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Class XIA

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34 views3 pages

Class XIA

Uploaded by

Aatish Madake
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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TERM-3/ 04-01-2024/CHEMISTRY / XI/ MARKS:40/TIME1.

30hrs
ra. General Instructions:
i) This question paper consists of 20 questions in 5 sections.
ii) All questions are compulsory. However, an internal choice is provided in
some questions. A student is expected to attempt only one of these
questions.
iii) Section A consists of 11 objective type
carrying 01 marks each. iv) Section B consists of 3 Very Short questions
carrying 02 marks each. Answers to these questions should be in the range of
30 to 50 words.
v) Section C consists of 3 Short Answer type questions carrying 03 marks
each. Answers to these questions should be in the range of 50 to 80 word
type questions.vi) Section D consists of 2 questions carrying .05 marks
each.vii) Section E consists of 1 case -base questions carrying 4 marks
each.

SECTION-A

Q.1 Which of the following molecular formulae belongs to the alkyne series? M
(a) C7H14. (b) C10H22 a
(c) C9H16. (d) C16H32 r
k

Q.2 The structure of 4-Methylpent-2-en-1-ol is:


(a) CH3CH2CH=CHCH2OH
(b) (CH3)2C=CHCH2CH2OH 1
(c) (CH3)2CHCH=CHCH2OH
(d) CH3CH(OH)CH-CH=C(CH3)2

Q.3 The addition of carbonyl compound to HCN is an example of


(a) Nucleophilic substitution
(b) Electrophilic addition 1
(c) Nucleophilic addition
(d) Electrophilic substitution

Q.4 During Lassaigne’s test set of Sulphur and nitrogen present in an organic compound
change into:
(a) Na2S and NaCN 1
(b) Na2SO4 and NaCN
(c) Na2S and NaCNO
(d) NaCN and NaCNO

Q.5 The IUPAC name of CH3CHO is:


(a) Acetaldehyde. (b) Methylaldehyde
(c) Formyl chloride. (d) Ethanal

1
1

Q.6 Find the molecule having the highest bond order


(a) O2+. (b) (b) O2–
(c) O22-. (d) O2 1

Q.7 Which of the following is not paramagnetic?


(a) CO. (b) N2+
(c) NO vvb (d) O2– 1

Q.8 When O2 changes to O2–, the electron goes to which of the orbitals?
(a) 𝜋 orbital. (b) 𝜎 orbital
(c) 𝜋* orbital. (d) 𝜎* orbital 1

Q.9 Find the diamagnetic species


(a) H2. (b) H2–
(c) He2+. (d) H2+ 1

Q.10 Homolytic fission leads to the formation of?


(a) nucleophile. (b) carboanion
(c) free radical. (d) carbocation 1

Q.11 In the following questions,an Assertion(A) is followed by a corresponding Reason(R).


Answer these questions selecting the appropriate option given below:
a) Both A and R are true, and R is the correct explanation of A. 1
b) Both A and R are true, and R is not the correct explanation of A.
c.(A) is correct and (R ) is incorrect
d.(A ) is incorrect and ( R ) correct.
Assertion(A): Organic compound generally not dissolve in water but soluble in organic
solvents.
Reason: Inorganic Compound generally dissolve in water but they can not dissolve in
organic solvent

SECTION B

Q.12 Why is it necessary to use acetic acid and not sulphric acid for acidification of sodium
extract for testing sulphur by lead acetate test?
2

Q13 Name a suitable technique of separation of the components from a mixture of calcium
sulphate and camphor.
2

Q.14 Write structural formulae for compounds named as-


(a) 1-Bromoheptane
(b) 5-Bromoheptanoic acid 2

SECTION C

Q15 What are hybridisation states of each carbon atom in the following compounds?
CH2=C=O,. CH3CH=CH2, (CH3)2CO,
3

Q.16 Discuss the chemistry of Lassaigne’s test. 3


Answer: Lassaigne’s test: Nitrogen, sulphur, halogens and phosphorous present in an

2
organic compound are detected by Lassaigne’s test.
First of all compounds are converted to ionic form by fusing the compound with sodium
metal.

Q.17 Draw the resonance structures for the following compounds. Show the electron shift using
curved-arrow notation. (a) C6H5OH (b) C6H5N02
OR 3
Explain geometrical isomerism with example.

SECTION D

Q18 a. In Dumas' method for estimation of nitrogen ,0.3 gram of an organic compound give 5
nitrogen collected at 300 Kelvin temperature and 715 mm pressure calculate the
percentage composition of nitrogen in the compound.(aqueous tension at 300k=15 mm
the compound.
b.An organic compound contains 69% carbon and 4.8% hydrogen, the remainder being
oxygen. Calculate the masses of carbon dioxide and water produced when 0.20 g of this
compound is subjected to complete combustion.

Q.19 Draw formulas for the first five members of each homologous series beginning with the
following compounds, 5
(a) H—COOH (b) CH3COCH3

SECTION E

Q.20 The atomic orbitals merge with each other to form the molecular orbital. The electrons of
the molecules fill the new energy states of the molecular orbitals, similar to filling up of the
energy states of the atomic orbitals.The application of molecular orbital theory involves 4
using principles from quantum mechanics to understand and predict the structure,
bonding, and properties of molecules.
Use the molecular orbital energy level diagram to show that
(i) N2 would be expected to have a triple bond,
(ii)F2 a single bond and

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