SplitPDFFile 441 To 473
SplitPDFFile 441 To 473
.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________
Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
27‐01‐23_Sr.Super60_NUCLEUS & ALL_BT_ Jee‐Main_GTM‐17_Test Syllabus
PHYSICS : TOTAL SYLLABUS
CHEMISTRY : TOTAL SYLLABUS
MATHEMATICS यश TG~ @bohring_bot
: TOTAL SYLLABUS
SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.Super60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_Q.P
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
3b
1. The angle between P and Q is cos 1 ,if P a 2b . Find Q , if P Q :
2a
1) a 2b 2) 2a b 3) a b 4) 2a 2b
A
2. If has the dimensions MLT 4 , what is A ?
0
1) Square of electric flux 2) Square of magnetic flux
3) Square of electric field 4) Square of energy
3. The velocity and acceleration of a particle at time t=0 are u a 2 i a 2 j (m/sec) and
a0 ai a j respectively. Find the angle made by the velocity of the particle at t=2 sec with
the initial velocity :
1) 0.25 2) 0.5
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT
3) 0.20 4) 0.40
Page 2
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6. The sphere A of mass m is at the bottom most position in a smooth wedge B of mass M and
moves in a radius R, as shown. Wedge B is placed on a smooth horizontal surface. The
minimum value of velocity with which sphere is projected so that it just reaches the top of
the wedge is:
1
1 2gR M m 2
1) 2gR 2 2)
M
1 1
2gRM 2
2gR M m 2
3) 4)
M m m
7. A thin wire of length L and uniform linear mass density is bent into a circular loop with
900
L3 L3 5 L3 3 L3
1) 2) 3) 4)
8 2 16 2 16 2 8 2
8. The masses and radii of the earth and moon are M 1 , R1 and M 2 , R2 respectively. Their centers
are distance d apart. The minimum speed with which a particle of mass m should be
projected from a point midway between two centers so as to escape to infinity is:
G M1 M 2 G M1 M 2
1) 2 2)
d d
2G M 1 M 2
3) 4) None of these
d
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9. A sphere of mass M is suspended from two wires of same length L and cross-sectional area
A with Young’s modulus Y1 and Y2 . The elastic potential energy of the system will be:
A, L, Y1 A, L, Y2
M 2g 2L 2M 2 g 2 L M 2 g 2L M 2 g 2 L Y1 Y2
1) 2) 3) 4)
A Y1 Y2 A Y1 Y2 2 A Y1 Y2 2 AYY 1 2
10. An open pipe is in 2nd harmonic with frequency f1 . Now one end of the tube is closed and
frequency is increased of f 2 such that the resonance again occur in nth harmonic. Choose the
correct option :
5 3
1) n 5, f 2 f1 2) n 3, f 2 f1
4 4
5 3
3) n 3, f 2 f1 4) n 5, f 2 f1
4 4
11. Three rods of identical cross-sectional area and made from the same metal form the sides of
an isosceles triangle ABC , right angled at B . The points Aand B are maintained at
temperature T and T 2 respectively. In the steady state, the temperature of the point C is
1 1 1 3
1) 2) 3) 4)
2 2 1 3 1 2 3 1 2 1
12. A rectangular glass slab ABCD of refractive index n1 is immersed in water of refractive
index n2 n1 n2 . A ray of light is incident at the surface AB of the slab. The maximum
value of the angle of incidence max , such that the ray comes out only from the other surface
यश TG~ @bohring_bot
CD , is given by :
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 4
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n n 1
1) sin 1 1 cos sin 1 2 2) sin 1 n1 cos sin 1
n2 n1 n2
n n
3) sin 1 1 4) sin 1 2
n2 n1
13. What is the limit of achieving maximum velocity for two charges of same mass m and
having unequal charges q1 and q2 in a gravity free space where they are at present distance
' a ' apart which is almost negligible compared to the distance where their velocity will be
maximum :
1 1 1 1
qq 2 qq 2 qq 2 q1q2 2
1) 1 2 2) 1 2 3) 1 2 4)
2 0 ma 4 0 ma 0 ma 4 2 0 ma
14. Statement-1: angular momentum of the planet orbiting around the sun remains constant
Statement-2 : Torque may act on the rotating planet under some specific conditions.
1) Statement -1 is true. Statement-2 is true and it is correct explanation for statement-1
2) Statement-1 is true. Statement-2 is true but it is not correct explanation for statement-1
3) Statement-1 is true. Statement-2 is false
4) Statement-1 is false. Statement-2 is true.
15. Statement-1: viscous force will not change the angular momentum of this satellite.
Statement-2 : Viscous force will change the velocity of satellite.
1) Statement -1 is true. Statement-2 is true and it is correct explanation for statement-1
2) Statement-1 is true. Statement-2 is true but it is not correct explanation for statement-1
3) Statement-1 is true. Statement-2 is false
4) Statement-1 is false. Statement-2 is true.
16. In the given circuit with steady current, the potential drop across the capacitor must be :
V V 2V
1) V 2) 3) 4)
यश TG~ @bohring_bot
2 3 3
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 5
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17. A square is made of wire of length 4a. what will be the maximum magnetic moment that can
be, achieved by geometrical changes out of the same perimeter. The current is I :
6a 2 I 2a 2 I 8a 2 I 4a 2 I
1) 2) 3) 4)
18. A coil having N terms wound tightly in the form of a spiral with inner and outer radii
a and b respectively. When a current I passes through the coil, magnetic field at the
centre is :
0 NI 2 0 NI 0 NI b 0 NI
1) 2) 3) ln 4)
b a 2b a a 2b a
19. In the network as shown, at a particular instant, current is 5A and decreasing. What should
be the rate of decrease of current so that points Aand B are at the some potential ? (Current
from A to B)
21. In the circuit as shown, charge q varies with time t as q t 2 4 where q is in C and time t
is in seconds. Find VAB at time t 3 sec (in V )
22. The potential difference across a 4H inductor vary with time as shown. The current is zero
at time t 0 . Find the current in A at time t 2sec.
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 6
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23. Find the recoil speed (approximately in m/sec) when a hydrogen atom emits a photon
during the transitions from n 5 to n 1
24. In ground state , find the ratio between total acceleration of the electron in singly ionized
helium atom and hydrogen atom.
25. Voltage versus time graph of a circuit element is shown in the figure. If capacitance C 2 F ,
find the current ( in Amp).
26. The point charges 2q, 2q and q are put on the vertices of an equilateral triangle of side
a. Find the work done by some external force in increasing the separation to 2a ( in J)
27. A body is cooled in 2 minutes in a room from 750 C to 650 C . If the same body is cooled
from 550 C to 450 C in the same room , find the time taken (in minute ). (room temperature
at 300 C )
28. n moles of hydrogen are mixed with two moles of helium. The speed of sound in mixture is
1
times the root mean square (rms) of the gas molecules in the mixture. Find the value of
2
n
29. If P V diagram of a diatomic gas plotted, it is straight line passing through origin. The
molar heat capacity of the gas in the process is IR where I is an integer. Find value of I
30. A vessel of volume 3V contains a gas at pressure 4P0 and another vessel of volume 2V
contains the same gas at pressure 1.5 p0 . Both vessels have the same temperature. when both
vessels are connected by a tube of negligible volume, the equilibrium pressure is IP0 ,where
यश TG~ @bohring_bot
I is an integer . find the value of I
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 7
SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.Super60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_Q.P
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. For a gas obeying vanderwaal’s equation at critical point
p 2 p 2 p
1) Both and 2 are zero 2) Only 2 is not zero
v T V v
p 2 p p 2 p
3) is zero but 2 is non zero 4) is non zero but 2 is zero
v T V v T V
32. A 20 ml sample of a 0.20 M solution of the weak diprotic acid H 2 A is titrated with 0.25M
NaOH . The concentration of solution at the second equivalent points
1) 0.10 M NaHA 2) 0.153 M Na2 A 3) 0.10 M Na2 A 4) 0.0769 M Na2 A
33. A first order reaction is 50% completed in 20 min at 270 C and in 5 min at 470 C . The
energy of activation of the reaction is
1) 43.85 KJ / mol 2) 55.14 KJ / mol 3) 11.97 KJ / mol 4) 6.65 KJ / mol
34. When a concentrated solution of an electrolyte is diluted
1) Its specific conductance increases
2) Its equivalent conductivity decreases
3) Its specific conductivity decreases and equivalent conductivity increases
4) Both specific and equivalent conductivity increases
35. In a 0.2 molal aquous solution of a weak acid HX the degree of dissociation is 0.25 . The
freezing points of the solutions will be nearest to: K f 1.86 k Kg mol 1
1) 0.260 C 2) 0.4650 C 3) 0.480 C 4) 0.4650 C
36. In NaCl the centers of two nearest like charged ions are present at a distance of
1 1 3 1
1) a 2 2) a 3) a 4) 2a
2 2 2 2
37. Match List-I with List-II
List I
List-II
Molecules
p IF7 (1) planar and polar
Q SO2 (2) Non- planar and polar
R SF4 (3) planar and non - polar
S CS2 (4) non planar and non-polar
1) P 4; Q 1; R 2; S 3 2) P 4; Q 2; R 1; S 3
3) P 3; Q 1; R 2; S 4 4) P 3; Q 1; R 4; S 2
यश TG~ @bohring_bot
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38. Statement-1 : H F bond length is smaller than the sum of the radius of H atom and F
atom.
Statement-2: The electronagativity difference gives a shrinkage in bond length.
1) Statement-1 is True, Statement-2 is True; Statement-2 is correct explanation for
Statement-1
2) Statement-1is Ture, Statement-2 is True; Statement-2 is NOT correct explanation for
Statement-1.
3) Statement-1 is True, Statement-2 is False.
4) Statement-1 is False, Statement-2 is True .
39. Statement-1: NaCl and KCl are anhydrous but MgCl2 and CaCl2 exists as MgCl2 . 6 H 2O
and CaCl2 . 6H 2O respectively
Statement-2: Hydration energies of group-2 ions are greater then those of group -1 ions
because of these small size and more charge they have strong attraction towards water
molecule.
1) Statement-1is True, Statement-2 is True ; Statement-2 is a correct explanation for
Statement-1
2) Statement-1 is True; Statement-2 is True; Statement-2 is NOT correct explanation for
Statement-1
3) Statement-1is True, Statement-2 is False.
4) Statement-1 is False, Statement-2 is True
40. B3 N 3 H 6 solution of hydrochloric acid ? Select correct about above reaction
1) No reaction
2) B3 N3 H 6 show substitution reaction and produce B3 N 3Cl6
3) B3 N 3 H 6 show addition reaction and produce B3 N 3 H 9Cl3 in which Cl is bonded to boron
4) B3 N3 H 6 show addition reaction and produce B3 N3 H 9Cl3 in which Cl is bonded to nitrogen
41. The number of stereoisomers possible for a compound of molecular formula
CH 3 CH CH CH OH CH 3
is
1) 2 2) 4 3) 6 4) 3
42. Which of the following has the shortest C Cl bond ?
Cl CH CH 2 Cl CH CH NO2
1) 2)
Cl CH CH CH 3 Cl CH CH OCH 3
3) 4)
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 9
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43. Which of the following compound will show highest dipole moment ?
O
O O
1) 2) 3) 4) O
44. The species which can best serve as an initiator for the cationic polymerization is
1) LiAlH 4 2) HNO3 3) AlCl3 4) BuLi
45. Statement 1: Acid chloride is more reactive than amide for addition followed by elimination
reaction.
Statement 2: Leaving power of NH 2 group is more than the Cl group.
1) Statement-1 and statement -2 are true and statement -2 is the correct explanation of
statement-1
2) Statement-1 and statement -2 are true but statement -2 is NOT a correct explanation of
statement -1
3) Statement-1 is true, statement -2 is false
4) Statement -1 is false, statement -2 is true
46. Which of the following statement is correct ?
1) RNA controls the synthesis of proteins
2) The sugar present in DNA is D ribose
3) RNA has double stranded Helix stricture
4) DNA mainly occurs in the cytoplasm of the cell
47. Assertion (A) : Formaldehyde is more reactive than benzaldehyde for nucleophilic addition
reaction.
Reason (R) : Formaldehyde is more stable than benzaldehyde
1) Both Assertion (A) and Reason (R) are correct
2) Both Assertion and Reason are wrong
3) Assertion is correct and Reason is wrong
4) Assertion is wrong and Reason is correct
48. The major product of the following reactions
CH 3
OH i ) aqu NaOH
ii ) CH 3 I
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 10
SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.Super60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_Q.P
CH 3
CH 3 CH 3
CH 3 OH
OH OH
OCH 3
CH CH 3 CH 3
1) 3
2) 3) 4)
49. Identify A in the given reaction,
OH
SOCl2
A major product
OH CH 2 OH
Cl
OH
OH CH 2Cl OH CH 2 OH
1) 2)
Cl
OH
Cl CH Cl Cl CH Cl
3) 2
4) 2
50. Assertion (A) :Acetone can be converted into acetic acid by I 2 / NaOH .
Reason (R) : Haloform reaction is given by methyl ketones.
1) Both A and R are true and R is the correct explanation of A.
2) Both A and R are true and R is NOT correct explanation of A.
3) A is true, but R is false
4) A is false, but R is true.
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 11
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51. The molar entropies of HI ( g ) , H g , I g at 298 k are 206.5,114.6 and 180.7 J mol 1 k 1
respectively. Using the G 0 given below. Calculate the bond energy of HI (Round of to
nearest integer)
HI g H g I g G 0 271.8 KJ
52. For the coagulation of 50 ml of ferric hydroxide sol 10 ml of 0.5 M KCl is required. What is
the coagulation value of KCl ?
53. The angular momentum of an electron in Bohr’s orbit of He is 3.1652 1034 Kg m2 / sec.
The wave number in terms of Rydberg constant (R) of the spherical line emitted when an
xR
electron falls from this level to the first excited state is then x y is .
y
Use h 6.626 1034 J .s
54. In an iodometric estimation, the following reactions occur
2Cu 2 4 I Cu2 I 2 I 2
0.12 mole of CuSO4 was added to excess of KI solution and the liberated iodine required
120 ml of hypo. The molarity of hypo solution was:
55. Pure nitrosyl chloride NOCl gas was heated to 2400 C in a 0.1L container. At equlilibrium
the total pressure was 1.0 atm and NOCl pressure was 0.64 atm. The value of K p is
58. Consider the sulphides HgS , PbS , CuS , NiS , As2 S3 and CdS . Number of these sulphides
soluble in 50% HNO3 is
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 12
SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.Super60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_Q.P
MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
61. Statement-1 :- Let the vector a i j k be vertical. The line of greatest slope on a plane
n1
ai ai 1 is S then S is equal to
i 1
1 x
2 2
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 13
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1 1
1) e x tan 1 x c 2) e x tan 1 x c
1 x2 1 x2
2 2
3) e x tan 1 x c 4) e x tan 1 x c
1 x2 1 x2
66. Three natural numbers are taken at random one by one with replacement from the set
A = x |1 x 100, x N . The probability that the AM of the number is 25 is
74 25 74
C C C72 74
1) 100 72 2) 100 2 3) 4)
C3 C3 1003 1003
67. From the top of a ‘h’ meters high cliff the angle depression of the top and bottom of a tower
are observed to be 300 and 600 respectively the height of the tower is
h 2h h h
1) 2) 3) 4)
3 3 2 4
68. If p: Nidhi is intelligent; q: Nidhi will pass, then the statement Nidhi is intelligent but will
not pass is written in symbols as
1) p q 2) p q 3) p q 4) p q
2 4 6
69. The value of cos cos cos is equal to
7 7 7
1 1 1
1) -1 2) 3) 4)
2 3 4
70. Let O be origin and point P1 1,1,1 lie on L1 x y z . Projection of OP1 on x-axis be
OM1 . Projection of OM1 on L1 be OP2 and so on. Then the value of PM
1 1 P2 M 2 ........
3 3 3 3 3
1) 2) 3) 4)
2 2 2 2
a b
71. Let A where a, b, c, d 0,1 the number of such A so that trace (A) > det(A)
c d
1) 13 2) 14 3) 12 4) 10
72. If y f x ax b is a tangent to circle x 2 y 2 2 x 2 y 2 0 then the value of
a b 2 a b a b 1 is equal to
2
1) 0 2) 1 3) 3 4) -3
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 14
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n 1
2 k
73. The value of (n k ) cos
k 1 n
( n 3 is an integer)
n n
1) 2) 0 3) 4) n
2 2
74. If 4 x 4 9 y 4 64 then the maximum value of x 2 y 2 is (where x and y are real)
4 4 32 32
1) 2) 13 3) 4)
3 3 3 13
75. A chord of the circle x y 4 x 6 y 0 passing through origin subtends an angle tan 1 (7 / 4)
2 2
at the point where the circle meets positive y-axis, then equation of the chord is
1) 2 x 3 y 0 2) x 2 y 0 3) x 2 y 0 4) 2 x 3 y 0
76. The probability that the triangle formed by choosing any three vertices from the vertices of a
cube is equilateral is
3 6 4 1
1) 2) 3) 4)
7 7 7 7
a a12 x y
77. Let A 11 , X 1 , Y 1 ( X 1 , Y 1 denote the transpose of X and Y )
a21 a22 x2 y2
x2 1 1 x2 1
1) sec 1 c 2) sec 1 c
2x 2 2x
1 x2 1 x2 1
1
3) sec 1 c 4) sec c
2 2 2
18 18
xi 8 9 and x 8
2
79. If i 45 then the standard deviation of the observations x1 , x2 ,.....x18
i 1 i 1
is
1) 4/9 2) 9/4 3) 3/2 4) 2/3
यश TG~ @bohring_bot
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80. The diameter of the circle having the pair of lines x 2 2 xy 3x 6 y 0 as its normals and
having the size just sufficient to contain the circle x(x-4)+y(y-3)=0 is
1) 10 2) 15 3) 7 4) 11
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
x
2
1
tan x dx
81. lim 0 where . is greatest integer function
x
x 1
2
The maximum value of P 1 x1 1 y1 1 x2 1 y2 where x1 x2 y1 y2 2
2 2 2 2
82.
x2 y 2
83. The lengths of perpendicular from the foci S and S on any tangent to ellipse 1
1
4 9
ac
are ' a ' and ' c ' respectively then the value of 0 xdx where denote fractional part of ‘x’
84. The number of solutions of the equation 2 x x 1 2 x is equal to_____ where
greatest integer function.
where denote greatest integer function and denote fractional part ‘x’
87. If A 1,2,3,4,5 then total number of reflexive relations on ‘A’ is 2 then
90. The sum of all the non-real roots of x 2 x 2 x 2 x 3 12 is ' 'then
यश TG~ @bohring_bot
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CHEMISTRY
31) 1 32) 4 33) 2 34) 3 35) 4
36) 1 37) 1 38) 1 39) 1 40) 3
41) 2 42) 2 43) 1 44) 3 45) 3
46) 1 47) 1 48) 2 49) 4 50) 1
51) 298 52) 100 53) 14 54) 1 55) 3
56) 1 57) 2 58) 4 59) 10 60) 1
MATHEMATICS
61) 4 62) 2 63) 1 64) 2 65) 1
66) 3 67) 2 68) 3 69) 2 70) 2
71) 1 72) 4 73) 1 74) 2 75) 3
76) 4 77) 2 78) 2 79) 3 80) 2
81) 2 82) 8 83) 2 84) 1 85) 2
86) 2 87) 20 88) 2 89) 15 90) 1
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 1
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SOLUTIONS
PHYSICS
1. 3b 3b 2
cos , Which gives 3b 2 2ab cos 0
2a 2ab
2 2 2
Given, P a 2 4b 2 4ab cos , And P Q
Equation (1) can be achieved if
2
P a 2 4b 2 4ab cos a 2 b 2 2ab cos
2
So, Q a 2 b 2 2ab cos Q a b
2. A 0 A 0 A MLT 4 given
0 0 0 1 / speed of light
2
ML2T 2
0 A ML T
1 2
0 A is the energy per unit volume.
L3
3. u and at are perpendicular vectors. Acceleration is constant. Equations of motion can
be applied.
At t 2sec, u 2a, at a 2 2 2 2a
2 2 1/2
2 1/2
Velocity at t 2sec v u at 2a 2 2a a 12
2
tan 1
at
tan
1 2 2a
tan
1
2
u
2 a
4. gx 2
Compare with y x tan 2
2u cos 2
3 4 3
tan ,cos ,sin
4 5 5
5. T mg
f
mg
For upper block to move along with block A ,
यश TG~ @bohring_bot
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SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_KEY &SOL’S
0 mg mg , 0 1.0
For block A to move along with other blocks,
f 1 f But f 1 4m m g
1.0
So, 5 mg 0 mg 0 0.20
5 5
f 0 mg
A
f1
4m g
6. Sphere just reaches the top of the wedge, It means relative velocity of sphere w.r.t
wedge is zero mu M m V
mu
So, V=horizontal velocity of sphere and wedge
M m
From conservation of mechanical energy,
1 2 1
mu M m V 2 mgR
2 2
1
u
2 M m m 2u 2
2
2gR M m 2
M m 2
gR u
m M
7. M L
L 2 R
R L / 2
MR 2 3 3 L2 3 L3
I x x1 MR 2 MR 2 L 2
4 8
2
2 2 2
8.
GM m GM m 2G M M 2GM
E 1
2
1 2
M1 M 2
d d d d
2
2
1 2Gm G M1 M 2
m e 2 M1 M 2 , e 2
2 d d
9. Equivalent spring constant of a wire is given by
YA Y 2 A Y1 A Y2 A
K Keq K1 K 2
L L L L
Y Y
Or Y 1 2
2
यश TG~ @bohring_bot
The system can be replaced as if suspended from a single wire of Young’s modulus Y.
1 stress
2
1
U stress strain volume AL
2 2 Y
2
1 Mg 1 M 2g 2L
AL
2 A Y A Y1 Y2
10. V V
f1 , f2 n , f 2 f1 and n is odd :
L 4L
5V 5
For n 5 , it is possible f 2 f1.
4 L 4
11. TB TA
The heat will flow C to B to maintain steady state. Applying condition formula to the
T T T TC TC T 2
sides AC andCB . a
a 2 AC CB a 2 a
T 3
On solving, C
T 2 1
n n n
sin max 1 cosC 1 .cos sin 1 2
n2 n2 n1
n n
max sin 1 1 cossin 1 2
n2 n1
13. At distance ' a ' apart, kinetic energy of the particles is assumed zero and at infinity
their kinetic energy will be maximum.
q1q2 1 q1q2
mVmax 2 2,Vmax
4 0 ma 2 4 0 ma
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SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_KEY &SOL’S
14. dL
0, L cons tan t
dt
No torque will act on planet under any condition otherwise L constant and planet
will become unstable
15. For satellite revolving in a circular orbit.
mv 2 GMm
2
r r
or mv r GMm cons tan t
2
2V V V
I
2 R R 3R
VP V V IR VQ
VQ VP IR
V V
R
3R 3
17. 2 r 4a
4a
r
2
2 2
2a 4a I
M IA I .
18. At a distance r , an elements of thickness dr is considered. Number of turns in the
N N
element .dr .dr
b a b a
0 dN I 0 I N dr
dB
.
2r 2 ba r
b
NI b
B dB 0 in
a
यश TG~ @bohring_bot
2b a a
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 5
SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_KEY &SOL’S
19. di
VA 1 5 15 5 103 VB
dt
VA VB ( given)
di
4 103 A / sec.
dt
20. Let R1 R2
Current flows in large coil of radius R2
i
Magnetic field at centre 0
2 R2
0i
Flux linked with smaller coil R 21B R 21
2 R2
Mi
0
2
R 1
M / i
2 R2
M R 21 / R2
Hence, R1 R2 otherwise, R1 R2
21. qt 4 2
dq di
i 2t and 2
dt dt
At t 3sec, q 5c and i 6 A
q di
VA L iR VB
c dt
q di
VA VB L iR
c dt
5
0.5 2 6 1 8V
3
22. di
VL L
dt
Ldi VL dt
L i f i0 Area under VL t graph
1
4 i f i0 8 2
2
यश TG~ @bohring_bot
if 2A
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 6
SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_KEY &SOL’S
23. 1
E photon 13.6 1 eV 13.0eV
25
E / c mv (momentum conserved )
E 13 1.6 1019
v 4 m / sec
mc 1.67 1027 3 108
24. a v2 / r
Z2
so, a
1 / 2
Thus aZ 3
3 3
a1 Z1 2
8
a2 Z 2 1
25. q CV
dq dv 8
i C 2 4 A
dt dt 4
26. W U f Ui
1
Ui
4 0 a
2q 2q 2q q 2q 0
Also U f 0
So, W 0
27. 1 2
1 2 0
t 2
75 65 75 65
30
2 2
For second case,
55 45 55 45
30
2 2
1
Divide eqn 1 by eqn. 2 , 2
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT
2
Page 7
SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_KEY &SOL’S
t 4min ute
28. 1
Given Vsound Vrms
2
1 1
RT 2 3RT 2
M 2M
3
So,
2
C n1C p1 n2C p 2
But p
Cv n1Cv1 n2Cv 2
3 3 5R / 2 n 7 R / 2
2 2 3R / 2 n 5 R / 2
n2
29. PV since graph is a straight line
PV 1 constant
For the processes PV x Constant , molar heat capacity is
R R
Given by C
1 1 x
But here, 1.4 and x 1
R R
C 3R IR( given)
1.4 1 1 1
So, I 3
30. No change in temperature
So, n1 n2 i n1 n2 f
PV PV PV PV
1 1
2 2 1 2
RT RT RT RT
PV PV
P 1 1 2 2
RT
4 P0 3V 1.5P0 2V
5V
3P0 IP given
So, I 3
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Sec: Sr.Super60_NUCLEUS & ALL_BT Page 8
SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_KEY &SOL’S
CHEMISTRY
31. At critical temperature slope of pressure volume curve is maximum and it is zero
32. H 2 A 2 NaOH Na2 A H 2O
4
Na2 A n NaOH 2n H 2 A
32 20
4
0.25 V 2 0.2 20
52
0.0769 V 32 ml
n Na2 A n H 2 A 20 0.2 4
33. 0.693 0.693
K1300 k k2320 k
20 5
k Ea 1 1 2.303RT2T1 k
log 2 Ea log 2
k1 2.303R x1 x2 T2 T1 k1
2.303 8.314 300 320 20
Ea log 55.14
20 10 3
5
34. On dilution number of ions decreases in unit volume hence specific conductance
decreases. But separation between ions also increases hence equivalent conductance
increases
35. i 1 1.25,T f K f .m.i i 0.633:
i 1 0.4650 C
2
36. a
Distance b/w two nearest Cl
2
a
Distance b/w two nearest Na
2
37. IF7 P.B.P., 0 , SO2 Bent , 0
CS 2 linear , 0 , SF4 See saw, 0
38. Due to electronegativity difference between F and H bond length is smaller.
39. IIA Cations have high hydrate formation nature due to their high charges.
40.
41. H
CH 3 CH CH C* CH 3
OH
n2
यश TG~ @bohring_bot
2n 22 4
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It exhibits both geometrical and optical isomerism
42. Cl CH CH NO2
In , double bond character in carbon chlorine bond is
maximum due to resonance and so the bond length is shortest
43.
O O
A dipolar resonance structure has aromatic character In the ring and would be
expected to make a major contribution to the overall structure
44. Lewis acids are the most common compounds used for initiation of cationic
polymerization. Some other lewis acids are SnCl4 , AlCl3 , BF3 , TiCl4
45. Weak bases are good leaving Groups
46. RNA controls the synthesis of proteins
47. Formaldeyde is more reactive for nucleophilic addition reaction
48. CH 3 CH 3
CH 3
ONa OCH 3
OH NaOH CH 3 I
NaI
49. OH OH
SOCl2
OH CH 2 OH Cl Cl
CH 2
In the case of OH group present on the aromatic ring, carbon - oxygen bond has
partial double bond character, hence, it is a strong bond and difficult to cleave.
50. O
CH3 C
Acetone contains methyl ketonic group and undergoes Haloform reaction
51. S 206.5 114.6 180.7 88.8
0
G 0 H 0 T S 0
H 0 271.8 298 88.8 1013 298.3
52. Coagulation value
Number of millimoles of electrolyte required
volume of colloidal solution (in litre)
10 0.5
1000 100
50
53. nh
The angular momentum
2
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34
n 6.626 10
.1652 1034 ,n 3
2
1 1 1 1 5R
v R.Z 2 . 2 2 v R.22. 2 2
n1 n2 2 3 9
X=5,y=9,x+y=14
54. Mole of pure CuSO4 0.12 mole of Na2 s2O3 react with I 2
Na2 s2O3 120 103 M 0.12 , M 1.0
55. 2 NOCl 2 NO g Cl 2
g
At eqm p-2x
p x 1; p 2 x 0.64, x 0.12
0.24 0.12 16.875 103
2
Kp atm
0.64
2
3
57. The number of optical isomers for Cr C2O4 3 is two
58. PbS , CuS , As2 S3 CdS are soluble in 50% HNO3 . Where as HgS , Sb2 S3 are
insoluble in 50% HNO3
59. Ho 67 4 f 11 6s 2
Ho 3 4 f 10
60. One hydrogen bonded H 2O molecule.
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Sec: Sr.Super60_NUCLEUS & ALL_BT Page 11
SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_KEY &SOL’S
MATHEMATICS
61. a b b b.a b b.b a 2(2i j k ) 6(i j k ) 2i 8 j 8k
62. x 1 a x2
Right hand side is non negative x R such that a x 2 0
So left hand side x 1 0 x 1
x 1 a x2
1 2a 1
x 1
2
a x2 x
2
1 2a 1
the root x does not satisfy x 1
2
1 2a 1
So it is not a root and x satisfies the equation for a 1
2
63. AM GM
a1 a3 a5 ...... a2 a4 a6 ........
2
a1 a3 a5 ..... a2 a4 a5 ......
n 1
20
or
2
a a k for k 0
i 1
i i 1
n 1 n 1
100 ai ai 1 k ai ai 1
i 1 i 1
Hence S = 100
64. At point of maxima f ' x 0 and f " x 0
f " x x 2 f 2 x 0
Since the curve is x 2 y 2 a 2 and x 2 f 2 x 0
2 2
x1 y1 a 2
Point lies outside hyperbola
Hence 2 tangents
65.
1 1 2 x
I e x tan 1 x dx
1 x
2 2 2
1 x 1 x 2
f x
f ' x
1
I e x tan 1 x c
1 x2
Using e x f x f ' x dx e x f x c
66. n S 1003
यश TG~ @bohring_bot
x1 x2 x3 75
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xi 1
74
C72
PE
1003
67. hx
tan 30
y
y h x 3
h
tan 600 h 3 y
y
1 2h
y h x
3 3
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1 0 0 0
0 ,
0 0 1
1 0 1 1
0 ,
1 0 0
0 1 1 1 1 0
0 , , ,
1 0 1 1 0
0 0 1 0 0 1
1 , , ,
1 1 1 1 0
1 1 0 1 1 1
1 0 , 1 1 , 1 1
72. Substitute y in equation of circle and put 0
x 2 ax b 2 x 2 ax b 2 0
2
x 2 1 a 2 x 2ab 2 2a b 2 2b 2 0
a 1 ab 1 a 2 b2 2b 2
2
Hence a b 2 a b a b 1 0
2
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SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_KEY &SOL’S
7
tan θ =
4
2
m
3 7
2m 4
1
3
3m 2 7
3 2m 4
12m 8 21 14m
1
26m 13 m
2
1
y x x 2y 0
2
76. n( s ) 8C3 56
Choosing a vertex 3 triangles can be formed from the diagonals of the faces not
8 3
passing through the vertex. But each triangle is repeated 3 times ....n( E ) 8
3
8 1
p( E )
56 7
77. A is symmetric A ' A now X'AY= X'AY ' (Y ' A ' X )
(Y ' AX ) ( X ' AY is 11 matrix)
1 0
Let E1 , E2
0 1
If X E1 and Y E2 then
E 11 AE2 E 12 E1 a12 a21
A is symmetric.
78. 1
1 2
x2 1 1
2 1 2 1 dx
x dx put x t
2 x
x x x 2 1 1
x x x x 2
x x
dt
t 2 sec
t t2 2
2 sec tan d 1
C
2 sec 2 tan 2
79. Let xi 8
18 18
9,
i 1 i 1
2
45
x xi
2
2
S .D i
n n
9 3
4 2
यश TG~ @bohring_bot
80. Normal’s 3, 3 2
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SRI CHAITANYA IIT ACADEMY, INDIA 27‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐17_KEY &SOL’S
Centre of given circle =(2,3/2)
Radius =5/2
Radius of required circle = 5 + 5/2
= 15/2
Diameter =15.
81. x
tan x
1 2
dx
lim 0
form
x
x 12
2
1 x2
lim tan x
1 2
x x 2
2
lim 2
x
2
82. let x1 2 cos
y1 2 sin
x2 2 sin
y2 2 cos
P 2 x1 y1 x2 y2 x1 y1 x2 y2
2 2 cos sin 2 cos sin 2sin cos 2sin cos
2 4cos 2sin 2
4
2428
83. x2 y2
The product of perpendicular from the foci on any tangent of 2 2 1 is a 2 a b
a b
2 2
x y
Here 1
4 9
ac 4
4
x x dx
0
4 4
xdx x dx
0 0
86
2
84. 2 x x 1 2 x …………………(1)
x 1 2 x
0 2 x 1
x 1 0
x 1 0
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1 x 0
2 2 x 0
2 x 2, 1
from equation (1)
2 x 0 2 x
2 x 2, 1
1
x 1,
2
85. y x cos x
x
x 0
86. 2 3 4 1
1 1 1 6 4 3 13
I x x x x x 2 x3
2 3
1 2 3 0
2 3 4 12 12
87. Number of reflexive relations
2
2n n
2255
220
88. 2 6( x 2) 2(2 x 1) 10 x 10
f '( x) ( x 2)2/3 2 (2 x 1) ( x 2)1/3
3 3( x 2)1/3 3( x 2)1/3
x 1 is a point of maximum and x 2 is a point of minimum
No.of extremum points is 2
89. x 1 y 2 z 3
1 2 2
po int on the
1, 2 2, 2 3
plane
6 11 5
6, 8,13
Hence
Dis tan ce 25 100 100
15
90. If x x y then y 2 5y 6 0
2
y 2
6 y 1 0 x 2 x 6 0, x 2 x 1 0
x 3, 2, x , 2
Sum of non-real roots = 2 =-1
यश TG~ @bohring_bot
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 17