Chapter 3
Chapter 3
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A. No reaction Displacement
B. Displacement No reaction
Use the Table above to answer the following questions about metals A, B, C and D.
(i) Which is the most reactive metal?
(ii) What would you observe if B is added to a solution of copper (II) sulphate?
(iii) Arrange the metals A, B, C and D in the order of decreasing reactivity.
Answer: Explanation
A + FeSO4
A + CuSO4
B + FeSO4
B + ZnSO4
C + FeSO4
C + CuSO4
C + ZnSO4
C + AgNO3
D + FeSO4/CuSO4/ZnSO4/AgNO3
From the above equations, we obtain:
(ii) If B is added to a solution of copper (II) sulphate, then it would displace copper.
B + CuSO4
(iii) The arrangement of the metals in the order of decreasing reactivity is: B > A > C > D
Question 4: Which gas is produced when dilute hydrochloric acid is added to a reactive metal? Write the chemical
reaction when iron reacts with dilute H2SO4.
Answer: Hydrogen gas is evolved when dilute hydrochloric acid is added to a reactive metal.
When iron reacts with dilute H2SO4, iron (II) sulphate with the evolution of hydrogen gas is formed.
Question 5: What would you observe when zinc is added to a solution of iron (II) sulphate? Write the chemical reaction
that takes place.
Answer: Zinc is more reactive than iron. Therefore, if zinc is added to a solution of iron (II) sulphate, then it would displace
iron from the solution.
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Question 1: (i) Write the electron-dot structures for sodium, oxygen and magnesium.
(ii) Show the formation of Na2O and MgO by the transfer of electrons.
(iii) What are the ions present in these compounds?
Answer: (i) The representation of elements with valence electrons as dots around the elements is referred to as electron-
dot structure for elements.
(ii)
(iii) The ions present in Na2O are Na+ and O2− ions and in MgO are Mg2+ and O2− ions.
Answer: Ionic compounds have strong electrostatic forces of attraction between the ions. Therefore, it requires a lot of
energy to overcome these forces. That is why ionic compounds have high melting points.
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Question 2: Name two metals which are found in nature in the free state.
Answer: The metals at the bottom of the reactivity series are mostly found in free state. For example: gold, silver, and
platinum.
Question 3: What chemical process is used for obtaining a metal from its oxide?
Answer: The chemical process used for obtaining a metal from its oxide is reduction. In this process, metal oxides are
reduced by using suitable reducing agents such as carbon or by highly reactive metals to displace the metals from their
oxides.
For example, zinc oxide is reduced to metallic zinc by heating with carbon.
Manganese dioxide is reduced to manganese by treating it with aluminium powder. In this case, aluminium displaces
manganese from its oxide.
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Question 1: Metallic oxides of zinc, magnesium and copper were heated with the following metals.
Metal
Zinc Magnesium Copper
Zinc oxide
– – –
Magnesium oxide
– – –
Copper oxide
– – –
Zinc oxide
No reaction Displacement No reaction
Magnesium oxide
No reaction No reaction No reaction
Copper oxide
Displacement Displacement No reaction
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Question 2: Which of the following methods is suitable for preventing an iron frying pan from rusting?
(a) Applying grease
(b) Applying paint
(c) Applying a coating of zinc
(d) all of the above.
Answer: (c) Applying a coating of zinc
(We can also apply grease and paint to prevent iron from rusting. However, in case of iron frying pan, grease and paint
cannot be applied because when the pan will be heated and washed again and again, the coating of grease and paint
would get destroyed.)
Question 3: An element reacts with oxygen to give a compound with a high melting point. This compound is also soluble
in water. The element is likely to be
(a) calcium
(b) carbon
(c) silicon
(d) iron
Answer: (a) The element is likely to be calcium.
Question 4: Food cans are coated with tin and not with zinc because
(a) zinc is costlier than tin.
(b) zinc has a higher melting point than tin.
(c) zinc is more reactive than tin.
(d) zinc is less reactive than tin.
Answer: (c) Food cans are coated with tin and not with zinc because zinc is more reactive than tin.
Question 5: You are given a hammer, a battery, a bulb, wires and a switch.
(a) How could you use them to distinguish between samples of metals and non-metals?
(b) Assess the usefulness of these tests in distinguishing between metals and non-metals.
Answer: (a) With the hammer, we can beat the sample and if it can be beaten into thin sheets (that is, it is malleable),
then it is a metal otherwise a non-metal. Similarly, we can use the battery, bulb, wires, and a switch to set up a circuit with
the sample. If the sample conducts electricity, then it is a metal otherwise a non-metal.
(b) The above tests are useful in distinguishing between metals and non-metals as these are based on the physical
properties. No chemical reactions are involved in these tests.
Question 6: What are amphoteric oxides? Give two examples of amphoteric oxides.
Answer: Those oxides that behave as both acidic and basic oxides are called amphoteric oxides.
Examples: aluminium oxide (Al2O3), zinc oxide (ZnO)
Question 7: Name two metals which will displace hydrogen from dilute acids, and two metals which will not.
Answer: Metals that are more reactive than hydrogen displace it from dilute acids. For example: sodium and potassium.
Metals that are less reactive than hydrogen do not displace it. For example: copper and silver.
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Question 8: In the electrolytic refining of a metal M, what would you take as the anode, the cathode and the electrolyte?
Answer: In the electrolytic refining of a metal M:
Anode Impure metal M
Question 9: Pratyush took sulphur powder on a spatula and heated it. He collected the gas evolved by inverting a test
tube over it, as shown in figure below.
(a) What will be the action of gas on
(i) dry litmus paper?
(ii) moist litmus paper?
(b) Write a balanced chemical equation for the reaction taking place.
Answer: (a) (i) There will be no action on dry litmus paper.
(ii) Since the gas is sulphur dioxide (SO2), it turns moist blue litmus paper to red because sulphur dioxide reacts with
moisture to form sulphurous acid.
(b)
Question 11: What type of oxides are formed when non-metals combine with oxygen?
Question 13: You must have seen tarnished copper vessels being cleaned with lemon or tamarind juice. Explain why
these sour substances are effective in cleaning the vessels.
Answer: Copper reacts with moist carbon dioxide in air to form copper carbonate and as a result, copper vessel loses its
shiny brown surface forming a green layer of copper carbonate. The citric acid present in the lemon or tamarind
neutralises the basis copper carbonate and dissolves the layer. That is why, tarnished copper vessels are cleaned with
lemon or tamarind juice to give the surface of the copper vessel its characteristic lustre.
Question 14: Differentiate between metal and non-metal on the basis of their chemical properties.
Answer:
Metal Non-metal
They react with water to form oxides and hydroxides. Some metals
react with cold water, some with hot water, and some with steam.
They react with dilute acids to form a salt and evolve hydrogen gas. They do not react with dilute acids.
However, Cu, Ag, Au, Pt, Hg do not react. These are not capable of replacing
hydrogen.
They react with the salt solution of metals. Depending on their
reactivity, displacement reaction can occur. These react with the salt solution of non-
metals.
Question 15: A man went door to door posing as a goldsmith. He promised to bring back the glitter of old and dull gold
ornaments. An unsuspecting lady gave a set of gold bangles to him which he dipped in a particular solution. The bangles
sparkled like new but their weight was reduced drastically. The lady was upset but after a futile argument the man beat a
hasty retreat. Can you play the detective to find out the nature of the solution he had used?
Answer:
He must have dipped the gold metal in the solution of aqua regia a 3:1 mixture of conc. HCl and conc. HNO
3. Aqua regia is a fuming, highly corrosive liquid. It dissolves gold in it. After dipping the gold ornaments in
aqua regia, the outer layer of gold gets dissolved and the inner shiny layer appears. That is why the weight of gold
ornament reduced.
Question 16: Give reasons why copper is used to make hot water tanks and not steel (an alloy of iron).
Answer: Copper does not react with cold water, hot water, or steam. However, iron reacts with steam. If the hot water
tanks are made of steel (an alloy of iron), then iron would react vigorously with the steam formed from hot water.
That is why copper is used to make hot water tanks, and not steel.