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XI Assignment CH 7

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11 views3 pages

XI Assignment CH 7

Uploaded by

vinayak5best
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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AMITY INTERNATIONAL SCHOOL, NOIDA

Class XI

Chemistry

Unit: 7(Equilibrium)
LEVEL- 1

1. Kb for NH4OH is 1.8 ×10-5 and for CH3NH2 is 4.4 ×10-4, which of them is a stronger base and
why? [CH3NH2] (1)

2. Ice melts slowly at a higher altitude. Explain. [ At higher altitudes the atmospheric pressure is
less.] (1)

3. Kc for the reaction , 1/2I2(g) + 1/2 H2 (g) HI(g) is 5 at a certain temperature .


Calculate the value of Kc at the same temperature for the given reaction : (2)
2HI(g) I2(g) + H2 (g) [KC= 0.04]

4. Classify each of the following substances into an acid or base or both and mention the
concept(s) on the basis of which you can do so. (3)

(i) HCl (ii) NH3 (iii) Na2CO3 (aq)

(iv) CH3COOH(aq) (v) CO2 (g) (vi) BF3

LEVEL- 2

5. The equilibrium constants for the three reactions : (1)


A + 2B C, K= 10-12

3B + 2C D, K = 104

A + 2B E, K = 109

In which case, the yield of products will be maximum? [K = 109]

6. Zinc is not precipitated as Zn(OH )2 on adding NH4OH to a Zinc salt solution (1)
containing NH4Cl.Give reason.[ NH4CL suppresses the ionization of NH4OH due to common ion
effect.]

7. Why do teeth undergo decay by eating sweets regularly? (1)

8. Derive the relationship between Kp and Kc. [Kp =Kc (RT)Δn ] (2)
9. Will AgCl be more soluble in aqueous solution or NaCl solution? Explain. (2)
[Solubility of AgCl in water decreases if NaCl is added to it.]
10. All Bronsted bases are Lewis bases but all Bronsted acids are not Lewis acids. (2)
Give reason [Lewis acids may not contain proton but can accept lone pair.]

11. What is the role of NH4Cl in group (III) analysis of basic radicals. Explain with the help of
chemical equations. [NH4Cl is added to suppress the ionisation of NH4OH because NH4Cl is a
strong electrolyte] (2)

12. Calculate pH of 0.1M solution of acetic acid if the degree of dissociation of acid (2)
is 0.02. (2.7 approx)

13. Equal volumes of 0.002M solution of NaIO3 and Cu(ClO3)2 are mixed together. Will it lead to
precipitation of copper iodate. Ksp(7.4×10−8) [precipitation will not occur] (2)

14. The equilibrium constant at 278 K for

Cu(s) + 2Ag+(aq) Cu2+(aq) + 2Ag(s) (3)

Is 2.0 x 1015 . In a solution in which copper has displaced some silver ions from the solution, the
concentration of Cu ions is 1.8 x10-2 mol L-1 and the concentration of Ag ions is 3.0 x10-9 molL-1. Is
this system at equilibrium? Justify your answer. [reaction is at equilibrium].

LEVEL- 3

15. Solubility of CO2 in water decreases with increase in temperature. Explain. (1)
[ on increasing temperature the kinetic energy increases and hence the intermolecular bonds b/w
the atoms breaks down]
16. What is the effect of decreasing the volume of the container in the reaction. (1)

2 C (s) + O2(g) 2CO(g) [the pressure will increase. By Le Chatelier's principle,


equilibrium will shift to the side accompanied by decrease of pressure]

17. Calculate the pH of a solution formed by mixing equal volumes of two solution of a strong acid
having pH =6 and pH=4 respectively. [pH=4.297] (2)

18. Prove that the pressure necessary to obtain 50 % dissociation of PCl5 at 500 K is numerically
three times the value of Kp . (3)

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