JEE: CLASS 12th Name……………….…………….

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Chemistry: CWT-03 Batch/Section……………….………
Chapter: Chemical Kinetics Exam Date………………………..

SECTION-A
1. The activation energies of the forward and 8. The half life for a reaction ________ of
backward reactions in the case of a chemical temperature.
reaction are 30.5 and 45.4 kJ/mol respectively. (1) Independent
The reaction is: (2) increases with increase
(1) Exothermic (3) Decreases with increase
(2) Endothermic (4) Dependent
(3) Neither exothermic nor endothermic 9. The rate of reaction 2A + B2 → 2AB is given by
(4) Independent of temperature the equation, rate = K[A]2[B2]. The value of rate
2. The rate constant of a first order reaction is 4 × constant can be increased by
10–3 sec–1. At a reactant concentration of 0.02 M, (1) Increasing the concentration of A
the rate of reaction would be – (2) Increasing the concentration of B2
(1) 8 × 10–5 M/sec (2) 4 × 10–3 M/sec (3) Increasing the temperature
–1
(3) 2 × 10 M/sec (4) 4 × 10–1 M/sec (4) doing all of the above
3. 2N2O5 ⎯→ 4NO2 + O2 10. For a reaction A→2B the concentration of A
for the above reaction which of the following is changes from 0.06M to 0.02M in 20 minute. The
not correct about rate of reaction ? rate of formation of B will be.
−d[N2O5 ] d[O ] (1) 0.002 M min-1 (2) 0.003 M min-1
(1) =2 2 (3) 0.004 M min -1
(4) 0.006 M min-1
dt dt
−2d[N2O5 ] d[NO2 ] 11. The rate of reaction triple when its temperature
(2) =
dt dt changes from 300 K to 310 K. Activation energy
−d[N2O5 ] 1 d[NO2 ] of such a reaction will be;
(3) = (R = 2 cal K-1 mol-1) (log 3 = 0.48)
dt 2 dt
(1) 20.5 kcal mol-1 (2) 40.0 kcal mol-1
−2d[N2O5 ] 4d[NO2 ] d[O2 ]
= =
-1
(4) (3) 30.0 kcal mol (4) 31.0 kcal mol-1
dt dt dt 1
4. The half life period of a first order reaction is 1 12. The plot of log10 k versus is linear with slope of
T
min 40 sec. Calculate its rate constant.
(1) 6.93 × 10–3 min–1 (2) 6.93 × 10–3 sec–1 − EA + EA
(1) (2)
(3) 6.93 × 10–3 sec (4) 6.93 × 103 sec R R
5. The rate of the reaction CCl3CHO + NO ⎯→ EA − EA
(3) (4)
CHCl3 + NO + CO is equal to K[CCl3CHO] 2.303R 2.303R
[NO]. If concentration is expressed in mol/L. 13. For a general chemical change 2A + 3B →
The unit of K is - Product. The rate of disappearance of A is r1 &
(1) L mol–1 sec–1 (2) mol–1 sec–1 B is r2. Relation between r1 & r2 will be
(3) L2 mol–2 sec–1 (4) sec–1 (1) 2r1 = 3r1 (2) 3r1 = 2r2
r1 4
6. Collision theory is applicable to (3) r1 = r2 (4) =
(1) First order reactions
r2 3
(2) Zero order reactions 14. A hypothetical reaction A2 + B2 ⎯⎯ → 2AB
(3) Bimolecular reaction follows the mechanism as given below
(4) Intra-molecular reactions A2 A+A (fast)
7. If Ef & Er are the activation energies of the A + B2 ⎯⎯ → AB + B (slow)
forward & reverse reaction and the reaction is A + B ⎯⎯ → AB (fast)
known to be exothermic then – The order of the over all reaction
(1) Ef < Er (2) Ef > Er 3
(1) 2 (2) 1 (3) (4) 0
(3) Ef = Er (4) Insufficient Data 2
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15. For the following reaction 19. In the presence of an acid, the initial
N2 + 3H2 → 2NH3 concentration of cane sugar was reduced from
The rate of appearance of NH3 was measured as 0.20 to 0.10 molar in 5 hours and from 0.2 to
9 × 10–3 mol·L-1sec-1. The rate of disappearance 0.05 molar in 10 hours. The reaction is of:
of H2 will be. (1) Zero order (2) First order
(1) 4.5 × 10-3 mol·L-1 sec-1 (3) Second order (4) Third order
(2) 13.5 × 10-3 mol·L-1 sec-1 20. Examine the statements carefully and mark the
(3) 27 × 10-3 mol·L-1 sec-1 correct answer according to the instructions
(4) 6 × 10-3 mol·L-1 sec-1 given below:
16. The rate law for the single step reaction A + 2B Statement-I: Concentration of reactant in zero
→ 3C, is given by order reaction is constant.
(1) Rate = k[A][B] (2) Rate = [A][B]2 Statement-II: For zero order reaction A ⎯⎯ → B,
(3) Rate = k[A]2[B] (4) Rate = k[A]2[B]2 successive half life of reaction decreases with the
17. Which of the following statement is incorrect? progress of the reaction.
(1) Unit of rate of disappearance is M sec –1 (1) If both the statements are true and statement-II
(2) Unit of rate of reaction is M sec –1 is the correct explanation of statement-I.
(3) Unit of rate constant k depends upon order (2) If both the statements are true but statement-II
(4) Unit of k for first order reaction is M sec–1 is not correct explanation of statement-I
(3) If statement-I is true and statement-II is
18. Which of the following statement is incorrect? false.
(1) A second order reaction must be a (4) If statement-I is false and statement-II is
bimolecular elementary reaction true.
(2) A bimolecular elementary reaction must be
a second order reaction
(3) Zero order reaction must be a complex
reaction
(4) First order reaction may be complex or
elementary reaction
SECTION–B
21. Reaction A + B ⎯→ C + D, follows rate law, 27. The Ea for the following A → B + 40 kJ is 80
r = k[A]1/2 [B]1/2 starting with 1M of A and B kJ/mole. Ea for the following reaction B → A
each. What is the time taken for concentration of will be (in kJ/mole)
A become 0.1 M? [Given k = 2.303 × 10–2 sec–1] 28. A gaseous compound A reacts by three
22. For the first order reaction A ⎯→ B + C, carried independent first order processes (as shown in
out at 27°C if 3.8 × 10–16 % of the reactant figure) with rate constant 2 × 10–3, 3 ×10–3 and
molecules exists in the activated state the Ea 1.93 × 10–3 sec–1 for products B, C and D
(activation energy) of the reaction is: respectively. If initially pure A was taken in a
closed container with p = 8 atm, then the partial
23. In a second order reaction when the pressure of B (in atm) after 100 sec. from start of
concentration of both reactant are equal, the experiment.
reaction is completed 20 % in 500 sec. How long B(g)
will it take for the reaction to go to 60 %
completion ? (in sec) A(g) K2
C(g)
24. A first order reaction is 20% complete in 10 min
what is the rate constant of the reaction - D(g)
25. The Ea for exothermic reaction A → B, 80 29. A reaction is found to have the rate constant xM-1
kJ/mol. the heat of reaction is 200 kJ/mol. Then sec-1 by what factor the rate is increased if initial
Ea for B → A ? concentration of A is tripled.
26. A zero order reaction completes 75 % in 6 hr. 30. When initial concentration of a reactant is
Then time taken for the completion of 87.5% doubled for a reaction. Its half-life is also get
will be. (in hour) doubled. The order of a reaction is.

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