PRO 1.SOLID STATE PYQ SOLUTIONS +—__- hn —_ CHEMISTRY 2023cuass 12" CHEMISTRY 1. SOLID STATE mnr-cerpva2023 1. What is the number of unit cells when one mole atom ofa metal that forms simple cubic structure? (A) 6.022 x 10 (B) 1.204 x 10% (C) 9.033 x 10° (D) 3.011 = 107 Tn Simple cube, Ne of atom= 1, no of Unit cele y TE no of Atoms = tmoly = 6022, (33 Gdems Ne: af Onit cal] = 6.022% ee . Acompound made of elements A and B form fec structure. Atoms of ‘A’ are at the corners and atoms of B are present at the centres of faces of cube. What is the formula of the compound? (A) AB (B) AB, (C) AB, ~— (D) A,Bcuass 12" CHEMISTRY 1. SOLID STATE MHT:-ceT-Pyq2023 3. What is the packing efficency of silver metal in its unit cell? (A) 52.4% (B) 68.0% (C) 32.0% (D) 74.0% Piver hag Fee Syst) Packine . 4 penta) . J any =44, (>) 4. Which from following metal has ccp crystal structure? (A) Cu (B) Zn (C) Mg (D) PoCLASS 12" CHEMISTRY 1. SOLID STATE nr-cer-pyaz023 5. Calculate the molar mass of an element having density 21g cm® that forms fcc unit cell. [a*. N, = 36 cm’ mol '] (A) 292.00 g mol ! (B) 189.00 g mol ! (C) 140.00 g mol! (D) 108.00 g mol! TH RCe, ney M= Say a yn I RRE 9 aH Pe he 6. Find the radius of metal atom in simple cubic unit cell having edge length 334.7 pm. (A) 167.35 pm (B) 334.70 pm (C) 144.93 pm (D) 118.32 pm Th Simple Cube 2 OW Le = 334.3 2. = 164-35 pmLass 12” CHEMISTRY 1. SOLID STATE Mnt:cer-p¥qa2023 7. Calculate the edge length of unit cell of metal which crystallises to bec structure. (Repeated in 2 shifts) (radius of metal atom = 173 pm) (A) 5.01 x 10* cm (B) 4.00 x 10% cm (C) 4.5 x 10% cm (D) 5.5 x 10% cm Th Bee, Y= BPM = 143% 8m (8) 8. Calculate the molar mass of an element with density 2.7 g cm® that forms fee structure. [a. N, = 40 cm? mol} (Repeated in 2 shifts) (A) 112 g mol! (B) 54 g mol! (C) 27 g mol! (D) 78 g mol! T fey n=4 Me $0? Nq n = 24X46 lo _# (= 23]Lass 12°" CHEMISTRY 1. SOLID STATE manrcerpvares | 9. What is the total number of Bravais lattices present for different crystal systems? (Repeated in 2 shifts) (A) 14 (B)7 (C)4 (D) 3 [A] 10. Which of the following characteristic properties is NOT true for crystalline solid? (A) These substances have sharp melting point. (B) These have different values of refractive index in different directions. (C) The constituent particles are orderly arranged. (D) These are isotropic.cass 2 cvemsre 1. SOLID STATE spur cer svoz0e 11. Calculate the number of atoms present in unit cell of an element having molar mass 190 g mol ' and density 20 g cm?. [a’. N, = 38 cm* mol '] (A) 1 (B) 2 (C) 6 (D)4 12. Find the radius of an atom in fee unit cell having edge length 393 pm (A) 196.51pm (B) 170.22pm (C) 78.63 pm (D) 138.93 pm Th FeCLASs 12" CHEMISTRY 1. SOLID STATE 300 pm? (A) 51.0 g mol ! (B) 60.0 g mol! (C) 81.3 g mol! (D) 96.8 g mol ! T Bcc, neo _ , — , Az 30°Pme Bx B8en "= 803 Na 7 _s ~ JExGx (Bese x33 a P29 PN C123 | = BSloys | = Sl Ime! ira (A) 1 x 10?! (B) 1.5 x 10?! (C) 3 x 102! (D) 6.0 x 10?! Mole Cny= Pass es _B-thes 3 So _— Msleasmass —te = ol N= 0-0) moje = 0-0\ % Gera yeie3 Storms 4 Otome — . Iy SS 4 Ont cay OO! XG-02r Kad oO _Ctoms = one X= 001% 022% (QR? cel) a = _6:022x 18! “Go [usmiet} 13. What is atomic mass of an element with BCC structure and density 10 gcm ‘ having edge length 14. What is the number of unit cells present in a cubic close pack crystal lattice having 4 atoms per unit cell and weighing 0.60 g (molar mass 60 g mol')? MHT-CET-PYQ202315. Which formula is used to calculate edge in bee structure? _v3e WH (A) a= Tay (B) 2 Br 8 Mg (C) a ailad (D) == v3 >) 16. Calculate the edge length of simple cubic unit cell it radius of an atom is 167.3pm (A) 473.2 pm (B) 334.6 pm (C) 386.3 pm (D) 836.5 pm In Simpla rel A= 2-y = 2 Gre. 2 ! = 334-6 Pm [8] eee 1. SOLID STATE datesc1ass 12” CHEMISTRY 1. SOLID STATE mur-cerpva223 | 17. Calculate the density of an element having molar mass 27 g mol ' that forms fcc unit cell [a*. N, = 38.5 cm’ mol] (A) 2.8 g cm? (B) 2.1 g cm? (C) 3.5 g cm? (D) 4.1 g cm? Th Feo, ne 4 ! = So ear Naxad = nr BES (og 3b = BWW geeq3 IA) 18. What type of following solids the ice is? (A) ionic solid (B) covalent network solid (C) molecular solid (D) metallic solidLass 12" CHEMISTRY 1. SOLID STATE mur-cerpva2023 19. Calculate the radius of metal atom in bec unit cell having edge length 287 pm (A) 124.27pm (B) 143.51pm (C) 101.45pm (D) 57.4 pm = PPR R art = \2y Pm (A) 20. What from followng metal has hep crystal structure? (A) Cu (B) Zn (C) Ag (D) Po jeCLASS 12 cHeMISTRY 1. SOLID STATE mur-cer-pva2023 Calculate the number of atoms present in unit cell, if an element having molar mass 23 g mol ' and density 0.96 g cm? [a’. N, = 48 cm’ mol '] (A) 1 (B) 2 (C)4 (D) 6 n 8aq3 Na — = S9E% YS 2°98 i 09g K 2:08 eg Which of the following statements is NOT true about polymorphism? (A) The existence of substance in more than one crystalline form. (B) Polymorphism occuring in element is called allotropy. (C) Polymorphism forms of a substance are formed under different conditons. (D) The crystal shape of polymorphic substances are identical to each other. [D)CLAS 12" CHEMISTRY 1. SOLID STATE mut.cer-pyq2023 23. Find the radius of metal atom in bec unit cell having edge length 450 pm. (A) 225.04 pm (B) 194.85 pm (C) 159.08 pm (D) 90.05 pm i 13. a G Ws - S43 x Ys ¥ = 43% les ~ '44-85 Poy [g) 24. Calculate the volume of unit cell if an element having molar mass 180 g mol"! forms fee unit cell. [p.N, = 120 x 10% g cm’ mol] (A) 6.00 x 103 cm? (B) 5.00 x 1073 cm?* (C) 4.00 x 10% em’ (D) 7.00 « 10 em? Th FCC, nay Oe AM SNA = 4x 18sa 1. SOLID STATE 25: MHT-CET-PYQ2023 Calculate the volume of unit cell it an element having molar mass 56 g mol ! that forms bec unit cells. [p.N, =4.8 x 10% g cm? mol '] (A) 1.17 « 1073 cm (B) 4.79 « 10-73 cm (C) 3.31 x 1073 cm? (D) 2.23 x 1073 cm’ Th Bcc led Vion (22-3 xi Fem? | i) 26. What is total number of crystal systems associated with 14 Bravais lattices? (A)7 (B) 14 (C)1 (D) 3 [A]| ciass 12" cwemistny 1. SOLID STATE mur-cerpvaz023 27. Inanionic crystalline solid atoms of element Y forms hep structure. The atoms of element X occupy one third of tetrahedral voids. What is the formula of compound? (A) XY, (B) XY (C) XY, (D) XY, Atoms of Rlement XY occupy o t. . Hebrahed RY ne thisd of era] Nols = 2 x y= 2 Ay 2 ose soa] (A) . Calculate the edge length of bcc unit cell if radius of metal atom is 227 pm (A) 4.54 « 10% cm (B) 5.24 x 10* cm (C) 6.42 x 108 (D) 1.135 x 10% cm Wa 224 Pm= 224 x eSay th Bcc, as 4x eS = = YRK22A HS Vaz = 52ux 108 onLass 12" CHEMISTRY 1. SOLID STATE mur-cerpva2023 29. ZT, In Calculate the density of metal having molar mass 210 g mol ! that forms simple cubic unit cell [a*. N, = 21.5 em’ mol '] (A) 9.77 g cm? (B) 7.15 g em? (C) 8.12 gem? (D) 6.94 g cm? Simple Cubse Unit ctl N=] . Calculate the molar mass of an element having density 2.8 g cnr? and forms fcc unit cell. [a°. N, = 38.5 cm’ mol] (A) 26.95 g mol" (B) 23.5 g mol! (C) 29.2 g mol! (D) 21.6 g mol"! In Feu nad $9? Na aaa + BX 35-5 yY OF K BR-6 lA) = 26-45 gmar!CLASS 12" CHEMISTRY 1. SOLID STATE Mur:-cerpvaa023 31. IfN denotes number of particles then what will be number of octahedral void? (A) N (B) N? (C) 3N (D) 2N For ‘N> atoms, Oba hed xa} Veid = A) 32. Find the edge length of bec unit cell if radius of metal atom is 126 pm. (A) 2.91 x 10% em (B) 4.52 x 10-* cm (C) 3.50 x 10% cm (D) 6.30 10% cm Y= [26 pm= | 26 K eS em, = 2-9) x1o8emCLASS 12” CHEMISTRY 1. SOLID STATE mur-cerpvo2023 33. Identify the compound exhibiting Frenkel defect. (A) Calcium fluoride (B) Sodium chloride (C) Potassium chloride — (D) Lithium chloride Age i Ag Be, fol, Cahs she [A] Frenke) detec 34. Which among the following is an example of simple cubic unit cell? (A) Polonium (B) Sodium (C) Magnesium (D) SilverCLASS 12 85. 36. coemistRY 1. SOLID STATE Calculate the volume of unit cell having density 7.8 gcm ‘and molar mass of element 56 g mol ! that crystallizes to form bec structure. (A) 2.38 x 108 cmé (B) 3.40 « 107 cm? (C) 4.5 x 10? cm (D) 1.00 x 10° cm* = 112 1823 UES = 2-39 KS Fen} If a, b, c are edges and a, B, y are bond angles between them then identify the correct combination for bec unit cell (A)a=b=canda=B=y=90° (B) a=b ¥ canda=fp=y=90° (Chazbzcandaz Bey 90° (D) a=b=canda=B=y # 90° aLass 12" CHEMISTRY 1. SOLID STATE 37. Calculate the number of atoms present in unit cell if an element having molar mass 27 g mol ' and density 2.7 g cm} [a*. N, = 40 cm’ mol '] (A) 1 (B)2 (C)3 (D) 4 38. What is the number of octahedral and tetrahedral voids in 0.5 mole compound respectively if it forms hep structure? (A) 3.011 x 10% and 6.022 x 107 (B) 6.022 x 10° and 3.011 x 10° (C) 2.011 x 10% and 4.022 x 10% (D) 6.022 x 103 and 1.024 x 10% Fer octe hedva LOmolg = 6022 % 1a OS mola = 2-011 \% 133 For +etsohedval, o- 5S role 2% 6-5 = | mele 6 [A] on Xjs3CAASs 12" CHEMISTRY 1. SOLID STATE murccer-pva2023 39. IfN denotes number of particles then what will be number of tetrahedral void? (A) N (B) N/2 (C) 2N (D) 3N For SN» atoms “Te reahed sa} Veid= oN [ej 40. Calculate the edge length of fec unit cell if radius of metal atom is 143 pm. (A) 404.5 pm (B) 303.2 pm (C) 286.0 pm (D) 715.0 pm xe _¥2. 4% 43 X10 41 xXjoo ~ A IYK% too \ Ly ~ 40pm [A]CLASS 12" CHEMISTRY 1. SOLID STATE 41. Identify the defect when a small amount of SrCl, is added to NaCl during crystallisation. (A) Substitutional impurity defect (B) Interstitial impurity defect (C) Metal deficiency defect (D) Frenkel defect 42. Calculate the number of atoms present in unit cell of an element having molar mass 56 g mol! and density 8.0 g cm”. [a°. N, = 14.0 cm’ mol] (A) 1 (B)2 (C)4 (D) 6 zs (! Jvo aan ™ 14 fi aa a. 4 “|| cuass12™ ceanstay 1. SOLID STATE 43. An element of BCC crystal structure has edge length of unit cell 2.93 A°. What is radius of atom? (A) 0.293 A° (B) 1.268 A® (C) 1.465 A® (D) 1.561 A° Y = 3 a — = tag , 088 LES ME 52 y x3 = 143% 6-72, = {2u6 ae [B) 44, Anelement crystallizes in BCC. Structure having density of unit cell 6.20 g cm. What is the edge length of unit cell if its atomic mass is 93? (A) ¥50x10"'°cm (B) J50x10%cm (C) ¥50x107cm (D) ¥50 «10cm Fox Bog Heo = 5x 1573 as wm Ale ; T es P= Sox gry ee. ee ae 620% Cx ea A= YS0 x (874 = _186 x13 S250 & Woy G20 KG Mm = Kes 2 MHT-CET-P¥Q2023CLASS 12” CHEMISTRY 1. SOLID STATE MHT-CET-PvQ2023 45. What is the percentage of unoccupied volume in simple cubic cell? (A) 52.4% (B) 47.64 % (C) 74.09 % (D) 26.09 % Sey (Shen PIE Cubse ceyy Fackin eth a MCeety = B2-a6 | 6 . | Occupied Velume = (00-S2-3¢ inl YF. by 4, (8) 46. Which from following is not an example of covalent network solid? (A) Silica (B) Boron nitride (C) Silicon carbide (D) Calcium fluoride 1B)Tare NET GE C1Ass 12" CHEMISTRY 1. SOLID STATE Mar-cer-pva2023 47. Whatis the number of unit cells in | mole atom of metal that forms fee structure? (A) 1.506 * 1073 (B) 3.011 x 10? (C) 6.022 x 107 (D) 9.033 x 10? Px Fee . »>Nxe t, moje. 6 022 123 asomg 4 ohms = L Unit c Gor, (23 iy APES EU cet} X%4= Gory (33 Ma GOI KS 4 =)soeue?> SA) 48. If at 0°C and | atmospheric pressure, 22.4 L of CH, contain N, number of molecules. Find the number of molecules of O, in 22.4 L at same temperature and pressure. N (A) = (B) N, (C) 2N (D) N. A 1 mo Mee ct goss 24 o [8] Na mrolecutescuass 12° CHEMISTRY 1. SOLID STATE 49, What is the total number of moles of atoms present in 3.2 g methane? (A)4mol (B)3mol (C) 2mol (D) 1 mol TA 7 Tn methane, CHA Tr chy, = \24\%4 There aye 5 Slows = 16 Gme\! ° Amel m™eKS of fens = n= Mass _ O-2% 5 ™o lay Mags, = | moje 1d] 50. Calculate the density of a metal having molar mass 180 g mol that forms fcc unit cells. [a’. N, = 36 cm’ mol '] (A) 20 g mol! (B) 32 g mol! (C) 14 g mol! (D) 18 g molt Fer Fee,CLAss 12" CHEMISTRY 1. SOLID STATE murcerpranaes 51. Calculate the radius of an atom of metal when it forms bee structure with unit cell edge length 227 pm. (A) 113.5 pm (B) 98.3 pm (C) 80.2 pm (D) 196.6 pm i = \ABKSCF WB em i) 52. Whatis the number of tetrahedral voids in 0.6 mol compound if it forms CCP structure? (A) 7.0 x 10 (B) 7.86 « 107 (C) 7.23 x 107 (D) 6.69 x 10? Te +rahessya) Vord= Bong ioeg = FA moje | moles G-or2 x (23 -2emele= 6-022 x bry% [eB = 2a ihe [<]CLASS 12 53. 1. SOLID STATE mur-cerpyaz023 CHEMISTRY Which from the following unit cells is present in hexagonal crystal system? (A) Body centred (B) Face centred (C) Base centred (D) Simple Calculate the total volume occupied by all atoms in bec unit cell of radius of atom is 3 x 10% cm. (A) 2.26 x 10% cm? (B) 1.15 x 10? em (C) 3.52% 102 cm3 — (D) 4.21 x 102 cm! Total volome ty Bcc = qe? © °8 P24 K G22 TAY56. CLASS 12°" CHEMISTRY 1. SOLID STATE mur-cer-pva2023 53: Which from the following statements is NOT true about Schottky defect? (A) It occurs in ionic compounds having high degree of ionic character. (B) It occurs in ionic compounds having high coordination number of anions. (C) It is possible in ionic compounds with small difference between sizes of cation and anions. (D) It occurs in ionic compounds with large difference between sizes of cations and anions. [D] Which of the following is NOT a SI unit? (A) kg (B)K (C)dm> (D)s fe]ctass 12” CHEMISTRY 1. SOLID STATE acre oveONS 57. Calculate the edge length of fec unit cell if the radius of a metal atom is 144 pm (A) 4.074 x 10% cm (B) 3.325 x 10* cm (C) 2.882 x 10% em (D) 7.213 x 10% cm | 4A m= 4 X18 em d= 4. Ie AXES ngs as SS ae + *108 cm [A] 58. Which of the following statements is NOT true about metallic solid? (A) It is crystalline solid (B) The constituent particles are held together by covalent bond (C) It is malleable and ductile (D) It is good conductor of heat and electricity [3]Lass 12” CHEMISTRY 1. SOLID STATE manr-cer-pva2023 59, Find the type of unit cell if its volume = 6.64 « 10 7? cm and density = 2.7 g cm * (molar mass of metal 27 g mol ') (A) simple cubic (B) body centred (C) face centred (D) hexagonal close packed iis Oo 1X 6 6Y KE = 348% 4 [TReB > Fee fe] 60. Whatis the edge length of unit cell when metal forms bee crystal structure? (radius of atom = 216 pm) (A) 216 pm (B) 499 pm (C) 611 pm (D) 108 pm or im 5 7 eee CFB (eB 4199. pen rR)CLASS 12° CHEMISTRY 1. SOLID STATE ol. MHT-CeT-PYQ2023 Calculate the density of element having mass 23 g mol ' that forms bec unit cell. [a*. Na = 45.62 cm’ mol '] (A) 1.8 gem? (B) 1.0 g cm? (C) 2.4g cm3 (D) 0.8 g cm? Fox Bee, neo S=_2KmM Na x03 =_2K23 NS 62 = 46 YS-62 = 26 Ie) 62. Calculate the total volume occupied by atoms in bec unit cell. (edge length of unit cell = 4 x 10° cm) (A) 4.35 x 10% cm? (B) 5.16 x 1023 em} (C) 3.54% 10% cm? (D) 5.56 « 103 cm? Fox Bcc, Tho) Velumne = {3 Tad — = VFB 21494 158) g = EAB KEN K Max Bey UBS KIS74X 10 Te - 7 Tg, = U3Y KI? In)63. a CLASS 12" CHEMISTRY Identify the compound exhibiting substitutional A= 2av pm= rsex is 3 impurity defect. (A) Sodium chloride (C) Brass In Brass, 1. SOLID STATE (B) Zinc sulfide (D) Silver bromide hes} atory (Cy) ic wep laced b tm purity atom ea fe) ocm = Neolume af unit cet = @-sex \o%)? = 23-94% (4x10 Te = 23q %73 4 64. Calculate the volume of unit cell having edge length 288 pm. (A) 2.39 x 102 cm? (C) 1.20 x 10 cm’ (B) 2.02 x 10 > cm? (D) 3.42 x 10° cm? [A) 4— —_—_——_ 7 CLAss 12" CHEMISTRY 1. SOLID STATE Murcer-pva2023 | | 65. What is the formula of compound consisting elements A and B crystallises in bec structure. In | this atoms of A are at the corners of cube and | atoms of B are at the centre of the cube? (A) AB, (B) AB, (C)AB__—(D) AB, Fe f= 1 = =] wx Fx B= 1 Qresent in canjre) AB (c) 66. What is number of particles present in a simple cubic unit cell? (A) 4 (B)5 (C) 1 (D) 2 [2]Lass 12" CHEMISTRY 1. SOLID STATE MHE-CET Pya2023 67. What is number of different type of unit cells present in tetragonal crystal system? (A) I (B) 2 (C) 3 (D) 4 68. Find the radius of an atom in FCC unit cell having edge length 405 pm. (A) 202.5 pm (B) 175.3 pm (C) 143.2 pm (D) 181.0 pm Q= YOR pm te jee aq = LY) K4os | g Qt Koya | = [Yo-%6 j = (we pm [<}| cuass 12” chemstay 1. SOLID STATE mnr.cer-pvaz023 69. Calculate the molar mass of metal having density 9.3 g cm } that forms simple cubic unit cell. (aN, = 22.6 cm* mol ') (A) 210.2 g mol! (B) 105.3 g mol ! (C) 52.6 g mol! (D) 70.2 g mol ! Pox Simple Cubje cell, N=] Ms Sa? wis aM 42) Kee 6 ——— = Dig. gmey! [AJ 70. Which from the following is not an example of amorphous solid? (A) Glass (B) Plastic (C) Rubber (D) Diamond Diarrond is. cary 2) alent Nefwork sy S}9)CLASS 12” CHEMISTRY 1. SOLID STATE murcerpvaz0a3 71. Which from the following combinations is an example for construction of n-type semiconductor? (A) Si doped with B (B) Si doped with P (C) Si doped with Ga (D) Si doped with In [8