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Conversion Chart - Haloalkanes (1) - 241125 - 170745

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318 views1 page

Conversion Chart - Haloalkanes (1) - 241125 - 170745

Uploaded by

savagesavneet23
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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HELPLINE: 7051068484

CRAZY CHEMISTRY
(Where knowledge is Everything)
-------------------------------------------------------------------------------------------------------------------

HALOALKANES AND HALOARENES


CONVERSION CHART

Aq. KOH
R–OH ALCOHOL
R–O Na
H R–O–R ETHER
Williamson
Reaction
A KCN H+/H2O RCOOH
R–CN
(Carboxylic Acid)
L (Alkyl Cynide/Nitrite)
+ AgCN
R–NC (Alkyl Isocynide)
O
KOH (Alcohlic)
A ALKENE (ALKENES)

L + Na / Dry Ether
R–X R–R (ALKANES)
(Wurtz Reaction)
K
Na – I / Acetone
R–X (Haloalkane)
A Finkelstein

R – CHO [O] R – COOH


N KOH (Aq.) R–OH CuROD/573K
(Alcohols) (Aldehyde)
E
KNO2
R–O–N=O (Nitrite)

AgNO2
R–NO2 (Nitroalkane)

+ NH3
R–NH2 (Amine)
Important Points

● If you want to convert Haloalkanes into Alkanes, use Wurtz Reaction.


● If you want to change position of Halogen atom in Haloalkanes, firstly use β-elimination
reaction (Alcohlic KOH). Then use Morkovnikov’s / Antimorkovnikov’s Rule.
● Conversion of Aryl Halide can be done in similar way like as Haloalkanes.
● If you want to convert Aniline into Chlorobenzene, firstly convert Aniline into Diazonium Salt
followed by Sandmeyer Reaction.

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