The Instantaneous Rate of Reaction
The Instantaneous Rate of Reaction
aA + bB → cC + dD
3 Rate constant:
The constant which defines the
relationship between the molar
concentration of the reactants and the
rate of the chemical reaction is known as
the rate constant.
The rate constant is symbolized as k.
4 The Order of reaction refers to the
relationship between the rate of a chemical
reaction and the concentration of the species
taking part in it. In order to obtain the
reaction order, the rate expression (or the
rate equation) of the reaction in question
must be obtained.
5
Zero- 0
order
reaction.
(b) First- 1
order
reaction.
(c) Second- 2
order
reaction.
6 Molecularity of a reaction:
The molecularity of a reaction is defined
as the number of reacting molecules that
collide simultaneously to bring about a
chemical reaction.
In other words, the molecularity of an
elementary reaction is defined as the
number of reactant molecules taking part
in the reaction.
The Molecularity of a reaction is a
theoretical concept.
The Molecularity of a reaction can never
be zero.
7 Order of a reaction is the sum of the
coefficients of the reacting species involved
in the rate equation. Molecularity is the
number of reacting species involved in
simultaneous collisions in an elementary or
simplest reaction. Order is an experimentally
determined quantity