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DPP-11 Text Solution 20230717095930

The document contains 20 multiple choice questions related to basicity, acidity, and resonance of organic compounds. The questions cover topics such as determining the order of basicity or acidity for various organic molecules, identifying which structures exhibit certain effects like inductive or resonance effects, and calculating bond orders and lengths in conjugated systems.

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38 views4 pages

DPP-11 Text Solution 20230717095930

The document contains 20 multiple choice questions related to basicity, acidity, and resonance of organic compounds. The questions cover topics such as determining the order of basicity or acidity for various organic molecules, identifying which structures exhibit certain effects like inductive or resonance effects, and calculating bond orders and lengths in conjugated systems.

Uploaded by

ansarinaved8920
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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DPP No.

11
TARGET : JEE-2024 Max. Time : 40 Min.

DPP No. : 11 (JEE-MAIN)


SCQ (Single Correct Type) :
1. Arrange basicity of the given compounds in decreasing order:
(i) CH3 – CH2 – NH2 (ii) CH2  CH – NH2 (iii) CH  C – NH 2
(A) i > ii > iii (B) i > iii > ii (C) iii > ii > i (D) ii > iii > i
Ans. (A)
Sol. – I effect  Basic strength .

2. Which molecule have highest Kb value ?

(A) (B) (C) (D)

Ans. (D)

3. Which molecule have lowest pkb value ?

(A) (B) (C) (D)

Ans. (D)
4. Which molecule have more tendency to accept H ?

(A) (B) (C) (D)

Ans. (A)
5. Which nitrogeous base is most basic in aqueous medium.

(A) (B) (C) (D)

Ans. (B)
6. Choose the strongest base among the following :

(A) (B) (C) (D)

Ans. (D)
Sol. Only in (D) the l.p of N atom is not involved in resonance with benzene ring.

PAGE # 1
7. Write the basicity order of the following compounds?

(A) I > III > IV > II (B) I > II > III > IV (C) I > IV > III > II (D) I > III > II > IV
Ans. (C)
8. The strongest base is :

(A) (B) (C) (D)

Ans. (B)
Sol. Nitrogen is less electronegative than oxygen & thus more basic atom & RNH2 is more basic than Ph-NH2
because lone pair of N is delocalised in Ph-NH2

9. Consider the set of three compounds, one set of three compound being
(1) MeNH2 (2) Me2NH and (3) Me3N and another set of three compounds being
(4) EtNH2 (5) Et2NH and (6) Et3N
Which is true about basicity of these compounds in water ?
(A) 2 > 1 > 3 and 5 > 4 > 6 (B) 2 > 3 > 1 and 5 > 4 > 6
(C) 2 > 1 > 3 and 5 > 6 > 4 (D) 3 > 2 > 1 and 6 > 5 > 4
Ans. (C)
Sol. In RNH2, R2NH, R3N; the order of base strength is 2º > 1º > 3º when R = Me and the order is 2º > 3º > 1º
when R  Me.

10. Which of the following will accept H+ ion with fastest rate ?

(A) (B) (C) (D)

Ans. (D)
11. In which of the following molecules all the effects namely inductive, mesomeric and hyperconjugation
operate :

(A) (B) (C) (D)

Ans. (C)

Sol.

H.C.
has all effect inductive, mesomeric & hyperconjugation.

PAGE # 2
12. The correct bond order is

(A) a > b > c (B) b > a > c (C) c > a > b (D) c > b > a
Ans. (C)

Sol. 
 



13. The bond length order of C = C in the following compound

, , ,

(A) I > II > III > IV (B) IV > III > II > I (C) IV > I > III > II (D) II > III > I > IV
Ans. (B)

14. (X) (C6H3ClBrCOOH) are a dihalosubstituted benzoic acids. The strongest acid among all isomers is -

(A) (B) (C) (D)

Ans. (B)

Sol. (Due to ortho effect)

15. What is the acidity order of the following compounds

(A) I > II > III > IV (B) II > III > IV > I (C) V > III > I > II > IV (D) V > III > II > I > IV
Ans. (C)

PAGE # 3
16. The H ion is most readily lost by :

(A) (B) (C) (D)

Ans. (D)
Sol. Benzoic acid is stronger acid than phenols.

17. The correct acid strength order is

(A) (B)

(C) (D)

Ans. (C)
Sol. o-Toluic acid is stronger acid than benzoic acid due to ortho effect.
18. The order of acidity of following acids is :

(A) I > II > III > IV (B) IV > III > II > I (C) IV > I > III > II (D) IV > III > I > II
Ans. (C)
19. Which of the following compound is not a resonance stablized?

(A) (B) (C) (D)

Ans. (B)
20. Number of  electrons in conjugation for these compounds

, , and will be respectively :

(A) 6, 6, 6, 6 (B) 6, 4, 6, 6 (C) 8, 6, 6, 6 (D) 6, 6, 8, 6


Ans. (A)

PAGE # 4

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