TOPIC: Thermodymics

46. Which of following is a path function: 46. fu es sdleI ki ki@ug%

(A) Intemal energy
(A) wjd Át Z

(B) Enthalpy (2) A

(C) Work C) dkz
(D) Entropy (D) both
47. Under which of the following conditions is the 47. I AH=AE+Pavf I esd sdl8IHkaj Igg%
relation AH=AE+PAV is A) Iea ic ij
(A) Constant pressure
(B) Ilelarij
(B) Constant temperature

(C)constant temperature and pressure

c)lelark vpi
) None of these
48. i e d dl8l kàte vdkkesvd 6 ds tj ds
48. Which of folloiwng is correct for free expansion
fy, Ighgso
of an ideal gas under adiabatic condition: (A) q 0 , AT <0, W: 00
(A) q 0, AT <0, W0
(B) q=0, AT:0, W =0
(B) q 0, AT 0, W = 0
(C) 0 , AT = 0, W =0 (C) 0, AT =0, W =0
(P) 9 0, AT = 0, W =0
(D) q 0 , AT = 0, W = 0

49. Which equation is correct for adiabatic process

49.
di6lkleldj.k:àrëe fo dsy, I ghg9%
A) Q==+W
(A)Q=+w
(B) AQ 0 (B) AQ 0

(C) AE Q (C) AE = Q

) P+AV=0 () P+AV=0

50. H,C+2HCI, AH =194 KJ. In this reaction, heat 50. H,+Cl,2HCI, AH=194 KJ. H viHD kdsy, HCa
of formation of HCI (in KJ) is : (in KJ) ds bHou dhA'tkD kgsh%
(A) 914 KJ (A) 914 KJ

(B) 97KJ (B) 97 KJ

(C)-97 KJ (C)-97KJ
()-194 KJ (D)-194KJ
51. Enthalpy change for the reaction 51. A'ekijarñdkeku upste;hvHo;k
4Hg)-24,0) is-8695 KJ. The dissociation energy
of H-H bond is :
4H)2H9) dsy,
ddd At keu Kr d , %
-869.5 KJ.
gIlaH-H dd dh
(A) 217.4 KJ (A) 217.4 KJ

(B)438.4 KJ (B)-438.4KJ
C)-869.6 KJ (C)-869.6KJ
(D) +434.8 KJ D) +434.8 KJ
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 52. For the reaction, AH=3 kJ, AS = 10 J/K beyond|52. 1dl hvH O Kd sy, AH=3 kJ VlbAS = 10 JIK gSS
which temperature this reaction will be dl rkeudshvito;klarAzrZide gahf%
spontaneous: (A) 300 K
(A) 300 K
(B) 200 K
(B) 200 K
(C) 273 K
(C) 273 K
) 373 K
( ) 373K
53. iry vly visiry ( dsy, m hr kdhÄ'ekD; k
53. The heat of neutralisation of any strong acid and
strong base is nearly equal to :
go
(A) -75.3 KJ
(A) -75.3 KJ
(B) +57.3 KJ
B) +57.3 KJ
C)-57.3 KJ
(C)-57.3KJ (D) 75.3 KJ
D) 75.3 KJ
54. e d sdldkeufudkyusdsy, g5iue dkiz
54. Hess law is used to calculate: d;kt kkgs%
(A) enthalpy of reaction
(A) vH3 kdhAek
(B) entropy of reaction (B) v H kdhuth
(work done in reaction c) vkdsik7
(D) all of these ) najIH
55. v kucg)+ 3H,(o) =2NH,(9), dsy, aH dl ds
55. For N9)+3H,9)2NH,(9), AH is equal to :
cig gek%
(A) AE +2RT (A) AE +2RT
(3) AE -2RT (B) AE-2RT
C) AE+RT (C) AE+RT
(D) AE-RT ) AE-RT
56. Heat of neutralisation will be minimum for which 56. fuieel sdl viHk0 kdsy, nmk hr kd hA"el ds
of following reaction : de gs%
(A) NaOH+H,SO, (A) NaOH+H,SO,
e) NHOH+CH,COOH (B) NH,OH+CH,COOH
(C) NaOH+ HCI C) NaOH+ HCI
D) NaOH+CH,COOH (D) NaOH+CH,cOOH
57. fheat of formation of So, is-298 kJ. What is heat 57. VX SodudhA"ek-298 kJ gB l xe lYQ
of combustion of 4 gm of sulphur: dsgu dhA'ekD, kgsh%
(A) 7KJ (A) 37 KJ

(B)-37.25 KJ (B)-37.25KJ
(C) 298 KJ (C) 298 KJ
D) 18.6KJ (D) 18.6 KJ
58. Which of following reaction define AG, 58. esi sdi8I hvHDkaG,dsy, nà; g9%
ACm+0,9)co, A) Cmre +0,(9)>Co)

)M4o)Fo)-»HFlg) ()Ho)F0)-HF(a)
(C) HP0,+HO2H,Po,
(C) HPO,+ HO2H,Po.
) sog)+o0)soo) o) soo)o0)sog)
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59. The correct relation between "K and standard 59. 'KnVSeud eir At ke8d8T kI CU 1ggS%
free ener9y change is:
(A) AG°=RTIogk
(A) AG°=RTlogk (B) AG°=RTInK
(B) AG°=RTinK
AG -log K
nRT
()T-log
nRT K
AG"
(o) nRT 2.303logk
AG"
(D)T2.303logk
nRT 60. Vya®° "N gsil hvtH;kdsy, rkii ed sile
60. f AG° is zero for a reaction then : IkodY Ighgsk%
(A) AH 0 (A) AH 0
(B) AS 0 (B) AS = 0

(C) K=0 (C) K 0

(D) K 1 D) K 1

61. For the reaction, 61. fn ; vHO kdk

N(g3H,o)2NH,(9); N9)+3H()+2NH,(g)%
AH -95.4 kJ and AS= -198.3 Jk'. Calculate the AH=-95.4 kJ viSas =-198.3 Jkr1gArk K dit
which the reaction will proceed in tlij vkvxfkesdlAir gs%
temperature at
forward direction:
(A) 450 K
(A) 450 K
(B) 581 K
B) 581 K
(C) 640 K
(C) 640 K

(D) 1100 K D) 1100 K

correct according to third sted sdleI kfod A"elír dhdsrh fir e ds

62. Which of following is 62.
law of thermodynamics: vutj I ghg%
A) AG =0 (A) A G =0

(B) AH=0 (B)AH=0

(C).AE =0 (C) TO
AE =
0

(D) AS =
0
(D) AS=0
63. (AH-AU) for formation of carbon monoxide from63. dkaee VEMdHudsy, 298 Kij (aH-au)
its elements at 298 Kis:
dkeu D kgk%
(A) -1238.78 J mol-
(A)-1238.78J mol-
(B) 1238.78 Jmo (B) 1238.78 Jmo
C)-2477.57 J mo (C)-2477.57 J mo
(D) 2477.57 J mo ) 2477.57 Jmol"
The enthalpies of combustion of carbon and
64. 64. dlcd vsdci elle Ru EMd sngu dhA"ekge"' e
respectively are -393.5 and
carbon monoxide are of formation of carbon
-393.5 vS-283 kJ motgAdkcä elsle R EMds
-283 kJ mol". Enthalpy %
monoxide per mole will be : Ibu dhA'ekif ely Kr d ,
(A) -110.5 KJ (A) -110.5 KJ

(B)-676.5KJ (B)-676.5 KJ
(C) 676.5 KJ
(C) 676.5 KJ
(D) 110.5 KJ
(D) 110.5 KJ

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65. The heat required to raise temperature of body | 65. l i d k dkrkeku 1c c<ksdsy, vktWAt Rils
by 1C is called as D kdgrsg%
(A) Specific heat (A) Wmek
(B) Thermal capacity (B) kgler k
(C) Latent heat C) mek
D) None of these ) e d sd Mgh
66. Thefollowing reactions carrled out in open vessel. 6. ivHDk [skkesdjib khgidl vHkds
The reaction for which AH AU will be: , AH AU gk%
(A) PCI9) PCI(9)+CL9) (A) PCL19) PCI,(9)+Cl19)
(8) 2cO(0)+0,0)2co,9) (B) 2C09)+0,(9)2c0.
C) N,)+3H(9) 2NH,9) C) N,9)+3H9)- 2NH,(0)
(D) Hg)+1L)2Hl(g)
() H)+19)2Hl(g)
67. The enthalpy of formation of NH, is -46 KJ mor', 67. NH, dabudiek-46 KJ mo" gßkufiivH0;k
The enthalpy change for reaction is: dsy, mekijr2 dkelu D; kglsk%
2NH,(aqg)>N,(9)+ 3H,(9) 2NH,(aq)N,(9)+ 3H,9)
(A) 23 KJ (A) 23 KJ

+92 KJ (B) +92KJ

B)
(C) 46 KJ
C) 46 KJ
D) 184 KJ
184 KJ
68. For the reaction,
68. uhsh sx; svHD; kdsy; s,

B AB, AH = -50k cal

B> AB, AH= -50kcal
vxj A, B, vk$ AB dh clk Åt ZCe' %
f bondenergies of A, B,and AB are respectively
X, X/2 and xkcal, the value of xis: x/2 vSx grlsx dkelu D kglak%
(A) 50 (A)
(B) 100 (B) 100
(C) 200 (C)2200
(D) 400. () 400.
69. In which of following AS is positive:
69. u esl sdl vHE;kdsy; as / uRd g
(A) HOHO
(A) HOH,O
(B) 3020 20201
(B) 3021020a
(C) HOH,O
(C) HO HO
(D)Na13202NH (D) N23H202N,0
70. Standard molar enthalpy of formation of Co, is
equal to: co,dd tbudheud tekidldsiki gah%
(A) zero
(A)
(B) the standard molar enthalpy of combustion of
gaseous carbon. (B) dd delud e j ng1 miekds
C) the sum
of standard molar enthalpies of fomation ( covDdhej cdad I IuMidsi gdsj
of CO and
O
(D) the standard molar enthalpy of combustion of P) d i dd Mbu dhelad ej nmekd l
carbon (graphite).

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71. Which one of following is an exothermic reaction: 71. uiuesd sdl8I hiel{h vt;kg%

(A) NaO+ 180.8kJ-2NO (A) Nag+ O20+ 180.8 kJ ->

2NO
(B) N210t 3 2)92 kJ>2NH, (8) N23292 kJ2NH,
C)CHOCO+H131.1 k (C)C+HOcoH-131.1 kJ
() Creonet 2S-> CS-91.9 kJ
(0)orpha)+ 2S > CS,20-91.9 kJ
72. At 27°C one mole of ideal gas is compressed 72. 27 Ci_d ely vkd 6 dd elu rk vi$nt3e. h
isothermally and reversible from a pressure of 2
atm to 10 atm. The value of AE and q are:
valHkese atm ricI s10atm rd ckkx; kr leaE
viSq dkeu D kgak: (if R =2 cal)
(if R=
2 cal) (A) 0,-965.84 cal.
(A) O,-965.84 cal. (B)-965.84 cal.,-865.58 cal.
(B)-965.84cal., -865.58 cal.
(C) 865.58 cal.,-865.58 cal.
(C) 865.58 cal,-865.58 cal. ) +965.84 cal., +865.58 cal.
D) +965.84 cal., +865.58 cal. 73. d vkd 6 d sely d;koc;kdk Dkgat c
73. What will the work done by 3 mole of an ideal ag fud esla4tj djrhgs
gas when it expands spontaneously in a vaccum.
(A) 0
(A)
(B)
(6) (C) 3J
3J
D) 9J
9J

74. For the reaction H H, at 373 Kand 1

74.
vHD kH,o HO dsy; S73 Krk vlßS
atm ncij dieikl EU Ighgs
atm pressure:
(A) AH 0
(A) AH 0
(B) AE 0
(B) AE =0
(C) AH= TAs
C) AH TAS
(D) AH= AE.
(D) AH= AE.
75. What is unit of entropy: 75. bHhdhdb2 kgs%
(A) cal K (A) cal K

(B) cal K (B) cal K

(C)cmK ()cm K
) cm K.
(D)cm K.
76.
The heat evolved in the combustion of glucose is
glven by the equation
78 iyMk Iealj.kesaýrdli dargueA'tkiurdyrh
CH+60,(96co,tg}+6H,O(g); AH=-680 Kcal
CH.0(+60(g>6co,g+61,01g); AH=-680 Keal
of
The weight of CO,(9) produced when 170 Kcal
heat is evolved in the combustion of glucose is : yts dsrgu es in 170 Kcal A'ekfudl yrhgsls
(A) 264 9
druk co.g) dkHj nRl gak%
(A) 264 g
(B) 669
(C) 11g B) 669
D) 44 9 C)11g
(D) 44g
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77. AH (298 K) of methanol is given by the chemical | 77. u i esl sil8I hvHDkelslg dhaH (298 K)ds
equation:

(A CH 2 CHOH (A) CH 0CHOH

() aw /°22GH,OH, (B) Crei)t+ 2H,CH,OH

(C)eamendyt* O22 CHOH C)Comre 2 CH,OH,
D) CO+2H0CH,OH ) cO+2H20CH,OH
78. Calculate the free energy for following reaction 78. upae; hvH0; kdsy: sook ij ,aH = 145.6 kJ
at 300K Given, AH= 145.6 kJ mo and AS =116 J
mo, AS= 116 J K mo"eir At laikelu Kr dj%
K mo
2 Cuo (s)Cu O(s)+1/20,(9)
2 Cuo
(s) Cu,o(s)+1/20,(9)
(A) 110.8 KJ mol
A) 110.8 KJ mok1
(B) 221.5 KJ mol
(B) 221.5 KJ mol-
(C) 55.4 KJ mo
C) 55.4 KJ mol-
() 145.6 KJ mol"
)145.6 KJ mol
79. ngu tekdsfy; siui esl sdle geikl ghgs%
79. Enthalpy of combustion of a substance is always:
A)>0
(A) >0
(B) 20
(B) 20
(C) s0

(C)s0 (D)<0.
(D)<0. 80. upste; hxh vHogk
80. For the gas phase reaction:

PC () PG+ C2(a u es sdlIh'k@ ghgs

which of the following conditions are correct
(A) AH = 0 v S < 0

(A) AH
0 and AS «0 (B) AH>0v as>0
(B) AH>0 and AS»0
(C) AH0vs <0
(C) AH<0 and AS<0
) AH> OvAs <0.
(D) AH 0 a n d AS <0.

of81. ,d ey vd kSdlke73 K dd eurk ij 1dI so.1

81. Calculate work done for
of an ideal
isothermal expansion
gas from an initial pressure
rd i|ß djusdsy; sd; sx; dkdh. kkdt ; s%
one mole
of 1 bar to final pressure of 0.1 bar at constant
temperature of 273 K: (A) 5227.2
(8) +5227.2J
(A)-5227.2J
(B) +5227.2J (C)-2257J
(C)-2257 J (D)+2257J.
(D)2257 J.
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82. 1 mole of methanol, when burnt in oxygen gives 82. 1 ely elly dkvki huds kkrgu djusj-723
out-723 KJ mo. Heat if 1 mole of oxygen is used KJ mo" meke gshgxj vOhudk,d ely
what will be amount of heat evolved :

(A) -723 kJ
y;kt ksiddruhteker guh%
(A) -723 kJ
(B) 964 kJ
B) 964 kJ
(C) 482 kJ
(C) 482 kJ
D) 241 kJ.
(D) 241 kJ.
83. 200 cm' of 0.1 MH,SO, is mixed with 150 cm' of 0.2
83. mden.2 eli KoH ds50
M KOH. Find the value of heat evolved : e9k9k
S 0kgae mekdketu Kk djs%
(A) 1.7 kJ (A) 1.7 k
(B) 17 kJ (B) 17 kJ

C) 71 kJ C) 71 kJ
D) None of these. (D) bued sd Mgh
84. Thespecies which by definiton has zero. Standard 84. ied i l dH Huetud rcrkh / Hrkz3sKij
molar enthalpy of formation at 298K is: Ne gsh%
(A) Br,(9) (A) Br.o)
(B) Ci, () (B) C,(o)
(C)HOo) C) HOg)
(D) CH) (D) CHg).
85. The direct conversion of A to Bis difflicult. Hence 85. Al s dkl Mkarylo dBu g y;s gayb i i
it is carried out by the following shown path :
jkrs s[ ko; kgs%

A
Given
50 eu, 30 eu, 20
AS 50 eu, AS 3 0 eu, 4SD 20 ASA ASc+D ASD
Ts As dkeu kk dja
e.u., where eu is entropy unit, then As4 S:

(A) +60 e.u (A) +60 e.u

(B) 100 e.uu (B) 100 e.u

(C)-60e.u (C)-60 e.u

(D)-100 e.u ()-100e.u.
86. 1Lof 1M NaOH solution when neutralised by HCI, 86. 1M NaOH dk1yhdkiu ldj.kk£ I sdjusij xj
x-kj of heat are liberated. Same volume of 1 M
NaOH when neutralised by H, so y-kj of heat are
Ä'ekfud yrhg3 lelu vkru 1MNeldkit Jelj.k
liberated. Then H,So,I sdjkusij yj yr hgsc %
(A) x= 2y (A) x = 2y

(B) X = y/2 (B)x = y/2

)y=3x (C)y 3x
)x= y (D) x = y

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 KACA NEET 2021 13-Jan-2021
87.
Standard entropy of X Y, and XY, are 60, 40 and
50 J K" mo respectively. For the reaction
87. x,Y,vY, dhekd thd kelu Ce RAo, 40 vS
50JK mo g%
X+ XY,, AH=-30 kJ to be at
xYxYs, AH=-30 kJ rlae; hvHgds
equilibrium the temperature will be:
fy: S lalAkij rk dhx. kkdj%
(A) 1250 K
(A) 1250 K

(B) 500 K
500 K

(C) 750 K 750 K

D) 1000 K. D) 1000 K.

Which of 88. fues sd6l helkar Ukxkg%

88. following is
intensive property:
(A) rkela
(A) temperature
(B);k
(B) viscosity

(C) surface tension C)iBrubo

(D) all of these. D) n i j IM

89. The enthalpy of formation of ammonia at 298 Kis 89. 298 K rk ij velkr;kdkl lou A'ekaH°=-
given as AH°=-46.11 kJ per mol of NH, (9).To which 46.11 ku if ely NH,(o) gAiiyík delh
of the following equation does this value apply:
I eldlj.kdsly, :glghgs%
N)ho)NH,( (A)10,(0)NH0)
B) N(g)+3H(g)> NH,9) (B) Ng)+3Hg)NH,9)
V

(C) N9)+3H,(9)- 2NH,g9 (C)N,(g)+3H,(9)- 2NH,(o)

N9)H19) NH,0 N0H0)NH,0

90. The spontaneous nature of a reaction is impossiDie 90. di8I HkZj vHo kd klar %zr Z i e gakvI &D
if:
g%
A) AH=+ve, AS = +ve (A) AH= +Ve, AS= +ve

(B) AH=-ve, AS =-ve (B) AH=-ve, AS=-ve

(C) AH=-ve, AS = +Ve

(C) AH=-ve, AS = +ve

(D) AH=+ve, AS =-ve

D) AH= +ve, AS=ve
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