Chapter One
Chapter One
(Chem M1012)
Chapter – One
Essential Ideas in Chemistry
✓ Describe the basic properties of each physical state of matter: solid, liquid, and gas
Chemistry is the study of matter and its properties, the changes that matter
undergoes, and the energy associated with those changes.
The science of chemistry deals with the makeup of the entire physical universe
Example
Today, the science of chemistry helps us to understand the essential nature of materials to
make better use of them and create new ones:
❖ Specialized drugs
❖ Advanced composites
❖ Synthetic polymers and
❖ Countless other new materials
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Cont’d
The scientific method
A set of procedures used to develop explanations of natural phenomena and
possibly to predict additional phenomena
1. Observations is
❖ Basic to scientific thinking
❖ The most useful observations are quantitative
A valid hypothesis need not be correct, but it must be testable. A hypothesis is often the reason
for performing an experiment
If the hypothesis is inconsistent with the experimental results, it must be revised or discarded
3. Experiment is
Note that hypotheses and models are mental pictures that are changed to match
observations and experimental results, not the other way around.
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1.1.3. The Domains of Chemistry
Chemists study describe the behavior of matter and energy in three different
domains:
❖ Macroscopic
❖ Microscopic and
❖ Symbolic
These domains provide different ways of considering and describing chemical
behavior
Macro is a Greek word that means “large”
One of the challenges for students in chemistry is recognizing that the same
symbols can represent different things in the macroscopic and microscopic
domains
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Cont’d
One of the features that makes chemistry fascinating is the use of a domain that
must be imagined to explain behavior in a domain that can be observed
A helpful way to understand the three domains is via the essential and
ubiquitous substance of water
Water is
The formula H2O, which can describe water at either the macroscopic or
microscopic levels, is an example of the symbolic domain
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Cont’d
(a) Moisture in the air, icebergs, and the ocean represent water in the macroscopic domain
(b) At the molecular level (microscopic domain), gas molecules are far apart and
disorganized, Solid water molecules are close together and organized, and liquid
molecules are close together and disorganized
(c) H2O symbolizes water, and (g), (s), and (l) symbolize its phases.
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1.2. State and classification of matter
1.2.1. State of matter
The science of chemistry deals with the makeup of the entire physical universe
The Properties of Matter
Matter is the “stuff ” of the universe: air, glass, planets, students-anything that
has mass and volume
Chemists are particularly interested in the composition of matter, the types and
amounts of simpler substances that make it up
A substance is a type of matter that has a defined, and fixed composition.
Properties:- the characteristics that give each substance its unique identity.
Particles in the gas usually have great distances between them, as they move randomly
throughout the entire container
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Cont’d
The physical states of matter. The magnified (blow-up) views show the atomic-scale
arrangement of the particles in the three states of matter.
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Cont’d
Plasma
• A fourth state of matter, plasma occurs naturally in the interiors of stars. Plasma is a
gaseous state of matter that contains appreciable numbers of electrically charged particles
• Pure substance have exactly the same makeup and properties. Any sample of sucrose
(table sugar) consists of 42.1% carbon, 6.5% hydrogen, and 51.4% oxygen by mass. Any
sample of sucrose also has the same physical properties, such as melting point, color, and
sweetness
• Pure substances may be divided into two classes: elements and compounds.
• Pure substances that can be broken down by chemical changes are called compounds.
• This breakdown may produce either elements or other compounds, or both. Mercury (II) oxide, an orange,
crystalline solid, can be broken down by heat into the elements mercury and oxygen.
Mixtures
➢ It is a material composed (consists) of more than one substance in variable composition and it is formed by
physical mixing without changing the identity of the components that made the mixture.
➢ The substance that make the mixture are called the components of the mixture
➢ Usually the mixtures are separated by physical means into two or more substances depending on their
physical difference in terms of color, texture, size, boiling point difference, solubility and shape etc.
1. Homogeneous mixture
It is the mixture having only one phase and the components that makes this mixture shows the
same properties throughout the sample or the mixture is uniform in its properties throughout
given samples.
The component of this type of mixture is not identified in our naked eye rather it needs a
powerful microscope. Example : metal alloy, brine solution (NaCl in water) etc
A homogeneous mixture also called solution, when the one component present in abundant
amount (called solvent) and the other present in smaller amount (called solute).
To separate the components in this type of mixture, we use melting point difference, density,
refractive index, specific heat capacity.
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Cont’d
2. Heterogeneous mixture
A mixture having more than one phase system and don’t show the same properties
throughout the sample and the components of the mixture can be identified based on
their physical difference like color, size, shape, magnetic property, etc
2. Physical properties: is the property measured without changing the chemical identity of
the substance.
Depending on the amount of the substance present, the physical properties of the
substance are two types
1. Intensive properties
2. Extensive properties
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Cont’d
1. Intensive properties
Are physical properties which are independent of the amount of the substance present and it
is often used for characterization of the substance since it is constant variable. Meaning
as the amount of the substance changed, the properties are still constant (not affected by
the quantity).
Example: temperature, density, color, specific heat capacity, refractive index etc
2. Extensive properties
Are physical properties that depend on the amount of the substance present. Meaning as the
amount of the substance changed, the properties are also changed.
The metric system develop as the result of the convention is called SI unit (international
system of unit) and there are two types:
1. Basic unit
Are the original unit like mass (kilogram, kg), length (meter, m), time (second, s),
temperature (Kelvin, K), amount of substance (mole, mol), electric current (ampere, A)
and luminous intensity (candela, cd)
Are units derived / obtained from basic units by either multiplying or dividing the
original units. Example : volume (cm3), density (g/cm3).
Conversion of units
The conversion-factor method can be used to convert any unit to another unit, provided a
conversion equation exists between the two units and it is a factor equal to 1.
• But when we measures quantities, the last significant digit in a measurement is somewhat
uncertain (not sure), i.e. the last digits in measurement shows the extent of error or
uncertainty.
Rule 3. Any zeroes to the left of the first non-zero digit are NOT significant (called leading
zeroes).
Rule 5. Zeroes at the end of a whole number that does not contain a decimal point Are not
significant.
Rule 6. When numbers are in scientific notation, disregard the power of ten and use the
above rules on the decimal number only.
Example : 3.8 x 10y has 2 significant digits, 3.080 x 10y has 4 significant digit,
4 dp 2 dp 2 dp
150.0 + 0.507 = 150.507 ➔ 150.5
1 dp 3 dp 1 dp
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Short and Brief Description
Whenever we divide/multiply the significant figures, the result should be the same as the
smallest number of significant figures in the data.
The final answer can contain no more significant figures than the least accurate
measurement
4 sf
𝟐.𝟓𝟑𝟏
Example: = 𝟎. 𝟎𝟓𝟖𝟎𝟓𝟎𝟓 → 𝟎. 𝟎𝟓𝟖𝟎 3 sf
𝟒𝟑.𝟔
3 sf
𝟎. 𝟎𝟎𝟓𝟓𝟖𝟎 𝒙 𝟔𝟕 = 𝟎. 𝟑𝟕𝟑𝟖𝟔 → 𝟎. 𝟑𝟕
Remark: during addition or subtraction decimal place are considered and during
multiplication or division significant figures are considered to write into final reports
Rule 1. If the digit is smaller than 5 (0-4), drop this digit and leave the remaining number
unchanged.
Rule 2. If the digit is larger than 5, drop this digit and add 1 to the preceding digit.
Case 1. if the digit before 5 is even, then drop this digit and leave the remaining number
unchanged.
Case 2. if the digit before 5 is odd, drop this digit and add 1 to the preceding digit.
a. 31.57 (to two significant figures) b. 8.1649 (to three significant figures)
c. 0.051065 (to four significant figures) d. 0.90275 (to four significant figures)
Example
Therefore, based on the source of the error, there are two types of error:-
1. Random error: is type of error caused due to personal error (such as lack of skill of
the person or carelessness, sight problem etc) and it is an indicator of the precision of
the measurement.
2. Systematic error: are errors caused due to instability of the instrument like power
fluctuation, instability of the signal etc. (it is instrumental error) and results deviation
from the accurate value. Such type of error are removed by calibrating the instrument
and it is an indicator of accuracy of the measurement.
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Accuracy and Precision
• Scientists typically make repeated measurements of a quantity to ensure the quality of
their findings and to evaluate both the precision and the accuracy of their results.
• Precision: refers to the reproducibility of the measurement and express the closeness of
the set of values obtained from identical measurements of a quantity.
➔Less precision implies there is more random error and vice versa
• Accuracy: is the agreement / closeness of the measured value to the true value and show
the degree of systematic error.
In graphs A and B: the random error is small (i.e precision is high:-are reproducible).
In A: the accuracy is high as well (all the values are close to 25.0 g). In B the accuracy is
low (i.e a systematic error). In graphs C and D, there is a large random error; that is, the
precision is low. Large random error is often called large scatter. In D there is also a
systematic error (all the values are high), whereas In C the average of the values is close to
the actual value.
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Cont’d
Example :- Suppose a quality control chemist at a pharmaceutical company is tasked with checking the
accuracy and precision of three different machines that are meant to dispense 283.5g (296 mL) of cough
syrup into storage bottles. She/he proceeds to use each machine to fill five bottles and then carefully
determines the actual volume dispensed, obtaining the results tabulated in Table 1.1.
Table 1.1: Volume (mL) of Cough Medicine Delivered by 283.5g (296 mL) Dispensers
298
296
294
Values
292
Disp1
290
Disp2
Disp3
288
286
284
1 2 3 4 5
Trial
• Dispenser #1 is working well, both accurately and precision Dispenser #2 is worse accuracy and worse
precision Dispenser #3 is precise but not accurate
• Dimensional analysis uses conversion factors to change the unit in an amount into an
equivalent quantity expressed with a different unit.
• For example, the lengths of 2.54 cm and 1 in. are equivalent (by definition), and so a
unit conversion factor may be derived from the ratio,
𝟐. 𝟓𝟒 𝒄𝒎
𝟐. 𝟓𝟒 𝒄𝒎 = 𝟏 𝒊𝒏. 𝒐𝒓 𝟐. 𝟓𝟒 𝒄𝒎Τ𝒊𝒏.
𝟏 𝒊𝒏.
▪ Beyond simple unit conversions, the factor-label method can be used to solve more
complex problems involving computations.
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Cont’d
▪ Regardless of the details, the basic approach is the same-all the factors involved in the
calculation must be appropriately oriented to ensure that their labels (units) will
appropriately cancel and/or combine to yield the desired unit in the result.
▪ As your study of chemistry continues, you will encounter many opportunities to apply this
approach.
Example
• What is the density of common antifreeze in units of g/mL? A 4.00-qt sample of the
antifreeze weighs 9.26 lb.
1. 0C, the Celsius scale (part of the metric system, used in most countries)
Both measures the same thing (temperature), but use different numbers :
▪ Boiling water (at normal pressure) measures 100 in celsius, but 212 in Fahrenheit
▪ Water freezes it measures 00 in Celsius, but 320 in Fahrenheit
▪ The scales start at a different number (0 vs 32), so we will need to add or subtract 32
▪ The scales rise at a different rate (100 vs 180), so we will need to multiply
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Cont’d
▪ The Celsius and Fahrenheit temperature scales, however, do not share a common zero
point, and so the relationship between these two scales is a linear one rather than a
proportional one
(y = mx + b)
▪ Celsius temperature - x
▪ Fahrenheit temperature – y
▪ slope - m, is computed to be
▪ The freezing temperature of water on this scale is 273.15 K and its boiling temperature is
373.15 K. Notice the numerical difference in these two reference temperatures is 100, the
same as for the Celsius scale, and so the linear relation between these two temperature
scales will exhibit a slope of 1K°C.
• The equations for converting between the Kelvin and Celsius temperature scales are derived
to be:
• The 273.15 in these equations has been determined experimentally, so it is not exact. Figure
1.9 shows the relationship among the three temperature scales.
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Cont’d
Figure 1.9: The Fahrenheit, Celsius, and kelvin temperature scales are compared.
• Normal body temperature has been commonly accepted as 37.0 °C (although it varies
depending on time of day and method of measurement, as well as among individuals).
What is this temperature on the Kelvin scale and on the Fahrenheit scale?
• Baking a ready-made pizza calls for an oven temperature of 450 °F. If you are in Europe,
and your oven thermometer uses the Celsius scale, what is the setting? What is the kelvin
temperature?