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Material Safety Data Sheet

Water MSDS

Section 1: Chemical Product and Company Identification

Product Name: Water Contact Information:

Catalog Codes: SLW1063 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7732-18-5 Houston, Texas 77396
RTECS: ZC0110000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Water
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Dihydrogen oxide 1-800-424-9300
Chemical Name: Water International CHEMTREC, call: 1-703-527-3887
Chemical Formula: H2O For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Water 7732-18-5 100

Toxicological Data on Ingredients: Not applicable.

Section 3: Hazards Identification

Potential Acute Health Effects:

Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes. Non-
hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs. Non-
corrosive to the eyes. Non-corrosive for lungs.
Potential Chronic Health Effects:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-irritating to the eyes.
Non-hazardous in case of ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs.
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.

Section 4: First Aid Measures

Eye Contact: Not applicable.

p. 1
Skin Contact: Not applicable.
Serious Skin Contact: Not available.
Inhalation: Not applicable.
Serious Inhalation: Not available.
Ingestion: Not Applicable
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances: Not Applicable
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Section 7: Handling and Storage

Precautions: No specific safety phrase has been found applicable for this product.
Storage: Not applicable.

Section 8: Exposure Controls/Personal Protection

Engineering Controls: Not Applicable

Personal Protection: Safety glasses. Lab coat.
Personal Protection in Case of a Large Spill: Not Applicable
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

p. 2
Odor: Odorless.
Taste: Not available.
Molecular Weight: 18.02 g/mole
Color: Colorless.
pH (1% soln/water): 7 [Neutral.]
Boiling Point: 100°C (212°F)
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 1 (Water = 1)
Vapor Pressure: 2.3 kPa (@ 20°C)
Vapor Density: 0.62 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not applicable
Solubility: Not Applicable

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Not available.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact.

Toxicity to Animals:
LD50: [Rat] - Route: oral; Dose: > 90 ml/kg LC50: Not available.
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Non-corrosive for skin. Non-irritant for skin. Non-sensitizer for skin. Non-permeator by skin. Non-hazardous in case of
ingestion. Non-hazardous in case of inhalation. Non-irritant for lungs. Non-sensitizer for lungs. Non-corrosive to the eyes. Non-
corrosive for lungs.
Special Remarks on Toxicity to Animals: Not available.

p. 3
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Water

Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations. Not applicable.
HMIS (U.S.A.):
Health Hazard: 0
Fire Hazard: 0
Reactivity: 0
Personal Protection: a
National Fire Protection Association (U.S.A.):
Health: 0
Flammability: 0
Reactivity: 0
Specific hazard:

p. 4
Protective Equipment:
Not applicable. Lab coat. Not applicable. Safety glasses.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/10/2005 08:33 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 5
 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 01.08.2015 Page 1 of 6
Distilled Water

SECTION 1 : Identification of the substance/mixture and of the supplier

Product name : Distilled Water
Manufacturer/Supplier Trade name:
Manufacturer/Supplier Article number: S25868
Recommended uses of the product and uses restrictions on use:
Manufacturer Details:
AquaPhoenix Scientific
9 Barnhart Drive, Hanover, PA 17331

Supplier Details:
Fisher Science Education
15 Jet View Drive, Rochester, NY 14624

Emergency telephone number:

Fisher Science Education Emergency Telephone No.: 800-535-5053

SECTION 2 : Hazards identification

Classification of the substance or mixture:

Not classified for physical or health hazards under GHS.

Hazard statements:
Precautionary statements:

Other Non-GHS Classification:

WHMIS
NFPA/HMIS

NFPA SCALE (0-4) HMIS RATINGS (0-4)

SECTION 3 : Composition/information on ingredients

Ingredients:

CAS 7732-18-5 Deionized Water 100 %

Percentages are by weight

Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com

 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 01.08.2015 Page 2 of 6
Distilled Water

SECTION 4 : First aid measures

Description of first aid measures
After inhalation: Move exposed individual to fresh air.
After skin contact: Wash affected area with soap and water.
After eye contact: Protect unexposed eye. Rinse/flush exposed eye(s) gently using water for 15-20 minutes.
Remove contact lens(es) if able to do so during rinsing. Seek medical attention if irritation persists or if
concerned.
After swallowing: Rinse mouth thoroughly. Do not induce vomiting. Have exposed individual drink sips of
water. Seek medical attention if irritation, discomfort or vomiting persists.

Most important symptoms and effects, both acute and delayed:

Irritation, Nausea,Headache, Shortness of breath.;
Indication of any immediate medical attention and special treatment needed:
If seeking medical attention, provide SDS document to physician.

SECTION 5 : Firefighting measures

Extinguishing media
Suitable extinguishing agents: If in laboratory setting, follow laboratory fire suppression procedures.
For safety reasons unsuitable extinguishing agents:
Special hazards arising from the substance or mixture:
Advice for firefighters:
Protective equipment:
Additional information (precautions): Move product containers away from fire or keep cool with water
spray as a protective measure, where feasible.

SECTION 6 : Accidental release measures

Personal precautions, protective equipment and emergency procedures:
Stop the spill, if possible. Contain spilled material by diking or using inert absorbent.
Environmental precautions:
Prevent from reaching drains, sewer or waterway. Collect contaminated soil for characterization per Section 13
Methods and material for containment and cleaning up:
If in a laboratory setting, follow Chemical Hygiene Plan procedures.Collect liquids using vacuum or by use of
absorbents. Place into properly labeled containers for recovery or disposal. If necessary, use trained response
staff/contractor.
Reference to other sections:

SECTION 7 : Handling and storage

Precautions for safe handling:
Follow good hygiene procedures when handling chemical materials. Avoid splashes or spray in enclosed areas.
Conditions for safe storage, including any incompatibilities:
Store in cool, dry conditions in well sealed containers.

SECTION 8 : Exposure controls/personal protection

Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com

 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 01.08.2015 Page 3 of 6
Distilled Water

Control Parameters: No applicable occupational exposure limits

Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in
the immediate vicinity of use/handling.
Respiratory protection: Not required under normal conditions of use. Use suitable respiratory
protective device when aerosol or mist is formed.
Protection of skin: The glove material has to be impermeable and resistant to the product/
the substance/ the preparation being used/handled.Selection of the glove
material on consideration of the penetration times, rates of diffusion and
the degradation.
Eye protection: Safety glasses with side shields or goggles.
General hygienic measures: The usual precautionary measures are to be adhered to when handling
chemicals. Keep away from food, beverages and feed sources. Wash
hands before breaks and at the end of work. Do not inhale
gases/fumes/dust/mist/vapor/aerosols. Avoid contact with the eyes and
skin.

SECTION 9 : Physical and chemical properties

Appearance (physical Explosion limit lower: Not Determined

Clear, colorless liquid.
state,color): Explosion limit upper: Not Determined

Odor: Odorless Vapor pressure: 17.5 mmHg @20C

Odor threshold: Not Determined Vapor density: Not Determined

pH-value: Not Determined Relative density: 1.000

Melting/Freezing point: 0C Solubilities:

Boiling point/Boiling Partition coefficient (n-

100C Not Determined
range: octanol/water):

Flash point (closed Auto/Self-ignition

Not Determined Not Determined
cup): temperature:

Decomposition
Evaporation rate: Not Determined Not Determined
temperature:

Flammability a. Kinematic:Not Determined

Not Determined Viscosity:
(solid,gaseous): b. Dynamic: Not Determined

Density: Not Determined

SECTION 10 : Stability and reactivity

Reactivity:
Chemical stability:No decomposition if used and stored according to specifications.
Possible hazardous reactions:
Conditions to avoid:Store away from oxidizing agents, strong acids or bases.
Incompatible materials:Strong acids.Strong bases.

Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com

 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 01.08.2015 Page 4 of 6
Distilled Water

Hazardous decomposition products:Carbon oxides (CO, CO2).

SECTION 11 : Toxicological information

Acute Toxicity: No additional information.

Chronic Toxicity: No additional information.

Corrosion Irritation: No additional information.

Sensitization: No additional information.

Single Target Organ (STOT): No additional information.

Numerical Measures: No additional information.

Carcinogenicity: No additional information.

Mutagenicity: No additional information.

Reproductive Toxicity: No additional information.

SECTION 12 : Ecological information

Ecotoxicity Persistence and degradability: Readily degradable in the environment.

Bioaccumulative potential:
Mobility in soil: Aqueous solution has high mobility in soil.
Other adverse effects:

SECTION 13 : Disposal considerations

Waste disposal recommendations:

Product/containers must not be disposed together with household garbage. Do not allow product to reach
sewage system or open water.It is the responsibility of the waste generator to properly characterize all waste
materials according to applicable regulatory entities (US 40CFR262.11). Consult federal state/ provincial and
local regulations regarding the proper disposal of waste material that may incorporate some amount of this
product.

SECTION 14 : Transport information

UN-Number
Not Dangerous Goods
UN proper shipping name
Not Dangerous Goods
Transport hazard class(es)
Packing group:Not Dangerous Goods
Environmental hazard:
Transport in bulk:
Special precautions for user:

SECTION 15 : Regulatory information

United States (USA)

Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com

 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 01.08.2015 Page 5 of 6
Distilled Water

SARA Section 311/312 (Specific toxic chemical listings):

None of the ingredients is listed
SARA Section 313 (Specific toxic chemical listings):
None of the ingredients is listed
RCRA (hazardous waste code):
None of the ingredients is listed
TSCA (Toxic Substances Control Act):
All ingredients are listed.
CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act):
None of the ingredients is listed

Proposition 65 (California):

Chemicals known to cause cancer:

None of the ingredients is listed
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed
Chemicals known to cause developmental toxicity:
None of the ingredients is listed

Canada

Canadian Domestic Substances List (DSL):

All ingredients are listed.
Canadian NPRI Ingredient Disclosure list (limit 0.1%):
None of the ingredients is listed
Canadian NPRI Ingredient Disclosure list (limit 1%):
None of the ingredients is listed

SECTION 16 : Other information

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the
SDS contains all the information required by the Controlled Products Regulations.Note:. The responsibility to
provide a safe workplace remains with the user.The user should consider the health hazards and safety information
contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment.The information contained herein is,
to the best of our knowledge and belief, accurate.However, since the conditions of handling and use are beyond
our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this
material.It is the responsibility of the user to comply with all applicable laws and regulations applicable to this
material.
GHS Full Text Phrases:

Abbreviations and acronyms:

IMDG: International Maritime Code for Dangerous Goods
PNEC: Predicted No-Effect Concentration (REACH)
CFR: Code of Federal Regulations (USA)

Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com

 Safety Data Sheet
according to 29CFR1910/1200 and GHS Rev. 3
Effective date : 01.08.2015 Page 6 of 6
Distilled Water

SARA: Superfund Amendments and Reauthorization Act (USA)

RCRA: Resource Conservation and Recovery Act (USA)
TSCA: Toxic Substances Control Act (USA)
NPRI: National Pollutant Release Inventory (Canada)
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)

Effective date : 01.08.2015

Last updated : 03.23.2015

Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com

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Material Safety Data Sheet

Acetic acid MSDS

Section 1: Chemical Product and Company Identification

Product Name: Acetic acid Contact Information:

Catalog Codes: SLA3784, SLA1438, SLA2101, SLA3604, Sciencelab.com, Inc.
SLA1258 14025 Smith Rd.
Houston, Texas 77396
CAS#: 64-19-7
US Sales: 1-800-901-7247
RTECS: AF1225000 International Sales: 1-281-441-4400

TSCA: TSCA 8(b) inventory: Acetic acid Order Online: ScienceLab.com

CI#: Not applicable. CHEMTREC (24HR Emergency Telephone), call:

1-800-424-9300
Synonym: Acetic acid; glacial acetic acid
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Acetic Acid, Glacial
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: C2-H4-O2

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Acetic acid 64-19-7 100

Toxicological Data on Ingredients: Acetic acid: ORAL (LD50): Acute: 3310 mg/kg [Rat]. 4960 mg/kg [Mouse]. 3530 mg/kg
[Rat]. DERMAL (LD50): Acute: 1060 mg/kg [Rabbit]. VAPOR (LC50): Acute: 5620 ppm 1 hours [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skin
contact (corrosive, permeator), of eye contact (corrosive). Liquid or spray mist may produce tissue damage particularly on
mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may
produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of the
eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,
occasionally, blistering.
Potential Chronic Health Effects:
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. TERATOGENIC
EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, mucous
membranes, skin, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated

p. 1
or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged
exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 463°C (865.4°F)
Flash Points: CLOSED CUP: 39°C (102.2°F). OPEN CUP: 43°C (109.4°F).
Flammable Limits: LOWER: 4% UPPER: 19.9%
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizing
materials, of metals.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available. Slightly explosive in presence of oxidizing materials.
Fire Fighting Media and Instructions:
Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,
water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards:
Reacts with metals to produces flammable hydrogen gas. It will ignite on contact with potassium-tert-butoxide. A mixture of
ammonium nitrate and acetic acid ignites when warmed, especially if warmed.
Special Remarks on Explosion Hazards:

p. 2
Acetic acid vapors may form explosive mixtures with air. Reactions between acetic acid and the following materials
are potentially explosive: 5-azidotetrazole, bromine pentafluoride, chromium trioxide, hydrogen peroxide, potassium
permanganate, sodium peroxide, and phorphorus trichloride. Dilute acetic acid and dilute hydrogen can undergo an
exothermic reaction if heated, forming peracetic acid which is explosive at 110 degrees C. Reaction between chlorine
trifluoride and acetic acid is very violent, sometimes explosive.

Section 6: Accidental Release Measures

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If
necessary: Neutralize the residue with a dilute solution of sodium carbonate.
Large Spill:
Flammable liquid. Corrosive liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. If the
product is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product is in
its liquid form: Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Absorb
with an inert material and put the spilled material in an appropriate waste disposal. Do not touch spilled material. Use water
spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance
on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
\Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not
breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and
eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and
sealed until ready for use. Avoid all possible sources of ignition (spark or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Synthetic apron. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves
(impervious).
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 10 STEL: 15 (ppm) [Australia] TWA: 25 STEL: 27 (mg/m3) [Australia] TWA: 10 STEL: 15 (ppm) from NIOSH TWA: 25
STEL: 37 (mg/m3) from NIOSH TWA: 10 STEL: 15 (ppm) [Canada] TWA: 26 STEL: 39 (mg/m3) [Canada] TWA: 25 STEL: 37
(mg/m3) TWA: 10 STEL: 15 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 10 (ppm) from OSHA (PEL) [United States]
TWA: 25 (mg/m3) from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

p. 3
Physical state and appearance: Liquid.
Odor: Pungent, vinegar-like, sour (Strong.)
Taste: Vinegar, sour (Strong.)
Molecular Weight: 60.05 g/mole
Color: Colorless. Clear (Light.)
pH (1% soln/water): 2 [Acidic.]
Boiling Point: 118.1°C (244.6°F)
Melting Point: 16.6°C (61.9°F)
Critical Temperature: 321.67°C (611°F)
Specific Gravity: 1.049 (Water = 1)
Vapor Pressure: 1.5 kPa (@ 20°C)
Vapor Density: 2.07 (Air = 1)
Volatility: Not available.
Odor Threshold: 0.48 ppm
Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -0.2
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether, acetone.
Solubility:
Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone. Miscible with Glycerol, alcohol, Benzene, Carbon
Tetrachloride. Practically insoluble in Carbon Disulfide.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources, incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, metals, acids, alkalis.
Corrosivity:
Highly corrosive in presence of stainless steel(304). Slightly corrosive in presence of aluminum, of copper. Non-corrosive in
presence of stainless steel(316).
Special Remarks on Reactivity:
Reacts violently with strong oxidizing agents, acetaldehyde, and acetic anhydride. Material can react with metals, strong
bases, amines, carbonates, hydroxides, phosphates, many oxides,cyanides, sulfides, chromic acid, nitric acid, hydrogen
peroxide, carbonates. ammonium nitrate, ammonium thiosulfate, chlorine trifluoride, chlorosulfonic acid, perchloric acid,
permanganates, xylene, oleum, potassium hydroxide, sodium hydroxide, phosphorus isocyanate, ethylenediamine, ethylene
imine.
Special Remarks on Corrosivity: Moderate corrosive effect on bronze. No corrosion data on brass
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

p. 4
Toxicity to Animals:
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral
toxicity (LD50): 3310 mg/kg [Rat]. Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 5620
1 hours [Mouse].
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage to
the following organs: kidneys, mucous membranes, skin, teeth.
Other Toxic Effects on Humans:
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (irritant), of ingestion, .
Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May affect genetic material and may cause reproductive effects based on
animal data. No human data found.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Extremely irritating and corrosive. Causes skin irritation (reddening and itching,
inflammation). May cause blistering , tissue damage and burns. Eyes: Extremely irritating and corrosive. Causes eye irritation,
lacrimation, redness, and pain. May cause burns, blurred vision, conjunctivitis, conjunctival and corneal destruction and
permanent injury. Inhalation: Causes severe respiratory tract irritation. Affects the sense organs (nose, ear, eye, taste),
and blood. May cause chemical pneumonitis, bronchitis, and pulmonary edema. Severe exposure may result in lung tissue
damage and corrosion (ulceration) of the mucous membranes. Inhalation may also cause rhinitis, sneezing, coughing,
oppressive feeling in the chest or chest pain, dyspnea, wheezing, tachypnea, cyanosis, salivation, nausea, giddiness,
muscular weakness. Ingestion: Moderately toxic. Corrosive. Causes gastrointestinal tract irritation (burning and pain of the
mouth, throat, and abdomen, coughing, ulceration, bleeding, nausea, abdomial spasms, vomiting, hematemesis, diarrhea.
May Also affect the liver (impaired liver function), behavior (convulsions, giddines, muscular weakness), and the urinary
system - kidneys (Hematuria, Albuminuria, Nephrosis, acute renal failure, acute tubular necrosis). May also cause dyspnea
or asphyxia. May also lead to shock, coma and death. Chronic Potential Health Effects: Chronic exposure via ingestion may
cause blackening or erosion of the teeth and jaw necrosis, pharyngitis, and gastritis. It may also behavior (similar to acute
ingestion), and metabolism (weight loss). Chronic exposure via inhalation may cause asthma and/or bronchitis with cough,
phlegm, and/or shortness of breath . It may also affect the blood (decreased leukocyte count), and urinary system (kidneys).
Repeated or prolonged skin contact may cause thickening, blackening, and cracking of the skin.

Section 12: Ecological Information

Ecotoxicity:
Ecotoxicity in water (LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours
[Fish (bluegill sunfish)]. >100 ppm 96 hours [Daphnia].
BOD5 and COD: BOD-5: 0.34-0.88 g oxygen/g
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification:

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CLASS 3: Flammable liquid. Class 8: Corrosive material
Identification: : Acetic Acid, Glacial UNNA: 2789 PG: II
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

New York release reporting list: Acetic acid Rhode Island RTK hazardous substances: Acetic acid Pennsylvania RTK: Acetic
acid Florida: Acetic acid Minnesota: Acetic acid Massachusetts RTK: Acetic acid New Jersey: Acetic acid California Director's
List of Hazardous Subtances (8 CCR 339): Acetic acid TSCA 8(b) inventory: Acetic acid CERCLA: Hazardous substances.:
Acetic acid: 5000 lbs. (2268 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada):
CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS E: Corrosive liquid.
DSCL (EEC):
R10- Flammable. R35- Causes severe burns. S23- Do not breathe gas/fumes/vapour/spray [***] S26- In case of contact with
eyes, rinse immediately with plenty of water and seek medical advice. S45- In case of accident or if you feel unwell, seek
medical advice immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 2
Reactivity: 0
Personal Protection: H
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 2
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves (impervious). Synthetic apron. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/09/2005 03:35 PM
Last Updated: 11/01/2010 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

p. 6
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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Material Safety Data Sheet

Oxalic acid dihydrate MSDS
Section 1: Chemical Product and Company Identification

Product Name: Oxalic acid dihydrate Contact Information:

Catalog Codes: SLO1429, SLO1054 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 6153-56-6 Houston, Texas 77396
RTECS: Not available. US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: No products were found. It is
a hydrate and exempt from TSCA inventory requirements. Order Online: ScienceLab.com

CI#: Not applicable. CHEMTREC (24HR Emergency Telephone), call:

1-800-424-9300
Synonym: Ethanedioic Acid, dihydrate
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Oxalic Acid, dihydrate
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: (COOH)2.2H2O

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Oxalic acid dihydrate 6153-56-6 100

Toxicological Data on Ingredients: Oxalic acid dihydrate LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skin
contact (permeator), of eye contact (corrosive). Slightly hazardous in case of skin contact (corrosive). The amount of tissue
damage depends on length of contact. Eye contact can result in corneal damage or blindness. Skin contact can produce
inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by
burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death.
Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching,
scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not
available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, the nervous system, mucous
membranes, heart, brain, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs damage.
Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local
skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.

p. 1
 Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Slightly explosive in presence of open flames and sparks. Non-explosive in presence of shocks.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: As with most organic solids, fire is possible at elevated temperatures
Special Remarks on Explosion Hazards:
Fine dust dispersed in air in sufficient concentrations, and in the presences of an ignition source is a potential dust explosion
hazard.

Section 6: Accidental Release Measures

Small Spill:

p. 2
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of sodium carbonate.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for
assistance on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not
present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate
the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Never add
water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as
oxidizing agents, metals, alkalis.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits:
TWA: 1 STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 1 STEL: 2 (mg/m3) from OSHA (PEL) [United States] TWA:
1 STEL: 2 (mg/m3) from NIOSH [United States] TWA: 1 STEL: 2 (mg/m3) [United Kingdom (UK)] TWA: 1 STEL: 2 (mg/m3)
[Canada]Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystalline solid )

Odor: Odorless.
Taste: Not available.
Molecular Weight: 126.07 g/mole
Color: Colorless. White.
pH (1% soln/water): Not available
Boiling Point: Not available.
Melting Point: 101.5°C (214.7°F)
Critical Temperature: Not available.

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Specific Gravity: Density: 1.653 @ 18.5 eg. C(Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: 4.4 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether.
Solubility:
Soluble in cold water, diethyl ether. Soluble in alcohol, glycerol. Insoluble in benzene, petroleum ether. Solubility in cold water:
1g/7ml. Solubility in hot water: 1g/2ml

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Excess heat, incompatible materials, dust generation.
Incompatibility with various substances: Reactive with oxidizing agents, metals, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Incompatible with chlorites, hypochlorites, silver and silver compounds, furfuryl alcohol. Hygroscopic; keep container tightly
closed.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Inhalation. Ingestion.

Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans:
May cause damage to the following organs: kidneys, the nervous system, mucous membranes, heart, brain, skin, eyes.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (permeator), of
eye contact (corrosive). Slightly hazardous in case of skin contact (corrosive).
Special Remarks on Toxicity to Animals:
LD50 data for Oxalic acid, ahydrous (CAS no. 144-62-7): LD50[rat] - Route: oral; Dose: 7500 mg/kg
Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects based on animal test data. No
human data found.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes skin irritation. Rare chemical burns may occur. Harmful if absorbed through the
skin. Eyes: Causes severe eye irritation with possible burns. It may result in corneal damage and conjunctivitis. Inhalation:
Causes irritation of the respiratory tract, ulceration of the mucous membranes. Inhalation of oxalic acid may also cause
digestive disturbances such as nausea and vomiting as well as affecting the nerves and urinary system and causing

p. 4
headache, muscular irrritability, weakness, and albuminuira Ingestion: Harmful if swallowed. Causes severe digestive tract
irritation and possible burns. It may affect the cardiovascular system, and urinary system. Symptoms may include vomiting
(often bloody or with coffee-ground appearance), diarrhea, bloody stool, hypermotility, abdominal pain, intense burning pain
in the throat, esophagus, stomach, ulceration/burning of the mouth, esophagus, and stomach, severe purging, weak pulse,
hypotension, caridac irregularities, cardiovascular collapse. Other symptoms may include convulsions, headache, twitching,
tetany, stupor, coma, tingling of fingers and toes, muscular irritability. Renal damage, as evidenced by oliguria, albuminuria,
hematuria, may occur because Oxalic acid can bind calcium to form calcium oxalate which is insoluble at physiological pH.
The calcium oxalate formed might precipitate in the kidney tubules. Hypocalcemia may also occur, which is what may affect
the function of the heart and nerves and cause the above cardiovasular and nervous system effects. Chronic Potential Health
Effects: Skin: Prolonged or repeated exposure may cause localized pain and cyanosis of the fingers, and even

Section 12: Ecological Information

Ecotoxicity:
Ecotoxicity in water (LC50): 4000 mg/l 24 hours [Fish (Bluegill)]. 1000 ppm 0.5 hours [Fish (Goldfish)]. 100 ppm 0.3 hours
[Fish (Trout)].
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Corrosive Solid, Acidic, Organic, n.o.s. (Oxalic Acid, Dihydrate) UNNA: 3261 PG: III
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations: Pennsylvania RTK: Oxalic acid dihydrate

Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Oxalic Acid, anhydrous (CAS no.
144-62-7) is listed on the Canadian DSL Oxalic Acid, dihydrate (CAS 6153-56-6) is not listed on the Canadian DSL. EINECS
no. for Oxalic Acid, anhydrous: 205-634-3 EINECS no. for Oxalic Acid, dihydrate: unlisted Oxalic Acid, dihydrate is on the
inventory lists for China, Japan, and Philippines.
Other Classifications:
WHMIS (Canada): CLASS E: Corrosive solid.
DSCL (EEC):
R21/22- Harmful in contact with skin and if swallowed. S24/25- Avoid contact with skin and eyes.
HMIS (U.S.A.):

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 Health Hazard: 3
Fire Hazard: 1
Reactivity: 0
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/10/2005 08:44 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 6
 Diethyl ether MSDS
Communication
Yeshiva Gedolah Imrei Yosef D'spinka
6 pag.

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Material Safety Data Sheet

Diethyl ether MSDS
Section 1: Chemical Product and Company Identification

Product Name: Diethyl ether Contact Information:

Catalog Codes: 10580,20581,30580,70580 Finar Limited
184-186/P, Chacharwadi Vasna,
CAS#: 60-29-7 Sarkhej-Bavla Highway,
Ta.: Sanand, Dist.: Ahmedabad,
RTECS: KI5775000
Email: info@finarchemicals.com
TSCA: TSCA 8(b) inventory: Ethyl ether Web: www.finarchemicals.com
CI#: Not available.
Synonym: Diethyl Ether; Ether
Chemical Name: Ethyl Ether
Chemical Formula: C4H10O

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Diethyl ether 60-29-7 100

Toxicological Data on Ingredients: Diethyl ether: ORAL (LD50): Acute: 1215 mg/kg [Rat]. VAPOR (LC50): Acute: 73000 ppm
2 hours [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:

Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of
skin contact (permeator).
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for
bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance
may be toxic to skin, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target
organs damage.

Section 4: First Aid Measures

Eye Contact:

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Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention if symptoms appear.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 180°C (356°F)
Flash Points: CLOSED CUP: -45°C (-49°F).
Flammable Limits: LOWER: 1.9% UPPER: 36%
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Extremely flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizing
materials, of acids.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Highly explosive in presence of open flames
and sparks, of heat. Slightly explosive in presence of oxidizing materials.
Fire Fighting Media and Instructions:
Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,
water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards:
Highly flammable. Will be easily ignited by heat, sparks, and flames. Vapors may travel to source of ignition and flash back.
Most vapors are heavier than air. Burns with smokey greenish flame. Violent reaction or ignition on contact with halogens
(e.g., bromine, chlorine), interhalogens (e.g., iodine heptafluoride), oxidants (e.g., silver perchlorate, nitrosyl perchlorate, nitryl
perchlorate, chromyl chloride, fluorine nitrate, permanganic acid, nitric acid, hydrogen peroxide, peroxodisulfuric acid, iodine
(VII) oxide, sodium peroxide, ozone, and liquid air), sulfur and sulfur compounds (e.g., sulfur when dried with peroxidized
ether, sulfuryl chloride).
Special Remarks on Explosion Hazards:
Vapors may form explosive mixtures with air. Vapor explosion hazard indoors, outdoors, or in sewers. Run off to sewer may
create a fire or explosion hazard. Containers may explode when heated. Tends to form explosive peroxides under influence
of light and air and evaporated to dryness. Explosive reaction with boron triazide, bromine trifluoride, bromine pentafluoride,

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perchloric acid, uranyl nitrate + light, wood pulp extracts + heat. Only electrical equipment of explosion proof type (group C
classification) is permitted to be operated in ether areas. May explode when brought in contact with anhydrous nitric acid.

Section 6: Accidental Release Measures

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:
Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined
areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS
and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not
breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and
eyes. Keep away from incompatibles such as oxidizing agents, acids, moisture.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and
sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Do not store above 30°C (86°F). Hygroscopic;
keep container tightly closed. Air Sensitive Sensitive to light.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 400 (ppm) from OSHA (PEL) [United States] TWA: 400 STEL: 500 CEIL: 500 (ppm) from ACGIH (TLV) [United States]
TWA: 1200 STEL: 1520 CEIL: 1500 (mg/m3) from ACGIH (TLV) [United States] STEL: 500 (ppm) [Australia] TWA: 1200 (mg/
m3) from OSHA (PEL) [United States] Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid. (volatile, mobile liquid )

Odor: Sweetish. Pungent. Ethereal.
Taste: Burning. Sweet.
Molecular Weight: 74.12g/mole
Color: Clear Colorless.

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pH (1% soln/water): Not available.
Boiling Point: 34.6°C (94.3°F)
Melting Point: -116.3°C (-177.3°F)
Critical Temperature: 192.7°C (378.9°F)
Specific Gravity: 0.7134 (Water = 1)
Vapor Pressure: 58.6 kPa (@ 20°C)
Vapor Density: 2.56 (Air = 1)
Volatility: Not available.
Odor Threshold: 0.83 ppm
Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 0.9
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, acetone.
Solubility:
Soluble in acetone. Partially soluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources, incompatible materials, light, air.
Incompatibility with various substances: Highly reactive with oxidizing agents, acids.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Air and light sensitive. Hygroscopic. Also incompatiable with bromoazide, chlorine, chlorine trifluoride, chromic anhydride,
chromyl chloride, lithium aluminum hydride, nitrosyl perchlorate, nitryl perchlorate, ozone, perchloric acid, permanganated,
sulfuric acid, potassium peroxide, sodium peroxide, triethyl aluminum trimethyl aluminum, bromine, iodine heptaflluoride,
silver perchlorate, fluorine nitrate, permanganic acid, nitric acid, hydrogen peroxide, peroxodisulfuric acid, iodine (VII)
oxide, peat soils, thiotriazyl perchlorate, sulfonyl chloride, sulfur, uranyl nitrate, acetyl peroxide, and wood pulp extracts.
Can react vigorously with acetyl peroxide, air, bromoazide, ClF3, CrO3, Cr(OCl)2, LiAlH2, NOClO4, O2, NClO2, (H2SO4 +
permanganates), K2O2, [(C2H5)3Al + air], [(CH3)3Al + air].
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Inhalation.

Toxicity to Animals:
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral
toxicity (LD50): 1215 mg/kg [Rat]. Acute toxicity of the vapor (LC50): 31000 0.5 hours [Mouse].
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage to
the following organs: skin, central nervous system (CNS).
Other Toxic Effects on Humans:

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Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals:
LD50 [Rabbit] -Route: Skin; Dose: >20 ml/kg LDL[Man] - Route: Oral; Dose: 260 mg/kg
Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic) based on animal data.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes skin irritation. It is not appreciably absorbed through intact skin. Eyes: Causes
eye irritation. Can cause slight , reversible eye injury from contact with liquid or vapor. Inhalation: It is rapidly absorbed through
lungs. Vapor mist causes irritation of the respiratory tract and mucous membranes. Affects behavior, sense organs, peripheral
and central nervous systems, liver and metabolism, cardiovascular system. Symptoms may include excitement, drowsiness,
headache, nausea, vomiting, paleness, decreased pulse and temperature, irregular respiration, coughing, bronchodilation,
increase in respiratory rate, increase in heart rate, excessive salivation, muscle relaxation, anesthetic effects, and possible
kidney irritation or injury, and temporarily abnormal liver function tests. Ingestion: May be harmful if swallowed. May cause
gastrointestinal tract irritation with nausea, vomiting

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation:
WHEN RELEASED INTO THE SOIL, THIS MATERIAL IS EXPECTED TO QUICKLY EVAPORAT WHEN RELEASED INTO
THE SOIL, THIS MATERIAL IS EXPECTED TO LEACH INTO GROUNDWATER. WHEN RELEASED INTO THE SOIL,
THIS MATERIAL IS NOT EXPECTED TO BIODEGRADE. WHEN RELEASED INTO WATER, THIS MATERIAL IS NOT
EXPECTED TO BIODEGRADE. WHEN RELEASED INTO THE WATER, THIS MATERIAL IS EXPECTED TO HAV HALF-
LIFE OF LESS THAN 1 DAY. WHEN RELEASED TO WATER, THIS MATERIAL IS EXP TO QUICKLY EVAPORATE. THIS
MATERIAL IS NOT EXPECTED TO SIGNIFICANTLY BIOACCUMULATE. THIS MATERIAL HAS A LOG OCTANOL-WATER
PARTITION COEFFICIENT LESS THAN 3.0. WHEN RELEASED INTO THE AIR, THIS MATERIAL IS EXPECTED TO BE
READILY DEGRADED BY REACTION WITH PHOTOCHEMICALLY PRODUCED HYDROXYL RADICA WHEN RELEASED
INTO THE AIR, THIS MATERIAL IS NOT EXPECTED TO BE DEGRADED B PHOTOLYSIS. WHEN RELEASED INTO THE
AIR, THIS MATERIAL IS EXPECTED TO HAVE HALF-LIFE BETWEEN 1 AND 10 DAYS.

Section 13: Disposal Considerations

Waste Disposal:
Consult with Local and Regional (State) authorities (waste regulators). Waste must be disposed of in accordance with federal,
state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 3: Flammable liquid.

Identification: : Diethyl ether UNNA: 1155 PG: I
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

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Connecticut hazardous material survey.: Ethyl ether Illinois toxic substances disclosure to employee act: Ethyl ether Illinois
chemical safety act: Ethyl ether New York release reporting list: Ethyl ether Rhode Island RTK hazardous substances:
Ethyl ether Pennsylvania RTK: Ethyl ether Florida: Ethyl ether Minnesota: Ethyl ether Massachusetts RTK: Ethyl ether
Massachusetts spill list: Ethyl ether New Jersey: Ethyl ether New Jersey toxic catastrophe prevention act: Ethyl ether
Louisiana spill reporting: Ethyl ether California Director's List of Hazardous Substances: Ethyl ether TSCA 8(b) inventory: Ethyl
ether TSCA 4(a) proposed test rules: Ethyl ether TSCA 8(a) PAIR: Ethyl ether
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F).
DSCL (EEC):
R12- Extremely flammable. R19- May form explosive peroxides. R22- Harmful if swallowed. S9- Keep container in a
well-ventilated place. S16- Keep away from sources of ignition - No smoking. S29- Do not empty into drains. S33- Take
precautionary measures against static discharges.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 4
Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 4
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/06/2010
Last Updated: 26/11/2012

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall Finar Limited be liable for any claims, losses, or damages of any third
party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if
Finar Limited has been advised of the possibility of such damages.

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Material Safety Data Sheet

Sodium hydroxide, Pellets, Reagent ACS MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sodium hydroxide, Pellets, Reagent ACS Contact Information:

Catalog Codes: SLS4090 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 1310-73-2 Houston, Texas 77396
RTECS: WB4900000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Sodium hydroxide
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Caustic Soda 1-800-424-9300
Chemical Name: Sodium Hydroxide International CHEMTREC, call: 1-703-527-3887
Chemical Formula: NaOH For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Sodium hydroxide 1310-73-2 100

Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,
of inhalation. The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage or
blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or
respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking,
unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs. Repeated or prolonged exposure to the
substance can produce target organs damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation.
Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying
degree of respiratory irritation or lung damage.

p. 1
 Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek immediate medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: of metals
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available. Slightly explosive in presence of heat.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
sodium hydroxide + zinc metal dust causes ignition of the latter. Under proper conditions of temperature, pressure and state
of division, it can ignite or react violently with acetaldehyde, ally alcohol, allyl chloride, benzene-1,4-diol, chlorine trifluoride,
1,2 dichlorethylene, nitroethane, nitromethane, nitroparaffins, nitropropane, cinnamaldehyde, 2,2-dichloro-3,3-dimethylbutane.
Sodium hydroxide in contact with water may generate enough heat to ignite adjacent combustible materials. Phosphorous
boiled with NaOH yields mixed phosphines which may ignite spontanously in air. sodium hydroxide and cinnamaldehyde +
heat may cause ignition. Reaction with certain metals releases flammable and explosive hydrogen gas.
Special Remarks on Explosion Hazards:
Sodium hydroxide reacts to form explosive products with ammonia + silver nitrate. Benzene extract of allyl benzenesulfonate
prepared from allyl alcohol, and benzene sulfonyl chloride in presence of aquesous sodium hydroxide, under vacuum
distillation, residue darkened and exploded. Sodium Hydroxde + impure tetrahydrofuran, which can contain peroxides, can

p. 2
cause serious explosions. Dry mixtures of sodium hydroxide and sodium tetrahydroborate liberate hydrogen explosively at
230-270 deg. C. Sodium Hydroxide reacts with sodium salt of trichlorophenol + methyl alcohol + trichlorobenzene + heat to
cause an explosion.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with
a dilute solution of acetic acid.
Large Spill:
Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep container dry. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable
respiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin
and eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis, moisture.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23°C (73.4°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Exposure Limits:
CEIL: 2 from ACGIH (TLV) [United States] [1995] Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.

Odor: Odorless.
Taste: Not available.
Molecular Weight: 40 g/mole
Color: White.
pH (1% soln/water): 13.5 [Basic.]

p. 3
Boiling Point: 1388°C (2530.4°F)
Melting Point: 323°C (613.4°F)
Critical Temperature: Not available.
Specific Gravity: 2.13 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Easily soluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances:
Highly reactive with metals. Reactive with oxidizing agents, reducing agents, acids, alkalis, moisture.
Corrosivity: Not available.
Special Remarks on Reactivity:
Hygroscopic. Much heat is evolved when solid material is dissolved in water. Therefore cold water and caution must be
used for this process. Sodium hydroxide solution and octanol + diborane during a work-up of a reaction mixture of oxime
and diborane in tetrahyrofuran is very exothermic, a mild explosion being noted on one occassion. Reactive with water,
acids, acid chlorides, strong bases, strong oxidizing agents, strong reducing agents, flammable liquids, organic halogens,
metals (i.e aluminum, tin, zinc), nitromethane, glacial acetic acid, acetic anhydride, acrolein, chlorohydrin, chlorosulfonic acid,
ethylene cyanohydrin, glyoxal, hydrochloric acid, sulfuric acid, hydrosulfuric acid, nitric acid, oleum, propiolactone, acylonitrile,
phorosous pentoxide, chloroethanol, chloroform-methanol, tetrahydroborate, cyanogen azide, 1,2,4,5 tetrachlorobenzene,
cinnamaldehyde. Reacts with formaldehyde hydroxide to yield formic acid, and hydrogen.
Special Remarks on Corrosivity: Very caustic to aluminum and other metals in presence of moisture.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans: Causes damage to the following organs: lungs.
Other Toxic Effects on Humans:
Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant,
permeator), of eye contact (corrosive), of ingestion, .
Special Remarks on Toxicity to Animals:

p. 4
Lowest Published Lethal Dose: LDL [Rabbit] - Route: Oral; Dose: 500 mg/kg
Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic). Investigation as a mutagen
(cytogenetic analysis), but no data available.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May be harmful if absorbed through skin. Causes severe skin irritation and burns. May
cause deep penetrating ulcers of the skin. Eyes: Causes severe eye irritation and burns. May cause chemical conjunctivitis
and corneal damage. Inhalation: Harmful if inhaled. Causes severe irritation of the respiratory tract and mucous membranes
with coughing, burns, breathing difficulty, and possible coma. Irritation may lead the chemical pneumonitis and pulmonary
edema. Causes chemical burns to the respiratory tract and mucous membranes. Ingestion: May be fatal if swallowed. May
cause severe and permanent damage to the digestive tract. Causes severe gastrointestinal tract irritation and burns. May
cause perforation of the digestive tract. Causes severe pain, nausea, vomiting, diarrhea, and shock. May cause corrosion and
permanent destruction of the esophagus and digestive tract.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Sodium hydroxide, solid UNNA: 1823 PG: II
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act: Sodium hydroxide New
York release reporting list: Sodium hydroxide Rhode Island RTK hazardous substances: Sodium hydroxide Pennsylvania
RTK: Sodium hydroxide Minnesota: Sodium hydroxide Massachusetts RTK: Sodium hydroxide New Jersey: Sodium hydroxide
Louisiana spill reporting: Sodium hydroxide California Director's List of Hazardous Substances: Sodium hydroxide TSCA 8(b)
inventory: Sodium hydroxide CERCLA: Hazardous substances.: Sodium hydroxide: 1000 lbs. (453.6 kg)
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): CLASS E: Corrosive solid.

p. 5
DSCL (EEC):
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 2
Personal Protection: j
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear
appropriate respirator when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/09/2005 06:32 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 6
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Material Safety Data Sheet

Phenolphthalein TS MSDS
Section 1: Chemical Product and Company Identification

Product Name: Phenolphthalein TS Contact Information:

Catalog Codes: SLP1345 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: Mixture. Houston, Texas 77396
RTECS: Not applicable. US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Water; Ethyl alcohol 200
Proof; Phenolphthalein, powder Order Online: ScienceLab.com

CI#: Not applicable. CHEMTREC (24HR Emergency Telephone), call:

1-800-424-9300
Synonym: Phenolphthalein TS
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Not applicable.
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: Not applicable.

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Water 7732-18-5 5.0
Ethyl alcohol 200 Proof 64-17-5 94
Phenolphthalein, powder 77-09-8 1

Toxicological Data on Ingredients: Ethyl alcohol 200 Proof: ORAL (LD50): Acute: 7060 mg/kg [Rat.]. 3450 mg/kg [Mouse].
VAPOR (LC50): Acute: 20000 ppm 8 hours [Rat]. 39000 mg/m 4 hours [Mouse]. Phenolphthalein, powder LD50: Not available.
LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:

Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Slightly hazardous in case of skin contact
(permeator). Non-corrosive for skin. Non-corrosive to the eyes. Non-corrosive for lungs.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof]. Classified
A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof]. Classified 1 (Clear evidence.) by NTP
[Phenolphthalein, powder]. Classified 2B (Possible for human.) by IARC [Phenolphthalein, powder]. MUTAGENIC EFFECTS:
Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for bacteria and/or yeast. [Ethyl alcohol 200
Proof]. Mutagenic for mammalian somatic cells. [Phenolphthalein, powder]. TERATOGENIC EFFECTS: Classified PROVEN

p. 1
for human [Ethyl alcohol 200 Proof]. DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol
200 Proof]. Classified Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof]. The substance is toxic to blood,
the reproductive system, liver, upper respiratory tract, skin, central nervous system (CNS). The substance may be toxic to
kidneys. Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention if symptoms appear.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: The lowest known value is 363°C (685.4°F) (Ethyl alcohol 200 Proof).
Flash Points:
The lowest known value is CLOSED CUP: 12.78°C (55°F). OPEN CUP: 12.78°C (55°F). (Cleveland). (Ethyl alcohol 200 Proof)
Flammable Limits: The greatest known range is LOWER: 3.3% UPPER: 19% (Ethyl alcohol 200 Proof)
Products of Combustion: These products are carbon oxides (CO, CO2).
Fire Hazards in Presence of Various Substances:
Highly flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizing
materials. Non-flammable in presence of shocks, of reducing materials, of combustible materials, of organic materials, of
metals, of acids, of alkalis, of moisture.
Explosion Hazards in Presence of Various Substances:
Slightly explosive in presence of oxidizing materials, of acids. Non-explosive in presence of open flames and sparks, of
shocks.
Fire Fighting Media and Instructions:
Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,
water spray or fog.
Special Remarks on Fire Hazards:

p. 2
Containers should be grounded. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME Vapor may travel considerable
distance to source of ignition and flash back. (Ethyl alcohol 200 Proof)
Special Remarks on Explosion Hazards:
Ethanol has an explosive reaction with the oxidized coating around potassium metal. Ethanol ignites and then explodes on
contact with acetic anhydride + sodium hydrosulfate (ignites and may explode), disulfuric acid + nitric acid, phosphorous(III)
oxide platinum, potassium-tert-butoxide+ acids. Ethanol forms explosive products in reaction with the following compound :
ammonia + silver nitrate (forms silver nitride and silver fulminate), iodine + phosphorus (forms ethane iodide), magnesium
perchlorate (forms ethyl perchlorate), mercuric nitrate, nitric acid + silver (forms silver fulminate) silver nitrate (forms ethyl
nitrate) silver(I) oxide + ammonia or hydrazine (forms silver nitride and silver fulminate), sodium (evolves hydrogen gas). (Ethyl
alcohol 200 Proof)

Section 6: Accidental Release Measures

Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:
Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined
areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS
and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do
not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear
suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids, alkalis.
Storage:
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and
sealed until ready for use. Avoid all possible sources of ignition (spark or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
Ethyl alcohol 200 Proof TWA: 1000 (ppm) from ACGIH (TLV) [United States] [1999] TWA: 1000 (ppm) from OSHA (PEL)
[United States] TWA: 1900 (mg/m3) from OSHA (PEL) [United States] TWA: 1000 (ppm) from NIOSH TWA: 1000 (ppm)
[United Kingdom (UK)] TWA: 1920 (mg/m3) [United Kingdom (UK)] TWA: 1000 STEL: 1250 (ppm) [Canada]Consult local
authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

p. 3
Physical state and appearance: Liquid.
Odor: Not available.
Taste: Not available.
Molecular Weight: Not applicable.
Color: Colorless.
pH (1% soln/water): Neutral.
Boiling Point: The lowest known value is 78.5°C (173.3°F) (Ethyl alcohol 200 Proof). Weighted average: 79.58°C (175.2°F)
Melting Point: May start to solidify at -114.1°C (-173.4°F) based on data for: Ethyl alcohol 200 Proof.
Critical Temperature: The lowest known value is 243°C (469.4°F) (Ethyl alcohol 200 Proof).
Specific Gravity: Weighted average: 0.8 (Water = 1)
Vapor Pressure: The highest known value is 5.7 kPa (@ 20°C) (Ethyl alcohol 200 Proof). Weighted average: 5.53 kPa (@
20°C)
Vapor Density: The highest known value is 1.59 (Air = 1) (Ethyl alcohol 200 Proof). Weighted average: 1.54 (Air = 1)
Volatility: Not available.
Odor Threshold: The highest known value is 100 ppm (Ethyl alcohol 200 Proof)
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, methanol, diethyl ether, acetone.
Solubility:
Easily soluble in cold water, hot water, methanol, diethyl ether. Soluble in acetone.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, heat, sources of ignition. (Ethyl alcohol 200 Proof)
Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Ethanol rapidly absorbs moisture from the air. Can react vigorously with oxiders. The following oxidants have been
demonstrated to undergo vigorous/explosive reaction with ethanol: barium perchlorate, bromine pentafluoride, calcium
hypochlorite, chloryl perchlorate, chromium trioxide, chromyl chloride, dioxygen difluoride, disulfuryl difluoride, fluorine nitrate,
hydrogen peroxide, iodine heptafluoride, nitric acid nitrosyl perchlorate, perchloric acid permanganic acid, peroxodisulfuric
acid, potassium dioxide, potassium perchlorate, potassium permanganate, ruthenium(VIII) oxide, silver perchlorate, silver
peroxide, uranium hexafluoride, uranyl perchlorate. Ethanol reacts violently/expodes with the following compounds: acetyl
bromide (evolves hydrogen bromide) acetyl chloride, aluminum, sesquibromide ethylate, ammonium hydroxide & silver
oxide, chlorate, chromic anhydride, cyanuric acid + water, dichloromethane + sulfuric acid + nitrate (or) nitrite, hydrogen
peroxide + sulfuric acid, iodine + methanol + mercuric oxide, manganese perchlorate + 2,2-dimethoxy propane, perchlorates,
permanganates + sulfuric acid, potassium superoxide, potassium tert-butoxide, silver & nitric acid, silver perchlorate, sodium
hydrazide, sulfuric acid + sodium dichromate, tetrachlorisilane + water. Ethanol is also incompatible with platinium, and
sodium. (Ethyl alcohol 200 Proof)
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

p. 4
 Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Inhalation.

Toxicity to Animals: Acute oral toxicity (LD50): 3450 mg/kg [Mouse]. (Ethyl alcohol 200 Proof).
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof]. Classified
A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof]. Classified 1 (Clear evidence.) by NTP
[Phenolphthalein, powder]. Classified 2B (Possible for human.) by IARC [Phenolphthalein, powder]. MUTAGENIC EFFECTS:
Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for bacteria and/or yeast. [Ethyl alcohol 200
Proof]. Mutagenic for mammalian somatic cells. [Phenolphthalein, powder]. TERATOGENIC EFFECTS: Classified PROVEN
for human [Ethyl alcohol 200 Proof]. DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol
200 Proof]. Classified Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof]. Contains material which may
cause damage to the following organs: kidneys.
Other Toxic Effects on Humans:
Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May affect genetic material (mutagenic) Causes adverse reproductive effects and birth defects (teratogenic) , based on
moderate to heavy consumption. May cause cancer based on animal data. Human: passes through the placenta, excreted in
maternal milk. (Ethyl alcohol 200 Proof)
Special Remarks on other Toxic Effects on Humans:
Acute potential health effects: Skin: causes skin irritation Eyes: causes eye irritation Ingestion: May affect behavior.
Moderately toxic and narcotic in high concentrations. May affect metabolism, gastrointestinal tract, blood, liver. May affect
respiratory tract, cardiovascular and urinary systems. Experimentaly tumorigen. Inhalation: May cause irritation of the
respiratory tract, headache, drowsiness, nausea, narcosis. (Ethyl alcohol 200 Proof)

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 3: Flammable liquid.

Identification: : Ethanol (Ethyl alcohol 200 Proof) UNNA: 1170 PG: II
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

p. 5
Federal and State Regulations:
California prop. 65: This product contains the following ingredients for which the State of California has found to cause
cancer, birth defects or other reproductive harm, which would require a warning under the statute: Ethyl alcohol 200 Proof;
Phenolphthalein, powder California prop. 65: This product contains the following ingredients for which the State of California
has found to cause birth defects which would require a warning under the statute: Ethyl alcohol 200 Proof California prop. 65:
This product contains the following ingredients for which the State of California has found to cause cancer which would require
a warning under the statute: Ethyl alcohol 200 Proof; Phenolphthalein, powder Rhode Island RTK hazardous substances:
Ethyl alcohol 200 Proof Pennsylvania RTK: Ethyl alcohol 200 Proof Florida: Ethyl alcohol 200 Proof Massachusetts RTK: Ethyl
alcohol 200 Proof New Jersey: Ethyl alcohol 200 Proof TSCA 8(b) inventory: Water; Ethyl alcohol 200 Proof; Phenolphthalein,
powder
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-2A: Material causing other toxic effects
(VERY TOXIC).
DSCL (EEC):
R11- Highly flammable. R22- Harmful if swallowed. R45- May cause cancer. S2- Keep out of the reach of children. S46-
If swallowed, seek medical advice immediately and show this container or label. S53- Avoid exposure - obtain special
instructions before use.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 3
Reactivity: 0
Personal Protection: h
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 3
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/10/2005 11:18 AM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 6
 He a lt h 1
3 3
Fire
1 0
Re a c t iv it y 0
P e rs o n a l E
P ro t e c t io n

Material Safety Data Sheet

Charcoal, Wood Powder MSDS

Section 1: Chemical Product and Company Identification

Product Name: Charcoal, Wood Powder Contact Information:

Catalog Codes: SLC2338 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 7440-44-0 Houston, Texas 77396
RTECS: FL7243500 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Charcoal, Activated
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: 1-800-424-9300
Chemical Name: Charcoal, Activated International CHEMTREC, call: 1-703-527-3887
Chemical Formula: C For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Charcoal, Activated 7440-44-0 100

Toxicological Data on Ingredients: Charcoal, Activated LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to mucous membranes. The substance may be toxic to
lungs. Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation occurs.

p. 1
Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Seek
medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 452°C (845.6°F)
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances:
Highly flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
Flammable solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Cool containing vessels
with water jet in order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards:
Flammable/combustible material. May be ignited by friction, heat, sparks, or flames. May reignite after fire is extinguished.
Freshly prepared material may heat spontaneously in air, and presence of water accelerates this.
Special Remarks on Explosion Hazards:
Material in powder form, capable of creating a dust explosion (forming explosive mixtures in air) when exposed to heat, flame,
or ammonium nitrate + heat. ammonium tetrachloride at 240 C, bromates, Ca(OCl)2, chlorates, Cl2, (Cl2 + Cr(OCl)2), ClO, F2,
iodates, IO5, (Pb(NO3)2, HgNO3, HNO3, (oils + air), (potassium + air), Na2S, Zn(NO3)2.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Spontaneously combustible solid. Stop leak if without risk. Absorb with an inert material and put the spilled material in an
appropriate waste disposal. Obtain advice on use of water as spilled material may react with it. Do not touch spilled material.
Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Cover with wet earth,
sand or other non-combustible material. Call for assistance on disposal. Be careful that the product is not present at a
concentration level above TLV. Check TLV on the MSDS and with local authorities.

p. 2
 Section 7: Handling and Storage

Precautions:
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe dust.
Keep away from incompatibles such as oxidizing agents, metals, acids.
Storage:
Store in a segregated and approved area. Keep in a cool and ventilated area away from combustible materials. Keep
container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible
sources of ignition (spark or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 3.5 (mg/m3) from ACGIH (TLV) [United States] TWA: 4 (mg/m3) [United Kingdom (UK)] Inhalation Respirable. TWA: 10
(mg/m3) [United Kingdom (UK)] Inhalation Total. TWA: 2 (mg/m3) [Canada] Inhalation Respirable.Consult local authorities for
acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Solid powder.)

Odor: Odorless.
Taste: Not available.
Molecular Weight: 12.01 g/mole
Color: Black
pH (1% soln/water): Not applicable.
Boiling Point: Not available.
Melting Point: 3500°C (6332°F)
Critical Temperature: 6810°C (12290°F)
Specific Gravity: 3.51 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.

p. 3
Dispersion Properties: Not available.
Solubility: Insoluble in cold water, hot water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Heat, ignition sources (flames, sparks), air,incompatible materials
Incompatibility with various substances: Reactive with oxidizing agents, metals, acids.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Incompatible with air, unsaturated oils, 2-Nitrobenzaldehyde, strong oxidizers such as fluorine, chlorine trifluoride, and
potassium peroxide.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans:
Causes damage to the following organs: mucous membranes. May cause damage to the following organs: lungs.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: May cause
respiratory tract irritation. Ingestion: May cause aspiration pneumonitis, vomiting, decreased gastrointestinal transit time,
gastrointestinal obstruction, constipation, a charcoal-containing empyema, intestinal perforation, charcoal deposits in the
esophageal and gastric mucosa, rectal ulcer. Chronic Potential Health Effects: Skin: Chronic skin exposure can result in
clogging of hair follicles, rendering them black. Inhalation: Chronic inhalation can cause carbon particles to accumulate in the
lungs. It may cause a pneumoconiosis called "Black Lung Disease" or "Coal Workers Pneumoconiosis". This is seen in coal
workers, but no evidence has been found for the equivalent with occupational exposure to activated carbon (charcoal).

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

p. 4
 Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 4.2: Spontaneously combustible substance.

Identification: : Carbon, activated UNNA: 1361 PG: III
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

Rhode Island RTK hazardous substances: Charcoal, Activated TSCA 8(b) inventory: Charcoal, Activated
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according to the EU regulations. Not applicable.
HMIS (U.S.A.):
Health Hazard: 1
Fire Hazard: 3
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 1
Flammability: 3
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Safety glasses.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/09/2005 04:51 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

p. 5
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

p. 6