DAYANAND SCIENCE COLLEGE, LATUR

12th MHT-CET : 2024-25

CHEMISTRY - I
Chapter : Electrochemistry
01. Which of the following aqueous solutions will a) 0.5 M NaCl b) 0.05 M NaCl
conduct an electric current quite well? c) 0.005 M NaCl d) 0.02 M NaCl
a) sugar b) glycerol 10. The unit of equivalent conductivity is
c) pure water d) HCl a) ohm cm
02. Molten KCl conducts electricity due to the b) ohm–1 cm+2 (g equivalent)–1
presence of c) ohm cm2 (g equivalent)
a) free ions d) S cm–2
b) free electrons 11. The Kohlrausch law is realted to
c) free molecules a) Conductance of ions at infinite dilution
d) Atoms of potassium and chloride b) Independent migration of ions
03. Solid NaCl is a bad conductor of electricity because c) Both (a) and (b)
a) Solid NaCl is covalent d) neither (a) and (b)
b) In solid state there are no ions 12. According to Kohlrausch law, the limiting value of
c) In solid NaCl, there is no migration of ions molar conductivity of an electrolyte A2B is
d) In solid NaCl , there are no electrons. a)  A +  B b)  A –  B
04. Water is non-electrolyte but conducts electricity on
 1 
dissolving a small amount of c)  A    B d) 2 A +  B
2
a) NaCl b) sugar
13. With increase in temperature the electrical
c) acetone d) oxygen
conduction of metallic conductor
05. The unit of cell constant is
a) increases
a) ohm–1 b) ohm - cm
–1 b) decreases
c) cm d) ohm–1cm2eq–1
c) remains the same
06. The unit of specific conductivity is
d) changes irregularly
a) ohms cm–1 b) ohms cm–2
14. During electric conduction, the composition of
c) ohms–1 cm d) ohms–1 cm–1
which of the following is unchanged ?
07. The cell constant is the product of resistance and
a) Graphite b) Zinc wire
a) conductance
c) Copper wire d) all
b) molar conductance
15. The degree of dissociation of an electrolyte does
c) specific conductance not depend on
d) specific resistance a) Nature of electrolyte
08. The increase in the value of molar conductivity of b) Catalytic action
acetic acid with dilution is due to
c) Dilution
a) decrease in interionic forces
d) Temperature
b) increase in degree of ionization
16. In the process of electrolysis using active electrodes
c) increase in self ionization of water the concentration of cathode and anode.
d) decrease in degree of ionization a) increases, decreases
09. Which of the following solutions has the highest b) decreases, decreases
equivalent conductance?
 Dayanand Science College, Latur (2) XII - Electrochemistry
c) increases, increases 24. Which of the following occurs at cathode
d) decreases, increases 1
 
17. In which of the following electrolysis, electrodes a) 2OH  H 2O  O 2  2e
2
act as active electrodes. Electrolysis of + –
b) Ag  Ag + e
a) fused NaCl between graphite electrodes
c) Fe2+  Fe3+ + e–
b) fused AgNO3 between platinum electrodes
d) Cu2+ + 2e–  Cu
c) Aqueous AgNO 3 so lut ion bet ween Ag
25. Which of the following reaction is used to make a
electrodes
fuel cell ?
d) Aqueous AgNO3 solution between pt electrodes
a) 2H2 (g) + O2 (g)  2H2 O (l)
18. The passage of current through a solution of certain
b) 2Fe (s) + O2 (g) + 4H+ (aq)  2Fe2+ (aq)
electrolyte results in the evolution of H2 at cathode
and Cl2 at anode. The electrolytic solution is + 2H2 O (l)
a) Water b) H2 SO4 c) Pb (s) + PbO2 (s) + 2H2 SO4 (aq) 
c) Aqueous NaCl d) Aqueous CuCl2 2PbSO4 (s) + H2 O (l)
19. On the basis of the position in the electrochemical d) Cd (s) + 2Ni(OH)3 (s)  CdO(s) + 2Ni(OH)2
series, the metal which displaces hydrogen from + 2H2O (l)
water and acids is 26. Corrosion is
a) Hg b) Al a) physical change
c) Cu d) Ag b) Neutralisation
20. A copper voltameter, a silver voltameter and a c) electrochemical change
water voltameter are connected in series and d) none is true
current is passed for some time. The ratio of the 27. Which of the following reaction occurs at the
number of moles of copper, silver and hydrogen cathode during the charging of lead storage battery?
formed at the cathode is a) Pb2+ + 2e–  Pb
a) 2 : 1 : 1 b) 1 : 1 : 1 b) Pb2+ + SO4 2–  PbSO4
c) 1 : 2 : 1 d) 1 : 2 : 2 c) Pb  Pb2+ + 2e–
21. Which of the following energy changes occur in d) PbSO4(S) + 2H2 O 
galvanic cell? PbO2(S) + 4H+ + SO4 2– + 2e–
a) Electrical energy  Chemical Energy 28. As lead storage battery is charged
b) Chemical Energy  Electrical Energy a) lead dioxide dissolves
c) Chemical Energy  Internal Energy b) sulphuric acid is regenerated
d) Internal Energy  Electrical Energy c) lead electrode becomes coated with lead
22. In a cell the following reaction takes place sulphate
Fe + CuSO4  FeSO4 + Cu d) the concentration of sulphuric acid decreases
The cell can be represented as 29. When a conductance cell was filled with a 0.0025M
a) Cu | CuSO4 || Fe | FeSO4 solution of K2 SO4 , its resistance was 326 ohm.
b) Pt | CuSO4 || FeSO4 | Pt The specific resistance (ohm–1 ) of the K2 SO4
c) Fe | FeSO4 || CuSO4 | Cu solution is
d) CuSO4 | Cu || FeSO4 | Fe a) 4.994 × 10–4 b) 5.997 × 10–4
23. The metal which cannot liberate H2 gas from c) 6.997 × 10–4 d) 7.997 × 10–4
hydrochloric acid 30. The specific conductance of a solution is 0.3568
a) Zn b) Cu ohm–1 . When placed in a cell the conductance is
c) Mg d) Al 0.0268 ohm–1. The cell constant is
a) 1.331 cm–1 b) 13.31 cm–1
c) 0665 cm–1 d) 6.65 cm–1
 Dayanand Science College, Latur (3) XII - Electrochemistry
31. If 0.01 M solution of an electrolyte has a resistance 37. Number of electrons required to deposit one mole
of 40 ohms in a cell having a cell constant of of Mg2+ ions is
0.4 cm–1 then its molar conductance will be a) 6.023 × 1023 b) 12.046 × 1023
a) 10 4 b) 10 3 c) 18.069 × 1023 d) 3.012 × 1023
c) 10 2 d) 10 38. The amount of electricity that can deposit 108 gm
32. Molar conductivity of a solution 1.26 × 102  –1 of silver from AgNO3 solution is
cm2 mol–1 , its molarity is 0.01. Its specific a) Faraday b) 1 Ampere
conductivity will be c) 1 coulomb d) None
a) 1.26 × 10–5 b) 1.26 × 10–3 39. One ampere of current is passed for 9650 seconds
c) 1.26 × 10–4 d) 0.0063 through molten AlCl3. What is the weight in grams
33. Specific conductance of 0.1 M sodium chloride of Al deposited at cathode ?
solution is 1.06 × 10 –2  –1 cm–1 . Its molar (Atomic weight of Al = 27)
conductance in ohm–1 cm2 mol–1 is a) 0.9 b) 9.0
a) 1.06 × 102 b) 1.06 × 103 c) 0.09 d) 90.0
c) 1.06 × 104 d) 5.3 × 102 40. 3 amperes of current is passed for 4 hours through
34. The variation of equivalent conductance of a weak Cu salt solution. The amount of copper deposited
electrolyte with (concentration)1/2 is represented is (Cu = 63.5)
as a) 1.433 g b) 14.3 g
c) 16 g d) 143 g
41. A silver cup is plated with silver by 965 coulomb
a)  b)  of electricity, the amount of Ag deposited is
c c
a) 9.89 g b) 107.87 g
c) 1.0787 g d) 1.002 g
42. The weight of copper deposited when 0.5 F of
c)  d) 
c
current is passed through CuSO4 solution is
c
a) 3.175 g b) 0.3175 g
35. The variation of equivalent conductance of strong c) 15.875g d) 6.35 g
electrolyte with (concentration) 1/2 is represented
43. The cell reaction of a cell is
by
Mg(s) + Cu2+(aq)  Cu(s) + Mg2+(aq)
If the standard reduction potentials of Mg and Cu
are – 2.37 and + 0.34 V respectively, the e.m.f. of
a)  b)  the cell is
a) + 2.03 V b) – 2.03 V
c c
c) + 2.71 V d) – 2.71 V
44. The voltage of a cell whose half-cells are given
below is
Mg2+ + 2e–  Mg(s) ; E0 = – 2.37 V
c)  d)  Cu2+ + 2e–  Cu(s) ; E0 = + 0.34 V
c c standard EMF of the cell is
a) – 2.03 V b) 1.36 V
36. The molar conductivities °NaOAC and °HCl at
infinite dilution in water at 25°C and 91.0 and 426.2 c) 2.7 V d) 2.03 V
S cm2 / mol respectively. To calculate °HOAc , 45. Three faradays of electricity are passed through
the additional value required is molten Al2 O3 , aqueous solution of CuSO4 and
molten NaCl taken in three different electrolytic
a) °NaCl b)  0H 2O cells. The amount of Al, Cu and Na deposited at
c) °KCl d) °NaOH the cathodes will be in the ratio of
 Dayanand Science College, Latur (4) XII - Electrochemistry
a) 1 mole : 2 mole : 3 mole 53. The overall reaction taking place at the anode during
b) 1 mole : 1.5 mole : 3 mole electrolysis of fused sodium chloride using suitable
c) 3 mole : 2 mole : 1 mole electrode is [MHT-CET 2015]
d) 1 mole : 1.5 mole : 2 mole a) oxidation of chloride ion
46. Given standard electrode potentials: b) reduction of sodium ions
Fe3+ + 3e–  Fe; E0 = – 0.036 V c) reduction of chlorine
Fe2+ + 2e–  Fe; E0 = – 0.440 V d) oxidation of sodium atoms
The standard electrode potential E0 for 54. Which among the following solutions is not used in
Fe3+ + e  Fe2+ is the determination of cell constant?
a) 0.476 V b) – 0.404 V [MHT-CET 2015]
c) 0.40 V d) + 0.772 V –2
a) 10 M KCl b) 10–1 M KCl
47. The standard EMF of the cell reaction c) 1 M KCl d) saturated KCl
Zn + Cu2+  Cu + Zn2+ is 1.10 V at 25°C. The 55. How many Faradays of electricity are required to
EMF for the cell reaction when 0.1 M Cu2+ and deposit 10 g of calcium from molten calcium
0.1 M Zn2+ solutions are used at 25°C, is chloride using inert electrodes? [MHT-CET 2016]
a) 1.10 V b) 0.110 V a) 0.5 F b) 1 F
c) – 1.10 V d) – 0.110 V c) 0.25 F d) 2 F
48. The standard reduction potential of three metals 56. In the cell represented by :
X, Y, Z are 0.52, – 3.03 and – 1.18V respectively.
The order of reducing power of the corresponding Pb(s) |Pb2 (aq) (1M)||Ag (aq) (1M)|Ag(s)
metals is the reducing agent is ...... [MHT-CET 2016]
a) Y > Z > X b) X > Y > Z a) Pb b) Pb2+
c) Z > Y > X d) Z > X > Y c) Ag d) Ag+
49. For a cell the cell reaction is 57. In the ry cell, what is the negative electrode?
Mg(s) + Cu2+ (aq)  Cu(s) + Mg2+(aq). [MHT-CET 2016]
If the S.R.P. values of Mg and Cu are – 2.37 V a) Zinc b) Graphite
and + 0.34 V respectively, the e.m.f. of the cell is
c) Manganese dioxide d) Ammonium chloride
a) + 2.03 V b) – 2.03V
58. Identify the weakest oxidising agent among the
c) + 2.71 V d) – 2.71 V
following [MHT-CET 2017]
50. The standard electrode potentials of zinc and +
copper are – 0.76 V and 0.34 V respectively. The a) Li b) Na +
c) Cd 2+ d) I2
Zn2  Cu2
EMF of the cell Zn Cu is 59. What is the SI unit of conductivity?
(0.1M) (0.1)M
[MHT-CET 2017]
a) 1.1 V b) – 1.1 V
a) S m b) Sm–1
c) 1.22 V d) 1.04 V
c) Sm2 d) Sm–2
51. How is electrical conductance of a conductor
related with length and area of cross-section of 60. Which among the following equations represents
the conductor? [MHT-CET 2014] the reduction reaction taking place in lead
a) G = l  K –1 b) G = K l –1 accumulator at positive electrode while it is being
c) G = K  l –1 d) G = K l –2 used as a source of electrical energy?
52. 20 ml of 0.1 M ferrous sulphate was completely [MHT-CET 2018]
oxidised using a suitable oxidising agent. What is a) Pb  Pb2 b) Pb 4  Pb
the number of electrons exchanged?
[MHT-CET 2014] c) Pb 2  Pb d) Pb 4  Pb2
a) 1.204 × 10 22 b) 193 61. The number of moles of electrons passed when a
c) 1930 d) 1.204 × 1021 current of 2 A is passed through a solution of an
electrolyte for 20 minutes is... [MHT-CET 2018]
 Dayanand Science College, Latur (5) XII - Electrochemistry
a) 4.1 × 10–4 mol b) 1.24 × 10–2 mol (Cell constant = 1.25 cm–1 ) [MHT-CET 2019]
c) 2.487 × 10–2 mol d) 2.487 × 10–1 mol a) 3.5  –1 cm2 mol–1 b) 2.5  –1 cm2 mol–1
62. Which among the following is correct for c) 2.0  –1 cm2 mol–1 d) 5.0  –1 cm2 mol–1
electrolysis of brine solution? [MHT-CET 2019] 69. In the reaction
a) Cl2 gas is liberated at the cathode
MnO 4(aq)  Br(aq)
 
 MnO2(s)  BrO3(aq)
b) O2 gas is liberated at the cathode
c) H2 gas is liberated at the cathode the correct change in the oxidation number of the
d) Sodium metal is collected at the anode species involved is ..... [MHT-CET 2019]
–1
a) Br to Br +5 b) Mn+7 to Mn+3
63. Calculate the emf of the following cell at 298 K;
E0 cell = 2.0 V c) Mn+7 to Mn+2 d) Br+5 to Br–1
Zn (s) | ZnSO 4 (0.01M)|| CuSO4 (1M)|Cu (s) 70. The conductivity of an electrolytic solution
decreases on dilution due to ... [MHT-CET 2019]
[MHT-CET 2019]
a) decrease in number of ions per unit volume
a) 2.0 V b) 1.0508 V
b) increase in percentage ionisation
c) 2.0929 V d) 2.0592 V
c) increase in ionic mobility of ions
64. In the electrolysis of aqueous sodium chloride with
d) increase in number of ions per unit volume
inert electrodes; the products obtained at the anode
and cathode respectively are ... [MHT-CET 2019] 71. Two electrolytic cells are connected in series
a) Cl2 and H2 b) Na and Cl2 containing CuSO4 solution and molten AlCl3. If in
electrolysis 0.4 moles of Cu are deposited on the
c) Cl2 and Na d) O2 and Na
cathode of the first cell the number of moles of Al
65. The molar conductivities for infinite dilution for
deposited on the cathode of the second cell is ....
sodium acetate, HCl and HaCl are
91 S cm2 mol–1 , 425.9 S cm2 mol–1 , and [MHT-CET 2019]
126.4 S cm2 mol–1 respectively. a) 0.6 mol b) 0.18 mol
The molar conductivity of acetic acid at infinite c) 0.27 mol d) 0.4 mol
dilution is ...... [MHT-CET 2019] 72. The correct representation for Nernst equation for
a) 930.5 S cm mol 2 –1 b) 390.5 S cm2 mol–1 the half cell reaction;
c) 530.9 S cm2 mol–1 d) 300.5 S cm2 mol–1 2
Cu (aq  
)  e  Cu (aq) is .... [MHT-CET 2019]
66. The standard emf of the cell
2
Cu (s) |Cu (aq) 
(1M)||Ag (aq) (1M)|Ag (s) 0 0.0592 [Cu  ]
a) E Cu  ,Cu 2
 ECu ,Cu 2  log
2 [Cu 2 ]
is 0.463 V. If the standard electrode potential of
Cu electrode is 0.337 V, what is the standard 0.0592 [Cu  ]
0
electrode potential of Ag electrode? b) ECu |Cu 2  ECu ,Cu 2  log
1 [Cu 2 ]
[MHT-CET 2019]
a) 0.626 V b) – 0.860 V 0.0592 [Cu  ]
0
c) – 0.126 V d) 0.800 V c) ECu ,Cu 2  ECu ,Cu 2  log
2 [Cu 2 ]
67. The molar conductivity of 0.05 M HCl is
163.3 S cm2 mol–1 at 298 K. What is the 0 0.0592 [Cu  ]
conductivit y of t he solut ion at the same d) ECu ,Cu 2  E Cu  ,Cu 2
 log
1 [Cu 2 ]
temperature? [MHT-CET 2019]
73. Standard hydrogen electrode (SHE) is a ....
a) 0.08165 S cm mol b) 0.8165 S cm2 mol–1
2 –1

c) 8.165 S cm–1 d) 0.008165 S+1 cm–1 [MHT-CET 2019]

a) primary reference electrode
M b) secondary reference electrode
68. The resistance of is 2.5 × 103 . What is the
10 c) metal-sparingly soluble salt electrode
molar conductivity of the solution? d) metal-metal ion electrode
 Dayanand Science College, Latur (6) XII - Electrochemistry
74. What is the molar conductivity at infinite dilution of c) 1.06 × 10–2  –1 cm2 mol–1
CaCl2 if the molar conductivity of Ca2+ ion and d) 1.06 × 102  –1 cm2 mol–1
Cl– ion at infinite dilution is 119 and 71  –1 cm2 82. What is the conductivity of 0.01 M NaCl solution
mol–1? [MHT-CET 2020] if resistance of NaCl solution and cell constant are
a) 431.0  cm mol b) 261.0  –1 cm2 mol–1
–1 2 –1
375 ohms and 0.5 cm–1 respectively at 298 K?
c) 126.0  –1 cm2 mol–1 d) 341.0  –1 cm2 mol–1 [MHT-CET 2020]
75. What is the cell constant of N/10 KCl solution at –3 –1 –1
a) 1.333 × 10  cm
25 ºC, if the conductivity and resistance of a
b) 1.333 × 10–4  –1 cm–1
solution is 0.0112 –1 cm–1 and 55  respectively?
[MHT-CET 2020] c) 1.875 × 10–4  –1 cm–1
a) 0.2 cm –1 b) 0.491 cm–1 d) 7.50 × 10–3  –1 cm–1
c) 2.0 cm–1 d) 0.616 cm–1 83. Which of the following statement is true for
76. Conductivity of a conductor is [MHT-CET 2020] electrolytic cell? [MHT-CET 2020]
a) inverse of resistivity a) Oxidation occurs at positive electrode
b) equal to resistivity b) Oxidation occurs at negative electrode
c) inverse of resistance c) Reduction occurs at positive electrode
d) inverse of conductance d) Anode is negative and cathode is positive
77. E0cell is 1.049 V and involves transfer of 2 electrons, electrode
calculate the equilibrium constant of the cell? 84. The distance bet ween the electrodes of a
[MHT-CET 2020] conductivity cell is 0.98 cm and the area of
a) 2.75 × 10 10 b) 3.625 × 1035 cross-sectionis 1.96 cm2. What is the cell constant?
c) 0.524 × 1035 d) 2.098 × 1010 [MHT-CET 2020]
78. A solution of CuSO4 is electrolysed using a current a) 0.5 cm –1 b) 1 cm–1
of 1.5 amperes for 10 minutes. What mass of
c) 2 cm–1 d) 1.5 cm–1
copper is deposited at the cathode?
85. During the electrolysis of aqueous sodium chloride;
(Atomic mass of Cu = 63.7) [MHT-CET 2020]
the product obtained at the anode is .....
a) 0.637 g b) 0.395 g
[MHT-CET 2020]
c) 0.297 g d) 0.150 g
79. If resist ivit y of a 0.8 M KCl solution is a) Na (s) b) H2(g)
2.5 × 10–3  cm, calculate the molar conductivity c) O2(g) d) Cl2(g)
of the solution [MHT-CET 2020] 86. Wheat is the standard potential of the cell
5 –1
a) 2 × 10  cm mol 2 –1
Ni| NI2  (1M)|| Cu 2 (1M)|Cu
b) 3 × 105  –1 cm2 mol–1
c) 5 × 105  –1 cm2 mol–1 E 0Cu  0.337 V; E 0Ni  0.236V
d) 4 × 105  –1 cm2 mol–1 [MHT-CET 2020]
80. What is the common unit of conductivity if the a) – 0.753 V b) 0.101 V
dimensions are expressed in CGS system? c) – 0.136 V d) 0.573 V
[MHT-CET 2020] 87. How many Faraday of electricity is required to
a)  –1 cm b)  cm deposit 0.6 g of magnesium at cathode when an
c)  cm –1 d)  –1 cm–1 aqueous solution of MgCl2 is electrolysed?
81. What is the molar conductivity of 0.1 M NaCl if its
(Molar mass of Mg = 24 g mol–1)
conductivity is 1.06 × 10–2  –1 cm–1?
[MHT-CET 2021]
[MHT-CET 2020]
–2 –1 2 –1 a) 5 F b) 1 F
a) 9.4 × 10  cm mol
b) 5.3 × 103  –1 cm2 mol–1 c) 2 F d) 0.05 F
 Dayanand Science College, Latur (7) XII - Electrochemistry

88. What is the SI unit of molar conductivity? a) 6.022 × 1021 b) 2.022 × 1023
[MHT-CET 2021] c) 3.011 × 1022 d) 5.022 × 1024
a) S cm –1 b) S m–1 96. What is the conductivity of 0.02 M HCl solution if
c) S m2 mol–1 d) S m mol–1 the molar conductivity of HCl is 408.4  –1 cm2
89. The resistance of a conductivity cell filled with mol–1 at 25 ºC? [MHT-CET 2021]
–3
a) 2.042 × 10  cm –1 –1
0.1 M KCl solution is 100 ohm and conductivity is
1.32 × 10–2 S cm–1 . What is the value of cell b) 4.897 × 10–3  –1 cm–1
constant of the cell? [MHT-CET 2021] c) 4.084 × 10–3  –1 cm–1
a) 1.32 cm –1 b) 0.66 cm–1 d) 8.168 × 10–3  –1 cm–1
c) 1.98 cm–1 d) 1.66 cm–1 97. What is the SI unit of conductivity ?
90. What is the number of moles of electrons passed [MHT-CET 2021]
when a current of 5 ampere is passed through a a) Sm–1 b)  –1 m2 mol–1
solution of FeCl3 for 20 minutes? c) Sm2 mol–1 d)  –1
[MHT-CET 2021] 98. 0.05 F electricity is passed through CuSO4 solution.
a) 4.25 × 10 –2 b) 1.56 × 10–2 Calculate the mass of Cu produced at the cathode?
c) 3.12 × 10–2 d) 6.25 × 10–2 (Molar mass of Cu = 63.5 g mol–1)
91. What will be the concentration of solution of [MHT-CET 2021]
electrolyte if its molar conductivity and conductivity
a) 2.54 g b) 1.59 g
ar e respect ively 230  –1 cm 2 mo l –1 and
c) 0.795 g d) 3.17 g
0.0115  –1 cm–1 at 298 K? [MHT-CET 2021]
99. What is the conductivity of 0.02 M KCl solution if
a) 0.04 M b) 0.01 M
cell constant is 1.29 cm–1 with resistance 645 ?
c) 0.03 M d) 0.05 M
[MHT-CET 2021]
92. Which among the following statements is true for a
a) 8.3 × 10  cm b) 2.5 × 10–3  –1 cm–1
–3 –1 –1
galvanic cell? [MHT-CET 2021]
c) 5.0 × 10–3  –1 cm–1 d) 2.0 × 10–3  –1 cm–1
a) The anode is positive and cathode is negative
100. How many Faraday of electricity is required to
b) Oxidation takes place at positive electrode and deposit 0.8 g of calcium at cathode by the
reduction at negative electrode electrolysis of CaCl2?
c) Anode is negative and cathode is positive (Molar mass of Ca = 40 g mol–1)
d) Electrical energy is converted to chemical energy [MHT-CET 2021]
93. Which among the following statements is true for a) 0.04 F b) 2 F
conductivity? [MHT-CET 2021] c) 2.5 F d) 4 F
a) It is directly proportional to resistance 101. Electrical conductance due to all the ions in 1 cm3
b) It is inversely proportional to molar conductivity of given solution is called as .... [MHT-CET 2021]
c) It is directly proportional to resistivity a) molar conductivity b) electrical conductance
d) It is inversely proportional to resistivity c) resistivity d) conductivity
94. The molar conductivity of 0.4 M KCl solution is 102. What is the mass of Cu produced when 2 ampere
2.5 × 105  –1 cm2 mol–1. What is the resistivity of current is passed through CuSO4 solution for
solution? [MHT-CET 2021] 33 minutes?
a) 2.5 × 102 b) 2.1 × 102 (Molar mass of Cu = 63.5 g mol–1)
[MHT-CET 2021]
c) 1 × 10–2 d) 2.8 × 10–2
a) 4.18 g b) 1.30 g
95. What is the number of electrons passed through an
c) 1.58 g d) 6.35 g
electrolyte solution when 1 ampere current is
passed for 16.1 minutes? [MHT-CET 2021]
 Dayanand Science College, Latur (8) XII - Electrochemistry
103. Resisdance of 0.01 M solution of an electrolyte is 110. The resistance of 0.2 M solution of an electrolyte
300 . If cell constant is 0.82 cm–1 , what is the is 30 ohm and conductivity is 1.2 sm–1 . What is
conductivity of the solution? the value of the cell constant?
[MHT-CET 2021] [MHT-CET 2021]
a) 2.7 × 10  cm b) 3.9 × 10–3  –1 cm–1
–3 –1 –1
a) 0.1 cm–1 b) 0.5 cm–1
c) 2.4 × 10–3  –1 cm–1 d) 3.6 × 10–3  –1 cm–1 c) 0.2 cm–1 d) 0.36 cm–1
104. What is the unit of molar conductivity? 111. The conductivity of a 0.3 M solution of KCl at
[MHT-CET 2021] 298 K is 0.0627 S cm–1 . What is its molar
–1
a)  cm mol–1 –1 b)  cm2 mol–1
–1
conductivity?
c)  –1 mol–1 d)  –1 cm–1 [MHT-CET 2021]
105. Identify reducing agent in the following . 2
a) 209 S cm mol –1 b) 188 S cm2 mol–1
MnO 4(aq)  Fe(aq)
2 2
 Mn (aq) 3
 Fe(aq) c) 109 S cm2 mol–1 d) 104 S cm2 mol–1
112. How many electrons flow through the wire if a
[MHT-CET 2021] current of 1.5 amperes flows through it for 3 hours?
a) Fe 3+ b) Fe 2+ [MHT-CET 2021]
c) MnO4 d) Mn2+ a) 1.01 × 10 23 b) 1.60 × 1019
106. What is the charge required for the reduction of c) 1.60 × 1023 d) 1.01 × 1019
2 moles of Cu2+ to Cu? 113. In the cell represented as
[MHT-CET 2021] Ni (s) | Ni 2 (1M)|| Ag  (1M)|Ag (s)
a) 2.89 × 105 C b) 1.93 × 105 C
the reducing agent is .......
c) 9.65 × 105 C d) 3.86 × 105 C
[MHT-CET 2021]
107. What is the conductivity of 0.02 M HCl solution if
a) Ag+ b) Ni
molar conductivity of the solution at 25 ºC is
412.3  –1 cm–1 mol–1? c) Ni2+ d) Ag
[MHT-CET 2021] 114. Which of the following solutions is used in the
–3 –1 –1 conductivity cell to measure cell constant?
a) 8.414 × 10  cm
[MHT-CET 2021]
b) 8.624 × 10–3  –1 cm–1
a) CuSO4 b) AgNO3
c) 8.880 × 10–3  –1 cm–1
c) ZnSO4 d) KCl
d) 8.246 × 10–3  –1 cm–1
115. What is the molar conductivity of 0.05 M solution
108. The electrical conductance of unit volume (1 cm3)
of sodium hydroxide if its conductivity is
of solution is called as ........
0.0118 S cm–1 at 298 K?
[MHT-CET 2021]
[MHT-CET 2021]
a) resistivity b) molar conductivity 2 –1
a) 590 S cm mol b) 423 S cm2 mol–1
c) conductivity d) electrical resistance
c) 236 S cm2 mol–1 d) 354 S cm2 mol–1
109. The conductivity 0.04 M BaCl2 solution is
116. How many Faraday of electricity is required to
0.0112  –1 cm–1 at 25ºC. What is its molar
produce 10 g of calcium metal from calcium ions?
conductivity?
(Molar mass = 40 g mol–1)
[MHT-CET 2021]
[MHT-CET 2021]
a) 140.0  –1 cm2 mol–1
2
a) 590 S cm mol –1 b) 423 S cm2 mol–1
b) 44.8  –1 cm2 mol–1
c) 236 S cm2 mol–1 d) 354 S cm2 mol–1
c) 357.0  –1 cm2 mol–1
d) 280.0  –1 cm2 mol–1
Dayanand Science College, Latur (9) XII - Electrochemistry

Answerkey
01. d 02. a 03. c 04. a 05. c 06. d 07. c 08. b 09. c 10. b
11. c 12. d 13. b 14. d 15. b 16. a 17. c 18. c 19. b 20. c
21. b 22. c 23. b 24. d 25. a 26. c 27. d 28. b 29. c 30. b
31. b 32. b 33. a 34. a 35. a 36. a 37. b 38. a 39. a 40. b
41. c 42. c 43. c 44. c 45. b 46. c 47. a 48. a 49. c 50. a
51. c 52. d 53. a 54. d 55. c 56. a 57. a 58. a 59. b 60. d
61. c 62. c 63. d 64. a 65. b 66. d 67. d 68. d 69. a 70. a
71. c 72. b 73. a 74. b 75. d 76. a 77. b 78. c 79. c 80. d
81. d 82. a 83. a 84. a 85. d 86. d 87. d 88. c 89. a 90. d
91. d 92. c 93. d 94. c 95. a 96. d 97. a 98. b 99. d 100. a
101. d 102. b 103. a 104. b 105. b 106. d 107. d 108. c 109. d 110. d
111. a 112. a 113. b 114. d 115. c 116. b