SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET

Last changed: 17/08/2005 Internal No.: 42.00.0040 Replaces date: 11/10/2004

BENTONITE, API
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Approved for use

Approved for laboratory use
Approved by M-I Norge AS

TRADE NAME BENTONITE, API

TYPE OF USE Viscosifier for water based drilling fluid.

Declaration number (PRN-no.)

1130203

National manufacturer/importer
Enterprise M-I Danmark ApS
Address Trafikhavnskaj 7, P.O.Box 1095
Postal code DK-6701 Esbjerg
Country Danmark
Telephone +45 75 13 00 55

Name E-mail Tel. (work)

Dagrunn Dirdal ddirdal@miswaco.com +47 51 57 73 29

2. COMPOSITION / INFORMATION ON INGREDIENTS

No Ingredient name EC No. CAS No. Conc. (wt%) Classification

1 BENTONITE CLAY 215-108-5 1302-78-9 60 - 100 %
Explanation of symbols: T+=highly toxic, T=toxic, C=corrosive, Xn=harmful, Xi=irritant E=Explosive, O=Oxidising,
F+=Extremely flammable, F=Highly flammable, N=Dangerous for the environment, Cancer=Carcinogenic, Mut=Mutagenic,
Rep=Toxic for reproduction, Conc.=Concentration

INGREDIENT COMMENTS
The product contains < 5% quartz (crystalline silica) and < 0,001% respirable quartz dust.

3. HAZARDS IDENTIFICATION

GENERAL
Not regarded as a health hazard under current legislation.

HEALTH
Dust particles can give sore and irritated eyes. The product contains small amounts dust of crystalline quartz which
can cause lung damage. It is also suspected to be carcinogenic. The risk for developing cancer depends on
exposure time- and level.

FIRE AND EXPLOSION

Substance or preparation is not combustible.

ENVIRONMENT
Not regarded as hazardous to the environment.

4. FIRST AID MEASURES

INHALATION
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical
advice if discomfort develops.
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MATERIAL SAFETY DATA SHEET
Last changed: 17/08/2005 Internal No.: 42.00.0040 Replaces date: 11/10/2004

BENTONITE, API

SKIN CONTACT
Rinse with water.

EYE CONTACT
Remove any contact lenses. Flush immediately with plenty of water, also under the eyelids. Get medical advice if
any discomfort continues.

INGESTION
Rinse nose, mouth and throat with water. Drink plenty of water.

MEDICAL INFORMATION
Treat symptomatically.

5. FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA
Use extinguishing media appropriate for surrounding fire.

FIRE AND EXPLOSION HAZARDS

Substance or preparation is not combustible.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS
Use personal protective equipment. See section 8.

METHODS FOR CLEANING UP

Collect in containers and seal securely. Avoid dust formation. Flush area with water. Be aware of risk of slippery
surface. In case of spillage to watercourse or lake: The product will sink.

OTHER INFORMATION
Inform Authorities if large amounts are involved.

7. HANDLING AND STORAGE

HANDLING ADVICE
Avoid inhalation of dust. Avoid handling which causes dust formation. Avoid spilling, skin and eye contact.

STORAGE
Store dry.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

EXPOSURE CONTROL
Provide adequate general and local exhaust ventilation. Provide eyewash station. Wash hands after each shift and
before eating, smoking or toilet use.

RESPIRATORY PROTECTION
Wear mask with filter P2 or P3 if formation of dust.

EYE PROTECTION
Use tight fitting goggles if dust is generated.

HAND PROTECTION
Use protective gloves made of: Rubber or plastic.
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MATERIAL SAFETY DATA SHEET
Last changed: 17/08/2005 Internal No.: 42.00.0040 Replaces date: 11/10/2004

BENTONITE, API

PROTECTIVE CLOTHING
Wear protective clothing according to requirement.

OEL value
Ingredient name Cas nr. Interval ppm mg/m3 Year Notification
NUISANCE DUST, TOTAL - 8h 10,0 2003
DUST
CRYSTALLINE QUARTZ, 14808-60-7 8h 0,1 2003 K
RESPIRABLE

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Powder.

Colour Grey-white.
Odour None.
Solubility Insoluble in water.

Physical and chemical parameters

Parameter Value/unit Method/reference Observation
pH in solution 9 - 10
Density 2,5 g/cm³ 25°C

10. STABILITY AND REACTIVITY

STABILITY
Normally stable.

11. TOXICOLOGICAL INFORMATION

GENERAL
In industry, inhalation represents the main hazard.

INHALATION
Short time exposure may cause unpleasantness and irritation of upper respiratory tract. Repeated or prolonged
inhalation may result in development of silicosis. This could cause permanent impaired lung function. The product
contains small amounts of quartz which is considered an experimental carcinogen.

SKIN CONTACT
Not expected to be irritant.

EYE CONTACT
May cause irritation.

INGESTION
May cause discomfort.

OTHER TOXICOLOGICAL INFORMATION

Respirable quartz: < 0,001% - test method XRD, Report No. 300174.

12. ECOLOGICAL INFORMATION

ECOTOXICITY
Not regarded as hazardous to the environment.
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MATERIAL SAFETY DATA SHEET
Last changed: 17/08/2005 Internal No.: 42.00.0040 Replaces date: 11/10/2004

BENTONITE, API
MOBILITY
Sinks in water.

OTHER INFORMATION
The product is listed in PLONOR List.

13. DISPOSAL CONSIDERATIONS

GENERAL REGULATIONS
The product is not regarded as hazardous waste. Recover and reclaim or recycle, if practical. Dispose of on site
landfill area.

14. TRANSPORT INFORMATION

Classified as Dangerous Goods: Yes No Not assessed

OTHER INFORMATION
Not classified as dangerous according to ADR, RID, IMDG and IATA.

15. REGULATORY INFORMATION

EC-Label No Yes Not assessed

COMPOSITION
BENTONITE CLAY (60 - 100 % )

LEGISLATION
Bekendtgørelse om klassificering, emballering, mærkning, salg og opbevaring af kemiske stoffer og produkter (29.
ATP).

OTHER INFORMATION
Not regarded as a health hazard under current legislation.

16. OTHER INFORMATION

VENDOR NOTES
M-I consider this document to give a correct description of the product. A Material Safety Data Sheet has the
character of guidelines and should therefore not be used as a specification of the product.

ISSUED: 17/08/2005

SDS is prepared by
Enterprise M-I Norge AS
Address Gamle Forusvei 43
Postal code 4033 STAVANGER
Country Norway
Telephone +47 51 57 73 00

Name E-mail Tel. (work)

Anne Karin Fosse afosse@miswaco.com +47 51 57 74 60