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Chemistry

electrochemistry class note help to make your notes easily

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0% found this document useful (0 votes)
13 views57 pages

Chemistry

electrochemistry class note help to make your notes easily

Uploaded by

bikash595177
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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ENGINEERING CHenistR (Bherrseccl Abed Sir vers = Cu + Zn + Ne HS Hidroger. CHydro p ° HP Onggen. CAcid produc.) S => Subphers (Enemy of metal) By Boron. Chamy + white colurad) He—> Heli Coun) Ne —} Neon (ies) => Argon. (Non - Reachve.) hy chlnin® (ory colsind) C Cabo C blocky cclonrad ) MWe DP 08/07/2023 ca whieh on. combustion produces seffcient ener f. fo corstruchie work. Tan, “Oration Renction [e+ 0,—> Cost + 4 eal | Kon. CRespinabion , coal/ twood busning ) CBening, of P/ Auto Busn ) Cnglhing hob burs wilh DAZZLING. LIGHT ) ie [ty FO, > 2440] , Crackers , RD, dynamite) Ly tre Ctenthe glyorie:) Strongest epi? fortes!) rd Development Explosive Arinitro exnine. 2 it ee eS | A bee volahiz matey comes oul fem the tapale. Bray's of Cool ae Ci inellds ) TAD Pewmate Analysis of Coal [8] Uimale. Praly si f coal | (Prammade, Pali ss of Coal . rege of rrofshina _walafile mater, caxkan and ash. Op igh oft crucible = a exighh of cools + crunible = bg. Ls ut. of coal = (a) 9 : j Pb the eoacthle in clechia. ain gyen Keeping. the. temp. 106% 100 and. heath for 60 mins. t Now morse frorm The. coal comes oul 5 bh stop heaking . Mow take cuh from elechit) ain’ gan. Hehe ccclglt oP conker cova cat Hhouds mais how, =e3, ° Sut. of mishow = Ch-e)a . ws Hage of moishine = Wt of motehvca { | Ba mn oF lage fi Me elle et ae feernace. fe Z mins, Now stop heahng and remove. thts venled Brel? oe Cab, i unighk 2 (i visto R voll maller) 2 ory volatile matlen = (e-Pg. P volafile. matter = oo sbslanes X) moisten S< oh 2 tk inside Hufle Penance in 700-250C fer wilh volhle + 2) The lefLis coal + eratible and bring, this crucible with ash, cool SP and ent . P (moishire, voll oe) & ash. We Weo, wR 1S ae > W& aa x Weos wl Kage oP ¢ = We. joo = aa nase We of He = aes 100 2x Wve = 4 (00 “18% Weoak : = 2x Cinenasa in ots of ObbeB) 100 LS x W eval, —=—> Hob H20 >» Condense” os ; QNaOl_, Wa.S%% + 2204 ang! = ngErug + 3 wor W804 ngEnns = 79 Eu,so 7 gE Naot Ny = Vues ; aaNet Ws eS e782 "ae 7160 ee a a0 0 bor = Ws) —"s) LODD ~ Wengut .xld xIdo eed VaSs) 4 Gam = Wate = rte) Ta “, (Wena = We¥) Y x O,14 Weoat das ae is Dt, 18 (9/2027 = Naso t Dogo? Na,S04 ye 202 ——> K2 S04 Laem dis one wee ve. ban aaloriinelere sal fish we weigh. coal, ee so g.c0,1 weet a Cubite ort) 5 dimole. § —> 1 mole S04 Usk Wausog As Hew 4 ‘ ee a 3a 233 os 233 Wg = > WBa304 ea of Sulphur ee pos x100 Werot Wesoq x32 5 « pa He 100 u of galphine = — 993 Pe alin ad fr sales Beste. of cook.- @Peterminalion. of Zage of Ash? Gio Cn proximale Probysis ) 3 the cousible is wetghel 4) Tho crusthle. + coal) ig weighed , | Huffle furnance. fon '30 mins caithoul- Id . (109-7) athe cool changes lato. ash, "Ten. we shop eahing and cool‘! . PE tos He weight oP Ceem osh aperucible ) x PS es es es ef as Wil oP! “eae i eile ga Ation of “pce of Oxvaen + = #400 Aoge Ogpen = 100~(Hage oP © 1S (@e hen anit mass on unit vol and the gases axe. allowed £0 cool, 7 % hest produc is called High Hah Galooific Value CHcv) on Gri OQlow Galonife Value CLev) on Neb | hers Unit mass on edie brolumee the. gqeses oe allowed 5 escape anata lane OH, is called LEV op NOV. _ Ley =Hev— talent hast of = Hev- 0.09HX 582 = on of cal Iga elegy Somb tolnipede IE iy had ih it is obsarbecl by the A. of 3b Wes axe, cased and Heb 5 Plus. gar pasces fom tara , ch Boh ig, obserbad Wg oh Colts (OH. m Po ida Tania ever ee a 3 ges Thus evo ae rf i etn obenrption, the ee ' of ON Nad fr cxref: oe B pitegon: to tha. sample -Prvat Jp neuhalise, the ammonia. evolve i, 2 (0.1 50-051 £125) mill petals ieee = at (012-5) 1000 Poe 223114 }000 Has 2804 + Cx # A subshlahion. cuhera o. nucleophile 1s sublileled with onolher one, is called SN reashor. * Rale = k [Hee - ce] [ou] Js ondee = 1+0=4 CH3 —> He Chebhyl) Cats EL Cethye) Cots —> Ph/B CPrenyl) Reactant 8 CeHs),¢¢0 + on > Coat a Subsfrate Reagent eee ea C3 OAS i ie { (Slow) hak 6 | are he Tg 09 4 © CH3—¢— eh ———> cats \ ( | ois cus s 7.3.71 oH Os e i) ! : OH fe), @H,— ¢— OH ae ae ] Chy — 2% 408 =>) Sta 4 i \ Os 3 Cua Se Te Reaction Progress ——> I L chlonid | Bo bulgl chloe _ $80.1, ewangerenh 4 Jeane I eieeeeeen ce sense CH 409 ——> os 4 a t bag eH ca pen oA | Gee en, Hove? Cae oy a | ie igh Tg Em lll 1 ee L chloride on i © ih uraees | | aa eH — @ echs + on? —> Os ( as | ou 2 | 3 cing pentyl cblida f Re ' ° ae Cok as 2 carbonium ion ‘s | Ring breaking! ‘and fring, les p || more. stable. hae Oly Ally, chbnide. 's forcuxable aN b y ) he Resonance” i's tha reasm, | ep reachion « a Srorder a Ml = 2 iF bigger aldo pops because o, eae : p>) Hore 0 HoH Onn WS Pp "shexto. hindrance”, 35 fo a Ho tN 4k ne emir ets Jonna, fhieg alkene is 2° majon protusk oft an “limirehien 4-H so more hypercarjaphiva, stroctana. ter He ra ea. ero | 1 Hoe end \, \ aon \ + Woe eek \ % eek oe Br tH; —¢ 6-H + HO Cminor) Caopenyl hamid ) Tree Reoical foe Apprtion Rene riow are ae H-Br me Oly 0g 4 ew, — cH, “ea i is be iso propy® brami ds. pref. bromide Cminon) (maiom) Ro Be: R-Or + O-R : Froa, rodcol HBr tykes ple with HE MCAT, oA bal ep rx” fakes plaa, only with. MBn, r ele ttle HO” Ci. oe caramel, A € Eee | " t Dy, 10/1] 2023 _ as a a tohealoed Inlermeliele - ee na? Cen fr ABr, on Pea coos oe Th ig agent ~ So we, wt, Int HN. | Coc 3 9 a. es &: aay HALA . 5 place if we ere poryl fbr 2 4 ] | | z : N pobersitibieria tn, 7 aif te eet cu ———— RO “NX eae F . oN fas > \p-Bp repultim. > Bp Bp repulsion A © b. a N My A oe eK 40%? me, ek ee a fe aol ee — - me | the. elechroregalivty oP ey lex is He. band angle, s Pe. i He ee © Ni inte J” _example _ e Pes iti keane se beKe mand double bord repulsion, * ere ene A ae Aged = NO; > AgNOs a, + Pg NO + NOP % ——- Ag&l e + a + N09. & ‘ Agrt NOs conkigt ai wo, Tt +O 8 is a —DL.OG/i1/2@3 NcE “Bonn “Tupry IN od ala ae Sen” HILO NAS) we en, OTST cs - Re Orbifadl com plex (see a8 33 a) Uhr] 345 8457 Crea Say if des = [rn eRe C1 at ays a Salons dsp? ; Jere * octahedral - SH Ga cate §- 7H dhamogreste we G3 4° Worren! > ~ F [Ky Llete a 4s 4p Fel < thr] wate ail O LT “ter” -in) GEES C2 feb) (1 BL cel TY i fo is ote toh | i. Hpoibon + ed ie Oruaclesnea. ¢ Oclahed edros- i? Teg Propextion + pawaragnehe bP ‘Nog. Warrent (A= n(nt2) = 1 quCat2) 1 less stable . ee 8 ir? Spin | Quanlurn number 9g = qiabr Lay wee a garuyye i. || ily egy > tle sein | ee | wom lig. | aoa pe : freen.[ = (hr), Bl Be a a N | oh @tahedrol , JP? less Paainges @ love spin compleXs | + ae ie a Vel4a) = 4 as apace x DO 9a . a ad rot = Or], EEO C1 } Li] = 34 4s 4p. 94 ree = (mr) Gila Bl fe Ol Pera Ae: > 99°87 octahedral | less sfoble, hight energy higl. povemagroha > oer orbital eornplex » > a= (n@aay = (50549) = 135 = 5.1 6H —> spin quantum noi +hx5 = 2 — spin mulliplicily ‘ stt= 2s + | =6. 4 42 Ky oe (en) | a wit = [he] 348 ° ae = Crd a 3d As [4 [uo] = tr) eee 2 be Aybridiscten Fane shaelund + squana. plaran + * domegne ce < 40e (eter) = 0° 1g 70 ssn= 2erb = \ 1 ik abe on | k, [Ni Ca] pe Ni? CAp] ital s1*1 pS rH feo: [A] SARITA] eee Foe a ee Cave & * Hybr' dicahion 30° chechune } detohedrad , “reg. peely + posomogrslie | i), marl 3 Hh ae VE = 28 Be spin quanben nO. + He tet =\ Spin imuliplicily SH = 28+ = 93 __ twiceo),] = [Ar 34895 te 3d 43 l | lard m CIT] | 3d 4s 4p) ([WCco.)= to) Ea Fe =] | Beech oT a Hyhridaation 5 gf Shuctore. ¢ \ehabolral a9 . prope + diamegrel e mag. moment tat = Yofor2) = O 4 i Spin gquanturs 1 spin rouligledy * én esl i i ee | ERIS | [eatwesde) ( (joe) | Ten cwtde] Looe] [C0 (nits), 904] Bo Leo (rts) \| 8 syle i ors, <-0.44,4 Fu6% 0) i =-0449 =-40e. % ; ky 1d a ee yee cesy = 0d, X93 * (40,0a,n1) | Cese =-01a,%4 * = +0046 =1.64y +P — =16 04 +P =-6Dq ~ count Eeposited ob electrode. is direclly. pro tamale oe a waQ w=Z@ (2 = deahaheel eniivolent) We zit c Oe 1b) il eonlachin Ng = 841090. Ne obey 5 | >te conduchanes of. tons of Imole cledrolyle in given sobibion '8 i} called molar. conductance . [Byiealenl _Gndachnce + | Net K «1000 | ert aqui of eledrolyfe. i Wy dha Goulscbna of ma of fon canduatante % | the. gien colin 15 called quivabnt PPebye Huckel Onsager Equation _ fr shovg, clechol les) t i | N | < {| Ne NE anlaley Kea. \] \eonslonb t I a (|e om Aig = Malan. conductors oe Celehelgle } at infinite dilulion ve —> 1d | KOHLRAUSCH’S LAW. |The euirlink condeahna. of an alecholyte af inPrite dilebion *'s | | equal to the summation off opuivalint conductance of in Pnite dilabin of cahim and anion. AG =A + 8 —s i Reus ae * Nee |

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