(This question paper contains 8 printed pages.

Your Roll No. 22000

Sr. No. of Question Paper: 2033

Unique Paper Code 2354001202

Name of the Paper : Introduction to Linear

Algebra
Name of the Course GE

Semester : II

Duration: 3 Hours Maximum MarkS : 90

Instructions for Candidates

1. Write your RollNo. on the top immediately on receipt

of this question paper.

2. Attempt allquestion by selecting two parts from each

question.

3. Part of the questions to be attempted together.

4. All questions carry equal marks.

1. ya) If x and y are vectors in R" then prove that

x.y| s (llx|Dllyl).

P.T.0.
2033 2 3
2033
Also verify it for vectors x -1,-1, 0] and Find Rank of the matrix
2. () Define rank of a matrix.

[3 5 21
y-[/2.Aa]. A=l 4 2 3

|-1 2 4
Use Gaussian Elimination to solve the following
system of linear equations. Indicate whether the ( Find all Eigen values corresponding to the matrix
A. Also, find the eigenspace for each of the eigen
system is consistent or inconsistent. Give the
complete solution set, if consistent.
[12 -51|
value of the matrix A, where A=
3x - 3y - 2z = 23

-6x + 4y + 3z -40 F3 1 -2]

Let A= 4 0 1 Determine whether the
-2x + y + z = -12 -2 4 -3
vector X = [5, 17, -20] is in row space of the
Use Gauss-Jordan row reduction method to find
matrix A. If so, then express X as a linear
the complete solution set for the following system combination of the rows of A.

of equations.

4x - 8y - 2z = 0 3. (a) Let V be a vector space. Let H and K be

subspaces of V. Prove that H n K is also a
3x - 5y - 2z = 0 subspace of V. Give an example to show that
HUK need not be a subspace.
2x - 8y + z = 0

P.T.O.
2033 4 2033 5

b) Prove or disprove that the set S={[1,2,1], [1,0.21 (b) Define linearly independent subset of a finite
[!,1,0]} forms a basis of RI. dimensional vector space V. Use Independent Test
Method to find whether the set S = {[1,0, 1,2],
e) Use the Diagonalization Method to determine [0,1,1,2], [1,1,1,3], (-1,2,3,1] }of vectors in R4 is
whether the matrix A is diagonalizable. If so. linearly independent or linearly dependent.
specify the matrices D and P and verify that
P-AP = D, where (c) Define basis of a vector space V. Show that the
subset {[1,0,-1], [1,1,1],[1,2,4]} of R forms a basis
19 -48 of R3
8 -21

5. (a) (i) Determine whether the following function is

a Linear Transformation or not?
(a) (i) Let S = {(x,y,z): x+y=z x, y, z E R}.
Show that S is a subspace of R³. L: R ’ R given by
L((x, X, X,]) = , xy, x,].
() Consider the vector space M(R) and the
sets
(ii) Suppose L: R R is a linear operator and
T,: the set of nonsingular 3x3 matrices
LÊ1,0,0] = -2,1,0], L[0,1,0] = [3,-2,1] and
T,: the set of singular 3x3 matrices. L[O,0,1] = [0,-1,3].

Determine T, and T, are subspaces of Find L[-3,2,4]. Give a formula for L[x, y, z],
Mu(R) or not? for any [x, y, z] E R°.

P.T.0.
2033 6 2033 7

(b) Consider the linear Transformation L: P,(R) -’ 6 (a) Let L: R' ’ R' be given by
Ma(R) given by
1
-3a -2c -b+ 4d
0
L(ax³ + bx? + cx + d) |4b-c+3d -6a -b+2d
1 -1 -] X,

Find the matrix for L with respect to the standard

(i) Is [1, -2, 3] in
basis for P, and M,: Also, Find the
dimension of Ker(L)? Why or why not?
(ii) Is [2, -1,4] in
Ker(L) and Range(L). Range(L)? Why or why not?
(b) Consider the linear
(c) Let L: P, ’ P, be given by
M3x3 given by
Transformation L: M,wa ’

L(p) =JP, for, p e P L(A) = A - AT,

where, A' represents the

A. Find the Ker(L) and
transpose of the matrix
Where, p represents the integration of p. Range(L) of the Linear
Find the matrix fr L with
respect to the Transformation, and verify
matrix to
standardbasis for P, and P,. Use this dim(Ker(L)) + dim(Range(L)) = dim(M,.).
matrix
calculate L(4x - 5x2 + 6x - 7) by
(c) Suppose that L: V ’ W is a
multiplication. linear Transformation.
Showthat if {L(v,), L(v,), ., L(v,)} is a
linearly
independent set of n distinct vectors in W, for

P.T.0.
2033 8

V,, Vy,
Some vectors V,, V ., v, e¬ V, then (v,, v,,
v}is linearly independent set in V. Is the converse
true? Justify with examples. Under what condition
the converse holds true, Justify.

(2000)
 [This question paper contains 8 printed pages.]
Your Roll No.200

Sr. No. of Question Paper : 1196 F

Unique Paper Code : 2172011201

Name of the Paper Chemistry of S- and P- Block

Elements

Name of the Course B.Sc. (Hons.) Chemistry

Semester : II

Duration :3 Hours Maximum Marks:90

Instructions for Candidates
1. Write your RollNo. on the top immediately on receipt
of this question paper.

2. Attempt any Six questions.

3. All questions carry equal marks.

1. Explain the following: (3×5)

() Graphite is a good conductor of electricity while

diamond is not.

P.T.0.
 2.
1196
() Na,c0, ()
statement. when Water.
o)
metals.
Chemistry slopeExplain 93°C. The isDilute increases
lonisation
blue
lineupward bond
why colouredsolution
Give crosses from
of is angle energy
Lithium most
from more of A1
examples in and
AG lines NH, alkali to
decreases
is left soluble paramagnetic Ga.
different =0? is metals
to in
in the 107°C
right.
Ellingham than in from
support from
What while liquid
in B
other NaHC0, nature. to
of happensdiagram in ammonia
alkali PH, A1
(5) the (5) but
in is

1196
(c) (b) (a) (c)
Why What structureand and onWhen cryptands. the
ethersand Explain is
comparison Why
further alkali syrupy
then
do are
heated is
helium briefly white
clathrates decreasesheating metals and
oxidation sulfur to
and the viscous. red
the with phosphorous
neon
compounds melts complex phosphorous? 3
again.
viscosity special
state Explain.
not to
of
Explain. a formation
form mobile reference
sulfur increases very
of
clathrates? noble
Phosphoric
in Give liquid, tendency reactive
to
P.T.0. gases? sharply
H,SO,. crown
(5) (5) the but (5) (5) acid in
of
 in diborane
Diborane. high (5) following (5) they (5) P.T.0.
at
are
Why halogens?
whenand the
low of
compounds?
bonding
formed structure
at to
ammonia acetate. compared
and products interhalogen
structure the beryllium
5 excess
temperatures?explain as
reactive
the
the compounds: Basic
(b}Diarescusswith and 1C1,
(1) are
What
(go
6. more
What reacts Draw (ii)
1196 (c)
and-Zone
(S) (5) stronger
reactions: (5) Beryllium),
most (5)
the
Hydrometallurgy a
following is have
PbC1,Explain. (except
and
H0 effect?SnC1,. metalsmetal reason.
the
A AgNOs+ softest
4 on balance (s) Give
XeF4
+
H0(NO:)2 BH6
+
H;0 pair than earth
note P4
+HNO3
inert the sulfate?
short and + agent alkaline
Mg SiH4 the be
Refining. Complete will
a
4.(aWrite is oxidizing Among insoluble
() (i) (ii) (iv) (v) What which
1196 (b) (a)
 7.
1196
(b) (a)
for of (b)
Arrange (j Diagram:Explain Arkel XeF,? areDiscuss
the their not Cr,0, no
detailsGivof
e
For the
same boiling the need de
be extraction the advantages the
Bocr
following reduced can
H,Se, points to following structure
be add process.
reduced Electrolytic
reduction
and
H,0, and by of
hydrides a
metals of 6
Cr. reductant. this of
H,Te, bond according
by theory XeF,
angle. from
in A1,
and increasing
HgO using
but to over
H,S. Give Al,0, and Ellingham MOT.
reasons V
order Ag,0, BT
(5) Can yan
(5) (S) (5) for What

8. 1 96
(b)
(a) (c)
as
Write Althoughthe ) Discuss Oxygen
an
maximum
strongest
solution.
Why? group.
electronegativity
main Variation S,
Allotropes ) a exists
short briefly molecule.
as
note reducingamongst the an
of theof
Carbon on following- Explain, 0, 7
ionization among
any molecule
twO agent alkali
atomic
radii
the
of while
the
inmetalsenergy elements
the sulfur
following:
aqueous it of
P.T.0. is of exists
the Li the and (5)
(5) is
 (5x2) (1500).
15
group
of chlorine
elements
8 of
oxo-acids
of
Hydrides
The
G) (iii)
1196
 Attemptany 3. 2. 1.
Instructions
Candidates Hours Semester
foDuration:
r 2 Name Name Unique
Paper
Code Sr. [This
compulsory. Attempt ofWrite No.
of of question
this the the of
question your Question
Course Paper
all paper
Each four parts Roll
paper. No. Paper contains
questions
question of
on
: 2172011202
: Haloalkanes, : : :
question a the II Haloarenes,
Alcohols,
Phenols,
Epoxides
B.Sc Ethers
and 1215 8
top
carries in No.?:20.9
YourRoll printed
immediately (Hons)
all. together.
Maximum
Marks: 60
15
Question pages.]
Chemistry
marks.
on Arenes, F
P.T.O. no receipt
1
is
 (d) 1215
(e) (c)
ethanol in
2-Bromopentane b) (a) for
Resorcinol
ZnCl, 200°C. Allyl presence of
AlC13:Benzene pressurePhenol product(s)
Writhte
the
Phenyl following.
is in is
is presencetreated
treated ether treated
is Name
treated with
with is with of with 2
heated the
complete
with sodium
CH,CN isopropyl carbon reaction.
sodium at
hydroxide, chemical
in temperature dioxide
methoxide presence chloride
(3x5=15)
reaction
under
of of in

2. 1215
3.
sá) (c) (5) (a) Give
(d)
aromatic Define Sy2
Neopentyl substitution
groups Reactivity well S,l p-Methoxy and
p-Niphenol.
trophenol reason
type as
reactions
aromaticity. at inversion for
or of
halides ortho
antiaromatic. reactions. increases of are the
aryl is
and of more following
are accompanied 3
Classify para halidesconfiguration.
slow with acidic
Justify position. (any
towards substitutiontowards than
these by
your
compounds both
racemization o-Nitrophenol three):
nucleophilic
answers (5x3=15) of
S,l
P.T.0. nitro
and as
as
1215 4
5
|215

()
(iv)
N

products formed
Explain the formation of different
(b)
NaCN and
is treated with
when ethyl bromide
AgCN.
(i)
and para directing
té) "CH, group of toluene is ortho
directing
whereas CHO in benzaldehyde is meta
reactions".
in electrophiiic aromatic substitution
Explain. (5x3=15)

i)
Illustrate the following:

(a) Internal Nucleophilic Substitution reaction with

stereochemical aspects.

P.T.0.
1215 6 7
1215
(any
(b) Hydrolysis of substituted epoxide under acidic and 6. Give the mechanism for the following reactions
basic conditions. three)

(c) Industrial preparation of phenol from benzene. Why

this process is considered to be an Cetls CHa
economical dil. H,SO4
process? -CHa
(5x3=15)
OH OH

Explain the following:

(a) Advantages of Friedal Craft's Acylation over

(b)
-CH3
Friedal Craft's Alkylation.
AICl,

(b) Only m-methoxyaniline is obtained when o

bromomethoxybenzene Or m

bromomethoxybenzene is treated with NaNH, in

liquid NH,
ÇH,OH Pb(OAc)4
(c)
(c) Secondary and tertiary alkyl halide are not used in CH,OH

the Willamson synthesis reaction. (5x3=15)

P.T.0.
1215 8

18 HH,O
HsC--OH + HgC0
(o labelled
Methyl Alcohol)

(Sx3=15)

(1500)
 [This question paper contains 8 printed pages.]
Your Roll No.220

Sr. No. of Question Paper: 1234 F

Unique Paper Code : 2172011203

Name of the Paper : CHEMICAL

THERMODYNAMICS AND
ITS APPLICATIONS

Name of the Course : B.Sc. (H) Chemistry

Semester : II

Duration: 3Hours Maximum Marks : 90

Instructions for Candidates

1. Write your Roll No. on the top immediately on receipt

of this question paper.

2. Attempt six questions in all.

3. Q.1 is compulsory.
4. Use of scientific calculators is allowed.

1. Attempt any five:

Why is the value of heat capacity at constant

pressuregreater than the value at constant volume?

P.T.0.
1234 2
3
1234
(b) Reversible processes cannot be carried n . ideal
isothermal expansion of
reality. Explain. (i) Reversible
gas.

(c) Partial molar volume of a component in a superheated water above

solution (ü Vaporization of
depends on the nature as well as the amount of
100°C.
the other components. Explain qualitatively.
(j) Melting of ice at freezing point.
(d) Steam at 1 bar is (5x3=15)
converted to liquid water
spontaneously at temperatures below 100°c
although this results in decrease in its entropy. of state of a gas is
(Yif the equation
Explain.

P+5V= RT; Show that P is a state function.

a

(e) If Joule Thompson Coefficient is positive for a

gas it indicates that attractive forces dominate
between molecules of the gas. Is this statement +1=0.
Also prove that OP
true? Explain giving reason

() Why is the partial molar Gibbs free energy called N(b) Show that isothermal reversible work of expansion
as Chemical potential? of an ideal gas is greater than that of a van der
Waals gas under similar conditions?.
Which of the following processes are
spontaneous
and why?
P.T.0.
 4
1234 5
1234
(c) The value of Cpm for a sample of a
perfect gas
was found to with
vary
temperature C./JK-I
as
relation Cp -Cy
mol-! =20.17 + 0.3665(T/K). seY Derive the
and AH for one mole
Calculate q,
of the gas
w, AU,
4.

when the starting from H = U+ PV.

temperature is raised from 25°C to 200°C
at hence
constant pressure. exact differential and
Show that dw is not an
(5,5,5)
function.
w is not a state
(a) Using indicator diagram show that more
work is
done by the system during? expansion of an ideal between bond dissociation
(c) What is the difference
gas in a reversible process than in an
irreversible
process.
enthalpy and bond energy?

reaction
/b) Show that chemical potential of a component in a The value of A_H° (298K) for the
108.76
mixture can be written in terms of enthalpy. Is N,H,(g) ’ N,H,(g) + H,(g) is found to be
this a partial molar quantity? Give reason.
kJ mol-, Calculate the bond enthalpy of N = N

(c) One mole of an ideal gas with C, =3/2 R bond assuming that the structure of N,H, is HN

undergoes adiabatic reversible expansion from 22.4 - NH.Given the following bond enthalpies : E-N
liters to 44.8 liters. If initial temperature is 27°C, 390.79 kJ mol-l and
= 163.18 kJ mol', &_H
calculate the final temperature and the work done
CH-H = 435.89 kJ mol-!.
(5,5,5)
in the process.
(5,5,5)

P.T.0.
 1234 7
6 1234
of constant
heat summation.
Hess's law
Derive the thermodynamic equation of state
State tungsten
of formation of
Calculate the enthalpy
OUY following data :
+P=T
OP carbide (WC) from the
H°298 -837.47
W(s) + 3/2 O, (g) ’ WO,(s)
starting from dU = dq WO, (s) + CO,
+ dw kJ mol-l wC (s) + 5/2 0, (g) ’
C (graphite) + O,
(g) 4,H°,298 =-1195.79 kJ mol-
What is residual entropy? A,H°9-393.51 kJ mol-!.,
Explain giving two (g) ’ CO, (g)
examples. (5,5,5)

(c) 5g ice at 273 K is added to 30 g

water at 323 K
in a thermally insulated
container. All the ice melts
when equilibrium is achieved. What is the
final 4,U
temperature? What is the total entropy change? 7. (a) Derive the relation
ÞT
Given A,H=334.72Jg1, C,(1,H,0) = 4.184 JK-Ig-!, p

(5,5,5)

6. Describe Joule's experiment and the result Define enthalpy of neutralization. Why is its value
obtained from it. What are its shortcomings? always negative? The value of enthalpy of
neutralization of strong acid and strong base is
(b) What is inversion temperature? Starting from the same for all acids and bases. Explain. Will there
definition of u,, show that T; = 1/a, where a, is be a change in the value of enthalpy
of
the isobaric expansivity of the gas at the neutralization if the acid or the base is a weak
temperature T; electrolyte? Give reason for your answer.
P.T.0.
1234 8

(c) Compute A,G for the process: H,0 (1, 2 atm, 373
K) ’ H,0 (g, 2 atm, 373 K). (5,5,5)

AS =C, h-va(g, -)
(a) Derive the relation AS=Cp In

starting from dH = Tda + VdP.

(b) Absolute entropy of liquid water at 298K has to

be calculated. Write all the steps involved. Also
write the final expression for calculation of
entropy.

(c) Calculate the entropy of separating the components

in 100 g of air. The composition is 21% volume
O 78% volume N, & 1% volume Ar (Atomic
Weight of Ar is 40). (5,5,5)

(2000)