutrons as compared to protons. Atom (4) 3
can be represented as :
36. In a multi-electronic species which of the order
(1) 44 Zr
40
(2) 46 Sr
38 corresponding to energy is incorrect :
(3) 47 Rb (4) 43 Nb
37 41 (1) 4s < 3d (2) 4f < 6p
32. Which of following are limitations of Bohr's model : (3) 6s < 5d (4) 5d < 4f
(a) It could not explain ability of atoms to form
37. If energy of 3s orbital is represented by E3s then
molecules by chemical bond
which of the following is correct :
(b) It fails to account for the finer details of H-spectrum
(c) It fails to explain spectrum of multi electronic (1) E3s(H) = E3s(Li) = E3s(Na)
species (2) E3s(H) > E3s(Li) > E3s(Na)
(d) It fails to explain stability of H-atom
(3) E3s(H) < E3s(Li) < E3s(Na)
(1) Only b, c, d (2) Only b, c
(4) E3s(Li) > E3s(Na) > E3s(H)
(3) Only a, b, c (4) All
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38. Maximum number of electrons in a shell are 42. A microscope using suitable photons is
equal to : employed to locate an electron in an atom within
a distance of 10 Å. What is the uncertainty
(1) n
involved in the measurement of its velocity ?
(2) 2n (1) 5.8 × 10–6 m/s
(3) n2 (2) 5.8 × 106 m/s

2
(3) 5.8 × 104 m/s
(4) 2n
(4) 5.8 × 10–4 m/s
39. Which of the following configuration has
43. A golf ball of mass 100 g and a speed of 50 m/s.
maximum exchange energy :
-
If the speed can be measured within accuracy of
(1) d1 2 %, uncertainity in position will be :
(1) 1.6 33
(2) d2 10 m
π

(3) d5 (2) 6.6 37

10 m
π
(4) d8 (3) 1.2 28
10 m
π
40. "Only two electrons may exist in the same
V orbital and these electrons must have opposite (4) 1.6 × 10–33 m
Al 44. Number of degenerated orbitals in 3rd shell of
spin". This statement belongs to :
H atom are :

Dement (1) Hund's rule

(2) Pauli exclusion principle 45.
(1) 3 (2) 5 (3) 9 (4) 18
Which statement is/are correct for 1s orbital :
(a) spherical
(3) Aufbau prinicple
(b) Non-directional
(4) de-Broglic hypothesis (c) Probability density is maximum at nucleus
41. Which of the following property of an electron and it decreases sharply as we move away from
does not remain always constant in an atom : it.
(1) Mass (1) Only a
(2) Charge (2) Only a and b
(3) Spin angular momentum (3) Only b
(4) orbital angular momentum (4) a, b and c
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ANSWER KEY
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
A. 3 3 4 2 3 2 1 3 2 1 2 2 4 4 1 4 3 4 1 4 3 4 4 3 4 3 3 4 2 4
Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A. 1 3 2 4 2 4 2 4 3 2 4 3 1 3 4 4 2 2 2 3 1 1 2 3 2 4 4 1 2 2
Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A. 4 3 2 4 4 4 3 1 3 3 3 1 3 2 1 2 1 1 1 2 3 2 4 3 2 2 3 2 4 1

HINT – SHEET

1. Ans ( 3 ) 7. Ans ( 1 )
Volume = ℓ × b × h CaCO3 → CaO + CO2
= m.m.m 50 1
mol of CaCO3 =
Volume = m3 100 2
volume of CO2 = mol × 22.4 ℓ
2. Ans ( 3 ) 1
22.4 11.2ℓ
nano = 10–9 2
8. Ans ( 3 )
micro = 10–6
CaCO3 → CaO + CO2
mega = 106 200
mol of CaCO3 = 2
giga = 1012 100
mol of solid residue (CaO) = 2
3. Ans ( 4 ) wt. of CaO = 2 × 56 = 112 g
Heavy water D2O 9. Ans ( 2 )
All other H2O 5 54 56 90 57 5
M avg
5. Ans ( 3 ) 100
Tap water and air are mixture. = 55.95
11. Ans ( 2 )
6. Ans ( 2 ) radius = 6400 km
500 = 6400 × 103 m
Mol of HCl = (M × V) = 2 1
1000 = 64 × 105 m
1
Mol of CaCO3 = diameter = 64 × 2 × 105
2
= 128 × 105 m
1
wt. of CaCO3 = 100 50g
12. Ans ( 2 )
2
NaCl = 23 µ + 35.5 µ
= 58.5 µ