Falcon Academy

2011E.C Chemistry 2nd Model For

Grade 12
Department of Natural Science
Time allowed1:30 min NO. Q 50
I. Choose the correct answer from the given alternatives
1. The maximum number of hydrogen bonds that a water molecule can have is
A.1 B. 2 C. 3 D. 4
2. The shape or the structure of a If7 molecule is
A. pentagonal bipyramid C. Trigonal bipyramid
B. square pyramid D. Octahedral
3. Hybridization of C2 and C3 in H3C-CH = C = CH – CH3 are
A. Sp, SP3 B. SP2, Sp C. SP2, Sp2 D. Sp, Sp
4. Which of the following pairs are the spectator ions of Mg(HCO3)2(aq) + 2HNO3(aq) Mg
(NO3)2 (aq) + 2CO2(g) + 2H2O(1)?
A. Mg2+ and NO-3 C. H+ and HCO-3
B. NO-3 and HCO-3 D. H+ and Mg2+
5. Which of the following is not a colligative property?
A. Freezing point depression
B. Osmotic pressure
C. Boiling point
D. Vapour pressure lowering
1
O2 ( g )
6. For the reaction N2O5(g) 2NO2(g) + 2 the rate of decomposition of N2O5 6.25 x
-3
10 mol/ls. What is rate of formation of NO2 and O2 respectively?
A. 6.25 x 10-3 mol/ls and 3.125 x 10-3 mol/Ls
B. 6.25 x10-3 mol/ls and 6.25 x 10-3 mol/Ls

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 C.6.25 x 10-3 mol/ls and 6.25 x10-2 mol/Ls
D. 1.25 x 10-2 mol/ls and 3.125 x 10-3 mol/Ls

7. The concentration of R in the reaction R P was measured as a function of time and

the following data is obtained
[R] [molar] 1.0 0.75 0.4 0.1

t (min) 0.0 0.05 0.12 0.18

What is the order of reaction?

A. first order C. third order
B. Second order D. Zero order
8. The zero order reaction, its 100% completion takes place of time ;
2k [ A ]o [ A ]o
A. [ A ]0 B. k C. [A]K D. 2 k
9. Why does the rate of reaction increase when powderd CaCO3 is used in stead of
marble chips ?

A. The powder CaCO3 acts as a catalyst

B. There is an increase on the concentration of CaCO3

C. There is an increase of the particle size of the CaCO3

D. There is an increase of the surface area of the CaCO3

10. Which of the following has formed coordinate covalent bond?

A. H2O B. NH4+ C. SO42- D. K2O

11. Which of the following would not make a good buffer solution?

A. CH3COO- and CH3 COOH C. SO42- and HSO-4

B. HCO3- and H2 CO3 D. NH3 and NH4+

12. Which of the following is not both a Bronsted – Lowry acid and Bronsted – Lowry

base?

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 A. HSO-4 B. H2PO4- C. HCO-3 D. OH-

13. An acid – base indicator, with KIn of 1x10-4 ionizes as HIn (yellow) + H2O
H3O+ + In – (red), which of the following statement is not true about the above
equilibrium?
A. The predominant color in its acid range is yellow
B. The PH at which the indicator changes color is 4
C. At PH 7 most of the indicator is in ht un-ionized form
D. None of the above
14. On which of the following principles does the first law of thermodynamics based on?
A. Action and reaction C. conservation of energy
B. Conservation of mass D. The entropy – temperature relation ship
15. Which of the following salt will be hydrolized to give acidic solution?
A. CH3 COO Na CH3 COONH4 C. NH4Cl D. Na2CO3
16. How much mililiter of water has to be evaporated from 250ml of 1.0 M Ca(OH)2 to
make it 3M?
A. 100 B. 150 C. 167 D. 200
17. Which of the following statement is correct about chemical reactions at equilibrium?
A. The forward and back ward reactions proceed at equal rates
B. The reactants involved in the reaction completely converted to products
C. The concentrations of reactants and products are equal
D. The for ward reaction is favored than the back ward reaction
18. A solution was prepared by adding 48g of methanol (CH3OH) in 81g of water (H2O) .
What is mole fraction of methanol in this solution?( molar mass: C=12, O= 16, H=1)
A. 0.25 B. 0.75 C. 1.5 D. 4.5
19. What is the mole fraction of water in the solution that is in question18?

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 A. 0.75 B. 0.25 C. 2.5 D. 1.25
20. What is the normality of the solution in question 18?
A. 12.52 Ν B. 18.52N C. 1.5N D. 4.5N

21. A solution contains 0.2 M of a weak monprotic acid, HA and 0.2M its sodium salt,
Na A. What is [H3O+] in the final solution if Ka of HA = 1.8 x 10-5?
A. 3.6 x 10-6 M B. 1 x 10-5M C. 1.8 x 10-5M D. 19 x 10-3 M

22. For the titration of 50ml 0.25 M H2 SO4 by NaOH solution of unknown

concentration the end point of a certain indicator is detected when 41ml of NaOH is
added what is the concentration of NaOH solution?
A. 0.1 M B. 0.25 M C. 0.41M D. 0.5M
23. What is the morality of a solution obtained by dissolving 0.01 mole of NaCl in 500
ml of solution?
A. 0.01M B. 0.005M C. 0.02 M D. 0.1M
24. Which set of the following contains only covalently bonded molecules?
A. BCl3 ,Si Cl4 , PCl3 C. NH4Br, N2H4, HCl
B. I2, H2S, Na Br D. O3, Na Cl, N2

25. A bond created by overlapping of one hybridized orbit on an other orbit is known as

A. sigma bond (δ bond) C. covalent bond

B. Dative bond D. pi bond ( π bond)

26. Which of the following molecule contains only single covalent bond?

A. O2 B. Cl2 C. N2 D.CO2
27. In which of the following compound would inter molecular hydrogen bonding occur?
A. HCHO B. PH3 C. CH3OH D. COCl2
28. Which of the following factor has a negligible effect on the rate of reaction of solid
substances?
A. Temperature B. Pressure C. surface area of reactants D. catalysts
29. Which of the following is incorrect statement?
A. Smaller the activation energy, the slower a reaction tends to be.

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 B. Reaction rates increase with increase in temperature
C. Positive catalysts decrease the rate of reation by increasing activation energy.
D. All are incorrect statements

30. Which of the following pairs have the same shape and hybridization?
A. NF3 and BF 3 C. BCl3 and BeCl2
B. BF-4 and NH+4 D. NH3 and NO-3
31. The shape of CH4 molecule is
A. planar B. pyramidal C. Tetrahedral D. Spherical
32.Which of the following is not a possible shape of a molecule?
A. Tetrahedral – GeCl4 C. trigonal bipyramidal – PCl5
B. bent – HCN D. T- shaped – BrF3
33. Which of the following is incorrect about anti – bonding molecular orbital?
A. It has an energy higher than that of the bonding molecular orbital
B. It is obtained by destructive interference of electron waves of atoms in the
molecule
C. It has a region of high electron density between the two nuclei
D. It involves an energy which is not conductive to increased stability
34. The enthalpy of formation of LiF is – 590 KJ/mol. What is the enthalpy of
sublimation of metallic lithium? (Use HIE = + 520 KJ/mol, HEA – 328 KJ/mol
H diss = +155 KJ/mol Hu = 1016KJ/mol)
A. 79KJ/mol B. 80KJ/mol C. 206KJ/mol D. 60KJ/mol
35. To prepare 200ml of 0.91M dilute H2SO4 aqueous solution from 18.2M concentrated
H2SO4 stock solution, what volume of stock solution is used?
A. 150ml B. 10ml C. 190ml D. 50ml
36. What volume of water should be added to have such a diluted solution in question
(35)?
A. 50ml B. 190ml C. 10ml D. 150ml

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37. According to lewis concept an acid is
A. proton acceptor C. lone pair electron acceptor
B. proton donor D. lone pair electron donor

38. For the reaction represented by H2PO-4 + NH3 HPO2-4 + NH+4 the acid – base
conjugate pair is
A. H2PO4- / HPO42- ; NH3 /NH4+ C. NH3/HPO42- ; NH4+/H2PO-4
B. H2PO-4/NH4+ ; HP2-OO2-4/NH3 D. H2PO4- /NH3; HPO2-4/NH+4
39. For the acid strength of HCN < CH3COOH < HF < HNO2 < HCOOH, What is the
correct increasing order in base strength of the conjugate bases of the acids?
A. CN-< CH3COO- < F- < NO-2 < HCOO-
B. HCOO- < NO-2 < F- < CH3COO- <CN-
C. CH3 COO- < HCOO- < CN- NO-2 < F-
D. F- < CN- NO2- < HCOO- < CH3COO-
40. A solution with a known concentration used to determine the unknown concentration
of the other solution is known as
A. acid – base indicator C. titrant
B. titration D. titrand
41.For the titration of weak acid by strong base the equivalence point is reached at the PH
A. equal to 7 B. less than 7 C. greater than 7 D. equal to 14
42. Which of the following is the formula of conjugate acid for the Bronsted – Lowry
base HSO-3?
A. SO32- B. H3SO+3 C. H2SO3 D. HSO-4
43.What is the PH of a solution that consists of 0.55M HCOOH and 0.63M HCOO Na?
(ka for HCOOH = 1.7x10-4) (Given – leg 1.48 = -0.17)
A. 3.8 B. 4.72 C. 2.9 D. 8.2

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44. A 0.1 M solution of nitrous acid (HNO2) is 7.1% ionized at equilibrium. What are the
values of [H+] and PH respectively? (Given – leg 7.1 = -0.851)
A. 7.1 x 10-3 and 2.15 C. 7.1 x 10-6 and 3.8
B. 1.4 x 10-12 and 11.85 D. 1.4 x 10-3 and 4.7

45. Which of the following mathematical expression correctly represents boiling point
election
A. Δ Tf = kf m C. Δ p = x solute Po
B. Δ Tb = kbm D. π = MRT
46. Which of the following colligative property increasesby adding non-volatile soute?
A. Osmotic pressure C. Boiling point elevation
B. freezing point depression D. vapour pressure lowering
47. Which of the following statement is correct about dilution process?
A. It is preparing solutions with high concentration
B. It is preparing solutions with lower concentration
C. Extra addition of solvent increases the concentration
D. All
48. At 700c the vapour pressure of pure water is 39kpa which one of the following is most
like vapour pressure for a 1.5M solution of sucrose (aq) at the seme temperature?
A. 37kpa B. 39kpa C. 41 kpa D. 45kpa
49. Which of the following is correct about equivalence point ?
A. The point at which complete neutralization takes place
B. the point at which only half neutralization takes place
C. the point at which more amount of the acid or balse remain un reacted
D. none of the above
50. The reaction of substances with water is known as
A. hydration C. carboxylation

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B. hydrogenation D. dehydrogenation

Set by Yaregal.T

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