2 L02 - Concentration2
2 L02 - Concentration2
1
Topics: Introduction to IAQ
Basic concepts of indoor air quality
(IAQ), significance of IAQ, SBS BRI,
Type of pollutants, concentration,
particle concentration,
Basic ventilation methods, threshold
limit values (TLVs)
2
Spengler et al., Indoor air quality handbook, 2000
3
Hourly PM10 distribution in a high-rise
office building in Hong Kong
45
35
Concentration (10 g/m )
3
30
-6
25
20
15
10
0
10:00 16:00 22:00 4:00 10:00 16:00 22:00 4:00 10:00
Time (Hour)
6
Spengler et al., Indoor air quality handbook, 2000
7
Topics: Introduction to concentration
Mass balance equation
Concept of mixing, air change per hour,
decay equation
Filtration efficiency, room cleaning
efficiency
Exposure and dose-response curves
8
2.1 The concept of concentration
Concentration of a pollutant is defined as the amount of the pollutant existing per
unit volume or unit mass of air.
The word “concentration” is used for either density Cg (kg/m3, commonly g/m3) or
volume fraction or concentration Cgv (m3/m3, commonly used one is ppmv, parts per
million in volume) or mass concentration Cgm (kg/kg, or usually mg/kg)
9
The mass and volume concentration of a gas can be converted back and forth if the
densities of the gas, and the air are known at the given conditions (temperature and
pressure, generally at the standard conditions, 20oC and 101,315 Pa).
a
Cgv Cgm
g
Where C gv is in ppmv, C gm is in ppmm or mg/kg, and both densities of air and the
gas are in kg/m3 respectively.
10
To convert the density of gases or vapour Cg (mg/m3), and ppmv, the following
equation can be used,
M
C g (in mg/m 3air) C gv (in ppmv)
24.5
where 24.5 is the molar volume of air, in litre per mole, under the standard
atmospheric conditions (20oC and 101,325 Pa).
Cg (in mg/m 3air) Cgv (in ppmv) g (in kg/m 3 ) 350 1.82 637 (mg/m3 air)
g 1.82
Cgm Cgv 350 =530.8 (mg/kg air)
a 1.2
11
Pollutant Molecular Weight ppm at 1 g/m3 3
g/m at 1 ppm
CO 28.01 8.588E-04 1164.4
CO2 44.01 5.466E-04 1829.5
HCHO 30.03 8.011E-04 1248.3
NO2 46.1 5.218E-04 1916.4
O3 48 5.012E-04 1995.4
TVOC 56.1 4.288E-04 2332.1
12
HK IAQ Objectives for Offices & Public Places
八小時平均值
參數 單位 8-hour Average
Parameter Unit 卓越級 良好級
Excellent Class Good Class
室內溫度 oC 20 – < 25.5 < 25.5
Room Temperature
相對濕度 % 40 – < 70 < 70
Relative Humidity
空氣流動速度 m /s < 0.2 < 0.3
Air Movement
二氧化碳 < 800 < 1,000
ppmv
Carbon Dioxide (CO2) =1.5g/m3 =1.8g/m3
一氧化碳 < 2,000 < 10,000
µg /m3
Carbon Monoxide (CO) =1.76ppm =8.6ppm
可吸入懸浮粒子 µg /m3 < 20 < 180
Respirable Suspended Particulates
二氧化氮
(PM10) < 40 < 150
µg /m3
Nitrogen Dioxide (NO2) = 0.02ppm =0.078ppm
臭氧
µg /m3 < 50 < 120
Ozone (O3)
甲醛
µg /m3 < 30 < 100,
Formaldehyde (HCHO)
總揮發性有機化合物
Total Volatile Organic Compounds µg /m3 < 200 < 600
(TVOC)
氡氣 Bq /m3 < 150 < 200
Radon (Rn)
空氣中細菌 cfu /m3 < 500 < 1,000 13
Airborne Bacteria
d
cdV A dA
c v (1)
dt V
In a scalar form,
A cv dA A cvcos dA (2)
We have
d
cdV c1v1 A1 c 2 v2 A2 (3)
dt V
n
If c is constant within the control volume V, V
d (cV )
c1v1 A1 c2 v 2 A2 (4)
dt
v1 A1 v 2 A2 q (5)
we have
V
dc
dt
q co c (7) 14
Define
q
n (air changes per second) (9)
V
nco c
dc
(10)
dt
Solution:
c co 1 e nt c I e nt (11)
15
Ventilation and SBS
Sundell et al. (1994)
Odds Ratio of SBS-symptoms
4
x
3 x
xx
x
2 x
x
x
x x x x
x x x x x
x
x x
1 x x
0
0 10 20 30 40 50 60
Outdoor air flow rate, L/s,p
Jan Sundel
Ventilation and sick leave
Milton et al. (2000)
% sick leave
2.5
(P<0.05)
2
35% lower
1.5
0.5
0
12 24
Ventilation rate (L/s per person)
Before 1900: After 1900: After 1990:
Miasma Influenza pandemic 1918-1919 Sick building syndrome
Lavoisier 1774 O2 Carrier 1919 “manufactured US Indoor Air Act of 1991
Lavoisier 1775 CO2 weather” Eurovent 2002
Polluted cities Paris and Fanger thermal comfort SARS epidemics 2003
London, late 18th and 19th Energy crisis 1973 WorldVent 2006
century
EuroVent
2002
WorldVent
20 ASHVE
2007
1914
15 Bilings
1895 Comfort ASHRAE
Yaglou
10 Flugge 1936 1973 ASHRAE
1905 1989/2004
5
ASA ASHRAE
1946 1981
0
1875 1900 1925 1950 1975 2000 2025
Year
18
Example 1 A lecturer works late in his office and leaves his office at 10:00 pm. By the time he
leaves, no mechanical ventilation is provided to his office. Assuming that the infiltration rate is
constant, 5 litre per second. The CO2 concentration is 1000 ppm at 10:00 pm. What will be the
CO2 concentration in his office when he returns at 8:00 am in the next morning? We assume that
outdoor air CO2 concentration is 350 ppm. The volume of the room is 36 m3.
Solution:
nco c
dc
(12)
dt
Its solution is
c co 1 e nt c I e nt (13)
Time t(hour) q = 5 l /s q = 20 l /s
10 pm 0 1000 ppm 1000 ppm
11 pm 1 744 ppm 438 ppm
12 pm 2 589 ppm 362 ppm
01 am 3 495 ppm 352 ppm
02 am 4 437 ppm 350 ppm
03 am 5 403 ppm 350 ppm
04 am 6 382 ppm 350 ppm
05 am 7 370 ppm 350 ppm
06 am 8 362 ppm 350 ppm
07 am 9 357 ppm 350 ppm
08 am 10 354 ppm 350 ppm 19
Example 1 A lecturer works late in his office and leaves his office at 10:00 pm. By the time he
leaves, no mechanical ventilation is provided to his office. Assuming that the infiltration rate is
constant, 5 litre per second. The CO2 concentration is 1000 ppm at 10:00 pm. What will be the
CO2 concentration in his office when he returns at 8:00 am in the next morning? We assume that
outdoor air CO2 concentration is 350 ppm. The volume of the room is 36 m3.
Solution:
nco c
dc
(12)
dt
Its solution is
c co 1 e nt c I e nt (13)
Time t(hour) q = 5 l /s q = 20 l /s
10 pm 0 1000 ppm 1000 ppm
11 pm 1 744 ppm 438 ppm
12 pm 2 589 ppm 362 ppm
01 am 3 495 ppm 352 ppm
02 am 4 437 ppm 350 ppm
03 am 5 403 ppm 350 ppm
04 am 6 382 ppm 350 ppm
05 am 7 370 ppm 350 ppm
06 am 8 362 ppm 350 ppm
07 am 9 357 ppm 350 ppm
08 am 10 354 ppm 350 ppm 20
Concentration decay in this room for
different flow rates
1000
Concentration (ppm)
900
n=0.5 (q = 5 l/s)
800 n=1 (q = 10 l/s)
700 n=2 (q = 20 l/s)
500
400
300
0 5 10 15
Time (Hr)
21
Example 2. For a room with an air change rate of 1 ACH, calculate the time required for
changing the room air with outside air by 99.9%?
n
h co c
dc
(13)
dt 3600
We refer the room air at time t =1 as the “old air”’ and the outside fresh air as the “new air”.
With this notation, at time t = 0, the concentration c of “old air” in the room is 100%. For the
quantity co in equation (13), we can set co =0.
We have
nh
t
c cI e 3600 (14)
If c = 0.001, i.e. the concentration of old air in the room is 0.1%, which means that the air was
replaced by new air 99.99%.
22
Example 2. For a room with an air change rate of 1 ACH, calculate the time required for
changing the room air with outside air by 99.9%?
n
h co c
dc
(13)
dt 3600
We refer the room air at time t =1 as the “old air”’ and the outside fresh air as the “new air”.
With this notation, at time t = 0, the concentration c of “old air” in the room is 100%. For the
quantity co in equation (13), we can set co =0.
We have
nh
t
c cI e 3600 (14)
If c = 0.001, i.e. the concentration of old air in the room is 0.1%, which means that the air was
replaced by new air 99.99%.
23
Concentration decay as a function of
air change per hour
1.2
Concentration decay
n=1
1
n=2
0.8 n=3
n=6
0.6 n=12
n=24
0.4
0.2
0
0 20 40 60 80
time (min) 24
When there is a pollutant source in the room,
V
dc
dt
q co c V pol (16)
c co cG 1 e nt c I e nt (18)
where
V pol
cG
q
25
Example 3. If the CO2 production rate of a person at an activity level of 1.2 met is 0.005 litre/s,
what outdoor air flow rate q per occupant is needed at this activity level if the CO2 concentration
is not to exceed 1000 ppm? Consider that the outdoor concentration is 350 ppm?
q co c V pol 0 (17)
V pol
q
co c
Thus,
V pol 0.005 10 3
q 7.7 10 3 m3/s=7.7 l/s
co c (1000 350) 10 6
26
Example 3. If the CO2 production rate of a person at an activity level of 1.2 met is 0.005 litre/s,
what outdoor air flow rate q per occupant is needed at this activity level if the CO2 concentration
is not to exceed 1000 ppm? Consider that the outdoor concentration is 350 ppm?
q co c V pol 0 (17)
V pol
q
co c
Thus,
V pol 0.005 10 3
q 7.7 10 3 m3/s=7.7 l/s
co c (1000 350) 10 6
27
We consider the same lecture theatre (20 m long, 15 m wide and 3 m
high) with 49 students and one teacher continuously occupying it
between 9:30 am and 11:30 am. The CO2 generation rate from each
person is 0.005 l/s, while the outdoor CO2 concentration is 350 ppm.
The infiltration rate is neglected, while the mechanical ventilation rate
is 250 l/s over the 2-hour period. It can be assumed that the CO2
concentration is uniform in the lecture theatre being considered. The
indoor CO2 concentration at 9:30 am is the same as the outdoor CO2
concentration.
28
Answer
(c2) 5
The concentration in the classroom towards the end of the two hour
lecture is above 1000 ppm, which does no satisfy he basic ASHRAE
standard requirement or Hong Kong IAQ requirement. The ventilation
rate for each person is not reasonable, i.e. 5 l/s/person, less than the
ASHRAE standard of 10 l/s per person, or 7.5 l/s per person in class
rooms. Thus the IAQ condition in the room is not acceptable when the
number of students is 49.
29
Measurement of amount of supplied ventilation air
nt q, C
C CI e 1.2
Concentration decay
n=1
1
n=2
Factors affecting n=3
0.8
concentration decay n=6
0.6 n=12
The air change rate, which is
n=24
ventilation flow rate divided by 0.4
the room volume
0.2
0
Ventilation rate determines the
0 20 40 60 80
amount of pollutant removed,
time (min)
and the remaining amount of
pollutant divided by volume, i.e.
concentration
31
Decay of droplet nuclei concentration in an isolation room
for different ventilation rates and duration of time
Ventilation rate 6 ACH 9 ACH 12 ACH 15 ACH 18 ACH 21 ACH 24 ACH
Time (minutes)
0 100.00% 100.00% 100.00% 100.00% 100.00% 100.00% 100.00%
33
Large space Small space
34
The size of a room matters
35
Air flows in buildings
Gravity current
Supply jet
Buoyancy flow
around a person
Thermal plume
Boundary
Layer flow
Potential
exhaust flow
36
Svenson, 1998 37
Svenson, 1998 38
39
40
2.2 Effect of Filtration Devices in a
Room
How a filtration device “works”?
Filtration device
qf
41
The balance equation becomes
V
dc
dt
q co c V pol q f c (22)
or
V
dc
dt
q q f c V pol qco (23)
The equation can be again solved, we define
qf
nf (24)
V
Then
V pol qco
c 1 e n n f t c e n n f t (25)
q q f I
q
Filtration device
qf
q
Concentration is c
42
Example 4. Still consider a lecturer office at HKU. Assume a day with air pollution index API
=100 with high respirable suspended particulates (RSP) outdoor concentration, say 180 g/m3.
Assume that no particles generated in the office, neglect the particle deposition effects. With a
natural ventilation flow rate 20 l/s through windows, calculate the concentration of RSP in the
office at steady state condition, which should give an indication of the performance of a particle
filter? We consider an electrostatic filter with a filtration efficiency of 99.97%, and the filter can
treat an air flow rate of 5 l/s
Solution:
q
Filtration device
qf
q
Concentration is c
43
Example 4. Still consider a lecturer office at HKU. Assume a day with air pollution index API
=100 with high respirable suspended particulates (RSP) outdoor concentration, say 180 g/m3.
Assume that no particles generated in the office, neglect the particle deposition effects. With a
natural ventilation flow rate 20 l/s through windows, calculate the concentration of RSP in the
office at steady state condition, which should give an indication of the performance of a particle
filter? We consider an electrostatic filter with a filtration efficiency of 99.97%, and the filter can
treat an air flow rate of 5 l/s
Solution:
q
Filtration device
qf
q
Concentration is c
44
Example 5. For a classroom with a ventilation flow rate of 500 L/s.
We intend to install portable air cleaners to reduce the pollutant
emission from the room by at least 50%, which is equivalent to
achieving a 50% or higher room air cleaning efficiency. A portable
air cleaner can filter with a filtration efficiency of 85%, and the
filter can treat an air flow rate of 200 L/s. How many such cleaners
are needed?
Solution
c nf c qf
r 50%
c nf q qf q
qf
q 500
As = 85%, =85/50-.85=0.85, hence ???? = = 588 L/s.
qf .85
45
On what ground that we determine
how much outdoor ventilation air is
needed in a building?
46 of 44 slides
Before 1900: After 1900: After 1990:
Miasma Influenza pandemic 1918-1919 Sick building syndrome
Lavoisier 1774 O2 Carrier 1919 “manufactured US Indoor Air Act of
Lavoisier 1775 CO2 weather” 1991
Polluted cities Paris and Fanger thermal comfort Eurovent 2002
London, late 18th and Energy crisis 1973 SARS epidemics 2003
19th century WorldVent 2006
EuroVent
2002
WorldVent
20 2007
ASHVE
1914
15 Bilings
1895 Comfort ASHRAE
Yaglou
10 1936 1973 ASHRAE
Flugge
1905 1989/2004
5
ASA ASHRAE
1946 1981
0
1875 1900 1925 1950 1975 2000 2025
Year
48 of 44 slides
Yaglou, 1937
49 of 44 slides
Yaglou, 1955
The tug of war phenomenon between
energy saving and IAQ
I want I want to
better IAQ use less
energy
I have so much
for my building,
the less cost
the better!
50 of 44 slides
Janssen (1999) reviewed the historical
records of ventilation rate determination,
and noted two schools of thought with
respect to ventilation in the last several
centuries, i.e.
51 `
Were the existing or previous ASHRAE
ventilation standards developed based on
health requirements?
Concentration profile
54
Gehr and Heyder: Particle-Lung Interactions, Marcel Dekker, 2000
55
Gehr and Heyder: Particle-Lung Interactions, Marcel Dekker, 2000
56
The concept of Body Burden (BB)
BB = A + S – L – T (26)
1 T
E c(t )dt (27)
T 0
For pollutants received through respiratory route, if the absorption rate is 100%, the dose is
defined as
D E V (g) (28)
E is the “averaged” integrated exposure level as defined earlier, (g/m3), V is the total air volume
that the person breathed during a defined period (m3).
57
For example, Fugas (1975) was the first to compute integrated exposure. The following example
is extracted from Fugas (1975).
58
Example 5: Calculate the formaldehyde dose for an autopsy instructor and a textile worker with
the following data per year.
It was suggested that the formaldehyde is quantitatively absorbed in the turbulent air stream in
the nasal passage where it dissolves in mucus. Thus, it is assumed that all formaldehyde is
absorbed. Thus, the dose becomes (assumes the breathing rate is 1 m3/hr).
60
Difficult issues
61
62
ftp://ftp.arb.ca.gov/carbis/research/seminars/marshall/marshall.pdf
63
ftp://ftp.arb.ca.gov/carbis/research/seminars/marshall/marshall.pdf
64
65
66
67
Prof. Fanger’s approach
68
Prof. Fanger
69
Prof. Fanger
70
Prof. Fanger
71
Teaching Schedule 2015-2016
Second Semester: Thursdays, 7:00 - 9:30 pm (2.5 hours), Venue: CBA
In-course assessment: 20% (10 for real in-course assessment, 1 hr, 10 for homework, all given by Yuguo Li)
Final exam: 80% 72
Topics: Introduction to concentration
Mass balance equation
Concept of mixing, air change per hour,
decay equation
Filtration efficiency, room cleaning
efficiency
Exposure and dose-response curves
73