MT - 03 (B) Solution
MT - 03 (B) Solution
F
20. (1) F = IIB sinq or sinq = A B
IIB
15 1 3 mF
sinq = = or q = 30°
10 ´1.5 ´ 2 2
FT - 03B 3
PART - II : CHEMISTRY 4 2
61. (3) 3 1 OH
51. (3) Gabriel phthalimide synthesis cannot be used for the 5 ||
preparation of aromatic primary amines because the C – X OH O
bond in an aromatic halide (aryl halide) is stronger and 3-Hydroxy-4-methylpentanoic acid
thus difficult to break. 62. (1) A – (iv), B – (iii), C – (i), D – (ii)
52. (4) In IVth group the S2– concentration increase when 63. (3) Pb(NO3)2 is a soluble colourless compound so it
cannot be used in confirmatory test of Pb+2 ion.
NH4OH is added because
1200 K
64. (2) CaCO3 CaO + CO2
NH 4+ + OH -
NH 4 OH 1 mol 1 mol
100 g 44 g
2H + + S2 -
H 2S As CaCO3 is 20% pure, So, mass of pure
20
- +
H 2O . So CaCO3 = 20 × =4g
OH + H S2– is increased. 100
100 g CaCO3 produces 44 g CO2
53. (1) Both statements are correct.
O O 44
\ 4 g CaCO3 produces × 4 g CO2
H 100
–
(i) OH
54. (1) + H ¾ ¾® = 1.76 g CO2
||
(ii) D
65. (2) Given
O C(s) + O2(g) ® CO2(g); DH1= –393.5 kJ mol–1 …(i)
55. (1) Reason is the correct explanation of Assertion. Due 1
.. CO(g) + O (g) ® CO2(g); DH2 = –283.5 kJ mol–1 …(ii)
to +M effect of - O
.. H , its intermediate carbocation is more 2 2
stable than the one in benzene. \ Heat of formation of CO = DH1 – DH2
= –393.5 – (–283.5) = –110 kJ
OH OH
66. (3) Due to the steric repulsion between the two hydrogen
Conc. HNO3 O2N NO2 atom this molecule can not achieve planarity, hence
56. (3) ¾¾¾¾¾® compound is not aromatic.
electrophilic
Substitution
67. (1)
(i) HC º C - CH2 - CH2 - CH2 - CH3
NO2 Hex -1- yne
Picric acid (ii) CH3 - C º C - CH2 - CH2 - CH3
57. (3) On dilution [H+] = 10–6 M = 10–6 mol L–1 Hex -2- yne
Now dissociation of water cannot be neglected,
(iii) CH3 - CH 2 - C º C - CH 2 - CH3
Total [H+] = 10–6 + 10–7 = 11 × 10–7
Hex -3- yne
pH = –log [H+] = –log (11 × 10–7) = 5.98
58. (4) For a spontaneous process, DStotal > 0 and since (iv) HC º C - CH - CH 2 - CH3
irreversible process is always spontaneous therefore |
DStotal > 0. CH3
Since DU = nCVDT and DT = 0 for isothermal process 3- Methylpent -1-yne
therefore DU = 0. (v) HC º C - CH 2 - CH - CH3
59. (4) In BF3, hybridisation is sp2 and number of electrons |
are 6. CH3
60. (2) 4- Methylpent -1-yne
CH3 CH3
Hg(OAc)2, H2O
(vi) CH3 - C º C - CH - CH3
CH3 – C – CH = CH2 ¾¾¾¾¾ ® H3C – C – CH – CH3 |
NaBH 4 CH3
CH3 CH3 OH 4- Methylpent -2-yne
(A)
B2H6 H2O2/OH –
(Markovnikov product) CH3
CH3 |
(vii) HC º C - C - CH 3
CH3 – C – CH2CH2 |
CH3
CH3 OH
3,3- Dimethylbut-1-yne
(B)
(Anti Markovnikov product) 68. (3)
6 FT-03B
69. (3) r = K [NH3]° = K = y × 10–4 mol L–1 s–1 81. (2) Statement I: Manganate and permanganate ions are
tetrahedral.
1 d [ H2 ] Statement II: Manganate ion is MnO2–
Now, =r 4 in which Mn is in +6
3 dt O.S. Due to unpaired e–, it is paramagnetic in nature.
It has dp- pp bonding.
d [H2 ]
Þ = 3r = 3y × 10–4 mol L–1 s–1 82. (3)
dt + –
NH2 N2 Cl BF4 F
70. (1) A – (i), B – (iii), C – (ii), D – (iv)
71. (1) Kp = Kc(RT)Dng NaNO2 HBF4 D
72. (1) Both the statements regarding spontaneity of a HCl, 278 K
reaction are correct, as DG = DH – TDS
(A) (B)
73. (3) E0 + > E 0 + , E 0 2+ < E0 83. (4)
Ag |Ag H |H 2 Cu /Cu O 2 , H + | H 2O
H H
1
— —
— —
74. (4) In isoelectronic species size µ . Hence correct (i) KOH (alc.)
Z CH3 – CH2 – C – C – H ¾¾¾¾® CH3CH2 – CH = CHBr
increasing order of ionic radii is : Ca2+ < K+ < Cl– < S2–
¾¾®
Br Br (ii) NaNH2 in liq. NH3
75. (3) -
H 2 N – (CH 2 ) 4 – CH – COO
| CH3CH 2 – C º C – H
+
NH3
84. (2) Mohr’s salt is ferrous ammonium sulphate FeSO4.
Lysine (NH4)2SO4. 6H2O
85. (1) The correct order of increasing acid strength
Since it contains more number of –NH2 groups as compared
CF3 . COOH > MeOCH2COOH > CH3COOH
to –COOH groups, hence it is basic amino acid. > (Me)2CH.COOH
76. (3) hn = hno + KE Electron withdrawing groups increase the acid strength
77. (3) 2Mn 2 + ¾¾
® 2Mn 3+ + 2e - , DG1° and electron donating groups decrease the acid strength.
86. (2) In lanthanides, there is poorer shielding of 5 d elec-
Mn 2+ -
+ 2e ® Mn, DG°2 trons by 4 f electrons resulting in greater attraction of the
DG3° = nucleus over 5 d electrons and contraction of the atomic
3Mn 2+
( aq ) ® Mn (s ) + 2Mn ( aq )
3+
radii.
87. (3) Sucrose is an example of disaccharide and non-
– 2 × F × E3° = – 2 ×F × [–1.51] – 2 × F × (–1.185) reducing sugar because it does not have free hemiacetal
linkage.
E3° = -2.695 It involves glycoside linkage between C1 of a-D-
0.0591 glucose C2 of b-D-fructose.
E3° = + log K eq ; 88. (4) Tertiary alkyl halides are not used for alkylation of
2
ammonia.
Keq = 6.29 ´ 10–92 » 6.3 ´ 10–92 89. (2) 2% aqueous solution of A : Solute A = 2g
78. (2) In KO2, the nature of oxygen species and the Solution A = 100g
oxidation state of oxygen atom are superoxide (superoxide
\ Solvent = 98g
ion is O2–) and –1/2 respectively.
8% aqueous solution of B : Solute B = 8g
79. (2) Enthalpy of formation of C 2H4,CO2 and H2O are
Solution B = 100g
52, – 394 and – 286 kJ/ mol respectively. (Given)
The reaction is
\ Solvent = 92g
Concentration of A in molality
C 2 H 4 + 3O 2 ® 2CO 2 + 2H 2 O.
change in enthalpy, 2 / MA 2
(m A )= =
(DH) = DHproducts – DHreactants 98 / 1000 0.098 M A
= 2 ´ (-394) + 2 ´ (-286) - (52 + 0) = – 1412 kJ/ mol. Concentration of B in molality
80. (2) Alkane with six or more C-atoms, when heated
8 / MB 8
under pressure in the presence of a catalyst Mo2O3 at (m B )= =
773 K at 10-20 atm. First cyclise and then aromatise to 92 /1000 0.092 M B
give benzene.
FT - 03B 7
Boiling point of solution A (Tb )Af = Boiling point of C2O42– ¾¾ ® 2CO2 + 2e– .......(iii)
On adding all three equations, we get
solution B (Tb )Bf Cr2O72– + Fe2+ + C2O2– +
4 + 14H + 3e
–
D [ Br - ] -5 D [ H + ]
90. (4)
Þ – =
Dt 6 Dt
D [ Br - ] 5 D [ H + ]
91. (2) Alcohols are versatile compounds. They react both Þ =
as nucleophiles and electrophiles. The bond between Dt 6 Dt
O—H is broken when alcohols react as nucleophiles. 2+
Alcohols as nucleophiles 96. (2) X = éë Ni ( en ) ( NH3 ) 4 ùû neither G.I. nor O.I.
H 2+
(i) R–O–H+ +C – .. –C – ® R –O–C– +H
R –+O +
Y = éë Ni ( en )2 ( NH3 )2 ùû G.I. as well as O.I.
137. (3) In a mature pollen grain, the generative cell is smaller which decreases the gender ratio. So, it has a statutory
and the tube (or vegetative) cell is larger. ban to avoid female.
11 m.u. 155. (2) Heroin is obtained by acetylation of morphine which
4 m.u. 7 m.u.
138. (3) is extracted from the latex of poppy plant.
P Q R 156. (2) Adenine is a type of purine, anthocyanin is an example
139. (4) Repeated or repetitive sequences make up a large of pigment, chitin is a homopolysaccharide and codeine is
portion of human genome. an example of alkaloid.
140. (2) C4 plants are more efficient in picking up CO2 even 157. (1) Genetic drift is a random process that can lead to large
when it is found in low concentration because of its high changes in population over a short period of time. Random
affinity for PEP. They show kranz anatomy i.e. vascular drift is caused by recurring small population sizes, severe
bundle is surrounded by bundle sheath and mesopyll cells. reductions in population size called "bottlenecks" and
141. (3) founder events where a new population starts from a small
number of individuals.
142. (2) Chargaff’s rule states that A = T and G º C. The molar
Crossing over which occurs during gamete formation results
amount of adenine = molar amount of thymine. The molar
in genetic recombination. Mutations are random in genetic
amount of guanine = molar amount of cytosine.
recombinations.
Hence, G is 17%, so, C = 17% 158. (1) Restriction endonuclease-Hind II, always cut DNA
A = 33%, so, T = 33% molecules at a particular point by recognising a specific
143. (1) 144. (1) 145. (1) sequence of six base pairs.
146. (2) In gene therapy method, genes are inserted into a 159. (1) Cell-mediated immune response is mainly responsible
person’s cells and tissues to treat a disease. Correction of for graft rejection in transplantation of organs.
a genetic defect involves delivery of a normal gene into 160. (4) Seminal plasma is secreted from male acessory glands
the individual or embryo to take over the function of and & it is rich in fructose, calcium and certain enzymes.
compensate for the non-functional gene. 161. (1) Frog has a well-developed close type of blood
147. (1) vascular system.
148. (4) The mother would have genotype IAIB and the father 162. (4) Sponges, cnidarians, flatworms and ctenophorans do
would have genotype ii. not have circulatory systems.
149. (3) Yellow round heterozygous pea plant may be 163. (3)
represented by genotype RrYy. On selfing such plants 164. (3) Increase in Ca++ level into the sarcoplasm leads to the
following results will be obtained. binding of calcium with a subunit of troponin on actin
150. (4) The lac operon consists of one regulatory gene (the filaments and there by remove the masking of active sites
i gene) and three structural genes (z, y, and a). for myosin. Utilizing the energy from ATP hydrolysis, the
myosin head now binds to the exposed active sites on
PART - IV : ZOOLOGY actin to form a cross bridge. This pulls the attached actin
151. (4) filaments towards the centre of ‘A’ band. The ‘Z’ line
152. (3) Estrogen produced by ovary have wide range of attached to these actins are also pulled inwards thereby
actions such as stimulation of growth and activities of causing a shortening of the sarcomere, i.e., contraction. It
female secondary sex organs, development of growing is clear from the above steps, that during shortening of the
ovarian follicles, appearance of female secondary sex muscle, i.e., contraction, the ‘I’ bands get reduced, whereas
characters. It also regulates female sexual behavior. the ‘A’ bands retain the length.
152. (3) The given apparatus shows sparged stirred tank 165. (4)
bioreactor. This apparatus carries out the fermentation 166. (3) Struthio (Ostrich) is the largest living flightless bird.
process by transferring oxygen to mass bioreactors. The
rate of oxygen mass transfer into a culture in a bioreactor 167. (1) 168. (3)
is affected by operational conditions and geometrical 169. (2) Uric acid accumulation in the joints can lead to painful
parameters as well as the physicochemical properties of movement of joint and is termed Gout.
the medium (containing nutrients, substances excreted 170. (4) Placenta functions as a gland, secreting human
by the micro-organism, and surface active agents that are chorionic gonadotrophin, progesterone, and oestrogens,
often added to the medium) and the presence of the micro- which regulate the maintenance of pregnancy.
organism. Thus, oxygen mass transfer coefficient values
171. (2)
in fermentation broths often differ substantially from
values estimated for simple aqueous solutions. 172. (1) Use of contraceptive pills is a widespread form of
154. (4) Amniocentesis is not a sex determination technique birth control.
in India and is not a strategy of RCH . Amniocentesis can 173. (2) Circulatory system in arthropods is of open type. i.e.
lead to female foeticide as it detects the sex of the foetus blood flows in irregular spaces called lacunae. It does not
flow in definite blood vessels.
10 FT-03B
174. (3) AIDS is caused by HIV. When HIV enters into helper numerous and most reactive in primitive atmosphere.
T-cells, it replicates and produces other viruses that kill Hydrogen atoms combined with all oxygen atoms to form
the helper T-cells. water leaving no free oxygen. Thus, primitive atmosphere
175. (2) A – (iv), B – (iii), C – (i), D – (ii) was reducing (without free oxygen) unlike the present
176. (2) B-cells work chiefly by secreting soluble substances oxidising atmosphere (with free oxygen).
called antibodies into the body’s fluids. An antibody is Formation of ozone layer is the consequence of modern
represented as H2L2. oxidising atmosphere having plenty of free oxygen. As
177. (3) more oxygen accumulated in the atmosphere (due to
178. (2) A-(iv); B-(iii); C-(i); D-(ii) photosynthesis), ozone began to appear in the top layers.
179. (4) In peroxidase and catalase which catalyse the break 193. (2)
down of hydrogen peroxide to water and oxygen, heme is (A) Gene gun - Used for transfer of gene in plant cells.
a prosthetic group. (B) Gene therapy- Replacement of a faulty gene by a
180. (1) Birds are uricotelic animals which excrete nitrogenous normal healthy gene
waste materials in the form of uric acid. (C) Gene cloning - To obtain identical copies of a particular
181. (1) DNA molecule
182. (3) Malignant tumours spread from one body part to (D) Genome - Total DNA in the cells of an organism
another whereas benign tumours are confined to a place. 194. (3) Pons are the region of human brain which has
183. (4) 184. (3) pneumotaxic centre that alters respiratory rate by reducing
185. (1) the duration of inspiration.
• Option (1) is incorrect because ricin is a toxin obtained 195. (3) Reptiles usually possess 3-chambered heart but
from Ricinus plant. Vinblastin and curcumin are drugs. crocodiles are an exception with 4-chambered heart.
• Morphine and codeine are alkaloids. Platypus is exception in mammals which are oviparous.
Cyclostomata is a class in the phylum chordata which
• Abrin is also a toxin obtained by plant Abrus.
consists of jawless fishes.
• Concanavalin A is a lectin.
196. (1)
186. (1)
197. (3) In the given statements, both assertion and reason
187. (2) The two enzyme are responsible for restricting the are correct but reason is not the correct explanation of
growth of bacteriophage in E. coli were isolated. One of assertion.
these added methyl group to DNA, while other cut DNA.
198. (2)
188. (4) Human insulin is made up of 51 amino acids arranged
199. (2) Ionizable nature is a particular characteristic of –NH2
in two polypeptide chains, A, having 21 amino acids and B,
and –COOH groups. In a solution containing different pH,
with 30 amino acids. The two polypeptide chains are
the structure of amino acid is expected to change. Amino acid
interconnected by two disulphide bridges.
in a dipolar ionic form is called zwitterion. For a particular
189. (4) Copper releasing IUD suppresses the motility of the amino acid there exists an isoelectric point at which the net
sperms and also reduces the fertilising ability of the sperms. charge on amino acid becomes zero.
190. (1) The route of water and solutes through the nephron
is as follows: From the glomerulus ® Bowman’s capsule
® proximal tubule ® loop of Henle ® distal tubule ®
collecting ducts.
191. (4) The z-line attached to these actin is pulled inwards, Here, in the given figure, (B) is a zwitterion.
thereby causing shortening of sarcomere. 200. (2) In the given statements both assertion and reason are
192. (2) The lightest atoms of nitrogen, carbon, etc. formed correct and reason is the correct explanation of assertion.
the primitive atmosphere. Hydrogen atoms were most