D Cotenation . Cotenation §s the Gngue Poopeaty due to hich tH Torens Covatent bonds Wh other Carbon atoms , a] “Teue q Hloab, Q Nuucno NL ConH Aremonivmn Urea, Cyanate 4D Acetic act by Kolbe to \e4s. 5\ Ethyne molecule Ts JP HMylosidised . eC sp*>se* >se AA ce) Orders of Electronegativity With tespect +0 hybridisation ts . Sp >sp* 7sP- @ Co) Statement I ts taconect tle Statement IE ts Corsoct Covcect Statement It op- hybrid. Ostia) Seems Srotter and. Stwonger bond fran SP hybetd. “osbitals. a) Falce* comect Gtatermert = The casbon Worth 6P- hybaid. Oxbital ts more electronegative, than GOE - WORKSHEET 14] Co) Both A and R are Comrecr and R is Coaxect explanation OF A» 4 a "fl = cec-e—n O-= H o& bonds = 4 TK bonds = 2 13 (Ci3d2,CO —* SP CHy |=—* 60 oe 3 &, 7S! SP SP, sp? 13] nCen Hyboidisation of C= SP Shape OF Hen = Linear we M4) Complete Structured acne. 1s) a Ethene =~, 2-0-2 1 te) CH CCHDG CHy 4] Bond - Ling \@] CuyCOHnye Ch, : corbon with SP —inibstd. Oxbital.Wow ho ete Ves | eee ee Wo G—€=c-C- En H I | ac} My We 7. { Y va + Bond - line formula ai] False; Solid wedge and dashed - wedge are used +0 Show bonds towards the user and away from the User Bespectively. 24] 1) Feamuork model fi) Ball ang stick rmodet Ti) Space Filing model 23) Benzenoid a aA—* ©) ae— c— &) om 5 heteroGy clic, °9 { a ) west Sines axe hhomecy chic « Fhiophene C ~ | Pyridine, aol we 2+) @) 22) Homologous Series 29) i) Haloalkanes it) Alkanones 30) True, 31) Guckminstes fullesene 32) a+ @) Boo c— Cu) 0 —+ C2 33) Unsaturate 84) CaoHe2 39) False. Tsivial mame of given Compound is neo- pentyl. 86) @) None OF the above carries Pag ecru O%a) 5 Crs) Gilg Cy 3- ethy\-454- di methy| heptane. 8, 2-34 s 6 og Cy CH “CH=CH CH=CH, position of methyl Gn3) °F Position oF Ethy| C0) = 3255) 6- tatmethyloctane 4) Ang Cod CHg OH, CHsCHOH and CH3),cHoH AN having -oH functional Qroup liberate hydrogen On Seaction With Sodium metal (Oheare as CH30chs fs Containing ether voup . and diethy| ether “does Nor Corttain Active hydeoger hydrogen attached +o Oxyge (ike alcohols. 42) Lowest- ud = Coo? ~Coti7 Sc=07 -on> See ge 3-keto - 2- enethyt hex - 4~enal ree? = 4 3 hs 14g) OW CHa = Gig OOH, O=C-OH, 4- hydiory hoptan - 2-one 46) 1) Brome | Halides i) Estey %) Amides 1) Casbamoyl [Amides . 44) Ans: Pentane oftetle 5 Rest Other compounds Contats Carboxylic Ocicl group (Coon) Suffix = -ofc acid . Nitsiles gzoup (- ¢ sn) Suffix = Nitsile. 4e) b i) Clg CHa— CH) — C- Ch Butanoy| Chloside, Functional group = Acyl chionde 24 4a) True ri OD Ls 0) + ochg 4 oy 5) Ne hOZBon, oy, 344 -dieetny| Phenol .o> (a) Comect Structure fs Lethal - 1 Stroro ~ 2 -nitto- benzene qo, F pe 7 ae 53) Structysal. Teomecs 54) Tue - 55) (a) Both Cad and Ce Positioned. Ssomer differ io Position OF monovalent functional groups. Functional group Somer Some molecular formic. but different functional gooups- 50), Metamers Jt asses due to diferent a\ky\ Chains on either side Of the Ffunctioray group fn he molecule - :- CutioO Tepresents Snetrory propane (cry 0C3 Hy) and ethoxyethare Ceatig OGH5) 57) Geometsical 5 Optical . 5% Wwue + + + Go) CH) chy < CHCCH3)2 < CcH3)3C 1) tletexopoior “ese ave also called jontc reactions . @2) Free Radi cal 63) (b)staterment CI) fs Cossect and a is Cossect statement:- Only heterolytic. Cleavage takes place “In Absence of light. Incowsect Gu) Fa\se; the Gtability of alkyl vadicad fs Eye CHrOH, < CHD, < Ceo, 65) “Re teagent that bri, an elechon Pais Sua called a nlucleaphile . Wheseas ne “Seager that takes away an electrory Pais fs called electtophile . @@) CAD - ©7) tb) G8) AICl3 ts the electrophi le , While vest ave. Oucleophi lesF Cotion Anyoo A ss aS 30) fa) Oo CHs cs Conditions for sesonance f 19 Cg-Cu co Gis ee 30) . 2 = ©) Nucleophfles : 465 CohsO7 pennies) a Arca, Electrophiles + BF3 » AIC» rece c » NOs > Giy-cHy ta option Cd) neither of ® Conditions follows g A) CHT - hence (d) ts (east wae Besonance Gtabilised . 33) 3) 81) Cc) Costect moveroent 73) Cossect = Intorsect ao @-o m- x au) Inductive Effect @) a tT effect [+e fey 4¢) Conno nical Stsuctures tape eeats 4) {) Same positfon of oucler (@ Se=o => -R effect ey Sane Number OF *” “anpatied. electsons Hence (A) 8 the Comect option |y Vue 84) Electromesic effect Tisa Aemposasy effect “The osganic Compounds having” a multiple bood Show this effect tm the Presence OF an attacking Yeagent only he 4 2. foe Cartacking 4 reagent) Positive elecko mesic eFFeck Cr€ effect) a es Doric iar —y & Be < Costockir q iM seagent J Negative electromeric effect (-€ effect) #8) A—*Q@) B—* (4) ow op— co) 2) o - bonding osbitar qo) Comtech = Tncorsect a ae Wa ae we x =m. Vv x covet Statement C1): Tp grabilises Grbo Cation 9) Ga) 92) Sublirnah 00 5 Caystallisation, AistiNation , di tferent’ao extraction aod Chrom atogsaphy 98) Sublimation 44) Solubility 4s) (a) 9) Distillation 93) Fractionad distillatron 98) Fea.chionating Cloumo - 4a) Higher » Lower 100) Cb) \0) Theoretical plote 102) True 103) Dist Nation Undey teduced Pressuse, Point 40 vermembes: Glycerol Can be Separated fyonq Spent — lye in Soap industey by using this techique. 104) (@) Vatuuco purop to 5) ly cena) .2 Volatile 5 inomiscible 109) False 5 Liquid boils thea Sum of vapour pressure 1S equcid 4o atenospheric Pressure, 108) Aniline - water 0g) True 119 Continuovs extsaction - + In this technique Same Solvent ts sepeatediy usec fox extradion of the Compound NA) Chromatography \12) 4) Rd somption Chromato- guaphy - Vi) Pastition Chsomartogrophy 13) @d) «Adsorption Chromatography ts based on the fact that difesert Compounds ose. a.dsosbed on an adsosbonr 40 different degrees. \i4) Yos 119) Co) Diffetertiad adsorption of the Substances On the Solid phase le) Neos NF) Retordation factor OF (RF) value 11g) Compound. X 5 Aligher the retardation factor y 6lower will be the elution Wa) Cad Ninhydsin - !20) Cb) Pastition 121) False; Tr acts as Stationary phase . l22) COo s Ho (23) Lassaigne’s fest ‘ (24) False ; EB will ee poussion blue Nepoe we to the presence nihogen (28) X= Sulphur - S>"+ Pb” —+ pbs, Black) 106) gs) Sh + (Fe Congo” —_, (recensnos]* Violet 124) N and § bothJi\C\, 129) True . \30)(C) Both state ments 13) a = 0.2724 80.4887 of hydvogen ig x Wt of Iho | AC OIC? is UU FUT +f. I OF Casbon = 12 Wtof Cos 4) ti) By Vi) T Gre Cosdect Wt of Con - ONI GM Wt OF Hao = O-lole gm Wt OF Compound = © 24 6 9m au Tota) wor of Goropard AD yous? xX100 U4 0-6 21-44]. “Total Wt of Compound 2 Pa x O04 Ving O-2UG@ 4-594-1- of TH’ is aaa]. 132)Durna's method 133) Upper 134) 0 “k Of Ne 28 8Voig(STP) 100, 22400 *~m ven mass = 0-309 Pressure Pj 2 HS - 1S = Foomml 4 Pv au = Lovo a Ty x Pa, = PIV, ¥293 00 KT, TOOXS0x273 400 K 300 Vo = 41*40 cro? AMoocnF Ny = 2 Jean 41690 Crp), 2 28x 4INGo 22400 Yo of N= 29 x41 Seer OE ED. 22400 x0-3 . = lta.False. Ajeldahl's method cannot be used fos nitrogen detesmination of Compounds having a nitso group Or Ato ~ group on Oitrogen: Present fn wings AS the Nitsogen OF these Compounds Cannot be Conv exted, to AMMonium Sulphate Crlay)aSoy Ondes the condition of this mediom . 134) Mass oF oxganit Compound 2 Og Volume of 1M Hasoy equiv ed. 2 tool 2. fork of 1M Hasoq = 20 eal oF Im nis Now \ooo col of 1M Nlhs contains 14 9M 20M of IM Ang would Comtain = 14 x20 {ood a Ni z_l¥x20 x loo ae (oF To00 oe > sels, 130) Cb) (32) Carsios method 1B3q\@ 1ags of Organic cn-O: <9 mass of Agar = 0129 a molecadac mass of AgGr = 19¢ gro 1889 Ayox Contains Bog bsoming Or(12g OF Ag Br will wn 2 32. yor contain 2 22. your 3 = 105g of bsomine ‘Ie of Boomine = 0-05 ols = 33°34, LY 840 luo) Ce) Cossect Reason: Gulphus gets procipiated a> White slid tu) X 2 Basoq x loo AU kmowon mass of an O¥ganic Compound ts heated in a Carivs tube uth sodion esoxide os Fuming nitric acid. Sulphur present in the Compounch ts oxidised +o Sulphusic acid. T+ is precipitated as basi um Sulphate by addimg excess OF bari chiotide Solution ta ea‘Weue molecwIar mass OF BaSoy =(34 492764 mee 9.33 9 Basey Contains 32g S' © 4813. Q BaSoy Containg = 82 x0-4813 gis) | 233, | “fe oF Sulphur = 820-4813 x100 233 xo1st | > Maho | = Y2-loy, A definite cnass of an Compound {s decomposed. | by heating in a Ghream of | Nitwogon gas. The enixtore | OF gaseous products toning | Oxygen is passed over xed- | hot coke When all the Oxygen is ConverFed +0 CO. this mixture is Passed through warn iodine pentaoxide Gos) When‘Co' ‘S oxidised to CO, Psodvcing Todine compa pert» O, + other iseouS | ais. Si Produck | ac +0, 2; 9¢0) Ta0s +8CO—— Te +o, | lus aElementad floalyser.